• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.466-470
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• 2014

In this paper, organic solvent electrolytes were prepared by a mixture of propylene carbonate (PC), dimethyl carbonate (DMC), tetraethylammonium tetrafluoroborate ($TEABF_4$)s to evaluate the ionic properties of propylene carbonate (PC)/dimethyl carbonate (DMC) mixtures as solvents for a capacitor application, in view of improving the electrochemical performances. The bulk resistance and interfacial resistance of the mixture electrolytes were investigated using an AC impedance method. The morphology of carbon-based electrodes which were contained in different electrolytes was analyzed by scanning electron microscopy (SEM) method. From the experimental results, by increasing the FEC content, capacitance of electrodes was increased, and the interfacial resistance was decreased. In particular, by a content of 2 vol % FEC in 0.2 M $TEABF_4$ PC/DMC solvent, the electrolyte showed the superior capacitance. However, when FEC content exceeds 2 vol %, the capacitance was decreased and the interfacial resistance was increased.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.10b
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• pp.1031-1036
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• 2000

In this study, a numerical simulation that can effectively predict the strengthening effect of repaired aged RC structures is developed using the axial deformation link elements. In repaired structures, concrete and interface are modeled as quasi-brittle materials. An elastic-perfectly plastic constitutive relationship is introduced for reinforcing bars. Also, a linear-elastic relationship for repair materials such as FRP or CFS. Structural deterioration in terms of corrosion of steel rebar is considered. The interfacial property between steel and concrete which is reduced by corrosion of steel rebar is obtained by comparing numerical results with experimental results of pull out tests. Obtained values are used in repaired reinforced concrete structures under flexural loading conditions. To investigate strengthening effect of the structures repaired with carbon fiber sheet(CFS), repaired and unrepaired RC structures are analyzed numerically. From analysis, rip-off, debonding and rupture failure mechanisms of interface between substrate and CFS can be determined. Finally, strengthening effect according to the variation of interfacial material properties is investigated, and it is shown that interfacial material properties have influence on the mechanical behavior of repaired structure systems Therefore, the developed numerical method using axial deformation link elements can use for determining the strengthening effects and failure mechanism of repaired aged RC structure.

• Composites Research
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• v.32 no.2
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• pp.96-101
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• 2019

Interfacial adhesion between fiber and resin are related to composites performance, so it is very important to evaluate them accurately. In this study, the interfacial properties of microdroplets under fatigue loading conditions were evaluated. The mechanical properties and interfacial adhesion of epoxy resin with dopamine were studied. Tensile specimens were prepared to evaluate mechanical properties and epoxy microdroplets specimens were used for the evaluation of interfacial adhesion. In addition, in the microdroplet fatigue test, the same diameter of the microdroplet was used and the experiment was performed under the same conditions. As a result, it was confirmed that mechanical and interfacial properties were improved when dopamine was applied to epoxy resin through tensile and microdroplet experiments. It is considered that dopamine improves the degree of curing of the epoxy resin and imparts hydroxyl groups to the epoxy resin to increase the mechanical properties and the interfacial adhesion between the glass fibers.

• Journal of Adhesion and Interface
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• v.12 no.1
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• pp.26-33
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• 2011

Phosphoric acid treatments were conducted to improve the adhesion property of polyketone film to rubber. The effects of phosphoric acid treatments were characterized by using a contact angle analyzer and a XPS (X-ray photoelectron spectroscopy). Morphological changes were observed by using a scanning electron microscope (SEM) and an atomic force microscope (AFM) as the acid treatment condition varied in concentration and time. The contact angle was found to significantly decrease with the acid treatment. According to the XPS, increased wettability was attributed to the inclusion of oxygen containing groups such as hydroxyl, carbonyl and carboxyl by acid treatments. Cracks and pores were produced on the polyketone film surface and thus, roughness increased with the acid treatment. Interfacial adhesion strength between polyketone and natural rubber was largely improved by acid treatment due to the increased wettability and roughness of the polyketone surface. However, the higher level of acid treatment caused the degradation of the polyketone surface, and thus, its interfacial adhesion consequently decreased.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.11a
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• pp.61-64
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• 2005

Recently to repair the structure of deteriorated concrete, LMC rehabilitation method is introduced. however, this method has the possible risks of brittle failure depending on bond performance of the interface. the prediction of interfacial behavior becomes essential to protect the failure. all of the studies which have been done about this field are only about material property such as strength, durability, bond. there is not enough data and studies about structural behavior and numerical analysis. therefore, in this study A flexural nonlinear analysis model of ABAQUS was proposed to predict the load-deflection response, interfacial stress, and ultimate strength. The parameter study showed that overlay thickness was a main influencing factor to the behavior of RC beam overlayed by LMC.

