• Title/Summary/Keyword: injection efficiency

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Fabrication and Characterization of Dye-sensitized Solar Cells based on Anodic Titanium Oxide Nanotube Arrays Sensitized with Heteroleptic Ruthenium Dyes

  • Shen, Chien-Hung;Chang, Yu-Cheng;Wu, Po-Ting;Diau, Eric Wei-Guang
    • Rapid Communication in Photoscience
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    • v.3 no.1
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    • pp.16-19
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    • 2014
  • Anodic self-organized titania nanotube (TNT) arrays have a great potential as efficient electron-transport materials for dye-sensitized solar cells (DSSC). Herewith we report the photovoltaic and kinetic investigations for a series of heteroleptic ruthenium complexes (RD16-RD18) sensitized on TNT films for DSSC applications. We found that the RD16 device had an enhanced short-circuit current density ($J_{SC}/mAcm^{-2}=15.0$) and an efficiency of power conversion (${\eta}=7.2%$) greater than that of a N719 device (${\eta}=7.1%$) due to the increasing light-harvesting and the broadened spectral features with thiophene-based ligands. However, the device made of RD17 (adding one more hexyl chain) showed smaller $J_{SC}(14.1mAcm^{-2})$ and poorer ${\eta}(6.8%)$ compare to those of RD16 due to smaller amount of dye-loading and less efficient electron injection for the RD17 device than for the RD16 device. For the RD18 dye (adding one more thiophene unit and one more hexyl chain), we found that the device showed even lower $J_{SC}(13.2mAcm^{-2}) $ that led to a poorest device performance (${\eta}=6.2%$) for the RD18 device. These results are against to those obtained from the same dyes sensitized on $TiO_2$ nanoparticle films and they can be rationalized according to the electron transport kinetics measured using the methods of charge extraction and transient photovoltage decays.

Removal of Total Organic Carbon and Micropollutants in Tertiary Treated Sewage by Medium Pressure UV/H2O2 (중압 자외선과 과산화수소 공정을 이용한 하수 3차 처리수중 총유기탄소와 미량오염물질 제거)

  • Lee, Jai-Yeop;Kim, Ilho
    • Journal of Korean Society on Water Environment
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    • v.36 no.4
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    • pp.314-321
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    • 2020
  • This study evaluated the applicability of UV-AOP process using medium-pressure UV lamp and H2O2 to remove TOC and emerging micropollutants in the effluent from a sewage treatment plant. The UV lamp with higher output(1.6~8.0 kW) showed slightly higher amount of power in removing TOC of 1 mg/L(0.09 kWh/mg/L~0.11 kWh/mg/L), however it was found that there was no significant difference for each cases. In addition, under the condition that the H2O2 concentration is sufficient, as the power consumption of the UV lamp increases, the unit TOC removal concentration per unit H2O2 decomposition concentration also increases, resulting in effective removal of TOC. The removal rate of 7 new trace contaminants, such as antibiotics by the UV-AOP tested, was at least 89.4%, and the ability to remove the emerging micro pollutants in the process was very effective. But, it was judged that it could not be excluded that the probablity of transforming to oxidated by-product in the case of a low TOC removal efficiency. Depending on the operating conditions of the UV and H2O2 processes, a higher BOD concentration is found in the treated water than in the influent, and it is necessary to review the UV power and proper injection conditions of H2O2 to maintain the BOD concentration increase below a certain level.

