• 제목/요약/키워드: internal electrodes

검색결과 164건 처리시간 0.028초

Reference Electrode for Monitoring Cathodic Protection Potential

  • Panossian, Z.;Abud, S.E.
    • Corrosion Science and Technology
    • /
    • 제16권5호
    • /
    • pp.227-234
    • /
    • 2017
  • Reference electrodes are generally implemented for the purpose of monitoring the cathodic protection potentials of buried or immersed metallic structures. In the market, many types of reference electrodes are available for this purpose, such as saturated calomel, silver/silver chloride and copper/copper sulfate. These electrodes contain a porous ceramic junction plate situated in the cylindrical body bottom to permit ionic flux between the internal electrolyte (of the reference electrode) and the external electrolyte. In this work, the copper/copper sulfate reference electrode was modified by replacing the porous ceramic junction plate for a metallic platinum wire. The main purpose of this modification was to avoid the ion copper transport from coming from the inner reference electrode solution into the surrounding electrolyte, and to mitigate the copper plating on the coupon surfaces. Lab tests were performed in order to compare the performance of the two mentioned reference electrodes. We verified that the experimental errors associated with the measurements conducted with developed reference electrode would be negligible, as the platinum surface area exposed to the surrounding electrolyte and/or to the reference electrolyte are maintained as small as possible.

내부 전극을 이용한 동적 전기 임피던스 단층촬영법 (Dynamic Electrical Impedance Tomography with Internal Electrodes)

  • 강숙인;김경연
    • 전기전자학회논문지
    • /
    • 제5권2호
    • /
    • pp.153-163
    • /
    • 2001
  • 전기 임피던스 단층촬영법은 물체 표면의 전극을 통하여 전류를 주입하고 유기된 전압을 측정한 후, 물체 단면의 저항을 분포를 복원하는 기법이다. 본 논문에서는, 대상물체의 저항을 값의 분포가 급변하는 상황에 대한 동적 전기저항 단층활영법을 제안하였다. 특히, 복원 성능을 개선하기 위하여 물체 내부의 구조를 전극으로 사용하였으며, 비 선형 역문제를 상태 추정문제로 설정하여 확장 칼만필터를 이용하여 상태변수(저항율)를 추정하였다. 또한 역문제의 부정치성을 완화시키기 위하여 수정된 Tikhonov 조정기법을 비용함수에 도입하였다. 제안된 알고리즘의 성능을 분석하기 위해 컴퓨터 시뮬레이션을 수행했으며, 기존의 방법들에 비해 개선된 결과를 얻었다.

  • PDF

FE and ANN model of ECS to simulate the pipelines suffer from internal corrosion

  • Altabey, Wael A.
    • Structural Monitoring and Maintenance
    • /
    • 제3권3호
    • /
    • pp.297-314
    • /
    • 2016
  • As the study of internal corrosion of pipeline need a large number of experiments as well as long time, so there is a need for new computational technique to expand the spectrum of the results and to save time. The present work represents a new non-destructive evaluation (NDE) technique for detecting the internal corrosion inside pipeline by evaluating the dielectric properties of steel pipe at room temperature by using electrical capacitance sensor (ECS), then predict the effect of pipeline environment temperature (${\theta}$) on the corrosion rates by designing an efficient artificial neural network (ANN) architecture. ECS consists of number of electrodes mounted on the outer surface of pipeline, the sensor shape, electrode configuration, and the number of electrodes that comprise three key elements of two dimensional capacitance sensors are illustrated. The variation in the dielectric signatures was employed to design electrical capacitance sensor (ECS) with high sensitivity to detect such defects. The rules of 24-electrode sensor parameters such as capacitance, capacitance change, and change rate of capacitance are discussed by ANSYS and MATLAB, which are combined to simulate sensor characteristic. A feed-forward neural network (FFNN) structure are applied, trained and tested to predict the finite element (FE) results of corrosion rates under room temperature, and then used the trained FFNN to predict corrosion rates at different temperature using MATLAB neural network toolbox. The FE results are in excellent agreement with an FFNN results, thus validating the accuracy and reliability of the proposed technique and leads to better understanding of the corrosion mechanism under different pipeline environmental temperature.

