• Title/Summary/Keyword: interfacial characteristic

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Study on the Adsorption Behavior of FeS in Anaerobic Conditions (혐기성 조건에서 FeS의 흡착 거동 연구)

  • 김정배
    • Journal of Environmental Science International
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    • v.6 no.5
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    • pp.505-512
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    • 1997
  • The Interfacial characteristics between various heavy metals and hydrous FeS were investigated. Heavy metals which have lower sulfide solubilities than FeS undergoes the lecttice exchange reaction when these metal tons contact FeS In the aqueous phase. For heavy metals which have higher suede solubilities than FeS, these metal ions adsorb on the surface of FeS. Such characteristic reactions were interpreted by the soled solution formation theory. The presence of ligand such as EDTA reduced largely metal removal efficiency due to formation of metal-ligand complex In the solution. In an attempt to elucidate the Interfacial characteristics, zeta potential of the hydrous FeS In the absence and In the presence of various metal loons were measured and analyzed.

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Characteristic of HVOF AISI316-WC Coating Layer on Stainless Steel Separator for PEMFC (고분자 전해질 연료전지용 스테인리스강 분리판의 HVOF AISI316-WC 코팅층 특성)

  • Nam, Dae-Geun;Kang, Nam-Hyun;Park, Yeong-Do;Kim, Young-Seok
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.10a
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    • pp.1-5
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    • 2008
  • Stainless steels have been widely considered as metallic separators, due to their passive surface film, which is good for corrosion resistance. However, the high resistivity of the passive film increases interfacial contact resistance between the separators and electrodes. Stainless steels thermal spray coated with a mixture of tungsten carbide and stainless steel powders showed that the coated layer safely combined with the matrix but they suffered many internal defects including voids and cracks. Many cracks were formed in the coated layer and the interface of the matrix and the coated layer during the rolling process. The coated and rolled stainless steels showed lower interfacial contact resistance and corrosion resistance than bare stainless steel because of low resistivity of tungsten carbide and numerous defects, which caused crevice corrosion, in the coated layer.

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Electrical Properties of Friction Welded joints between Cu-Al (마찰용접을 적용한 Cu-Al Busbar의 전기적 물성 연구)

  • Kim, Ki-Young;Choi, In-Chul;ITO, Kazuhiro;Oh, Myung-Hoon
    • Journal of the Korean Society for Heat Treatment
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    • v.33 no.6
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    • pp.284-289
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    • 2020
  • Since the dissimilar bonded interface usually consists of intermetallic compounds (IMCs) layer and cracks, their mechanical and electrical properties can be influenced by microstructure at interface between two different metals. In this study, the friction welded Cu-Al busbar, which is widely used to connect a secondary battery and their component, is selected to analyze the influence of interfacial characteristic on their tensile strength and electric conductivity. Then, the electrical characteristics of Cu busbar and Cu-Al busbar were investigated by thermal flow analysis and temperature rise test. In addition, the relationship between the maximum saturation temperature and the electrical conductivity were discussed in terms of interfacial characteristics of the friction welded Cu-Al busbar.

Fiber Orientation Effects on the Fracture Process and Acoustic Emission Characteristics of Composite Laminates

  • Woo, Sung-Choong;Kim, Jung-Heun;Choi, Nak-Sam
    • Journal of the Korean Society for Nondestructive Testing
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    • v.25 no.6
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    • pp.451-458
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    • 2005
  • The effects of fiber orientation on acoustic emission(AE) characteristics have been studied for various composite laminates. Reflection and transmission optical microscopy were used to investigate the damage zone of specimens. AE signals were classified through short time Fourier transform(STFT) as different types: AE signals with a high intensity and high frequency band were due to fiber fracture, while weak AE signals with a low frequency band were due to matrix cracking and/or interfacial cracking. Characteristic feature in the rate of hit-events having high amplitudes showed a procedure of fiber breakages, which expressed the characteristic fracture processes of notched fiber-reinforced plastics with different fiber orientations. As a consequence, the behavior of fracture in the continuous composite laminates could be monitored through nondestructive evaluation(NDE) using the AE technique.

