• 제목/요약/키워드: inner layer

검색결과 900건 처리시간 0.023초

Corrosion of Fe-9%Cr-1%Mo Steel at 600 and 700℃ in N2/(0.5, 2.5)%H2S-mixed Gas

  • Lee, Dong Bok;Abro, Muhammad Ali;Yadav, Poonam;Bak, Sang Hwan;Shi, Yuke;Kim, Min Jung
    • 한국표면공학회지
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    • 제49권2호
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    • pp.147-151
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    • 2016
  • The T91 steel (Fe-9%Cr-1%Mo) was corroded at 600 and $700^{\circ}C$ for 5 - 70 h in the $N_2$/(0.5, 2.5)%$H_2$Smixed gas at one atm. It was corroded fast, forming the outer FeS layer and the inner (FeS, $FeCr_2O_4$)-mixed layer. The formation of the outer FeS layer facilitated the oxidation of Cr to $FeCr_2O_4$ in the inner layer. Since the nonprotective FeS scale was present over the whole scale, T91 steel displayed poor corrosion resistance.

불균일계에서의 초음파 캐비테이션 물리적 및 화학적 효과 연구 (Sonochemial and Sonophysical Effects in Heterogeneous Systems)

  • 이덕영;손영규
    • 한국물환경학회지
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    • 제35권2호
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    • pp.115-122
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    • 2019
  • The objective of this study was to investigate the sonophysical and sonochemical effects induced by acoustic cavitation in heterogeneous systemin a 28 kHz double-bath reactor using calorimetry, the aluminiumfoil erosion test, and the luminol test. With no glass beads, calorimetric power in the inner vessel increased as much as the outer sonoreactor lost and total calorimetric power was maintained for various liquid height conditions (0.5 ~ 7 cm) in the vessel. Higher calorimetric energy was obtained at higher liquid height conditions. Similar results were obtained when glass beads were placed with various beads heights (0.5 ~ 2.0 cm) and relatively high calorimetric energy was obtained in spite of large attenuation in the glass beads layer. An aluminium foil placed between the bottom of the inner vessel and the glass beads layer was damaged, indicating significant sonophysical effects. Much less damage was detected when the foil was placed above the beads layer due to large attenuation of ultrasound. Sonochemical effects, visualized by sonochemiluminescence (SCL), also decreased significantly when the beads were placed in the vessel. It was established that the optimization of the liquid height above the solid-material layer could enhance the sonophysical and sonochemical effects in the double-bath sonoreactors.

고온 이산화황 환경 내 내열 크롬강에 대한 부식특성 연구 (High Temperature Corrosion Properties of Heat Resistant Chrome Steels in SO2 Atmosphere)

  • 이한상;정진성;김의현
    • 대한금속재료학회지
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    • 제47권2호
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    • pp.99-106
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    • 2009
  • The high temperature corrosion properties of heat resistant steels were investigated in oxidation atmosphere including sulfur dioxide. The heat resistant steels of T22, T92, T122, T347HFG and T304H were evaluated at 620, $670^{\circ}C$ for 400 hours. The corrosion rates showed a decreasing tendency while chrome contents of those steels increased from 2 mass.% to 19 mass.%. The in crease in temperature increasement has an more effect on the corrosion rates of low chrome steels than high chrome steels. The weight gains of T22, T92, T304H at $670^{\circ}C$ were 3.7, 1.65, 1.23 times compared with those at $620^{\circ}C$. The external scale formed on T22 was composed of hematite, magnetite and Fe-Cr spinel and internal layer including iron oxide mixed with sulfide. The scales formed on T92, T122, T304H consisted of an outer layer of hematite and inner layer of chrome oxide and hematite. The proportion of chrome oxide at inner layer was increased when the chrome contents in heat resistant steels were increased.

