• 제목/요약/키워드: interfacial energy

검색결과 625건 처리시간 0.031초

접착부재의 초음파 감쇠계수에 의한 계면균열 길이의 측정 (Measurement of Interfacial Crack Length by Ultrasonic Attenuation Coefficients on Adhesively Bonded Components)

  • 정남용;박성일
    • 한국자동차공학회논문집
    • /
    • 제12권1호
    • /
    • pp.130-137
    • /
    • 2004
  • The ultrasonic attenuation coefficients were measured by interfacial crack length in the adhesive components of double-cantilever beam(DCB). The energy release rate, G, was obtained by the experimental measurement of compliance. The numerical analysis by the boundary element method(BEM) and Ripling's equation was investigated. The experimental results represent that the relation between interfacial crack length for the ultrasonic attenuation coefficient and energy release rate is increased proportionally. A measurement method of the interfacial crack length by the ultrasonic attenuation coefficient was proposed and discussed.

High performance of inverted polymer solar cells

  • Lee, Hsin-Ying;Lee, Ching-Ting;Huang, Hung-Lin
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
    • /
    • pp.61.2-61.2
    • /
    • 2015
  • In the past decades, green energy, such as solar energy, wind power, hydropower, biomass energy, geothermal energy, and so on, has been widely investigated and developed to solve energy shortage. Recently, organic solar cells have attracted much attention, because they have many advantages, including low-cost, flexibility, light weight, and easy fabrication [1-3]. Organic solar cells are as a potential candidate of the next generation solar cells. In this abstract, to improve the power conversion efficiency and the stability, the inverted polymer solar cells with various structures were developed [4-6]. The novel cell structures included the P3HT:PCBM inverted polymer solar cells with AZO nanorods array, with pentacene-doped active layer, and with extra P3HT interfacial layer and PCBM interfacial layer. These three difference structures could respectively improve the performance of the P3HT:PCBM inverted polymer solar cells. For the inverted polymer solar cells with AZO nanorods array as the electronic transportation layer, by using the nanorod structure, the improvement of carrier collection and carrier extraction capabilities could be expected due to an increase in contact area between the nanorod array and the active layer. For the inverted polymer solar cells with pentacene-doped active layer, the hole-electron mobility in the active layer could be balanced by doping pentacene contents. The active layer with the balanced hole-electron mobility could reduce the carrier recombination in the active layers to enhance the photocurrent of the resulting inverted polymer solar cells. For the inverted polymer solar cells with extra P3HT and PCBM interfacial layers, the extra PCBM and P3HT interfacial layers could respectively improve the electron transport and hole transport. The extra PCBM interfacial layer served another function was that led more P3HT moving to the top side of the absorption layer, which reduced the non-continuous pathways of P3HT. It indicated that the recombination centers could be further reduced in the absorption layer. The extra P3HT interfacial layer could let the hole be more easily transported to the MoO3 hole transport layer. The high performance of the novel P3HT:PCBM inverted polymer solar cells with various structures were obtained.

  • PDF

Impact Fracture and Shear Strength Characteristics on Interfacial Reaction Layer of Nb/MoSi2 Laminate Composite

  • Lee, Sang-Pill;Yoon, Han-Ki;Park, Won-Jo
    • International Journal of Ocean Engineering and Technology Speciallssue:Selected Papers
    • /
    • 제3권1호
    • /
    • pp.35-39
    • /
    • 2000
  • The present study dealt with the relationships among the interfacial shear strength, the thickness of interfacial reaction layer and the impact value of $Nb/MoSi_2$ laminate composites. In addition, the tensile test was conducted to evaluate the fracture strain of $Nb/MoSi_2$ laminate composites. To change the thickness of the reaction layer, $Nb/MoSi_2$ laminate composites alternating sintered MoSi2 layers and Nb foils were fabricated as the parameter of hot press temperature. It has been found that the growth of the reaction layer increases the interfacial shear strength and decreases the impact value by localizing a plastic deformation of Nb foil. There also exist appropriate shear strength and the thickness of the reaction layer, which are capable of maximizing the fracture energy of $Nb/MoSi_2$.

