• 한국해양환경ㆍ에너지학회지
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• 제2권2호
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• pp.60-69
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• 1999

본 논문에서는 국내 최초로 수중확산관을 통해 하ㆍ폐수 1차 처리수를 해양방류하고 있는 마산ㆍ창원 하수종말처리장의 해양방류수에 대한 초기ㆍ근역 희석률을 현장관측과 CORMIX 모형계산을 통해 비교 검토하였다. 수심 15m 내외의 방류수역에서 수온약층이 수심 4m～6m에서 형성된 1998년 하계에 관측된 염분도로부터 희석률을 구하였으며, 또한 해수밀도의 수직 분포와 해류자료를 입력하여 모형으로부터 하 폐수 플륨의 이동확산 양상과 초기희석률을 계산하였다. 방류지점의 관측된 염분도 분포로부터 구한 희석률은 32～48이며, 모형에 의해 계산된 초기ㆍ근역 희석률은 29～43으로 두 결과 모두 매우 낮은 하계 소조시의 희석률을 보이고 있다. 이는 조류가 약한 소조기의 정체 시에는 방류수에 포함된 오염물질로 인해 해양방류수역의 수질오염이 더욱 가중될 수 있음을 보여준다.

• Biotechnology and Bioprocess Engineering:BBE
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• 제6권6호
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• pp.410-418
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• 2001

The effects of several variables on the refolding of hen egg white lysozyme have been studied, Lysozyme was denatured in both urea, and guanidine hydrochloride(GuHCl), and batch refolded by dilution (100 to 1000 fold) into 0.1 M Tris-HCI, pH 8.2 mM EDTA 3 mM reduced glutathione and 0.3 mM oxidised glutathions. Refolding was found to be sensitive to temperature, with the highest refolding yield obtained at 50$\^{C}$. The apparent activation energy for lysozyme re-folding wasf ound to be 56kJ/mol, Refolding by dilution results in low concentrations of both de-naturant and reducing agent species. It was found that the residual concentrations obtained dur-ing dilution(100-fold dilution:[GuHCI]=0.06 mM, [DTT]=0.15 mM) were significant and could inhibit lysozyme refolding. This study has also shown that the initial protein concentration (1-10mg/mL) that is refolded is an important parameter. In the presence of residual GuHCl and DTT higher refolding yields were obtained when starting from higher initial lysozyme concentra-tions. This trend was reversed when residual denaturant components were removed from the re-folding buffer.

• 한국미생물·생명공학회지
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• 제23권6호
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• pp.717-722
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• 1995

Using a flocculating Saccharomyes cerevisiae CA-1, an air-lift reactor equipped with a modified settler was used for ethanol fermentation. The effects of conditions such as aeration rate, initial glucose concentration, and dilution rate were studied using the air-lift reactor. In batch fermentation, optimum aeration rate was 0.5 vvm. In continuous fermentation, aeration rate and initial pH were fixed 0.5 vvm and 4.5, substrate concentration and dillution rate were changed 10-15% and 0.1-1.3. The maximum ethanol productivity was shown to be 20.4 g/l$\cdot $h in 10% glucose and 0.7 h$^{-1}$ dilution rate., and optimum operation condition considering the ethanol productivity and glucose utilization ratio was 0.5 h$^{-1}$ dilution rate in 10% glucose concentration.

• 대한기계학회논문집B
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• 제28권1호
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• pp.1-8
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• 2004

An study has been performed with axisymmetric coflow diffusion flames to investigate the influence of air-side fuel side dilution and initial preheated temperature on the soot formation in methan/air flames. Soot quantities are determined by using PLII(Planar Laser Induced Incandescence), such a $C_2$H$_2$ major species(CH$_4$, $O_2$, $N_2$) and temperature are simulated by chemkin code. The numerical analysis was performed with transport properties and detailed reaction mechanisms m axisymmetric coflow diffusion flames. The study of how flame temperature and $N_2$ dilution of air and fuel side influence the soot concentrations is focused. Soot concentrations results on PLII show that preheated temperature contributes to an increase in the soot volume fraction, and soot formation Is more productive to air side dilution than to fuel side dilution. $C_2$H$_2$ concentrations have a similar tendency to soot concentrations.