Comparative Analysis of Histological Changes in Ussurian Bullhead, Leiocassis ussuriensis, and Korean Bullhead, Pseudobagrus fulvidraco, in the Early Period of Growth

  • In Bon, Goo;Hyun Woo, Gil;In-Seok, Park
    • 한국발생생물학회지:발생과생식
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    • 제17권4호
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    • pp.427-434
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    • 2013
  • The histological changes in the Ussurian bullhead, Leiocassis ussuriensis, and the Korean bullhead, Pseudobagrus fulvidraco, were observed during the early period of growth. The retinas size of both species increased in the 9 days post-hatching (DPH) (p<0.05). In the just-hatched Ussurian bullhead, the retina already consisted of six layers: the epithelial layer, ganglion cell layer, inner nuclear layer, inner plexiform layer, outer limiting membrane layer, and rod and cone layer. The Korean bullhead had the same components. At 50 DPH, the thickness of the retina was $538.0{\pm}7.19{\mu}m$ in the Ussurian bullhead and $558.9{\pm}9.44{\mu}m$ in the Korean bullhead. The relative thickness of each layer of the retina did not differ significantly in the two species. Although the growth of the Korean bullhead's retina was faster, the relative thickness of each layer in the retina did not change during early development. After hatching, some parts of the tissue gradually became denser. Immediately after hatching, the kidney and midgut epithelium of the Ussurian bullhead and Korean bullhead were already formed and grew gradually thereafter. From 0 DPH to 30 DPH, the nuclear height in the midgut epithelium did not differ significantly between the two species, but at 50 DPH, it was $11.4{\pm}2.45{\mu}m$ in the Korean bullhead and $9.9{\pm}2.13{\mu}m$ in the Ussurian bullhead. During the experimental period, the major axes, minor axes, surface areas, and volumes of the proximal tubule cells in the kidney did not differ significantly between the two species. Thus, the early histological development of the Ussurian bullhead is similar to that of the Korean bullhead.

Biphasic Release Characteristics of Dual Drug-loaded Alginate Beads

  • Lee, Beom-Jin;Cui, Jing-Hao;Kim, Tae-Wan;Heo, Min-Young;Kim, Chong-Kook
    • Archives of Pharmacal Research
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    • 제21권6호
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    • pp.645-650
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    • 1998
  • The dual drug-loaded alginate beads simultaneously containing drug in inner and outer layers were prepared by dropping plain (single-layered) alginate beads into $CaCl_2$ solution. The release characteristics were evaluated in simulated gastric fluid for 2 h followed by intestinal fluids thereafter for 12 h. The surface morphology and cross section of dual drug-loaded alginate beads was also investigated using scanning electron microscope (SEM). The poorlv water-soluble ibuprofen was chosen as a model drug. The surface of single-layered and dual drug-loaded alginate beads showed very crude and roughness, showing aggregated particles, surface cracks and rough crystals. The thickness of dual drug-loaded alginate beads surrounded by outer layer was ranged from about 57 to 329mcm. The distinct chasm between inner and outer layers was also observed. In case of single-layered alginate bead, the drug was not released in gastric fluid but was largely released in intestinal fluid. However, the release rate decreased as the reinforcing $Eudragit^{\circledR}$ polymer contents increased. When the plasticizers were added into polymer, the release rate largely decreased. The release rate of dual drug-loaded alginate beads was stable in gastric fluid for 2 h but largely increased when switched in intestinal fluid. The drug linearly released for 4 h followed by another linear release thereafter, showing a distinct biphasic release characteristics. There was a difference in the release profiles between single-layered and dual drug-loaded alginate beads due to their structural shape. However, this biphasic release profiles were modified by varying formulation compositions of inner and outer layer of alginate beads. The release rate of dual drug-loaded alginate beads slightly decreased when the outer layer was reinforced with $Eudragit^{\circledR}$ RS1OO polymers. In case of dual drug-loaded alginate beads with polymer-reinforced outer layer only, the initial amount of druc released was low but the initial release rate (slope) was higher due to more swellable inner cores when compared to polymer-reinforced inner cores. The current dual drug-loaded alginate beads may be used to deliver the drugs in a time dependent manner.

