• Bulletin of the Korean Chemical Society
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• 제10권5호
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• pp.437-442
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• 1989

The cmc's of sodium dodecyl sulfate (SDS)/Triton X-100 surfactant mixtures were determined by surface tension measurement at various surfactant compositions. The cmc values were lower than those predicted from ideal mixture. The regular solution theory was applied to calculate the interaction parameter, micellar composition, and the activity coefficients of surfactants in the mixed micelle. The interaction parameter (${\beta}$) was - 2.1. The nonideality arised largely from decreased activity of SDS in the mixed micelle. The mean aggregation numbers (${\bar{n}}$) and micropolarity of hydrocarbon region of the mixed micelles were determined by luminescence probe techniques. The total aggregation number (${\bar{n}}_{SDS}+{\bar{n}}_{TX}$) in mixed micelles showed little dependency on the composition of the micelle. The apparent dielectric constant of the hydrocarbon region of the micelle vs micellar composition plot showed positive deviation from linearity. Emission and emission quenching of excited tris(2,2'-bipyridine)ruthenium(Ⅱ) cation, $(Ru(bpy)_3^{2+})$, by methylviologen ($MV^{2+}$) were also investigated in the mixed micellar solutions. The quenching rate was lowest when the mole fraction of SDS in the surfactant mixtures (${\alpha}_{SDS}$) is about 0.25 and highest at ${\alpha}_{SDS}$ = 0.85. This was explained in terms of combined effects of binding of the cations with the micelle and mobility of the bound cations on the surface of the micelles.

• Elastomers and Composites
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• 제54권3호
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• pp.209-219
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• 2019

It is important to analyze crosslink densities of rubber articles because the physical properties are dependent on the crosslink densities. In this paper, analytical techniques for the measurement of crosslink densities of rubber vulcanizates are described. The most widely used method to measure the crosslink density is a swelling method combined with the Flory-Rehner equation. Application of the interaction parameter (${\chi}$) of rubber and swelling solvent is critical because the crosslink density is absolutely dependent on the ${\chi}$ value. Methods for obtaining ${\chi}$ employ not only solubility parameters of the polymer and swelling solvent but also inverse gas chromatography (IGC). The solubilities of rubbers can be obtained using micro differential scanning calorimetry (${\mu}DSC$), intrinsic viscosity measurement, and UV-visible spectroscopy. Nuclear magnetic resonance (NMR) spectroscopy has been also used for the measurement of the crosslink density using the $T_2$ relaxation time, which is determined by spin-spin relaxation in solid-state NMR. For sulfur-cured rubber vulcanizates, crosslink densities according to the crosslink types of mono-, di-, and polysulfides are measured by treating the rubber samples with a chemical probe composed of thiol and amine compounds. Measurement methods of physical crosslinking by filler, crystallization, and ionic bonding have also been introduced.

• Current Applied Physics
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• 제18권11호
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• pp.1313-1319
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• 2018

The coil-to-globule behavior of poly{${\gamma}$-2-[2-(2methoxyethoxy)ethoxy]ethoxy-3-caprolactone} (PMEEECL) as a ${\gamma}$-substituted poly (${\varepsilon}$-caprolactone) was investigated via atomistic molecular dynamics (MD) simulation. For this purpose, radius of gyration, end-to-end distance and radial distribution function of the chain in the presence of water were calculated. Consequently, the lower critical solution temperature (LCST) of PMEEECL chain at which the coil-to-globule transition takes place, was determined in each calculated parameter curve. The simulation results indicated that the LCST of PMEEECL was occurred at close to 320 K, which is in a good agreement with previous experimental results. Additionally, the appearance of sudden change in both Flory-Huggins interaction parameter (${\chi}$) and interaction energy between the PMEEECL chain and water molecules at about 320 K confirmed the calculated LCST result. The radial distribution function (RDF) results showed that the affinity of the PMEEECL side chain to water molecules is lower than its backbone.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2023년도 학술발표회
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• pp.287-287
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• 2023

Surface water-groundwater interaction (SWGI) is an important hydrological process that influences both the quantity and quality of water resources. However, regional scale SWGI model calibration and uncertainty analysis have been a challenge because integrated models inherently carry a vast number of parameters, modeling assumptions, and inputs, potentially leaving little time and budget to explore questions related to model performance and forecasting. In this study, we have proposed the application of iterative ensemble smoother (IES) for uncertainty analysis and calibration of the widely used integrated surface-subsurface model, SWAT-MODFLOW. SWAT-MODFLOW integrates Soil and Water Assessment Tool (SWAT) and a three-dimensional finite difference model (MODFLOW). The model was calibrated using a parameter estimation tool (PEST). The major advantage of the employed IES is that the number of model runs required for the calibration of an ensemble is independent of the number of adjustable parameters. The pilot point approach was followed to calibrate the aquifer parameters, namely hydraulic conductivity, specific storage, and specific yield. The parameter estimation process for the SWAT model focused primarily on surface-related parameters. The uncertainties both in the streamflow and groundwater level were assessed. The work presented provides valuable insights for future endeavors in coupled surface-subsurface modeling, data collection, model development, and informed decision-making.

