• Title/Summary/Keyword: interfacial adhesion

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Morphology and Impact Strength of High Density Polyethylene/Polyamide Alloy (HDPE/PA 알로이의 모포로지와 충격강도)

  • Lee, Yong-Moo;Kang, Doo-Whan
    • Elastomers and Composites
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    • v.28 no.4
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    • pp.283-292
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    • 1993
  • The morphology and impact strength of alloys of high density polyethylene(HDPE) and nylon-6(PA) with modified $ethylene-{\alpha}-olefin$ copolymer(OCP) as compatibilizer and impact modifier were measured by the scanning electron microscope(SEM) and the notched Izod impact test(and the high rate impact test), respectively. HDPE is incompatible with PA and specimens obtained from simple mechanical mixing show the inferior properties. However, it was indicated that OCP played roles of not only impact modifier but also compatibilizer. High rate impact test results were different from those of the notched Izod impact test, but in both tests OCP was effective for HDPE/PA blends. From SEM observation, the size of the dispersed phase in alloys prepared with OCP is much smaller than that of alloys without OCP and the interfacial adhesion of alloys prepared with OCP is also better. Toughening mechanism of polymer blends was discussed by combining the morphology analysis with mechanical and thermal properties.

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Influence of water saturation on fracture toughness in woven natural fiber reinforced composites

  • Kim, Hyo-Jin;Seo, Do-Won
    • Advanced Composite Materials
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    • v.16 no.2
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    • pp.83-94
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    • 2007
  • Woven sisal textile fiber reinforced composites were used to evaluate fracture toughness, tensile and three-point bending. The water absorption testing of all specimens was repeated five times in this study. All specimens were immersed in pure water during 9 days at room temperature, and dried in 1 day at $50^{\circ}C$. Two kinds of polymer matrices such as epoxy and vinyl-ester were used. Fractured surfaces were taken to study the failure mechanism and fiber/matrix interfacial adhesion. It is shown that it can be enhanced to improve their mechanical performance to reveal the relationship between fracture toughness and water absorption fatigue according to different polymer matrices. Water uptake of the epoxy composites was found to increase with cycle times. Mechanical properties are dramatically affected by the water absorption cycles. Water-absorbed samples showed poor mechanical properties, such as lower values of maximum strength and extreme elongation. The $K_{IC}$ values demonstrated a decrease in inclination with increasing cyclic times of wetting and drying for the epoxy and vinyl-ester.

Biocomposites from polypropylene and corn cob: Effect maleic anhydride grafted polypropylene

  • Husseinsyah, Salmah;Marliza, M.Z.;Selvi, E.
    • Advances in materials Research
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    • v.3 no.3
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    • pp.129-137
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    • 2014
  • Biocomposites from polypropylene (PP) and corn cob (CC) were investigated. The effect of corn cob content and maleic anhydride polypropylene (MAPP) as compatibilizer were studied. Results showed that addition of corn cob (CC) in PP have decreased the tensile strength and elongation at break, whereas modulus of elasticity of biocomposites increased. The biocomposites with the MAPP as compatibilizer exhibited higher tensile strength and modulus of elasticity compared biocomposites without MAPP. The morphology study of biocomposites indicates that enhanced the interfacial interaction and adhesion between filler and matrix with the presence of MAPP.

A Study on the Dielectric Properties of Mica-reinforced Silicone Composites (마이카 강화 실리콘 복합재료의 제작과 그 유전적 특성에 관한 연구)

  • 조정수;곽영순;김순태;박차수;박정후
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.41 no.6
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    • pp.640-651
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    • 1992
  • This paper describes the electric properties of mica reinforced silicone composites with the parameter of curing condition of silicone resin, application amount of silane coupling agent to the mica paper and the mica wt% to the composite. Heat-resistant silicone resin and mica paper made of mica flakes are used to prepared the mica/silicone composite as matrix and filler, respectively. To improve the dielectric properties and interfacial adhesion between matrix and filler, silane coupling agent is applied on the mica paper. As for matrix, tan$\delta$ value of 30$0^{\circ}C$ heat-treated silicone resin is the lowest under 1%. The optimal wt% of coupling agent is 0.3% to the weight of mica paper. 80 wt% of mica as filler to the mica/silicone composite shows the best electric properties. And the mica reinforced silicone composite shows good high-frequency and mechanical tensile stress properties.

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Corrosion Properties of Carbon-Coated Metallic Bipolar Plate for PEMFC (고분자 전해질 연료전지 금속 분리판 적용을 위한 탄소 박막의 증착과 내식성 평가)

  • Jang, Dong-Su;Lee, Jung-Joong
    • Journal of Surface Science and Engineering
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    • v.48 no.3
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    • pp.87-92
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    • 2015
  • Carbon thin films were deposited on STS 316L sheets by inductively coupled plasma enhanced magnetron sputtering with or without substrate bias voltage. Typical Raman spectrum for amorphous diamond-like carbon (DLC) was obtained, and the interfacial contact resistance (ICR) was measured to show its conductive nature. The electrochemical impedance spectroscopy (EIS) was used to investigate the corrosion mechanism of the carbon coating under the polymer electrolyte membrane fuel cell (PEMFC) condition. According to the pore-corrosion mechanism, the electrolyte penetrates the carbon coating through the pores and reacts with the substrate. As the substrate corrosion proceeds, the pore enlargement occurs and the surface area of the substrate exposed to the electrolyte. Applicability of the carbon coating for the PEMFC bipolar plate was evaluated by potentiodynamic polarization experiments. Finally, an adhesion problem was briefly considered.