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진동만의 빈산소수괴 형성기구 (Mechanism of Oxygen-Deficient Water Formation in Jindong Bay)

  • 김동선;김상우
    • 한국해양학회지:바다
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    • 제8권2호
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    • pp.177-186
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    • 2003
  • 하계 진동만 저층수의 저산소화에 미치는 성층 및 바람의 효과를 고려한 수평 및연직 유동성분의 영향을 조사하여 내만역에서의 빈산소수괴 형성기구를 밝혔다. 진동만에서 수온, 염분, 용존산소 및 풍향, 풍속은 1998년 3월부터 1999년 2월 사이에 조사하였다 저층수에서 5 이하의 낮은 용존산소농도가 5월에서 9월에 걸쳐 존재하였으며, 표층수의 고온·저염화에 따라 강한 약층이 형성되어 연직기울기는 매우 크게 나타난 하계(7∼8월)에 3 이하의 극히 낮은 용존산소농도가 출현하였다. 이와 같은 저농도의 용존산소는 특히 만 안쪽 정점에서 춘계(5∼6월)에도 관찰되었다. 또한, 하계(8∼9월)에 5 이하의 낮은 용존산소농도를 가지는 저층수가 약 4∼6 m 수층까지 표층쪽으로 부상하는 특징적인 현상이 나타났다 여름철 진동만에서 바람의 효과를 고려한 잔차류의 연직성분을 살펴보면, 이 지역에서 우세한 북풍이나 서풍계열의 바람에 의해서 만 바깥쪽을 하강류역이, 만 안쪽은 상승류역이 발생한다. 또한, 하강류역인 만 바깥쪽에서 만 안쪽으로 향하는 저층류가 발달하였는데, 이것은 표층으로부터 침강된 유기물질의 만 안쪽으로의 유입을 초래할 수 있을 것으로 기대된다. 한편 말 안쪽에서 나타나는 상승류의 존재가 만 안쪽에서 형성된 저층의 빈산소수를 표층 근처까지 부상하게 하는 역할을 하는 것으로 보인다.

다구찌 실험계획법을 이용한 소구경화기 총열 내부용 Cr-Mo-V강의 질화공정 최적화 (Optimization of Inner Nitriding Process for Cr-Mo-V Steel of Small Arms Barrel by using Taguchi Experimental Design Method)

  • 권혁린;김동은;손형동;신재원;박재하;강명창
    • 한국기계가공학회지
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    • 제17권3호
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    • pp.148-154
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    • 2018
  • When shooting small arms, the inner surface temperature is heated up to about $700{\sim}1,000^{\circ}C$ by the friction of the bullet and the inner wall of the barrel and the combustion of propellant. High-temperature propellant gas and high-speed movement of the bullet cause corrosion of the inner wall, which is noticeable immediately in front of the chamber. In this study, the mechanical properties of Cr-Mo-V steel, which is the base material, were tested using Taguchi experimental design to find the best nitriding treatment conditions. For the nitriding process, the working time, salt bath temperature, and salt concentration were combined as three conditions and placed in the $L_9(3^4)$, orthogonal array table. The thicknesses of the white layer and the nitrogen diffusion layer were measured after nitriding under each condition in a salt bath furnace. Durability was evaluated by measuring the degree of dispersion through actual shooting because it was difficult to evaluate the mechanical properties of the cylinder inner structure. As a result, it was confirmed that the durability was optimal at $565^{\circ}C$, 1 hour, 0.5%. These optimal conditions were selected by the statistical analysis of the Minitab program(ver.17).