  • PDF

Effect of Sputtering Power on the Change of Total Interfacial Trap States of SiZnSnO Thin Film Transistor

  • Ko, Kyung-Min;Lee, Sang Yeol
    • Transactions on Electrical and Electronic Materials
    • /
    • 제15권6호
    • /
    • pp.328-332
    • /
    • 2014
  • Thin film transistors (TFTs) with an amorphous silicon zinc tin oxide (a-2SZTO) channel layer have been fabricated using an RF magnetron sputtering system. The effect of the change of excitation electron on the variation of the total interfacial trap states of a-2SZTO systems was investigated depending on sputtering power, since the interfacial state could be changed by changing sputtering power. It is well known that Si can effectively reduce the generation of the oxygen vacancies. However, The a-2SZTO systems of ZTO doped with 2 wt% Si could be degraded because the Si peripheral electron belonging to a p-orbital affects the amorphous zinc tin oxide (a-ZTO) TFTs of the s-orbital overlap structure. We fabricated amorphous 2 wt% Si-doped ZnSnO (a-2SZTO) TFTs using an RF magnetron sputtering system. The a-2SZTO TFTs show an improvement of the electrical property with increasing power. The a-2SZTO TFTs fabricated at a power of 30 W showed many of the total interfacial trap states. The a-2SZTO TFTs at a power of 30 W showed poor electrical property. However, at 50 W power, the total interfacial trap states showed improvement. In addition, the improved total interfacial states affected the thermal stress of a-2SZTO TFTs. Therefore, a-2SZTO TFTs fabricated at 50 W power showed a relatively small shift of threshold voltage. Similarly, the activation energy of a-2SZTO TFTs fabricated at 50 W power exhibits a relatively large falling rate (0.0475 eV/V) with a relatively high activation energy, which means that the a-2SZTO TFTs fabricated at 50 W power has a relatively lower trap density than other power cases. As a result, the electrical characteristics of a-2SZTO TFTs fabricated at a sputtering power of 50 W are enhanced. The TFTs fabricated by rf sputter should be carefully optimized to provide better stability for a-2SZTO in terms of the sputtering power, which is closely related to the interfacial trap states.

탄소섬유쉬트로 보강된 철근콘크리트보의 계면박리에 대한 해석적 연구 (Analytical Study on Interface Debonding of Reinforced Concrete Beams Strengthened with Carbon Fiber Sheet(CFS))

  • 심종성;배인환
    • 콘크리트학회지
    • /
    • 제11권2호
    • /
    • pp.177-186
    • /
    • 1999
  • 본 연구의 목적은 탄소섬유쉬트로 보강된 시험체의 주요 파괴모드인 계면모드인 계면박리 모드에 의한 부재의 파괴를 규명하는 것이다. 탄소섬유쉬트로 보강된 손상된 보시험체의 계면박리 모드를 해석하기 위하여 선형탄성 파괴역학(LEFM)의 컴플라이언스법과 유한요소법을 사용하여 계면파괴 역학변수인 에너지해방율(strain energy release rate, G)을 고찰하였다. 손상된 단순 보시험체의 해석결과, 최대 에너지해방율($G_{max}$)은 에폭시 접착두께에 관계없이 바깥 휨균열에서 시작된 계면 전단 균열 길이가 18mm 부근에서 발생하였다. 보강보의 강도 해석결과, 극한강도 설계법에 따른 단면의 공칭 휨 강도에 대한 계면박리에 의해 부재가 파괴되는 것으로 해석되었다. 또한 적용된 접착두께 1mm~3mm는 에너지해방율에 거의 영향을 미치지 않아 계면박리의 주요 인자가 아닌 것으로 나타났다.

$Al/Al_2O_3$ 계면의 젖음특성 및 계면반응 (Wetting Characteristics and Interfacial Reaction at $Al/Al_2O_3$ Interface)

  • 권순용;정대영;최시경;구형회;이종수
    • 한국세라믹학회지
    • /
    • 제31권8호
    • /
    • pp.815-822
    • /
    • 1994
  • Sessile drop studies of molten Al on single crystal sapphire substrate were conducted to understand the wetting behavior and interfacial reaction at Al/Al2O3 interface. To investigate the wetting mechanism, the variation in contact angle was determined with time. The contact angle obtained in this study decreased exponentially with time. This result means that the driving force for wetting is the reduction in interfacial energy between liquid Al and sapphire caused by the interfacial reaction. The closer examination revealed that the reaction was the dissolution of sapphire by molten Al. Ti has been frequently used to improve wetting on ceramic materials. Therefore, the influence of Ti content on the wetting behaviour was investigated in this work. The equilibrium wetting angles of pure Al, Al-0.3 wt%Ti, and Al-1.0 wt%Ti at 100$0^{\circ}C$ were 63$^{\circ}$, 59$^{\circ}$, and 54$^{\circ}$respectively. The difference is considered as the result of the change in interfacial energy caused by the reaction between Ti and sapphire and the interfacial reaction formed the reaction products of varying stoichiometry (TiO, Ti2O3, TiO2 etc.).