A Review Study in Treatment for Anxiety Disorder in Traditional Chinese Medicine (불안장애 치료에 관한 최근 임상연구 동향)

  • Lee, Seung-Hwan;Kang, Min-Jeong;Lim, Jung-Hwa;Seong, Woo-Yong
    • Journal of Oriental Neuropsychiatry
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    • v.23 no.2
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    • pp.1-12
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    • 2012
  • Objectives : This study is set out to discover more about the treatment of anxiety disorder in Traditional Chinese Medicine. Methods : We searched the database-China Academic Journals(CAJ). For papers published since 2007-2011, which are classified in categories. Results : We have finally selected 23 articles, and the results were as follows: 1. Stages of Anxiety disorder are discussed in various aspects. 2. Diagnostic criteria and evaluation criteria were the same, especially, in the CCMD and HAMA was used most frequently. Adverse effects were reported using TESS. 3. There are various ways, such as Herbal medicine, acupuncture, electroacupuncture stimulation, acupoints injection, and abdominal massage therapy to treat Anxiety disorders in TCM. 4. Zizyphus jujuba, Poligala tenuifolia, Poria cocos are mainly used in herbal medicine. Sinmun(HT7), Sameumgyo(SP6), Naegwan(PC6) are mainly used in acupuncture points. 5. The treatment group, cured by herbal medicine or acupuncture, was similar in its therapeutic efficiency to that of the control group, which was cured by western medicine. In some cases, the treatment group was better off than the control group. Herbal medicines have been reported that they have less side effects and drug addiction than the western medicines. We predict that herbal medicine in the treatment for anxiety disorders will have an advantage. Conclusions : There are a wide range of approaches in the treatments for Anxiety disorders in TCM. In some aspects, herbal medicine is more effective than that of the western medicine. According to this study, we predict that herbal medicine in the treatment for anxiety disorders, has some advantage. Therefore, there is a need for more clinical research for this disorder in Korean traditional medicine.

Effect of Electrical Preactivation of Recipient Cytoplasm on In Vitro Development in Nuclear Transplant Rabbit Embryos (수핵란의 전활성화가 토끼 핵이식 수정란의 체외발달에 미치는 효과)

  • 전병균;송상현;정기화;곽대오;이효종;최상용;박충생
    • Korean Journal of Animal Reproduction
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    • v.21 no.3
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    • pp.219-228
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    • 1997
  • To examine the efficiency of nuclear transplantation the influence of electrical preactivation of recipient cytoplasm on the in vitro developmental potentyl in the nuclear transplant rabbit embryos were evaluated. The embryos of 16-cell stage were collected and synchronized to G1 phase of 32-cell stage. The recipient cytoplasms were obtained by removing the first polar body and chromosome mass by non-disruptive microsurgery procedure. The separated G1 phase blastomeres of 32-cell stage were put into the non-preactivated and/or the preactivated recipient cytoplasm by electrical stimulation. After culture until 20h post-hCG injection, the nuclear transplant oocytes were electrofused. The fused nuclear transplant embryos were co-cultured with rabbit oviduct epithelial cells and monitored every 24h to assess for developmental rate. After in vitro culture for 120h, the nuclear transplant embryos developed to blastocyst stage were stained with Hoechst 33342 and their blastomere were counted. The electrofusion rate was similar to the non-preactivated and preactivated recipient cytoplasm(81.8 and 85.7%, respectively). However, the in vitro developmental rate to blastocyst stage with the non-preactivated recipient cytoplasm (57.1%) was found significantly (P<0.05) higher, compared to the preactivated recipient cytoplasm(20.8%). The cell counts of nuclear transplant embryos developed to blastosyst stage were increased significantly (P<0.05) more in the non-preactivated recipient cytoplasm (163.7 cells), as compared with the preactivated recipient cytoplasm(85.4 cells). These results considered better that non-preactivated oocytes, MII phase oocytes, were used for recipient cytoplasms in the rabbit nuclear transplant procedure.

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Degasser for Products Produced Using Research to Improve the Quality (제품생산 시 탈가스 장치를 이용한 품질향상에 관한 연구)

  • Kang, Seog Joo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.8
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    • pp.4713-4716
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    • 2014
  • Several methods that have been used to manage a degasing process in recent years, such as an injection method that uses aluminum molten metal powder and chemicals, and the input method that supplies argon and nitrogen, or chlorine gas using a gas blow-tube. On the other hand, these methods have some problems, and it is a difficult process to handle pollution due to the production of considerable toxic gases, such as chlorine and fluoride gas, irregular effects, and lowering work efficiency due to the excessive processing time. The problems that are most fatal are the production of considerable sludge due to a reaction of aluminum molten metal with chemicals, loss of metals, and the decreasing life of refractory materials. To solve these problems, this study developed a technology that is related to continuous casting of molten aluminum metal and monolithic degasing apparatus.