• Journal of the Korean Ceramic Society
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• v.37 no.2
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• pp.128-133
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• 2000

In this work, soft carbons produced by pyrolysis of petroleum and coal-tar pitch were used as the negative electrode for Li-ion batteries. We studeid the charge/discharge capacity and the interfacial reaction of these electrodes by constructing a half cell. Charge/discharge property was studied by a constant-current step and the interfacial reaction between the electrolyte and the surface of a carbon electrode was studied by the cyclic voltammetry. The initial charge/discharge capacity for the coal-tar pitch carbon increased exceedingly with the heat treatment temperature. On hte other hand, the capacity of the petroleum pitch carbon increased with temperature up to 1000$^{\circ}C$, thereafter decreased continuously. While the charge capacity decreased with the cycle number, the reversibility increased above 90%. In addition, the thermal stability and crystallization of petroleum and coal-tar pitches were analyzed by TGA and XRD, respectively.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.17 no.4
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• pp.303-311
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• 2005

The problem of conjugate laminar film condensation of the pure saturated vapor in forced flow over a flat plate has been investigated as boundary layer solutions. A simple and efficient numerical method is proposed for its solution. The interfacial temperature is obtained as a root of 3rd order polynomial for laminar film condensation, and it is presented as a function of the conjugate parameter. The momentum and energy balance equations are reduced to a nonlinear system of ordinary differential equations with four parameters: the Prandtl number, Pr, Jacob number, $Ja^{\ast}$, defined by an overall temperature difference, a property ratio R and the conjugate parameter ${\zeta}$. The approximate solutions thus obtained reveal the effects of the conjugate parameter.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.20 no.3
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• pp.284-291
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• 2011

Numerical experiments on biological interfacial layer, DEJ by finite element software ABAQUS have been conducted to study its fracture behavior including crack bridging / arresting characteristics in the model. Crack growth simulation has been carried out by numerical tool, XFEM, devoted to study cracks and discontinuities. The fracture toughness of DEJ has been estimated before and after crack bridging. The implications of bridging in numerical study of fracture behavior of DEJ-like biological interface have been discussed. It has been observed that the results provided by the numerical studies without proper accommodation of bridging phenomenon can mislead. This study can be helpful for understanding the DEJ-like biological interface in terms of its fracture toughness, an important material characteristics. This property of the material is an important measure that has to be taken care during design and manufacturing processes.

• Proceedings of the KIEE Conference
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• 2002.11a
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• pp.124-126
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• 2002

In this study, composite materials were put to dry interfacial treatment by use of plasma technology. It has been presented that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system pressure, 100 W of discharge power, and 3 minutes of discharge time. Also, the surface resistance rate, dielectric property and tensile strength were improved.

• The Journal of Korean Academy of Prosthodontics
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• v.44 no.6
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• pp.683-689
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• 2006

Statement of problem. Interfacial toughness is important in the mechanical property of layered dental ceramics such as core-veneered all-ceramic dental materials. The interfaces between adjacent layers must be strongly bonded to prevent delamination, however the weak interface makes delamination by the growth of lateral cracks along the interface. Purpose. The purpose of this study was to determine the effect of the reaction layer on the interfacial fracture toughness of the core/veneer structure according to the five different divesting. Materials and methods. Thirty five heat-pressed Lithia-based ceramic core bars (IPS Empress 2), $20mm{\times}3mm{\times}2mm$ were made following the five different surface divesting conditions. G1 was no dissolution or sandblasting of the interaction layer. G2 and G3 were dissolved layer with 0.2% HF in an ultrasonic unit for 15min and 30 min. G4 and G5 were dissolved layer for 15min and 30min and then same sandblasting for 60s each. We veneered bilayered ceramic bars, $20mm{\times}2.8mm{\times}3.8mm$(2mm core and 1.8mm veneer), according to the manufacturer's instruction. After polishing the specimens through $1{\mu}m$ alumina, we induced five cracks for each of five groups within the veneer close to interface under an applied indenter load of 19.6N with a Vickers microhardness indenter. Results. The results from Vickers hardness were the percentage of delamination G1:55%, G2:50%, G3:35%, G4:0% and G5:0%. SEM examination showed that the mean thickness of the reaction layer were G1 $93.5{\pm}20.6{\mu}m$, G2 $69.9{\pm}14.3{\mu}m$, G3 $59.2{\pm}20.2{\mu}m$, G4 $0.61{\pm}1.44{\mu}m$ G5 $0{\pm}0{\mu}m$. The mean interfacial delamination crack lengths were G1 $131{\pm}54.5{\mu}m$, G2 $85.2{\pm}51.3{\mu}m$, and G3 $94.9{\pm}81.8{\mu}m$. One-way ANOVA showed that there was no statistically significant difference in interfacial crack length among G1, G2 and G3(p> 0.05). Conclusion. The investment reaction layer played important role at the interfacial toughness of body ceramic bonded to Lithia-based ceramic.