New electron source and electron collection source for the internal electron circuit in FL tubes

  • Ozawa, Lyuji;Tian, Yakui;Kato, Masatoshi
    • Journal of Information Display
    • /
    • 제12권2호
    • /
    • pp.69-75
    • /
    • 2011
  • A new electron source and an electron collection source were found for the closure of the internal electron circuit inside fluorescent lamp (FL) tubes. The sources are formed in front of the polarized electric-insulator particles on the metal electrodes at both ends of the FL tube. The appearance and disappearance of both sources are controlled by the electric voltages applied to the metal electrodes. The electrons and $Ar^+$ for the sources are generated by the ionization of the Ar atoms, and they return to the Ar atoms at the electron collection source. Thus, the Ar atoms are preserved in the FL tubes, ensuring a long operation life for such tubes.

Mesh 형 전극의 조밀도 변화에 따른 중첩방전형 오존발생기의 특성 (The Characteristics of a Superposed Discharge Type Ozonizer with variation of Mesh)

  • 송현직;이동헌;김태주;이광식;전병준;하장호
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 2003년도 하계학술대회 논문집 C
    • /
    • pp.1834-1836
    • /
    • 2003
  • In this paper, a superposed discharge type ozonizer(SDO) has been designed and manufactured. SDO is equipped with three electrodes(central, internal and external electrodes), and it is composed of two gaps. Ozone is generated by overlapping silent discharge, which is respectively came from two gaps. At this time, Internal electrode consists of a mesh type. This paper describes the discharge and ozone generation characteristics of SDO with variation of mesh and discharge wattage.

  • PDF

Electrodes for contact electric welding of aluminium alloys

  • Bondar, M.P.;Moon, J.G.
    • 대한용접접합학회:학술대회논문집
    • /
    • 대한용접접합학회 1997년도 특별강연 및 추계학술발표 개요집
    • /
    • pp.184-193
    • /
    • 1997
  • Aluminium and aluminium alloys have the high electrical and heat conductivity. It gives rise to difficulties for a choice of electrodes material for their contact electric welding. This paper describes the investigations performed to solve the above problem. The purpose of this investigation was to obtain dispersion-hardening alloys by the internal oxidation method, to optimize their contents and treatment modes, to produce electrodes of these alloys and to test them. The strengthing effect of alloys with oxide particles depends on their size stability at high temperatures. Despite of the fact, that oxides are the most stable of all the non-metallic phases their coagulation takes place. Based on the early results, we chose two types of alloys, first No. 1 Cu - 0,4%Al and second No. 2 Cu - 0,2%Be for production of electrodes. These alloys had not additional alloying elements. These alloys were prepared as 1 mm plates and flake-formed 200 m thick, and also No. 1 as a powder of size 100 mkm (received from Korea). The large samples for electrodes were produced by three methods : explosive welding method, dynamic one including the explosion compression of electrode blank and the quasi-dynamic method including the high-speed compression of dense briquest and the further hot extrusion of a rod.

  • PDF

하이브리드 (활성탄소+LiCoO2) 전극의 전기화학적 특성 (Electrochemical Performance of Hybrid (Activated Carbon+LiCoO2) Electrode)

  • 김익준;전민제;양선혜;김현수;문성인;오대희
    • 한국전기전자재료학회논문지
    • /
    • 제19권9호
    • /
    • pp.849-854
    • /
    • 2006
  • In this study, the hybrid electrodes, composed of the activated carbon powders and $LiCoO_{2}$ powders, were prepared as a cathode for the high-capacitance type hybrid capacitor, and the electrochemical properties of the hybrid electrodes were examined in terms of the weight composition and the milling time of $LiCoO_{2}$ powders. The specific volumetric capacities were increased with increasing of the composition of $LiCoO_{2}$ powders in the hybrid electrodes. On the other hand the coin cell capacitors, using the hybrid electrodes with $LiCoO_{2}$ poweders milled for 200 h, have exhibited the lower internal resistivities and the better capacity retention after 100 charge-discharge cycle than those of the coin cell capacitors using the hybrid electrodes with raw $LiCoO_{2}$ powders.

