• Title/Summary/Keyword: initial state

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Synthesis of polymer - based inverted opal and transformation of its optical properties

  • Masalov, Vladimir M.;Dolganov, Pavel V.;Sukhinina, Nadezhda S.;Dolganov, Vladimir K.;Emelchenko, Gennadi A.
    • Advances in nano research
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    • v.2 no.1
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    • pp.69-76
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    • 2014
  • We have obtained opal-like photonic crystals based on opals and inverted opals exhibiting a shift of the selective reflection band toward longer and shorter wavelengths with respect to the diffraction band of the initial opal consisting of $SiO_2$ spheres. The contribution of frames forming three-dimensional periodic structures and that of fillers to the spectral arrangement of the diffraction bands has been determined.

Biochemical Characterization of the Dual Positional Specific Maize Lipoxygenase and the Dependence of Lagging and Initial Burst Phenomenon on pH, Substrate, and Detergent during Pre-steady State Kinetics

  • Cho, Kyoung-Won;Jang, Sung-Kuk;Huon, Thavrak;Park, Sang-Wook;Han, Ok-Soo
    • BMB Reports
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    • v.40 no.1
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    • pp.100-106
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    • 2007
  • The wound-inducible lipoxygenase obtained from maize is one of the nontraditional lipoxygenases that possess dual positional specificity. In this paper, we provide our results on the determination and comparison of the kinetic constants of the maize lipoxygenase, with or without detergents in the steady state, and characterization of the dependence of the kinetic lag phase or initial burst, on pH, substrate, and detergent in the pre-steady state of the lipoxygenase reaction. The oxidation of linoleic acid showed a typical lag phase in the pre-steady state of the lipoxygenase reaction at pH 7.5 in the presence of 0.25% Tween-20 detergent. The reciprocal correlation between the induction period and the enzyme level indicated that this lag phenomenon was attributable to the slow oxidative activation of Fe (II) to Fe (III) at the active site of the enzyme as observed in other lipoxygenase reactions. Contrary to the lagging phenomenon observed at pH 7.5 in the presence of Tween-20, a unique initial burst was observed at pH 6.2 in the absence of detergents. To our knowledge, the initial burst in the oxidation of linoleic acid at pH 6.2 is the first observation in the lipoxygenase reaction. Kinetic constants (Km and kcat values) were largely dependent on the presence of detergent. An inverse correlation of the initial burst period with enzyme levels and interpretations on kinetic constants suggested that the observed initial burst in the oxidation of linoleic acid could be due to the availability of free fatty acids as substrates for binding with the lipoxygenase enzyme.

Study on characteristics of initial rock stress state at shallow depth of the gneiss region in the central part of seoul (서울 중심부 편마암 분포지역 저심도 구간의 암반 초기응력 분포특성 연구)

  • Bae, Seong-ho;Jeon, Seok-won;Choi, Yong-Kun;Kim, Jae-min
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.5 no.2
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    • pp.147-159
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    • 2003
  • Since early in the 90's, as the need for construction of underground rock structures has been largely increased, the in-situ rock stress measurement has been widely carried out to provide the quantitative information on the initial stress state of test site at the design stage of underground rock structures. Among the diverse method developed for measuring rock stress, hydraulic fracturing method is most popularly used because it is applicable at pre-construction stage and has no limit in testing depth. In this paper a study on initial rock stress state at shallow depth of the plain gneiss region in the central part of Seoul was performed on the basis of the in-situ hydraulic fracturing stress measurement results from the 11 test boreholes. And overall characteristics of the initial stress field of the study area are discussed.

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Rigorous dynamic simulation and determination of initial operating conditions for two-bed PSA processes (두 탑 PSA공정의 상세 동적모사 및 초기운전조건 결정)

  • Hwang, Deok-Jae;Moon, Il
    • 제어로봇시스템학회:학술대회논문집
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    • 1997.10a
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    • pp.1520-1523
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    • 1997
  • A rigorous dynamic simulation was performed in binary gas mixture H$_{2}$/CO (70:30 vol.%) to determinate start-up operating conditions of PSA(Pressure Swing Adsorption) processes. The rigorous dynamic model for the PSA process contains an Ergun equation for expressing the pressure drop in a bed, and valve equations to compute the boundary pressure change of the bed. As the result of the continuous dynamic simulation of 100 operating cyles in various initial conditions, the unsteady-state appeared in the early period and the cyclic steady-state came out about 20th cycle in feed condition and vaccum condition, and 30th cycle in pure H$_{2}$ condition. As time goes by valve equations made change the pressure at each end of the bed in ressurization, countercurrunt-depressurization and pressure equalization steps. The H$_{2}$ purity and the recovery is 99.99% and 86.73% respectively, which is slightly higher than the experimental data. Main contributiion of this study includes supplying fundamental technologies of handling combined variables PSA processes by developing rigorous models.

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Initial Sintering Behaviour of the Powder Injection Molded W-15wt%Cu Nanocomposite Powder (분말사출성형한 W-l5wt%Cu 나노복합분말의 초기소결거동)

  • 윤의식;유지훈;이재성
    • Journal of Powder Materials
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    • v.5 no.4
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    • pp.258-264
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    • 1998
  • The initial sintering behaviour of the powder injection molded (PIMed) W-l5wt%Cu nanocomposite powder was investigated. The W-Cu nanocomposite powder was produced by the mechanochemical process consisting of high energy ball-milling and hydrogen reduction of W blue powder-CuO mixture. Solid state sintering of the powder compacts was conducted at $1050^{\circ}C$ for 2~10 hours in hydrogen at mosphere. The sintering behaviour was examined and discussed in terms of microstructural developments such as W-Cu aggregate formation, pore size distribution and W grain growth. The volume shrinkage of PIM specimen was slightly larger than that of PM(conventional PM specimen), being due to fast local densification in the PIM. Remarkable decrease of carbon and oxygen in the PIM enhanced local densification in the early stage of solid state sintering process with eliminating very fine pores less than 10 nm. In addition, such local densiflcation in the PIM is presumably responsible for mitigating of W-grain growth in the initial stage.

