• Title/Summary/Keyword: inorganic oxide

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Titanium oxide nanoparticle hybridized liquid crystal display in vertical alignment

  • Lee, Won-Gyu;O, Byeong-Yun;Im, Ji-Hun;Park, Hong-Gyu;Kim, Byeong-Yong;Na, Hyeon-Jae;Seo, Dae-Sik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.160-160
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    • 2009
  • In recent years, the merging of nanomaterials and nano-technology into electro-optic (EO) device technology such as liquid crystal displays (LCDs) has attracted much attention because of their unique electro- and magneto-optic properties and novel display applications. One example of hybrid LC-inorganic systems is semiconductor nanorods added to LC for their strong reorientation effect and tunable refractive index. Doping of nanoparticles in LC or polymers can lead to changes in performance characteristics such as electro-optical, dielectric, memory effect, phase behavior, etc. Due to the tunability of LCDs with mixed inorganic materials, low voltage operation of a LC system can also be achieved using the significant electro-optical effect achieved through suspension of ferroelectric nanoparticles in NLC.

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Nanocrystals and Their Biomedical Applications

  • Jun, Young-wook;Jang, Jung-tak;Cheon, Jin-woo
    • Bulletin of the Korean Chemical Society
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    • v.27 no.7
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    • pp.961-971
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    • 2006
  • Shape controlled synthesis of inorganic nanocrystals is one of the important issues in materials chemistry due to their novel shape dependent properties. Although various shapes of nanocrystals have been developed, a systematic account on the shape control of these nanocrystals still remains an important subject in materials chemistry. In this article, we will overview the recent developments in the geometrical shape evolution of semiconductor and metal oxide nanocrystals obtained by nonhydrolytic synthetic methods. Many structurally unprecedented motifs have appeared as zero-dimesional (D) polyhedrons, one-D rods and wires, two-D plates and prisms, and other advanced shapes such as branched rods, stars, and inorganic dendrites. Important parameters which determine the geometrical shapes of nanocrystals are also illustrated. In addition, as a possible application of such nanocrystals for biomedical sciences, we further describe their utilizations for cancer diagnosis through nanocrystal-assisted magnetic resonance imaging (MRI).

Layered Silicate-Polymer Nanocomposites

  • Jeong, Han-Mo
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.18-18
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    • 2003
  • Natural clays are composed of oxide layers whose thickness is about 1nm and cations existing between the layers. A number of these layers makes primary particles with a height of about 8∼10nm and these primary particles make aggregates with a size of about 0.1∼10$\mu\textrm{m}$. When layered silicate was made to be organophilic, by exchanging the interlayer cations with organic cationic molecules, the matrix polymer can penetrate between the layers to give a nanocomposite, where 1nm-scal clay layers exist separately in a continuous polymer matrix. These nanostructured hybrid organic-inorganic composites have attracted the great interest of researchers over the last 10 years. They exhibit improved performance properties compared with conventional composites, because their unique phase morphology by layer intercalation or exfoliation maximizes interfacial contact between the organic and inorganic phases and enhances interfacial properties. Since the advent of nylon-6/montmorillonite nanocomposite developed by Toyota Motor Co., the studies on layered silicate-polymer nanocomposites have been successfully extended to other polymer systems. They greatly improved the thermal, mechanical, barrier, and even the flame-retardant properties of the polymers.

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Reaction Mechanism in the Formation of PMN-PT-BT Solid Solution (PMN-PT-BT 고용체의 합성반응기구)

  • Park, Hyun;Lee, Eung-Sang
    • Journal of the Korean Ceramic Society
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    • v.31 no.12
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    • pp.1443-1448
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    • 1994
  • Pb(Mg1/3Nb2/3)O3-PbTiO3-BaTiO3 solid solution was formed by mixed-oxide method. The phase during formation was analysed by XRD and formation mechanism was investigated. While heat-treating Pb(Mg1/3Nb2/3)O3 composition, the first, Pb2Nb2O7 and Pb3Nb2O8 pyrochlore phases are formed, and finally Pb(Mg1/3Nb2/3)O3 perovskite phase with containing Pb3Nb4O13 pyrochlore phase is obtained at 80$0^{\circ}C$. When Pb(Mg1/3Nb2/3)O3 composition is modified with PbTiO3 which have strong ionic bonding and high tolerance factor, the amount of pyrochlore phase is decreased by increasing of stability in perovskite structure.

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Preparation of Titanium Carbide Fiber-Reinforced Alumina Ceramic Matrix Composites by Self-Propagating High-Temperature Synthesis

  • Yun, Jondo;Bang, Hwancheol
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.171-175
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    • 1998
  • $Al_2O_3$-TiC composites were prepared from aluminum, titanium oxide, and carbon fibers by self-propagating high-temperature synthesis(SHS). After the SHS reaction, the TiC phase in the sample was found either fibrous or non-fibrous shape. The fraction of the fibrous TiC phase varied with the amount of $Al_2O_3$ diluent addition. The optimum amount of diluent to make fibrous carbide was determined to be 30%. The fibers were hollow inside and made of multiple grains with a composition of titanium carbide. The hollow fiber formation mechanism was suggested and discussed. The synthesized powders were consolidated to dense composites by hot pressing at $1750^{\circ}C$ under 30 MPa.