이중층 티타늄 전극으로 구성된 TCO-less 염료감응형 태양전지 제작에 관한 연구 (Fabrication of Transparent Conductive Oxide-less Dye-Sensitized Solar Cells Consisting of Titanium Double Layer Electrodes)

  • 심충환;김윤기;김동현;이해준;이호준
    • 전기학회논문지
    • /
    • 제60권1호
    • /
    • pp.114-118
    • /
    • 2011
  • Dye-Sensitized Solar Cells(DSSCs) consist of a titanium dioxide($TiO_2$) nano film of the photo electrode, dye molecules on the surface of the $TiO_2$ film, an electrolyte layer and a counter electrode. But two transparent conductive oxide(TCO) substrates are estimated to be about 60[%] of the total cost of the DSSCs. Currently novel TCO-less structures have been investigated in order to reduce the cost. In this study, we suggested a TCO-less DSSCs which has titanium double layer electrodes. Titanium double layer electrodes are formed by electron-beam evaporation method. Analytical instruments such as electrochemical impedance spectroscopy, scanning electron microscope were used to evaluate the TCO-less DSSCs. As a result, the proposed structure decreases energy conversion efficiency and short-circuit current density compared with the conventional DSSCs structure with FTO glass, while internal series impedance of TCO-less DSSCs using titanium double layer electrodes decreases by 27[%]. Consequently, the fill factor is improved by 28[%] more than that of the conventional structure.

마그네슘 금속연료전지의 출력특성에 관한 연구 (A Study of Power Output Characteristics for the Magnesium Metal Fuel Cell)

  • 김용혁
    • 전기학회논문지P
    • /
    • 제63권3호
    • /
    • pp.212-217
    • /
    • 2014
  • The electric power output characteristics of magnesium fuel cell were investigated with regard to internal resistance. A equivalent circuit with the series-connected three internal resistance was introduced to analyze of the response to change of power. The power output analysis was employed in order to investigate the effect of internal resistances for the electrolyte concentration, air electrode area, Mg electrode area and distance between the electrodes. It was confirmed that internal resistance is generated by the electrolyte, air electrode and metal electrode, then those Internal resistances had a significant effect on the power output decrease. The power output was a maximum when the load resistance maches the internal resistance of the magnesium fuel cell. The fuel efficiency was only 50% at maximum power output. Higher fuel efficiency was achieved when the load resistance is greater than the internal resistance.

미생물 연료 전지의 반응조 형상에 따른 전기 생산효율 비교 (Comparison of Electricity Generation Efficiencies depending on the Reactor Configurations in Microbial Fuel Cells)

  • 이윤희;어성욱
    • 한국물환경학회지
    • /
    • 제26권4호
    • /
    • pp.681-686
    • /
    • 2010
  • Two different MFC designs were evaluated in batch mode: single compartment combined membrane-electrodes (SCME) design and twin-compartment brush-type anode electrodes (TBE) design (single chamber with two air cathodes and brush anodes at each side of the reactor). In SCME MFC, carbon anode and cathode electrodes were assembled with a proton exchange membrane (PEM). TBE MFC was consisted of brush-type anode and carbon cloth cathode electrodes without the PEM. A brush-type anode was fabricated with carbon fibers and was placed close to the cathode electrode to reduce the internal resistance. Substrates used in this study were glucose, leachate from cattle manure, or sucrose at different concentrations with phosphate buffer solution (PBS) of 200 mM to increase the conductivity thereby reduce the internal resistance. Hydrogen generating bacteria (HGB) were only inoculated in TBE MFC. The peak power densities ($P_{peak}$) produced from the SCME systems fed with glucose and leachate were 18.8 and $28.7mW/m^2$ at external loads of 1000 ohms, respectively. And the $P_{peak}$ produced from TBE MFC were 40.1 and $18.3mW/m^2$ at sucrose concentration of 5 g/L and external loads of 470 ohms, with a mediator (2-hydroxy-1, 4-naphthoquinone) and without the mediator, respectively. The maximum power density ($P_{max}$) produced from mediator present TBE MFC was $115.3mW/m^2$ at 47 ohms of an external resistor.