The Structure, Surface Morphology and Electrical Properties of ZrO2 Metal-insulator-metal Capacitors (ZrO2 MIM 캐패시터의 구조, 표면 형상 및 전기적 특성)

  • Kim Dae Kyu;Lee Chongmu
    • Korean Journal of Materials Research
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    • v.15 no.2
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    • pp.139-142
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    • 2005
  • [ $ZrO_2$ ] gate dielectric thin films were deposited by radio frequency (rf)-magnetron sputtering and its structure, surface morphology and electrical peoperties were studied. As the oxygen flow rate increases, the surface becomes smoother. The experimental results indicate that a high temperature annealing is desirable since it improves the electrical properties of the $ZrO_2$ gate dielectric thin films by decreasing the number of interfacial traps at the $ZrO_2/Si$ interface. The carrier transport mechanism is dominated by the thermionic emission.

Interface and Surface Properties by Surface Treatment of Zirconia for All Ceramic Crown (전부도재관용 지르코니아의 표면처리에 따른 표면특성 및 계면특성 관찰)

  • Kim, Chi-Young;Chung, In-Sung;Choi, Sung-Min
    • Journal of Technologic Dentistry
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    • v.35 no.2
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    • pp.137-142
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    • 2013
  • Purpose: This study was to observe the surface and interfacial characteristic of Zirconia by surface treatment. And it was observed the roughness and contact angle according to processing, and the interfacial properties by surface treatment on zirconia. Methods: The oxide formation and ion diffusion between core and veneer ceramic were determined by the X-ray Dot Mapping of EPMA(Electron probe micro analyzer). The roughness was measured by 3D Digital microscope and the contact angle according to processing of zirconia was observed using distilled water on the surface. Results: The surface roughness of the specimens Z04, Z12, Z15 was measured $0.67({\pm}0.03){\mu}m$, $0.50({\pm}0.12){\mu}m$, $0.35({\pm}0.09){\mu}m$, respectively. As results of contact angle test, Z04, Z12, Z15 of specimen group without binder treatment was measured $46.79({\pm}3.17)^{\circ}$, $57.47({\pm}4.83)^{\circ}$, $56.19({\pm}2.66)^{\circ}$, respectively. but, L04, L12, L15 of specimen group without binder treatment was measured $63.84({\pm}2.20)^{\circ}$, $66.08({\pm}0.16)^{\circ}$, $65.10({\pm}1.01)^{\circ}$, respectively. Average contact angle of L15 was measured $65.10({\pm}1.01)^{\circ}$. In X-ray Dot Mapping results, thickness of binder including Al element was measured that each of L04, L12, L15 were $20{\mu}m$, $15{\mu}m$, $10{\mu}m$. Conclusion: The more rough surface increases the wettability, but the sintered exclusive binder decreases the wettability.

Effect of Surface Treatment of Polycarbonate Film on the Adhesion Characteristic of Deposited SiOx Barrier Layer (폴리카보네이트 필름 표면 처리가 증착 SiOx 베리어층 접착에 미치는 영향)

  • Kim, Gwan Hoon;Hwang, Hee Nam;Kim, Yang Kook;Kang, Ho-Jong
    • Polymer(Korea)
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    • v.37 no.3
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    • pp.373-378
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    • 2013
  • The interfacial adhesion strength is very important in $SiO_x$ deposited PC film for the barrier enhanced polycarbonate (PC) flexible substrate. In this study, PC films were treated by undercoating, UV/$O_3$ and low temperature plasma and then the effect of physical and chemical surface modifications on the interfacial adhesion strength between PC film and $SiO_x$ barrier layer were studied. It was found that untreated PC film shows significantly low interfacial adhesion strength due to the smooth surface and low surface free energy of PC. Low temperature plasma treatments resulted in the increase of both surface roughness and surface free energy due to etching and the appearance of polar molecules on the PC surface. However, UV/$O_3$ treatment only shows the increase of surface free energy by developed polar molecules on the surface. These surface modifications caused the enhancement of surface interfacial strength between PC film and $SiO_x$ barrier. In the case of undercoating, it was found that the increase of surface interfacial strength was achieved by adhesion between various acrylic acid on acrylate coated surface and $SiO_x$ without increase of polar surface energy. In addition, the barrier property is also improved by organic-inorganic hybrid multilayer structure.