  • PDF

도파민이 첨가된 에폭시 기지재의 기계적 물성 및 유리섬유 간 계면접착력 향상 (Epoxy Matrix with Adding Dopamine for Improving Mechanical Property and Interfacial Adhesion with Glass Fiber)

  • 신평수;김종현;백영민;박하승;박종만
    • Composites Research
    • /
    • 제32권2호
    • /
    • pp.96-101
    • /
    • 2019
  • 섬유와 수지 간 계면접착력은 복합재료 성능과 관련되므로 이를 정확하게 평가하는 것은 매우 중요하다. 본 연구에서는, 피로 하중 조건에서의 마이크로드롭렛 실험에 의한 계면접착력 평가를 실시하였다. 도파민이 적용된 에폭시 수지에 대하여 기계적 물성 및 계면접착력을 측정하였다. 기계적 물성을 평가하기 위해 인장 시편을 제작하였고, 계면 접착력 평가를 위하여 유리섬유에 에폭시 마이크로드롭렛을 만든 시편을 사용하였다. 특히 마이크로드롭렛 피로 실험 시 동일한 직경의 마이크로드롭렛을 사용하여 동일한 조건에서 실험하였다. 그 결과 인장 및 마이크로드롭렛 실험을 통해 에폭시 수지에 도파민이 적용될 때 기계 및 계면접착력이 향상됨을 확인하였다. 도파민이 에폭시 수지의 경화정도를 향상시키고 에폭시 수지에 하이드록실 그룹을 부여하여 기계적 물성 및 유리섬유 간 계면 접착력을 증가시켰을 것으로 사려된다.

Effect of Graphitic Nanofibers on Interfacial Adhesion and Fracture Toughness of Carbon Fibers-reinforced Epoxy Composites

  • Kim, Seong-Hwang;Park, Soo-Jin
    • Composites Research
    • /
    • 제34권2호
    • /
    • pp.82-87
    • /
    • 2021
  • The mechanical properties of carbon fiber-reinforced epoxy composites (CFRPs) are greatly dependent on the interfacial adhesion between the carbon fibers and the epoxy matrix. Introducing nanomaterial reinforcements into the interface is an effective approach to enhance the interfacial adhesion of CFRPs. The main purpose of this work was to introduce graphitic nanofiber (GNFs) between an epoxy matrix and carbon fibers to enhance interfacial properties. The composites were reinforced with various concentrations of GNFs. For all of the fabricated composites, the optimum GNF content was found to be 0.6 wt%, which enhanced the interlaminar shear strength (ILSS) and fracture toughness (KIC) by 101.9% and 33.2%, respectively, compared with those of neat composites. In particular, we observed a direct linear relationship between ILSS and KIC through surface free energy. The related reinforcing mechanisms were also analyzed and the enhancements in mechanical properties are mainly attributed to the interfacial interlocking effect. Such an effort could accelerate the conversion of composites into high performance materials and provide fundamental understanding toward realizing the theoretical limits of interfacial adhesion and mechanical properties.

이방성재료 접합 띠판에 대한 면외 동적계면균열 (Mode III Dynamic Interfacial Crack in Bonded Anisotropic Strip Under Anti-Plane Deformation)

  • 박재완;최성렬
    • 대한기계학회:학술대회논문집
    • /
    • 대한기계학회 2000년도 추계학술대회논문집A
    • /
    • pp.111-116
    • /
    • 2000
  • A semi-infinite interfacial crack propagated with constant velocity in two bonded anisotropic strip under out-of-plane clamped displacements is analyzed. The asymptotic stress and displacement fields near the crack tip are obtained, where the results get more general expressions applicable not only to isotropic/orthotropic materials but also to the extent of the anisotropic material having one plane of elastic symmetry for the interfacial crack. The dynamic stress intensity factor is obtained as a closed form, which is decreased as the velocity of crack propagation increases. The critical velocity where the stress intensity factor comes to zero is obtained, which agrees with the lower value between the critical values of parallel crack merged in the material 1 and 2 adjacent to the interface. The dynamic energy release rate is also obtained as a form related to the stress intensity factor.

  • PDF

Pb(Zr, Ti)$O_3$ 박막에서 결정립 크기 포화 현상에 관한 연구 (A Study on the Saturation of Grain Size in Pb(Zr, Ti)$O_3$ Thin Films)

  • 이장식;김찬수;주승기
    • 한국세라믹학회지
    • /
    • 제37권6호
    • /
    • pp.530-536
    • /
    • 2000
  • During the grain growth of the PZT thin films by selective nucleation method using PZT seed, it was found that the grain size was saturated with the annealing temperature. The saturation of grain size was analyzed by the interfacial energy which appeared during the crystallization. The factors affecting the saturation of grain size were found to be the interfacial energy between perovskite phase and pyrochlore phase, and PZT thin film and the bottom Pt electrode. When the ion damage was introduced to the grain-size saturated PZT thin films, further lateral growth was observed. Pt bottom electrode thickness was changed to control the interfacial energy between the PZT thin film and the Pt bottom electrode. When Pt thickness was increased, the grain size was also increased, because the lattice parameter of Pt films was increased with the thickness of the Pt films. The incubation time of nucleation was increased with the amount of the ion damage on the Pt films.

  • PDF