• Title/Summary/Keyword: internal materials

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Study on Internal Reforming Characteristic of 1 kW Solid Oxide Fuel Cell Stack (1 kW 고체산화물 연료전지 스택의 내부개질 특성 연구)

  • CHOI, YOUNGJAE;AHN, JINSOO;LEE, INSUNG;BAE, HONGYOUL;MOON, JIWOONG;LEE, JONGGYU
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.4
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    • pp.377-383
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    • 2017
  • This paper presents the performance characteristics of a 1 kW solid oxide fuel cell (SOFC) stack under various internal reforming and fuel utilization conditions. The Research Institute of Industrial Science & Technology (RIST) developed the 9-cell stack using a $20{\times}20cm^2$ anode supported planar cell with an active area of $324cm^2$. In this work, current-voltage characteristic test, fuel utilization test, continuous operation, and internal reforming test were carried out sequentially for 765 hours at a furnace temperature of $700^{\circ}C$. The influence of fuel utilization and internal reforming on the stack performance was analyzed. When the 1 kW stack was tested at a current of 145.8 A with a corresponding fuel utilization of 50-70% (internal reforming of 50%) and air utilization of 27%, the stack power was approximately 1.062-1.079 kW. Under continuous operation conditions, performance degradation rate was 2.16%/kh for 664 hours. The internal reforming characteristics of the stack were measured at a current of 145.8. A with a corresponding fuel utilization of 60-75%(internal reforming of 50-80%) and air utilization of 27%. As fuel utilization and internal reforming ratio increased, the stack power was decreased. The stack power change due to the internal reforming ratio difference was decreased with increasing fuel utilization.

Real-time Internal Stress of Nickel Sulfamate Electroform (니켈쌀파메이트 전주층의 실시간 잔류응력)

  • Kim I.;Kang K.;Lee J.;Kwon S.C.;Kim M.;Lee J.Y.
    • Journal of the Korean institute of surface engineering
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    • v.38 no.1
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    • pp.14-20
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    • 2005
  • The control of internal stress is extremely important in electroforming because of the deliberately low adhesion between the electro form and the mandrel. Excessive tensile or compressive stress can cause distortion, separation problem, curling, peeling or separation of electroform prematurely from the mandrel, buckling and blistering. Nickel sulfamate bath has been widely used in electroforming because of its low internal stress and moderate hardness. In this study, real-time stress sensor has been used for stress control in chloride-free nickel sulfamate bath for 400 mm x 300 mm x 500 ㎛ nickel electroform. It was found that compressive stress found at low current density indicated the contamination of electrolyte, which is very useful in procuring buckling and peeling of electroform. No compressive stress is allowed for plate electroform. The real-time stress can also be used for accurate stress control of nickel electroform. The tensile stress was found to be increased slightly with increase in nickel electroform thickness, i.e., from initial 1.47 ksi to 2.02 ksi at 320 ㎛.

Analysis of Internal Structure in Alkali-Activated Fire Protection Materials Using Fly ash (플라이애시를 활용한 알칼리 활성화 내화성 마감재의 내부구조 분석)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.104-112
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    • 2012
  • This study involves investigating the correlation between variation of internal structure and heating temperature of alkali-activated fire protection materials using fly ash. Dehydration and micro crack thermal expansion occur in cement hydrates of cementitious materials heated by fire. Internal structure difference due to both the dehydration of cement hydrates and pore solution causes and influences changes in the properties of materials. Also, this study is concerned with change in microstructure and dehydration of the alkali-activated fire protection materials at high temperatures. The testing methods of alkali-activated fire protection materials in high temperature properties are make use of TG-DSC and mercury intrusion porosimetry measurements. The study results show that the alkali-activated fire resistant finishing material composed of potassium hydroxide, sodium silicate and fly ash has the high temperature thermal stability. These thermal stability is caused by the ceramic binding capacity induced by alkali activation reaction.

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Thermomechanical Analysis of Functionally Gradient Al-$SiC_{p}$ Composite for Electronic Packaging (전자패키지용 경사조성 Al-$SiC_{p}$ 복합재료의 열 . 기계적 변형특성 해석)

  • 송대현;최낙봉;김애정;조경목;박익민
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.04a
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    • pp.175-183
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    • 2000
  • The internal residual stresses within the multilayered structure with shan interface induced by the difference in thermal expansion coefficient between the materials of adjacent layers often provide the source of failure such as delamination of interfaces and etc. Recent development of the multilayered structure with functionally graded interface would be the solution to prevent this kind of failure. However a systematic thermo-mechanical analysis is needed fur the customized structural design of multilayered structure. In this study, theoretical model for the thermo-mechanical analysis is developed for multilayered structures of the Al-$SiC_p$ functionally graded composite for electronic packaging. The evolution of curvature and internal stresses in response to temperature variations is presented for the different combinations of geometry. The resultant analytical solutions are used for the optimal design of the multilayered structures with functionally graded interface as well as with sharp interface.

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Enhancement of the Surface Smoothness of Cu Ribbon for Solar Cell Modules

  • Cho, Tae-Sik;Cho, Chul-Sik
    • Transactions on Electrical and Electronic Materials
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    • v.16 no.1
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    • pp.20-24
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    • 2015
  • We studied the relationship between the surface smoothness of the internal Cu ribbon and the morphology of the Sn-Pb plating layer for solar cell modules. A bumpy surface was observed on the surface of the solar ribbon, which caused irregular reflection of light. Large, Pb-rich, primary ${\alpha}$-phases were found below the convex surface of the solar ribbon, passing from the surface of the internal Cu ribbon to the surface of the plating layer. The primary ${\alpha}$-phases heterogeneously nucleated on the convex surface of the Cu ribbon, and then largely grew to the convex surface of the plating layer. The restriction of the primary ${\alpha}$-phase's formation was enabled by enhancing the smoothness of the Cu ribbon's surface; it was also possible to increase the adhesive strength and decrease contact resistance. We confirmed that the solar ribbon's surface smoothness depends on the internal Cu ribbon's surface smoothness.