• Structural Engineering and Mechanics
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• 제89권2호
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• pp.135-153
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• 2024

In this study, the impact response of a nanobeam with a moving nanoparticle is investigated. Timoshenko beam theory is used to model the nanobeam behavior and nonlocal elasticity theory is used to consider the effects of small dimensions. The interaction between the nanoparticle and nanobeam has been described using Lennard-Jones potential theory and the equations are discretized by the radial basis meshless method and a mathematical model is presented for the nanobeam-nanoparticle system. Validation of the proposed model is achieved by comparing the obtained natural frequencies with reference values, demonstrating good agreement. Dimensionless frequency analysis reveals a decrease with increasing nonlocal parameter, pointing out a toughening effect in nanobeam. The dynamic response of the nanobeam and nanoparticle is obtained by time integration of equations of motion using Newmark and Wilson-𝜃 methods. A comparative analysis of the two methods is conducted to determine the most suitable approach for this study. As a distinctive aspect in this study, the analysis incorporates the deformation of the nanobeam resulting from the nanoparticle-nanobeam interaction when calculating the Lennard-Jones force in the nanobeam-nanoparticle system. The numerical findings explore the impact of various factors, including the nonlocal parameter, initial velocity, nanoparticle mass, and boundary conditions.

• Structural Engineering and Mechanics
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• 제15권1호
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• pp.21-38
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• 2003

The formulation of a new bridge-vehicle system using shell with eccentric beam elements has been introduced in a companion paper (Part I). The new system takes into account of the contribution of the twisting and pitching modes of vehicles to the bridge responses. It can also be used to study the dynamic transverse load distribution of a bridge. This paper presents a parametric study on the impact induced by one vehicle or multi-vehicle running across a bridge using the proposed model. Several parameters were considered as variables including the mass ratio, the speed parameter, the frequency ratio and the axle spacing parameter to investigate their effects on the impact factor. A total number of 189 cases were carried out in this parametric study. Within the realistic range of vehicle considered, the maximum impact factors could be 2.24, 1.78 and 1.49 for bridges with spans 10 m, 20 m and 30 m respectively.

• Steel and Composite Structures
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• 제36권5호
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• pp.603-615
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• 2020

The present manuscript focuses on the flow and heat transfer of the dusty fluid along exponentially stretching cylinder. Enormous attempts are made for fluid flow along cylinder but the study of fluid behavior along exponentially stretching cylinder is discussed lately. Using appropriate transformations, the governing partial differential equations are converted to non-dimensional ordinary differential equations. The transformed equations are solved numerically using Shooting technique with Runge-Kutta method. The influence of the physical parameters on the velocity and temperature profiles as well as the skin fraction coefficient and the local Nusselt number are examined in detail. The essential observations are as the fluid velocity decreases but temperature grows with rise in particle interaction parameter, and both the fluid velocity and temperature fall with increase in mass concentration parameter, Reynold number, Particle interaction parameter for temperature and the Prandtl number.

• 유통과학연구
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• 제18권1호
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• pp.59-69
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• 2020

Purpose: This study aims to examine such relationships as the experiential value that customers respond to with regard to maintenance service by empirically revealing how the quality of auto maintenance and repair service affects both customer satisfaction and intention to reuse the same service through the Perceived-experiential Value of customers. Research design, data and methodology: The research model was designed with service qualities such as human quality, material quality, interaction quality, and system quality as independent variables, perceived-experiential value as a parameter, and service satisfaction and return visit intention as dependent variables. Through a questionnaire composed of 24 items, a total of 319 survey data from customers with the experience of using car maintenance service centers in Korea were collected and analyzed using a structural equation. Results: The material quality did not affect the customers' perceived-experiential value, whereas the interaction quality had the greatest influence. It is confirmed that human quality, interaction quality, and system quality can generate customer satisfaction and repurchase intention through the perceived-experiential value. Conclusions: The experiential value of customers can play an important medium role in improving satisfaction, with customers considering interaction quality important. Therefore, the auto maintenance and repair service should consider relationship-focused service strategies.

• 전기화학회지
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• 제16권4호
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• pp.211-216
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• 2013

At Pt(111), Pt(100), Pt, and Rh interfaces, the Frumkin adsorption isotherm of underpotentially deposited hydrogen (UPD H) and related electrode kinetic data are determined using the standard Gibbs energy of adsorption. The Temkin adsorption isotherm of UPD H correlating with the Frumkin adsorption isotherm of UPD H is readily determined using the correlation constants between the Temkin and Frumkin or Langmuir adsorption isotherms. At the Pt(111), Pt(100), Pt, and Rh interfaces, the lateral repulsive interaction between the UPD H species is interpreted using the interaction parameter for the Frumkin adsorption isotherm. The lateral repulsive interaction between the UPD H species at the Pt(111), Pt(100), Pt, and Rh interfaces is significantly different from the lateral attractive interaction between the overpotentially deposited hydrogen (OPD H) species at Pt, Ir, and Pt-Ir alloy interfaces.

• IEIE Transactions on Smart Processing and Computing
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• 제2권3호
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• pp.117-129
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• 2013

The increasing demand for monitoring wildfires and their impact on the land surface have prompted studies of burned area extraction and analysis. To differentiate burned and unburned area, the earlier method of the Moderate Resolution Imaging Spectro-radiometer (MODIS) Burned Area Detection Algorithm was proposed to estimate the change in land surface based on the reflectance energy. The energy, whose wavelengths are sensitive to burning, was selected to calculate the change parameter $Z_{score}$. This method was applied using the MODIS images to produce a MODIS Burned Area product. The approach was to simplify this algorithm to make it compatible with the Landsat 7 ETM+ SLC-off images. To extract the refined version of burned regions, post-processing was carried out by applying a median filter, dilation morphology algorithm, and finally a gap filling method. The experimental results showed that the detailed burned areas extracted from the proposed method exhibited more spatial details than those of the MODIS Burned products in the large U.S areas. The results also revealed the discontinuous distribution of burned regions in Vietnam forests.