• Title/Summary/Keyword: inorganic

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Thin Film Encapsulation with Organic-Inorganic Nano Laminate using Molecular Layer Deposition and Atomic Layer Deposition

  • Yun, Gwan-Hyeok;Jo, Bo-Ram;Bang, Ji-Hong;Seong, Myeong-Mo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.270-270
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    • 2016
  • We fabricated an organic-inorganic nano laminated encapsulation layer using molecular layer deposition (MLD) combined with atomic layer deposition (ALD). The $Al_2O_3$ inorganic layers as an effective single encapsulation layer were deposited at 80 degree C using ALD with alternating surface-saturation reactions of TMA and $H_2O$. A self-assembled organic layers (SAOLs) were fabricated at the same temperature using MLD. MLD and ALD deposition process were performed in the same reaction chamber. The prepared SAOL-$Al_2O_3$ organic-inorganic nano laminate films exhibited good mechanical stability and excellent encapsulation property. The measurement of water vapor transmission rate (WVTR) was performed with Ca test. We controlled thickness-ratio of organic and inorganic layer, and specific ratio showed a lowest WVTR value. Also this encapsulation layer contained very few pin-holes or defects which were linked in whole area by defect test. To apply into real OLEDs panels, we controlled a film stress from tensile to compressive and flexibility defined as an elastic modulus with organic-inorganic ratio. It has shown that OLEDs panel encapsulated with nano laminate layer exhibits better properties than single layer encapsulated in acceleration conditions. These results indicate that the organic-inorganic nano laminate thin films have high potential for flexible display applications.

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Isolation of soybean mutants with high and low inorganic phosphorus

  • Sundaramoorthy, Jagadeesh;Seo, Yean Joo;Park, Gyu Tae;Lee, Jeong-Dong;Park, Soon-Ki;Seo, Hak Soo;Song, Jong Tae
    • Journal of Applied Biological Chemistry
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    • v.59 no.3
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    • pp.261-264
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    • 2016
  • In soybean (Glycine max (L.) Merr.) seeds, phosphorus (P) is primarily stored in the form of phytate, which is generally indigestible by monogastric animals such as human, pig, poultry, and fish. Thus, this study was conducted to isolate soybean mutants with high available P. Inorganic P content was assessed in a total of 1,266 ethyl methanesulfonate (EMS) $M_4$ lines from the Pungsannamul cultivar. Among the tested lines, four EMS lines (PE379, PE432, PE2205, and PE2503) showed higher mean inorganic P ($1.21-1.56gkg^{-1}$) than did the Pungsannamul cultivar ($0.90gkg^{-1}$). Additionally, six EMS lines (PE718, PE828, PE1466, PE1552, PE3378, and PE3386) showed lower mean inorganic P ($0.38-0.60gkg^{-1}$). The high inorganic P mutants isolated in this study will be further investigated for phytate and total P levels. Moreover, the high and low inorganic P lines will be utilized in a future study of the biochemical pathway of phytate.

Evaluation of calcium carbonate scale formation on system design of seawater reverse osmosis plants (해수담수화 시설의 시스템 구성에 따른 $CaCO_3$ 스케일 형성능 진단)

  • Kang, Nam-Wook;Choi, Yang-Hun;Lee, Hye-Ju;Lee, Seock-Heon;Kweon, Ji-Hyang
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.2
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    • pp.143-155
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    • 2010
  • Fouling by inorganic scales needs to be prevented to effectively operate sea water reverse osmosis(SWRO) membrane systems. The extents of inorganic scaling with different array designs including one-pass, two-pass and several hybrid designs were evaluated using seawater from southern sea near the city of Chang-Won. The used methods for evaluation were Stiff and Davis Index(S&DSI) calculation and several laboratory experiments. The formation potential of inorganic scale fouling was quite great under the examined conditions, which was confirmed by the laboratory experimental results. The inorganic scale was not avoidable fouling if any anti-scaling measures were not applied. The RO showed decreased flux under the scale formation conditions. The increases in S&DSI from 1.43 to 5 made small decreases in flux, which indicated that formation of inorganic scales had more substantial effects on RO flux than amount of inorganic scales.

Effect of Precursor Ratio on the Properties of Inorganic-Organic Hybrid TiO2-SiO2 Coating (유무기 TiO2-SiO2 혼성코팅에 미치는 전구체 배합비율의 영향)

  • Kim, Dong Kyu;Maeng, Wan Young
    • Korean Journal of Materials Research
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    • v.26 no.5
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    • pp.271-280
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    • 2016
  • When a single inorganic precursor is used for the synthesis of a sol-gel coating, there is a problem of cracking on the surface of coating layer. In order to solve this problem of surface cracking, we synthesized inorganic-organic coatings that have hybrid properties of inorganic and organic materials. Sols of various ratios (1:0.07, 0.2, 0.41, 0.82, 1.64, 3.26, 6.54, 13.2) of an inorganic precursor of Tetrabutylorthotitanate ($Ti(OBu)_4$, TBOT) and an organic precursor of ${\gamma}$-Methacryloxy propyltrimethoxysilane (MAPTS) were prepared and coated on stainless steels (SUS316L) by dip coating method. The binding structure and the physical properties of the synthesized coatings were analyzed by FT-IR, FE-SEM, FIB (Focused Ion Beam), and a nano-indenter. Dynamic polarization testing and EIS (electrical impedance spectroscopy) were carried out to evaluate the micro-defects and the corrosion properties of the coatings. The prepared coatings show hybrid properties of inorganic oxides and organic materials. Crack free coatings were prepared when the MAPTS ratio was above a critical value. As the MAPTS ratio increased, the thickness and the corrosion resistance increased, and the hardness decreased.