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Investigation into the stability of ion beam treated inorganic alignment layer

  • Kim, Kyung-Chan;Ahn, Han-Jin;Kim, Jong-Bok;Hwang, Byung-Har;Baik, Hong-Koo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.328-329
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    • 2005
  • Inorganic alignment layer (IAL) was deposited on an indium-tin-oxide (ITO) by using reactive sputtering deposition method. After deposited, IAL was irradiated by $Ar^+$ ion beam (IB) for liquid crystal (LC) alignment. IAL treated by various conditions such as IB energy, IB incident angle, and IB irradiation time had excellent alignment property and electro-optical property the same as that of PI. We investigated into the stability of ion beam treated IAL after a lapse of long time. However IAL irradiated IB did not occur degradation of electro-optical property. The results implied that IAL irradiated IB was adopted as LC alignment layer instead of rubbed polyimide.

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Preparation of reflexite collimating film (RCF) by ink-jet technique with organic-inorganic hybrid precursor

  • Hu, Yi;Liu, Jiun-Shing;Lyu, Jhong-Ming;Liu, Tung-Cheng
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1459-1461
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    • 2009
  • In this study, we prepared the multi-refraction film thin by ink-jet technique with sol-gel precursor. The precursors were prepared by using some transition metal alk-oxide and the tetraethylorthosilicate (TEOS) mixed separately with n-Butyl Alcohol and PVB (Poly(vinyl butyral)).The structure and morphology of the resulting films were investigated by atomic force microscope (AFM). It is shown that the shape of the pattern of the films would affect the refraction proportion.

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Preparation and application of gel type polymer electrolyte for PEFC (PEFC 연료전지용 겔 타입 고분자 전해질 합성 및 응용)

  • Lee, Sang-Yong;You, Ji-Yeon;Kim, Han-Joo;Oh, Mee-Hye;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.42-45
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    • 2003
  • Inorganic polymer based hybrid membranes consisting of zirconium oxide and polydimethylsiloxane (PDMS) have been synthesized by sol-gel processes. The hybrid membranes showed thermal stability and flexibility up to $300^{\circ}C$. The membrane becomes proton conducting polymer electrolyte when added with 12-phosphotungstic acid (PWA). The conductivity of the membranes was measured in the temperature range from room temperature to $150^{\circ}C$ under saturated humidity and a maximum conductivity of $5{\times}10^{-5}\;Sm^{-1}$ was obtained at $150^{\circ}C$.

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A Study on the Liquid Crystal Orientation Characteristics of the Inorganic NiOx Film with Aligned Nanopattern Using Imprinting Process (무기막 NiOx의 정렬 패턴 전사를 이용한 액정의 배향 특성 연구)

  • Oh, Byeong-Yun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.5
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    • pp.357-360
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    • 2019
  • We demonstrate an alignment technology using an imprinting process on an inorganic NiOx film. The aligned nanopattern was fabricated on a silicon wafer by laser interference lithography. The aligned nano pattern was then imprinted onto the sol-gel driven NiOx film using an imprinting process at an annealing temperature of $150^{\circ}C$. After the imprinting process, parallel grooves had been formed on the NiOx film. Atomic force microscopy and water contact angle measurements were performed to confirm the parallel groove on the NiOx film. The grooves caused liquid crystal alignment through geometric restriction, similar to grooves formed by the rubbing process on polyimide. The liquid crystal cell exhibited a pretilt angle of $0.2^{\circ}$, which demonstrated homogeneous alignment.

Organic and inorganic carbon-14 in discharges of JSC Institute of Nuclear Materials

  • E.I. Nazarov;A.A. Ekidin;A.V. Kruzhalov;M.E. Vasyanovich;A.I. Lysikov;P.N. Kalinkin;I.M. Russkikh
    • Nuclear Engineering and Technology
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    • v.55 no.6
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    • pp.2107-2111
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    • 2023
  • The aim of the study is the activity concentration measurements of organic and inorganic 14C in the discharges of JSC "Institute of Nuclear Materials" (INM). In INM the research water-water reactor "IVV-2M" is operating. Collecting of 14C species was performed using a 14C sampler with a chromium oxide and platinum catalysts at different temperatures: 400, 550 and 700 ℃. The measurements of 14C activity were performed using a liquid scintillation counter. The share of organic 14C in emissions ranged from 0.30 to 0.84 and depends on the temperature of the catalyst, core structure and reactor operating mode.