• 제목/요약/키워드: internal electrode

검색결과 279건 처리시간 0.036초

$\beta$-carotene glass의 광기전력효과 (Photovoltaic effect in $\beta$-carotene glass)

  • 김의훈
    • 전기의세계
    • /
    • 제20권4호
    • /
    • pp.23-30
    • /
    • 1971
  • The photovoltaic behaviors ahve been observed with a sandwich-type cell, consisting of a junction between .betha.-carotene and stannic oxide conducting layer to provide a junction electrode. In the stannic oxide and .betha.-carotene junction it was found that its electromotive forse decreased to a value smaller than the original one. This is due to a space charge formation. Photovoltage reached approximately 40mV with an irradiation energy of 250Kcal/M$^{2}$hr. It appeared that a magnitude of the photovoltaic response was proportional to the logarithm of irradiance. The time constant of the photovoltaic effect was shown to be approximately 0.7 sec. The wavelength dependence of the photovoltaic behavior was very anomalous. It is assumed that such an anomalous photoresponse depends on a internal capacitance due to some bubble during process to make a cell.

  • PDF

Differences in Design Considerations between InGaN and Conventional High-Brightness Light-Emitting Diodes

  • Lee, Song-Jae
    • Journal of the Optical Society of Korea
    • /
    • 제2권1호
    • /
    • pp.13-21
    • /
    • 1998
  • Based on the escape cone concepts, high-brightness light-emitting diodes (LEDs) have been analyzed. In AlGaAs or InGaAlP LEDs, photon absorption in the ohmic region under the electrode is known to be significant. Thus, ins general, a thick window layer (WL) and a transparent substrate (TS) would minimize photon shielding by the electrodes and considerably improve photon output coupling efficiency. However, the schemes do not seem to be necessary in InGaN system. Photon absorption in ohmic contact to a wide bandgap semiconductor such as GaN may be negligible and, as a result, the significant photon shielding by the electrodes will not degrade the photon output coupling efficiency so much. The photon output coupling efficiency estimated in InGaN LEDs is about 2.5 - 2.8 times that of the conventional high-brightness LED structures based on both WL and TS schemes. As a result, the extenal quantum efficiency in InGaN LEDs is as high as 9% despite the presumably very low internal quantum efficiency.

Methods to Improve Light Harvesting Efficiency in Dye-Sensitized Solar Cells

  • Park, Nam-Gyu
    • Journal of Electrochemical Science and Technology
    • /
    • 제1권2호
    • /
    • pp.69-74
    • /
    • 2010
  • Methodologies to improve photovoltaic performance of dye-sensitized solar cell (DSSC) are reviewed. DSSC is usually composed of a dye-adsorbed $TiO_2$ photoanode, a tri-iodide/iodide redox electrolyte and a Pt counter electrode. Among the photovoltaic parameters of short-circuit photocurrent density, open-circuit voltage and fill factor, short-circuit photocurrent density is the collective measure of light harvesting, charge separation and charge collection efficiencies. Internal quantum efficiency is known to reach almost 100%, which indicates that charge separation occurs without loss by recombination. Thus, light harvesting efficiency plays an important role in improvement of photocurrent. In this paper, technologies to improve light harvesting efficiency, including surface area improvement by nano-dispersion, size-dependent light scattering efficiency, bi-functional nano material, panchromatic absorption by selective positioning of three different dyes and transparent conductive oxide (TCO)-less DSSC, are introduced.

인산형 단위 연료전지의 조업 연구 (Operational Study of the Phosphoric Acid Type Unit Fuel Cell)

  • 이갑수;김화용
    • 한국수소및신에너지학회논문집
    • /
    • 제3권2호
    • /
    • pp.63-69
    • /
    • 1992
  • 2개의 단위전지를 제작하여 각각 산소와 공기를 산화제로 하여 조업하였다. 산소를 사용한 단위전지의 350시간 조업후의 개전압 강하는 30mV였고 내부저항도 증가하였다. 공기를 사용한 단위천지의 250시간 조업후의 개전압강하는 130mV였고 산소를 사용한 경우와는 개전압 차이는 90mV였다. 공기를 이용한 단위전지의 조업 성능을 향상시키기 위하여는 전해질의 공급방법과 전극의 물질전달특성에 관한 연구가 필요하다.

  • PDF

Ca 첨가에 의한 $BaTiO_3$의 환원억제기구 (The Role of Calcium as a Reduction Inhibitor in $BaTiO_3$)

  • 황연;김윤호;박순자
    • 한국세라믹학회지
    • /
    • 제27권6호
    • /
    • pp.741-746
    • /
    • 1990
  • Dielectrics which do not lose their high insulation resistance in reducing atmosphere are necessary for multilayer ceramic capacitors with Ni internal electrode. In this study we investigated the Ca ion site occupancy in A-site excess Ca-doped BaTiO3 by measuring the insulation resistance, lattice constant and Curie temperature. Its Curie temperature, which was lower than that of the pure BaTiO3, was more lowered by sintering in reducing atmosphere. Lattice constnat of c-axis decreased and that of a-axis increased, suggesting substitution of Ca ions for Ti ions. Hence CaTi" acts as an acceptor to maintain high insulation resistance.ance.