• 한국수자원학회논문집
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• 제33권2호
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• pp.207-217
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• 2000

밀도성층화된 흐름 수역으로 방류되는 부력제트에 의한 초기확산을 해석하기 위하여 수치모형을 적용하였다. 수치모형은 제트적분모형으로서 흐름수역의 원역에서의 대표적 특성으로 밝혀진 쌍와흐름특성을 모형에 반영한 Gaussian-vortex모형이다. 수치모형의 현장 적용성을 검토하기 위하여 수표면에서의 초기희석에 대한 관측이 수행된 6개의 해양방류관에 수치모형을 적용하였다. 현장관측자료에 대한 수치모형의 적용결과, 개발된 수치모형이 하수확산관에 의해 해양으로 방류되는 오염물질의 초기 확산해석에 활용될 수 있음을 알 수 있었다.

• Journal of Radiation Protection and Research
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• 제23권1호
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• pp.1-6
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• 1998

영광 원전 지역에 적용될 수 있는 액체 방사성 물질의 확산 모델을 개발하였다. 영광에서의 해양 확산 조건은 매우 복잡하기 때문에 수치적 모델을 적용하는 것은 매우 어렵다. 따라서 비교적 단순하면서도 신뢰성 있는 미규제 지침 1.113에서 제시한 통계적 모델을 적용하였다. 이를 통해, 발전소 운전 조건이나, 피폭 경로에 따른 희석 인자를 계산할 수 있는 컴퓨터 코드를 개발하였다. 액체 방사성 물질의 확산에 대해서, 혼합 범위에 따라 근거리 혼합 모델과 원거리 혼합 모델로 구분하여 모델을 개발하였다. 근거리 혼합 현상은 부력과 초기 운동량 및 난류에 의해 결정된다. 원거리 혼합에서는 대기 중의 구름 확산과 유사하게 가우시안푸륨 모델을 적용할 수 있다. 서로 다른 피폭 경로에 대해 물리적으로 타당한 적분을 수행함으로서, 경로에 따른 희석 인자를 구할 수 있었다. 개발된 모델을 사용하여 계산한 결과에 의하면, 현행 영광 ODCM에 사용되는 희석 인자는 상당히 과평가되어 있음을 알 수 있다.

• 한국해양환경ㆍ에너지학회지
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• 제3권1호
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• pp.35-44
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• 2000

1999년 2월에 관측한 수온 및 염분도 분포로부터 마산ㆍ창원 하수종말처리장의 해양 수중방류수에 대한 동계의 근역희석률을 산정하였다. 소조기의 약한 주변유속과 수온약층에 의해 하수플륨이 포착되어 희석률이 30～40정도로 저조했던 하계의 경우와는 달리 동계 소조기의 경우에는 주변해수의 수직적 등밀도혼합이 전 층에서 형성되어 하수플륨이 수표면까지 상승하며 희석률도 90～130정도로 훨씬 큰 것으로 나타났다. CORMIX2 모형의 모의결과에서도 소조기의 약한 유속(Ua=6.0cm/s)의 경우 동계 희석률이 하계 희석률보다 약 3배 정도 증가하였으며 대조기의 강한 유속(Ua=15.5cm/s)의 경우에는 두 계절의 희석률 차이가 30%정도로 미미하였다. 이는 수중방류 하수의 근역희석 및 혼합과정이 주변해수의 밀도성층 효과보다는 유동성분에 더 큰 영향을 받기 때문인 것으로 사료된다.