Synthesis and Characterization of Graphene Based Unsaturated Polyester Resin Composites

  • Swain, Sarojini
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.2
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    • pp.53-58
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    • 2013
  • Graphene-based polymer nanocomposites are very promising candidates for new high-performance materials that offer improved mechanical, barrier, thermal and electrical properties. Herein, an approach is presented to improve the mechanical, thermal and electrical properties of unsaturated polyester resin (UPR) by using graphene nano sheets (GNS). The extent of dispersion of GNS into the polymer matrix was also observed by using the scanning electron microscopy (SEM) which indicated homogeneous dispersion of GNS through the UPR matrix and strong interfacial adhesion between the GNS and UPR matrix were achieved in the UPR composite, which enhanced the mechanical properties. The tensile strength of the nanocomposites improved at a tune of 52% at a GNS concentration of 0.05%. Again the flexural strength also increased around 92% at a GNS concentration of 0.05%. Similarly the thermal properties and the electrical properties for the nanocomposites were also improved as evidenced from the differential scanning caloriemetry (DSC) and dielectric strength measurement.

Analysis of Bonding Interfaces between Cemented Carbide and Stainless Steel made via Hot Vacuum Brazing (고온 진공 브레이징을 이용한 초경합금과 스테인리스강의 접합 계면 특성)

  • Park, D.H.;Hyun, K.H.;Kwon, H.H.
    • Transactions of Materials Processing
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    • v.29 no.6
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    • pp.307-315
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    • 2020
  • The cemented carbide and stainless steel were bonded using a hot-vacuum brazing method to analyze the bonding interface. Since it is suitable for the hot vacuum brazing, nickel metal was used as a binder among the main components of the cemented carbide, and a new cemented carbide material was developed by adjusting the alloy composition. The paste, which is one of the important factors affecting the hot vacuum brazing bonding, was able to improve brazing adhesion by mixing solder as Ni powder and a binder as an organic compound at an appropriate ratio. Division of the stainless steel yielded a dense brazing result. This study elucidated the interfacial characteristics of wear-resistant parts by bonding stainless steel and cemented carbide via hot vacuum brazing.

Intercalation Behavior of Clay in Polypropylene/Montmorillonite/Wood Nanocomposites (폴리프로필렌/몬모릴로나이트/목분 나노복합체에서의 클레이 박리거동)

  • Kim, Jin Sung;Lee, Sun Young;Yoon, Ho Gyu
    • Journal of the Korean Society of Industry Convergence
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    • v.13 no.2
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    • pp.93-98
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    • 2010
  • Polypropylene / montmorillonite / wood flour nanocomposites are melt-mixed by using a twin screw extruder. The montmorillonite is intercalated by the wood flour and the basal spacing of montmorillonite is increased with increasing the content of wood flour. The exfoliation constantly occurs by adding more than 10 wt.% of maleic anhydride-grafted polypropylene as the compatibilizer, which is used for improving the interfacial adhesion between matrix and filler. Also, the maleic anhydride-grafted polypropylene enhances the mechanical properties of the nanocomposites.

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Surface Characterization and Morphology in Ar-Plasma-Treated Polypropylene Blend

  • Weon, Jong-Il;Choi, Kil-Yeong
    • Macromolecular Research
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    • v.17 no.11
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    • pp.886-893
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    • 2009
  • Surface modifications using a radio frequency Ar-plasma treatment were performed on a polypropylene (PP) blend used for automotive bumper fascia. The surface characterization and morphology were examined. With increasing aging time, there was an increase in wettability, oxygen containing polar functional groups (i.e., C-O, C=O and O-C=O) due to oxidation, the amount of tale, and bearing depth and roughness on the PP surface, while there was a decrease in the number of hydrocarbon groups (i.e., C-C and C-H). AFM indicated that the Ar-plasma-treatment on a PP blend surface transforms the wholly annular surface into a locally dimpled surface, leading to an improvement in wettability. SEM showed that the PP layer observed in the non-plasma-treated sample was removed after the Ar-plasma treatment and the rubber particles were exposed to the surface. The observed surface characterization and morphologies are responsible for the improved wettability and interfacial adhesion between the PP blend substrate and bumper coating layers.

Optimum Conditions for Improvement of Mechanical and Interfacial Properties of Thermal Treated Pine/CFRP Composites (열처리된 Pine/탄소섬유 복합재료의 기계적 및 계면물성 향상을 위한 최적 조건)

  • Shin, Pyeong-Su;Kim, Jong-Hyun;Park, Ha-Seung;Baek, Yeong-Min;Kwon, Dong-Jun;Park, Joung-Man
    • Composites Research
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    • v.30 no.4
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    • pp.241-246
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    • 2017
  • The brittle nature in most FRP composites is accompanying other forms of energy absorption mechanisms such as fibre-matrix interface debonding and ply delamination. It could play an important role on the energy absorption capability of composite structures. To solve the brittle nature, the adhesion between pines and composites was studied. Thermal treated pines were attached on carbon fiber reinforced polymer (CFRP) by epoxy adhesives. To find the optimum condition of thermal treatment for pine, two different thermal treatments at 160 and $200^{\circ}C$ were compared to the neat case. To evaluate mechanical and interfacial properties of pines and pine/CFRP composites, tensile, lap shear and Izod test were carried out. The bonding force of pine grains was measured by tensile test at transverse direction and the elastic wave from fracture of pines was analyzed. The mechanical, interfacial properties and bonding force at $160^{\circ}C$ treated pine were highest due to the reinforced effect of pine. However, excessive thermal treatment resulted in the degradation of hemicellulose and leads to the deterioration in mechanical and interfacial properties.