Crystallographic and Interfacial Characterization of Al2O3 and ZrO2 Dielectric Films Prepared by Atomic Layer Chemical Vapor Deposition on the Si Substrate (Si 기판에서 원자층 화학 기상 증착법으로 제조된 Al2O3 및 ZrO2 유전 박막의 결정학적 특성 및 계면 구조 평가)

  • Kim, Joong-Jung;Yang, Jun-Mo;Lim, Kwan-Yong;Cho, Heung-Jae;Kim, Won;Park, Ju-Chul;Lee, Soun-Young;Kim, Jeong-Sun;Kim, Geun-Hong;Park, Dae-Gyu
    • Korean Journal of Materials Research
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    • v.13 no.8
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    • pp.497-502
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    • 2003
  • Crystallographic characteristics and interfacial structures of $Al_2$$O_3$and $ZrO_2$dielectric films prepared by atomic layer chemical vapor deposition (ALCVD) were investigated at atomic scale by high-resolution transmission electron microscopy (HRTEM) and energy dispersive X-ray spectroscopy (EDS)/electron energy-loss spectroscopy (EELS) coupled with a field-emission transmission electron microscope. The results obtained from cross-sectional and plan-view specimens showed that the $Al_2$$O_3$film was crystallized by annealing at a high temperature and its crystal system might be evaluated as either cubic or tetragonal phase. Whereas the $ZrO_2$film crystallized during deposition at a low temperature of ∼$300^{\circ}C$ was composed of both tetragonal and monoclinic phase. The interfacial thickness in both films was increased with the increased annealing temperature. Further, the interfacial structures of X$ZrO_2$$O_3$and $ZrO_2$films were discussed through analyses of EDS elemental maps and EELS spectra obtained from the annealed films, respectively.

The Study on the Two-Phase Flow in the Microchannel Using DSMC(Direct Simulation Monte Carlo) Method (DSMC(Direct Simulation Monte Carlo)방법을 이용한 마이크로관 내에서의 2 상유동에 관한 연구)

  • Lee, Jin-Ho;Ryu, Dong-Hun;Lee, Tae-Hong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.12
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    • pp.1667-1672
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    • 2003
  • In contrast to the high demand for MEMS devices, microflow analysis is not feasible even for single-phase flow with conventional Navier-Stokes equation because of non-continuum effect when characteristic dimension is comparable with local mean free path. DSMC is one of particle based DNS(Direct Numerical Simulation) methods that uses no continuum assumption. In this paper, gas flow in microchannel is studied using DSMC. Interfacial shear and flow characteristics are observed and compared with the results of gas flow that is in contact with liquid case and solid wall case. The simulation is limited to the case of equilibrium steady state and evaporation/condensation coefficient is assumed to be the same and unity. System temperature remains constant and the interfacial shear appears to be small compared to the result with solid wall. This is because particles evaporated and reflected from the liquid surface form high density layer near the interface with liquid flow.

Characteristic Studies of Plasma Treated unidirectional Hildegardia Populifolia Fabric

  • Prasad, C. Venkata;Lee, D.W.;Sudhakara, P.;Jagadeesh, D.;Kim, B.S.;Bae, S.I.;Song, J.I.
    • Composites Research
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    • v.26 no.1
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    • pp.54-59
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    • 2013
  • This study deals with effect of plasma treatment on the properties of unidirectional ligno cellulosic fabric Hildegardia Populofolia (HDP) fabric. Thermal stability of the fabric was determined by differential scanning calorimetry (DSC) and Thermo gravimetric analysis (DSC). Morphological properties was analyzed by SEM analysis and found that the surface was rough upon plasma treatment which provides good interfacial adhesion with matrix during composite fabrication. Thermal stability and mechanical properties of the plasma treated fabric slightly increases compare to alkali and untreated fabric. It was observed that tensile properties of the fabric increases upon plasma treatment due to the formation of rough surface. SEM analysis indicates formation of rough surface on plasma treatment which helps in increasing the interfacial interaction between the matrix (hydrophobic) and fabric (hydrophilic).