Influential Factors for NO_X Reduction Performance of Urea-SCR System for an In-use Medium Duty Diesel Engine (중형 운행 경유차용 Urea-SCR 시스템의 아랫첨자 $NO_X$ 저감성능에 미치는 영향인자)

  • Kim, Hong-Suk;Jeong, Young-Il;Song, Myoung-Ho;Lee, Seang-Wock;Park, Hyun-Dae;Hwang, Jae-Won
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.1
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    • pp.154-161
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    • 2009
  • This study is a part of project of urea-SCR system development for an in-use medium duty diesel engine. This study shows the effect of ammonia oxidation catalyst and SCR volume on $NO_X$ reduction performance. When AOC(Ammonia Oxidation Catalyst) is not used, the urea injection should be controlled accurately to prevent $NH_3$ slip. However, it is found that the accurate $NH_3$ slip control is not easy without AOC in real engine operating conditions, because $NH_3$ and $NO_X$ reaction characteristics change with many factors such as exhaust gas temperature and $NH_3$ absorbance on SCR. SCR volume is also one of important design parameters. This study shows that $NO_X$ reduction efficiency increases with increase of SCR volume especially at high space velocity and low exhaust gas temperature conditions. Additionally, this paper shows the emissions of EURO-2 medium duty diesel engine can be improved to the level of EURO-5 with a DPF and urea-SCR system.

Human Safety of rbST Contained in Milk (우유중 함유된 rbST의 인체에 대한 안전성)

  • 송지용
    • Proceedings of the Korean Society of Food Hygiene and Safety Conference
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    • 1994.12a
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    • pp.15-26
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    • 1994
  • Bovine somatotropin(bST) or bovine growth hormone (bGH) is a protein of 191 amino acids produced by the anterior pituitary gland of cattle. Recombinant bovine somatotropin(rbST) is biosynthetic versions of the naturally occurring pituitary hormone in cows. The use of rbST in dairy cows promises to improve the efficiency of milk production around the world. Using recombinant DNA technology, bST can now be produced in commercial quantities. The recombinant bST(rbST) is biologically identical to the found in the bovine pituitary. Milk from rbST-treated cows has been found to have the same nutritional value and composition as milk from untreated cows. In November of 1993, rbST finally was approved by the FDA, nearly 10 years after filing a licence applica-tion. rbST has been one of the most extensively studied animal drug products to be reviewed by the agency. Three scientific facts will help to reassure the public about the safety of the milk suppy.: 1. rbST has no biological activity in humans when indigested orally or when given by intramuscular injection. 2. Insulin-like growth factor 1(IGF-1) is not orally active. Any changes in IGF-1 levels in milk are well within normal variation and are lower than those reported in human milk. 3. All cow's milk contains bST, and no significant change in bST levels in milk occurs as a result of giving cows supplemental bST. Based on the scientific evidence, the public can be confident that milk and meat from rbST-treated cows is safe to consumers.

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Study on Autotrophic Denitrification by the Injection of Spent Sulfidic Caustic in a Hybrid Bardenpho Process (Hybrid Bardenpho 공정에서 Spent Sulfidic Caustic의 주입을 통한 독립영양 탈질에 관한 연구)