• 동굴
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• 제71호
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• pp.5-11
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• 2006

A theoretical investigation of the solid phase mechanochemical synthesis of nano sized target product on the basis of dilution of the initial powdered reagent mixture by another product of an exchange reaction is presented. On the basis of the proposed 3 mode particle size distribution in mechanically activated mixture, optimal molar ratios of the components in mixture are calculated, providing the occurrence of impact friction contacts of reagent particles and excluding aggregation of the nanosized particles of the target reaction product. Derivation of kinetic equations for mechanochemical synthesis of nanoscale particles by the final product dilution method in the systems of exchange reactions is submitted. On the basis of obtained equations the necessary times of mechanical activation for complete course of mechanochemical reactions are designed. Kinetics of solid phase mechanosynthesis of nano TlCl by dilution of initial (2NaCl+$Tl_2SO_4$) mixture with the exchange reaction product (diluent,$zNa_2SO_4$, z=z*=11.25) was studied experimentally. Some peculiar features of the reaction mechanism were found. Parameters of the kinetic curve of nano TlCl obtained experimentally were compared with those for the model reaction KBr+TlCl+zKCl=(z+1) KCl+TlBr (z=z1*=13.5), and for the first time the value of mass transfer coefficient in a mechanochemical reactor with mobile milling balls was evaluated. Dynamics of the size change was followed for nanoparticle reaction product as a function of mechanical activation time.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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• pp.405-406
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• 2005

A theoretical investigation of the solid-phase mechanochemical synthesis of nano-sized target product on the basis of dilution of the initial powdered reagent mixture by another product of an exchange reaction is presented. On the basis of the proposed 3-mode particle size distribution in mechanically activated mixture, optimal molar ratios of the components in mixture are calculated, providing the occurrence of impact-friction contacts of reagent particles and excluding aggregation of the nanosized particles of the target reaction product. Derivation of kinetic equations for mechanochemical synthesis of nanoscale particles by the final product dilution method in the systems of exchange reactions is submitted. On the basis of obtained equations the necessary times of mechanical activation for complete course of mechanochemical reactions are designed. Kinetics of solid phase mechanosynthesis of nano-TlCl by dilution of initial (2NaCl + $Tl_2SO_4$) mixture with the exchange reaction product (diluent, $zNa_2SO_4$, $z=z^*=11.25$) was studied experimentally. Some peculiar features of the reaction mechanism were found. Parameters of the kinetic curve of nano-TlCl obtained experimentally were compared with those for the model reaction KBr + TlCl + zKCl = (z + 1) KCl + TlBr ($z=z_l^*=13.5$), and for the first time the value of mass transfer coefficient in a mechanochemical reactor with mobile milling balls was evaluated. Dynamics of the size change was followed for nanoparticle reaction product as a function of mechanical activation time.

• 대한기계학회논문집B
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• 제27권9호
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• pp.1209-1219
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• 2003

The dynamic behaviors of the single vortex interacting with $CH_4-Air$ jet diffusion flame are investigated numerically. The numerical method is based on a predict-corrector scheme for a low Mach number flow. A two-step global reaction mechanism is adopted as a combustion model. Studies are conducted in fixed initial velocities for the three cases according as where $CO_2$ is added; (1) without dilution, (2) dilution in fuel stream and (3) dilution in oxidizer stream. A single vortex is generated by an axisymmetric jet, which is made by an impulse of a cold fuel when a flame is developed entirely in a computational domain. The simulation shows that $CO_2$ dilution in fuel stream results in somewhat larger vortex radius, and greater amount of entrainment of surrounding fluid than in other cases. Thus, the dilution of $CO_2$ in fuel stream enhances the mixing in single vortex and increases the stretching of the flame surface. The budgets of the vorticity transport equation are examined to reveal the mechanism of vortex formation when $CO_2$ is added. It is found that, in the case of $CO_2$ dilution in fuel stream, the vortex destruction due to volumetric expansion and the vortex production due to baroclinic torque are more dominant than in other cases.