• Bulletin of the Korean Chemical Society
• /
• 제16권9호
• /
• pp.873-885
• /
• 1995

The local structural and thermodynamical properties of blends A-B/H of a diblock copolymer A-B and a homopolymer H are studied using the polymer reference interaction site model (RISM) integral equation theory with the mean-spherical approximation closure. The random phase approximation (RPA)-like static scattering function is derived and the interaction parameter is obtained to investigate the phase transition behaviors in A-B/H blends effectively. The dependences of the microscopic interaction parameter and the macrophase-microphase separation on temperature, molecular weight, block composition and segment size ratio of the diblock copolymer, density, and concentration of the added homopolymer, are investigated numerically within the framework of Gaussian chain statistics. The numerical calculations of site-site interchain pair correlation functions are performed to see the local structures for the model blends. The calculated phase diagrams for A-B/H blends from the polymer RISM theory are compared with results by the RPA model and transmission electron microscopy (TEM). Our extended formal version shows the different feature from RPA in the microscopic phase separation behavior, but shows the consistency with TEM qualitatively. Scaling relationships of scattering peak, interaction parameter, and temperature at the microphase separation are obtained for the molecular weight of diblock copolymer. They are compared with the recent data by small-angle neutron scattering measurements.

• 아동학회지
• /
• 제36권2호
• /
• pp.1-16
• /
• 2015

The purpose of this study is to investigate the effects of father's play beliefs on father-child interaction and child's social skills. The subjects were 370 fathers of 1, 2 and 3 graders of elementary schools who lived in Seoul and Gyeonggi area. The results were as follows; First, the differences were found to be significant between the whole of father's play hours, play focus beliefs, study focus beliefs and father-child interaction, and their sub-variables of disciplinary action, sensitiveness, and affectionate expression; and between the whole of child's social skills and its sub-variables of cooperative action, self-assertion and self-control. Second, the higher play focus beliefs, the more positive interaction on the child, and specifically they use much democratic disciplinary action, sensitiveness and affectionate expression. Third, as to the effect of the father's play focus beliefs on the child's social skills, father-child interaction was found to act as a partial parameter, while as to the effect of the father's study focus beliefs on the child's social skills, father-child interaction was found to act as a full parameter.

• 제어로봇시스템학회:학술대회논문집
• /
• 제어로봇시스템학회 1993년도 한국자동제어학술회의논문집(국제학술편); Seoul National University, Seoul; 20-22 Oct. 1993
• /
• pp.451-455
• /
• 1993

Interaction between system and disturbance results in system with time-dependent parameter. Parameter variation due to interaction has random characteristics. Most of the randomly varying parameters in control problem is regarded as white noise random process which is not a realistic model. In real situation those random variation is colored noise random process. Modified F-P-K equation is proposed to get the response of the random parametric system using some correction factor. Proposed technique is employed to obtain the colored noise parametric system response and confirmed via Monte-Carlo Simulation.

• 한국지진공학회:학술대회논문집
• /
• 한국지진공학회 1999년도 춘계 학술발표회 논문집 Proceedings of EESK Conference-Spring
• /
• pp.267-274
• /
• 1999

Since the seismic response of dams can be strongly influenced by the dam-reservior interaction in needs to be taken into account in the seismic design of dams. In general a substructure method is employed to solve the dam-reservoir interaction problem in which the dam body is modeled with finite elements and the infinite region of a reservoir using a transmitting boundary. When the water is modeled as a compressible fluid the equation is formulated in frequency domain. But nonlinear behavior of dam body cannot be studied easily in the frequency domain method. In this study time domain formulation of the dam-reservoir-soil interaction is proposed based onthe lumped parameter modeling of the reservoir region, The frequency dependent dynamic-stiffness coefficients of the reservoir are converted into frequency independent lumped-parameters such as masses dampers and springs. The soil-structure interactionis modeled using lumped parameters in similar way. the ground is assumed as a visco-elastic stratum on the rigid bedrock. The dynamic stiffnesses of the rigid surface foundation are calculated using the hyperelement method and are converted into lumped parameters. The application example demonstrated that the lumped parameter model gives almost identical results with the frequency domain formulation.