  • Lee, Jae-Ho;Park, So-Ra;Park, Jeung-Jin;Byun, Im-Gyu;Park, Tae-Joo
    • Journal of Korean Society on Water Environment
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    • v.24 no.5
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    • pp.563-568
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    • 2008
  • In petroleum refining industry, caustic (NaOH) solution is used to remove $H_2S$ from hydrocarbon streams in naphtha cracking process. Once $H_2S$ is absorbed in caustic solution, the solution becomes known as spent sulfidic caustic (SSC), which contains high concentrations of hydrogen sulfide and alkalinity. This study was focused on the evaluation of autotrophic denitrification by SSC in a hybrid Bardenpho process. SSC was injected to the anoxic (1) and anoxic (2) tank at different S/N ratio. In a previous lab-scale study, as we operated a modified Ludzack-Ettinger process, it was observed that the COD increment of effluent and nitrification failure happened because of non-biodegradable matters in SSC and high pH, respectively. Thus cilia media was packed at 2.4%(v/v) in all aerobic tanks and the pH of SSC was neutralized from 13.3 to 11.5 with addition of sulphuric acid ($H_2SO_4$). Consequently, these strategies were successful because no COD increment of effluent was observed and nitrification failure did not happen. The maximum TN removal efficiency was 77.5% when SSC was injected to both the anoxic (1) and anoxic (2) tanks. The mean TN concentration of effluent in this condition was 5.8 mg/L.

Design of 77 GHz Radar Transmitter Using 13 GHz CMOS Frequency Synthesizer and Multiplier (13 GHz CMOS 주파수 합성기와 체배기를 이용한 77 GHz 레이더 송신기 설계)

  • Song, Ui-Jong;Kang, Hyun-Sang;Choi, Kyu-Jin;Cui, Chenglin;Kim, Seong-Kyun;Kim, Byung-Sung
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.23 no.11
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    • pp.1297-1306
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    • 2012
  • This work presents a 77 GHz radar transmitter for the automotive radar system. An integrated 13 GHz frequency synthesizer fabricated using 130 nm RF CMOS process drives a commercial W-band compound semiconductor monolithic multifunction amplifier(MPA), which includes a frequency multiplier by six to generate 77 GHz transmitting signal. The 13 GHz frequency synthesizer includes a high efficiency injection buffer of 4 dBm output power to drive the MPA. The output power of 77 GHz radar transmitter is higher than 13.99 dBm and the magnitude of the reference spur relative to the carrier is -36.45 dBc. The phase noise is -81 dBc/Hz at 1 MHz offset frequency from the carrier.

Orange Phosphorescent Organic Light-emitting Diodes Using a Spirobenzofluorene-type Phospine Oxides as Host Materials

  • Jeon, Young-Min;Lee, In-Ho;Lee, Chil-Won;Lee, Jun-Yeob;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2955-2960
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    • 2010
  • Spiro-type orange phosphorescent host materials, 9-diphenylphosphine oxide-spiro[fluorene-7,9'-benzofluorene] (OPH-1P) and 5-diphenylphosphine oxide-spiro[fluorene-7,9'-benzofluorene] (OPH-2P) were successfully prepared by a lithiation reaction followed by a phosphination reaction with diphenylphosphinic chloride. The EL characteristics of OPH-1P and OPH-2P as orange host materials doped with iridium(III) bis(2-phenylquinoline)acetylacetonate ($Ir(pq)_2acac$) were evaluated. The electroluminescence spectra of the ITO (150 nm)/DNTPD (60 nm)/NPB (30 nm)/OPH-1P or OPH-2P: $Ir(pq)_2acac$ (30 nm)/BCP (5 nm)/$Alq_3$ (20 nm)/LiF (1 nm)/Al (200 nm) devices show a narrow emission band with a full width at half maximum of 75 nm and $\lambda_{max}$ = 596 nm. The device obtained from OPH-1P doped with 3% $Ir(pq)_2acac$ showed an orange color purity of (0.580, 0.385) and an efficiency of (14 cd/A at 7.0 V). The ability of the OPH-P series to combine a high triple energy with a low operating voltage is attributed to the inductive effect of the P=O moieties and subsequent energy lowering of the LUMO, resulting in the enhancement of both the electron injection and transport in the device. The overall result is a device with an EQE > 8% at high brightness, but operating voltage of less than 6.4 V, as compared to the literature voltages of ~10 V.