  • PDF

기판온도 변화에 따른 ZnO:Al 투명 전도막의 특성 변화 (A study on the properties of transparent conductive ZnO:Al films on variation substrate temperature)

  • 양진석;성하윤;금민종;손인환;신성권;김경환
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2001년도 추계학술대회 논문집
    • /
    • pp.525-528
    • /
    • 2001
  • ZnO:Al thin film can be used as a transparent conducting oxide(TCO) which has low electric resistivity and high optical transmittance for the front electrode of amorphous silicon solar cells and display devices. This study of electrical, crystallographic and optical properties of Al doped ZnO thin films prepared by Facing Targets Sputtering (FTS), where strong internal magnets were contained in target holders to confine the plasma between the targets, is described. Optimal transmittance and resistivity was obtained by controlling flow rate of O$_2$ gas and substrate temperature. When the of gas rate of 0.3 and substrate temperature 200$^{\circ}C$ , ZnO:Al thin film had strongly oriented c-axis and lower resistivity(<10$\^$-4/Ω-cm).

  • PDF

Rosen type 적층형 압전변압기의 제작 및 전기적 특성 (Fabrication and electrical properties of Rosen-type multilayer piezoelectric transformer)

  • 이창배;윤중락;이경민;우병철
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2007년도 추계학술대회 논문집
    • /
    • pp.250-250
    • /
    • 2007
  • In this paper, multilayer piezoelectric transformer for high power is presented. This piezoelectric transformer, with a multilayered construction in the thickness direction, was fabricated at the sintering temperature of $1055^{\circ}C$. The electrical properties of multilayer piezoelectric transformer as a function of Internal electrode structure, with same size, were investigated. Also, the multilayer piezoelectric transformer with different layer number of 5, 10, 15 layers, were investigated.

  • PDF

Fuel-Flexible Anode Architecture for Solid Oxide Fuel Cells

  • Hwan Kim;Sunghyun Uhm
    • 공업화학
    • /
    • 제34권3호
    • /
    • pp.226-240
    • /
    • 2023
  • This paper provides an overview of the trends and future directions in the development of anode materials for solid oxide fuel cells (SOFCs) using hydrocarbons as fuel, with the aim of enabling a decentralized energy supply. Hydrocarbons (such as natural gas and biogas) offer promising alternatives to traditional energy sources, as their use in SOFCs can help meet the growing demands for energy. We cover several types of materials, including perovskite structures, high-entropy alloys, proton-conducting ceramic materials, anode on-cell catalyst reforming layers, and anode functional layers. In addition, we review the performance and long-term stability of cells based on these anode materials and assess their potential for commercial manufacturing processes. Finally, we present a model for enhancing the applicability of fuel cell-based power generation systems to assist in the realization of the H2 economy as the best practice for enabling distributed energy. Overall, this study highlights the potential of SOFCs to make significant progress toward a sustainable and efficient energy future.

Preparation and properties of Bi-based lead-free ceramic multilayer actuators

  • Nguyen, Van-Quyet;Han, Hyoung-Su;Lee, Han-Bok;Yoon, Jong Il;Ahn, Kyoung Kwan;Lee, Jae-Shin
    • Journal of Ceramic Processing Research
    • /
    • 제13권spc2호
    • /
    • pp.282-285
    • /
    • 2012
  • Lead-free (Bi0.5Na0.41K0.09)TiO3 (BNKT) multilayer ceramic actuators were prepared using tape-casting and screen-printing techniques. Co-firing behavior of BNKT/AgPd laminates was examined as a function of sintering temperature. It was found that co-firing induced bending and electrical properties were very sensitive to sintering condition. By optimizing sintering conditions, lead-free electrostrictive multilayer actuators with normalized strain Smax/Emax of 266 pm/V have been successfully fabricated, which is promising for lead-free actuator applications.

$TiS_2$ Composite/SPE/Li Cell의 충방전에 따른 AC 임피던스의 변화 (Variation of AC Impedance of the $TiS_2$ Composite/SPE/Li Cell with Cycling)

  • 김종욱;구할본;문성인;윤문수
    • 대한전기학회:학술대회논문집
    • /
    • 대한전기학회 1995년도 하계학술대회 논문집 C
    • /
    • pp.1034-1038
    • /
    • 1995
  • The purpose of this study is to research and develop $TiS_2$ composite cathode for lithium polymer battery(LPB). $TiS_2$ electrode represent a class of insertion positive electrode used in Li secondary batteries. In this study, we investigated preparation of $TiS_2$ composite cathode and AC impedance response of $TiS_2$ composite/SPE/Li cells as a function of state of charge(SOC) and cycling. The resistance of B type cell using $TiS_2PEO_8LiClO_4PC_5EC_5$ composite cathode was lower than that of A type cell using $TiS_2PEO$ composite cathode. The cell resistance of B type cell is high for the first few percent discharge, decreases for midium discharge and then increases again toward the end of discharge. We believe the magnitude of the cell resistance is dominated by passivation layer impedance and small cathode resistance. AC impedance results indicate that the cell internal resistance increase with cycling, and this is attributed to change of passivation layer impedance with cycling. The passivation layer resistance($R_f$) of B type cell decreases for the 2nd cycling and then increases again with cycling. Redox coulombic efficiency of B type cell was about 141% at 1st cycle and 100% at 12th cycle. Also, $TiS_2$ specific capacity was 115 mAh/g at 12 cycle.

  • PDF