• Korean Journal of Chemical Engineering
• /
• 제35권11호
• /
• pp.2269-2282
• /
• 2018

Mixed micelle formation behavior of cationic surfactant-cetyltrimethylammonium bromide (CTAB) and anionic surfactant sodium dodecyl sulfate (SDS) in aqueous as well as in urea medium from 303.15 K to 323.15 K at 5 K interval was carried out by conductometric method. The differences between the experimental values of critical micelle concentrations (cmc) and ideal critical micelle concentrations ($cmc^{id}$) illustrate the interaction between the amphiphiles studied. The values of micellar mole fraction ($X_1^{Rub}$ (Rubingh), $X_1^M$ (Motomura), $X_1^{Rod}$ (Rodenas) and $X_1^{id}$(ideal) of surfactant CTAB determined by different proposed models and outcome indicate high involvement of CTAB in SDS-CTAB mixed micellization, which enhance by means of the augment of mole fraction of CTAB. The negative value of interaction parameter (${\beta}$) showed an attractive interaction involving CTAB and SDS. Activity coefficients were less than unity in all case, which also reveals the presence of interaction between CTAB & SDS. The negative ${\Delta}G^0_m$ values imply the spontaneous mixed micellization phenomenon. The attained values of ${\Delta}H^0_m$ were positive at inferior temperature, while negative at superior temperature. The negative ${\Delta}H^0_m$ values in urea ($NH_2CONH_2$) medium illustrate exothermic micellization process. The magnitudes of ${\Delta}S^0_m$ were positive in almost all cases. The excess free energy of mixed micelle formation (${\Delta}G_{ex}$) was found to be negative, which indicates the stability of mixed micelle as compared to the individual's components micelles.

• 전력전자학회논문지
• /
• 제23권5호
• /
• pp.321-327
• /
• 2018

DC microgrid system composed of multiple converters has a tendency to make the system unstable due to the interaction of converters. To solve this problem, in this paper, the interaction between cascaded converters with LC input filter is analyzed with impedance modeling using g-parameter. The input impedance and the output impedance of the system can be obtained through this technique. The stability of the system can be determined by applying Middlebrook's stability criterion to the impedance. Virtual impedance is added to the controller to enhance stability. The validity of the analysis is verified by the result of several simulations and experiments.

• Wind and Structures
• /
• 제21권1호
• /
• pp.85-103
• /
• 2015

Aerodynamic forces of vortex-induced vibration and galloping are going to be coupled when their onset velocities are close to each other, which will induce the cross-wind amplitudes of the structures increased continuously with ever-increasing wind velocities. The main purpose of the present work is going to propose an empirical formula to predict the response amplitude of VIV-galloping interaction. Firstly, two typical mathematical models for the coupled oscillations, i.e., Tamura & Shimada model and Parkinson & Corless model are comparatively summarized. Then, the key parameter affecting response amplitude is determined through comparative numerical simulations with Tamura & Shimada model. For rectangular cylinders with the side ratio from 0.5 to 2.5, which are actually prone to develop the VIV and galloping induced interaction responses, an empirical amplitude prediction formula is proposed after regression analysis on comprehensively collected experimental data with the predetermined key parameter.

• 설비공학논문집
• /
• 제9권4호
• /
• pp.527-535
• /
• 1997

Vapor-liquid equilibrium apparatus is designed and set up. The vapor-liquid equilibrium data of the binary system HFC32/134a are measured in the range between 258.15 and 283.15K at compositions of 0.2, 0.4, 0.6 and 0.8 mole fraction of HFC32. Twenty-two equilibrium data are obtained. Based upon the present data, the binary interaction parameter for Carnahan-Starling-De Santis equation of state is calculated. Temperature range of data is extended to 313.04K using the data in the open literatures. Interaction parameters are determined at nine isotherms.

• 대한금속재료학회지
• /
• 제50권2호
• /
• pp.116-121
• /
• 2012

Equilibria between Mn-Si melts and $MnO-SiO_2$ slags were studied at 1673 K and 1773 K in MnO crucibles to accurately determine the thermodynamic property of the Mn-Si melts. The Unified Interaction Parameter Formalism (UIPF) was used to describe the thermodynamic property of the Mn-Si liquid. Using the UIPF, the experimental results obtained in the present study were thermodynamically analyzed to determine the activity coefficient of Si at infinite dilution and the 1st- and 2nd-order self-interaction parameters of Si in the Mn-Si melts.

• 대한조선학회논문집
• /
• 제60권5호
• /
• pp.341-350
• /
• 2023

In this paper, numerical experiments are performed to examine the collision between a solitary wave and a wave-packet (dispersive wave) in shallow water. We attempt to introduce the improved Boussinesq equation governing the experiments, which is solved by using a semi-analytical approach, called Pseudo-parameter Iteration method(PIM). Using various numerical experiments, we have observed that the wave-packet (propagating dispersive wave) experiences a phase shift after collision with a solitary wave. This phenomenon may be considered as a nonlinear wave-wave interaction in shallow water.