The Responses of a Small Lake Watershed to an Inorganic Carbon Cycle (무기탄소 순환에 대한 소규모 호수 유역의 반응)

  • Cho, Youngil
    • Journal of Korean Society on Water Environment
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    • v.29 no.5
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    • pp.610-617
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    • 2013
  • Investigating the budgets of alkalinity and dissolved inorganic carbon (DIC) in lake water systems is significant for the examination of the behavior of a lake as a sink or a source with respect to the circulation of inorganic carbon chemistry. Budgets of total alkalinity ($Alk_T$) and DIC in Onondaga Lake, which was polluted by chronic calcium (Ca) loading in spite of the closure of soda ash ($Na_2CO_3$) facility, were determined by the analyses of inorganic carbon chemistry in tributary stream channels linked to the lake. AlkT and DIC fluxes of Onondaga Creek and Ninemile Creek occupied 65% and 54%, respectively, as larger tributary streams in comparison with other tributaries as well as different input sources. Budget calculations indicate that 18% of AlkT and 11% of DIC inputs to Onondaga Lake, respectively, remained immobilized in the Lake. This suggests that Ca chronically leached had been precipitated with inorganic carbon or remineralized by secondary mineral formation during the experimental period. In this study, the assumed mass balance calculation in Onondaga Lake with tributary streams resulted in exhibiting that the lake played a role of the sink for the inorganic carbon cycle.

Preparation and Characterization of a Layered Organic-inorganic Composite by the Electrophoretic Deposition of Plate-shaped Al2O3 Particles and Electrophoretic Resin (전기영동적층법을 통한 판상 알루미나 입자와 전기영동 수지의 배향 유무기 복합체 제조 및 물성평가)

  • Park, Hee Jeong;Lim, Hyung Mi;Choi, Sung-Churl;Kim, Younghee
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.460-465
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    • 2013
  • Plate-shaped inorganic particles are coated onto a stainless steel substrate by the electrophoretic deposition of a precursor slurry which includes the inorganic particles of $Al_2O_3$ and polymer resin in mixed solvents to mimic the abalone shell structure, which is a composite of plate-shaped inorganic particles and organic interlayer binding materials with a layered orientation. The process parameters of the electrophoretic deposition include the voltage, coating time, and conductivity of the substrate. In addition, the suspension parameters are the particle size, concentration, viscosity, conductivity, and stability. We prepared an organic-inorganic composite coating with a high inorganic solid content by arraying the plate-shaped $Al_2O_3$ particles and electrophoretic resin via an electrophoretic deposition method. We analyzed the effect of the slurry composition and the electrophoretic deposition process parameters on the physical, mechanical and thermal properties of the coating layer, i.e., the thickness, density, particle orientation, Young's modulus and thermogravimetric analysis results.

Study on the Water Vapor Permeation Properties of the Inorganic Thin Composite Film for the Passivation Layer in the OLED (유기 EL 보호층으로 적용하기 위한 무기 복합 박막의 투습율 특성 연구)

  • 김광호;이주원;김영철;주병권;김재경
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.4
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    • pp.432-438
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    • 2004
  • In this study, we investigated the WVTRs Properties of inorganic thin composite films(ITCFs) to be newly adopted as the passivation layer of the OLED to replace the inorganic compound material Because we thought that inorganic compound materials were limited to enhance the barrier property of thin film. So, ITCFs were fabricated by mixing the cooperated material with the base material. And then, ITCFs were deposited onto the plastic substrate using the electron beam evaporation system and the water vapor transmission rates(WVTRs) were measured using the Mocon equipment. As a result of the WVTR measurement, we could analyze the WVTR values for various ITCFs. ITCFs had a remarkably lower value than the inorganic compound film. Through the analysis of thin film, we can understand the crystal structure and mixed amount. Therefore, ITCFs can be used as the inorganic passivation layers of OLED with the inorganic compound film.

Effect of Retention System on the Characteristics of Floc and Retention (보류 시스템이 Floc 특성과 보류에 미치는 영향)

  • 김용식;원종명
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.3
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    • pp.9-17
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    • 2001
  • The floc characteristics of base paper stock for coating by the retention aid system consisting of polyacrylamide (high molecular weight low charge density, HMLC) and PEI without and with anionic inorganic oxide (IO) were investigated under various shear conditions of MDDA (modified dynamic drainage analyzer). The floc size was increased with cationic electrolytes dosage whatever inorganic oxide is applied or not. The effect of inorganic oxide on the floc size showed the different result between PAM and PEI. The smaller floc was obtained by PAM without inorganic oxide, but larger floc was obtained by PAM with inorganic oxide. However, the effect of shear force was not observed. Floc formation index was decreased by the addition of cationic electrolytes with or without inorganic oxide. Floc formation index had better correlation format formation index than floc size. The relationships between wet web permeability and mat air permeability showed the significant linear correlation ($R^2$=0.97~0.98) for HML PAM and PEI. Floc formation index gave more useful information than the retention measurement when the performance of retention aids is evaluated at the laboratory before applying at the paper mill.

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Enhanced Crystallization of Amorphous Silicon using Electric Field

  • Song, Kyung-Sub;Jun, Seung-Ik;Park, Sang-Hyun;Park, Duck-Kyun
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.06a
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    • pp.243-246
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    • 1997
  • A new technique for low temperature crystallization of amorphous silicon, called field aided lateral crystallization(FALC) was attempted. To demonstrate the concept of FALC, thin layer of nickel(30${\AA}$) was deposited on top of amorphous silicon film and the electric field was applied during the crystallization. The effects of electric field on the crystallization behavior of amorphous silicon film were investigated.

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