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EFFCTS OF TILLAGE SYSTEMS ON THE QUALITY OF RUNOFF FROM SLUDGE-AMENDED SOILS

  • Mostaghimi, Saied;Bruggeman, Adriana C.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 1993.10a
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    • pp.984-993
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    • 1993
  • land application of sewage sludge requires careful monitoring because of its potential for contamination of surface water and groundwater. A rainfall simulator was used to investigated the effects of freshly applied sludge on runoff of sediment and nutrients from agricultural crop lands. Rain was applied to 16 experimental field plots. A three run sequence was used to simulate different initial moisture conditions. Runoff, sediment and nutrient losses were monitored at the base of each plot during the simulated rainfall events. Sludge was surface applied and incorporated at conventionally -tilled plots and surface applied at no-till plots, at rates of 0, 75, 150 kg-N/ha. No-till practices greatly reduced runoff, sediment , and nutrient losses form the sludge treated plots, relative to the conventional tillage practices. Incorporation of the sludge was effective in reducing nutrient yields at the conventionally-tilled plots. This effect was more pronounced during the third rain torm, with wet initial conditions. Peak loadings of nutrients appeared during the rainstorm with wet initial conditions.

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Analysis of the two dimensional sheet debris flight equations: initial and final state

  • Scarabino, A.;Giacopinelli, P.
    • Wind and Structures
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    • v.13 no.2
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    • pp.109-125
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    • 2010
  • This work presents some analytical and numerical results of a dynamic analysis of the dimensionless 2-D sheet flight equations. Two empirical models for aerodynamic forces and moments are used and compared. Results show that the initial condition of rest is always unstable, and for long times three distinct flight regimes are possible, depending on the initial angle of attack, the Tachikawa number, Ta (in fact, the parameter chosen was its inverse, ${\Omega}$), and a mass ratio ${\Phi}$. The final orbits in the velocity space and their maximum kinetic energy are compared with a theoretical asymptotic state of the motion equations, and some design considerations are proposed.

Production of Red Pigments by Monascus purpureus in Solid-state Culture

  • Lee Bum-Kyu;Piao Hai Yan;Chung Wook-Jin
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.7 no.1
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    • pp.21-25
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    • 2002
  • To maximize and sustain the productivity of Monascus pigments, various environmental and nutritional parameters, such as the initial moisture content, pH, inoculum size, sample size, and nutrient supplement, that influence pigment production were evaluated in solid-state cultures as follows: initial moisture content, $50\%;$ pH, 6.0; inoculum size $1\;\times\;10^4$ spore cells $(grams\;of\;dry\;solid\;substrate)^{-1};$ sample size, 300 g. All supplementary nutrients (carbon, nitrogen, and mineral sources) added has inhibitory effects on the cell growth and red pigment production. In open tray culture the maximum biomass yield and specific productivity of red pigments were 223 mg DCW $(grams\;of\;initial\;dry\;substrate)^{-1}$ and, $47.6\;OD_{500}\;(DCW\;grams)^{-1}h^h{-1}$ respectively.

A Numerical Study of Initial Unsteady Flow and Mixed Convection in an Enclosed Cavity Using the PISO Algorithm (PISO 알고리즘을 이용한 밀폐공간내에서의 유동 및 혼합대류에 관한 연구)

  • Choi, Y.G.;Chung, J.Y.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.2 no.1
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    • pp.63-73
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    • 1990
  • A numerical analysis of initial unsteady state flow and heat transfer in an enclosed cavity has been performed by the Modified QUICK Scheme. The stable QUICK Scheme which modified the coefficient always to be positive is included in this numerical analysis. The implicit method is applied to solve the unsteady state flow; between iterations the PISO (Pressure - Implicit with Splitting of Operators) algorithm is employed to correct and update the velocity and pressure fields on a staggered grid. The accuracy of the Modified QUICK Scheme is proved by applying fewer grid systems than those which Ghia et al. and Davis applied. The initial unsteady mixed convection in an enclosed cavity is analyzed using the above numerical procedure. This study focuses on the development of the large main vortex and secondary vortex in forced convection, the effects of the Rayleigh Number in natural convection and the relative direction of the forced and natural convection.

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Ultimate torsional strength of cracked stiffened box girders with a large deck opening

  • Ao, Lei;Wang, De-Yu
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.8 no.4
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    • pp.360-374
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    • 2016
  • The present paper studies the ultimate torsional strength of stiffened box girders with large deck opening due to the influence of cracks. Three types of hull girders with different spans are provided for comparison. Potential parameters which may have effects on the torsional strength including the mesh refinement, initial deflection, material strain hardening, geometric properties of crack and stiffener are discussed. Two new concepts that play an significant role in the ultimate strength research of damaged box girders are introduced, one of which is the effective residual section (ERS), the other is the initial damage of the failure zone (IDFZ) for intact structures. New simple formulas for predicting the residual ultimate torsional strength of cracked stiffened box girders are derived on the basis of the two new concepts.