A Study on Internal Control Systems of BSC(Balanced Scorecard) : Gumi Industrial Complex (BSC(Balanced Scorecard) 관점의 내부통제시스템에 대한 연구 : 구미산업단지)

  • Kim, Tae-Sung;Seo, Mi-Ra
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.32 no.2
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    • pp.21-28
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    • 2009
  • This research made an actual study of the Internal Control Systems on medium and small business company located on Gumi industry area. From this study, we learned that work scope, approval procedure and proof documents are well prepared, but some problem of the lack of communication has arose and it should be more complementary. Findings from this study show that the materials and purchasing processes are generally well-operated, but the information-sharing and training related to materials code are still insufficient and require more complementary systems.

A Study on Martensite Transformation of Fe-Ni Alloy Nanoparticles (Fe-Ni 합금 나노 분말의 마르텐사이트 변태에 관한 연구)

  • Yu, Yeon-Tae
    • Korean Journal of Materials Research
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    • v.13 no.8
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    • pp.491-496
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    • 2003
  • Fe-Ni alloy nanoparticles were prepared by ERC (Evaporation and Rapid Condensation) method, and the crystal structure and the behavior of martensite for the nanosized alloy particles were investigated by X-ray diffraction analysis. The relation between the rate of martensite transformation and the internal strain of austenite was discussed. The lattice spaces of austenite and martensite for the nanoparticles agreed with those of the bulk materials. The rate of martensite transformation from austenite and the internal strain of austenite was reduced with decreasing the average size of Fe-Ni nanoparticles. It was thought that the residual austenite in the Ni content range of 11∼l5at% was caused by the internal strain, and the residual martensite in the Ni content range of 32∼36at% had its origin in the high surface energy of nanoparticles.

Precise Determination of Silicon in Ceramic Reference Materials by Prompt Gamma Activation Analysis at JRR-3

  • Miura, Tsutomu;Matsue, Hideaki
    • Nuclear Engineering and Technology
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    • v.48 no.2
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    • pp.299-303
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    • 2016
  • Prompt gamma activation analysis using a thermal neutron-guided beam at Japan Atomic Energy Agency JRR-3M was applied for the precise determination of Si in silicon nitride ceramic reference materials [Japan Ceramic Reference Material (JCRM) R 003]. In this study, the standard addition method coupled with internal standard was used for the nondestructive determination of Si in the sample. Cadmium was used as internal standard to obtain the linear calibration curves and to compensate for the neutron beam variability. The analytical result of determining Si in JCRM R 003 silicon nitride fine powder ceramic reference materials using prompt gamma activation analysis was in good agreement with that obtained by classical gravimetric analysis. The relative expanded measurement uncertainty (k = 2) associated with the determined value was 2.4%.

Experimental Study on Reinforcement Effects of Soil Shear Strength by Nylon Net(Substitute Materials Simulating a Root System) -Analysis using Simple Shear Tester under Soil Suction Control - (Nylon Net(대체근계)의 토질강도보강효과에 대한 실험적 연구 - 토양수분제어하의 단순전단시험에 의한 해석 -)

  • Lee, Chang-Woo;Youn, Ho-Joong;Jeong, Yongho
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.9 no.3
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    • pp.76-81
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    • 2006
  • The reinforcement of soil shear strength by nylon net as substitute materials simulating a fine root system was evaluated by soil strength parameters(apparent cohesion(c) and internal friction angle(tan${\phi}$), using simple shear tester which clearly depicts shear deformation and controls soil suction. And the results of shear test by using bamboo as a substitute materials simulating a main root system and using nylon net as a substitute materials simulating a fine root system were compared. The reinforcement of soil strength by nylon net are expressed by apparent cohesion more than internal friction angle. In addition the increment of apparent cohesion by nylon net reached a peak in suction 60 $cmH_2O$. Different from with bamboo, the possibility of the change on internal friction angle(tan${\phi}$) caused by the soil water condition was shown in shear strain 20% condition. These results show that the mechanism of reinforcement by substitute materials simulating root system may be different in the condition of various soil water content.

Fabrication of Internal Gratings in PDMS Using a Femtosecond Laser

  • Park, Jung-Kyu;Cho, Sung-Hak;Yu, Jae-Yong;Kim, Jae-Gu;Sugioka, Koji;Hong, Jong-Wook;Heo, Won-Ha;Hwang, Kyung-Hyun
    • Laser Solutions
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    • v.14 no.1
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    • pp.1-5
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    • 2011
  • Photo-induced gratings m flexible PDMS (polydimethly siloxane) film are directly written by a high-intensity femtosecond (130fs) Ti: Sapphire laser (${\lambda}_p$ = 800nm). The refractive index modifications with $4\;{\mu}m$ diameters were photo-induced after the femtosecond irradiation with peak intensities of more than $1{\times}10^{11}W/cm^2$. The graded refractive index profile was fabricated to be a symmetric around the center of the point at which femtosecond laser by controlling both laser power and focused depth. The change on refractive index in the laser-modified regions was estimated to be approximately $10^{-3}$. The internal flexible symmetric diffraction gratings in PDMS film was successfully fabricated using a femtosecond laser.

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