Localization of cytoskeletal proteins in Pneumocystis carinii by immuno-electron microscopy

  • Yu, Jae-Ran;Pyon, Jae-Kyong;Seo, Min;Jung, Byung-Suk;Cho, Sang-Rock;Lee, Soon-Hyung;Hong, Sung-Tae
    • Parasites, Hosts and Diseases
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    • 제39권1호
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    • pp.13-21
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    • 2001
  • Pneumocystis carinii causes serious pulmonary infection in immuno-suppressed patients. This study was undertaken to observe the cytoskeletal proteins of P. carinii by immune-electron microscopy. P. carinii infection was experimentally induced by immunosuppression of Sprague-Dawley rats for seven weeks, and their lungs were used for the observations of this study. The gold particles localized actin, tropomyosin, and tubulin. The actin was irregularly scattered in the cytoplasm of the trophic forms but was much more concentrated in the inner space of the cell wall of the cystic forms called the inner electron-lucent layer No significant amount of tropomyosin was observed in either trophic forms or cystic forms. The tubulin was distributed along the peripheral cytoplasm and filopodia of both the trophic and cystic forms rather than in the inner side of the cytoplasm. Particularly, in the cystic forms, the amount of tubulin was increased and located mainly in the inner electron-lucent layer of the cell wall where the actin was concentrated as well. The results of this study showed that the cell wall of P carinii cystic forms is a structure whose inner side is rich in actin and tubulin. The location of the actin and tubulin in P. carinii suggests that the main role of these proteins is an involvement in the protection of cystic forms from the outside environment by maintaining rigidity of the cystic forms.

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가막만 빈산소 수괴의 특성 (The Characteristics of Oxygen Deficient Water Mass in Gamak Bay)

  • 김정배;이상용;유준;최양호;정창수;이필용
    • 한국해양환경ㆍ에너지학회지
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    • 제9권4호
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    • pp.216-224
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    • 2006
  • 하계 가막만에서 발생하는 빈산소 수괴의 형성과정과 그 특성을 규명하기 위하여 2005년 6월 17일부터 2005년 9월 12일까지 주 간격으로 조사하였다. 표층 수온은 내만에서 만 입구로 갈수록 낮았으나, 저층 수온은 만 입구와 내만보다 만 중앙에서 높게 나타났다. 수괴의 수직적인 성층은 매우 발달하였으며, 수온약층은 수심 3-5m에서 관측되었다. 저층의 빈산소 수괴는 7월초에 내만 안쪽에서 나타났으며, 8월초에는 만 중앙부까지 확산되었다. 수괴의 평균투명도와 광소멸 계수($K_d$)는 각각 4.0m와 0.47로 나타났다. 저층의 영양염과 클로로필 ${\alpha}$ 농도는 표층보다 유의하게 높았으며, 만 입구보다 내만에서 높게 나타났다. 빈산소 수괴의 저층에서 퇴적물의 산소투과 깊이는 지극히 낮았으며, 산소소모율은 빈산소가 소멸된 수괴에서 보다 낮았다. 빈산소 수괴가 발생하는 기간동안 용존 산소 농도는 저층의 영양염 농도와 유의한 역 상관관계를 보였으나, 표층 영양염 농도와는 유의한 관계를 보이지 않았다. 저층에서 산소 감소의 촉진은 퇴적물에서 산소소모율 증가와 저층 부근에서 미생물에 의한 유기물 분해 때문인 것으로 판단되었다.

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The influences of film density on hydration of MgO protective layer in plasma display panel

  • Lee, Jung-Heon;Eun, Jae-Hwan;Park, Sun-Young;Kim, Soo-Gil;Kim, Hyeong-Joon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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    • pp.228-231
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    • 2002
  • We report the effect of density of thin films on moisture adsorption and hydration of MgO thin film, usually used as a protective layer in AC-PDP After hydration, lots of hemispherical shaped clusters, $Mg(OH)_2$, formed on the surface of MgO thin films. However clusters formed on low-density thin films were bigger than those on high-density films. From ERD spectra, it seemed that the concentration of hydrogen was very high in the region 20 nm from the surface of MgO thin film. The low-density thin film had more hydrogen than high-density thin film. From simulation results of ERD and RBS it was found that hydration reaction also occurred in the inner part of the film. So diffusion of Mg atoms from the inner part of the film to the surface and $H_2O$ molecules from the surface to the inner part of the film is important. And because low density thin film has many short paths for diffusion of Mg atoms and $H_2O$ molecules, low-density thin film is more hydrated. So to suppress hydration of MgO thin films, high-density thin film is needed.

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