• Proceedings of the Korea Concrete Institute Conference
• /
• 2000.10b
• /
• pp.1189-1194
• /
• 2000

The purpose of this investigation is to establish which consequence is happen about initial curing concrete's compressive strength of 7days, 28days which changes W/C ratio by the change of vibrating speed and vibrated time. An experimental parameter is fixed 4 degrees of W/C ratio(45%, 50%, 55%, 60%), 3 degrees of vibrated time(3hr, 6hr, 12hr) and different vibrating speed(0.25kine, 0.5kine, 1kine). As the result, compressive strength of 7days was increased when vibrating speed and vibrated time is 1kine, 12h and also compressive strength of 28days was increased when vibrating speed and vibrated time is 0.25kine and 3hr.

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2019.11a
• /
• pp.85-86
• /
• 2019

In this study, when the normal concrete became a $20^{\circ}C$ image after the exposure time at an external temperature of $-15^{\circ}C$, the limit point of the early frost damage was analyzed. As a result, it was confirmed that the degree of concretion was higher than the external level after carrying in and after exposure, and that the initial Tokai damage was observed after 12 hours of exposure.

• Korean Journal of Materials Research
• /
• v.22 no.2
• /
• pp.71-77
• /
• 2012

When a new bonding agent using coal ash is utilized as a substitute for cement, it has the advantages of offering a reduction in the generation of carbon dioxide and securing the initial mechanical strength such that the agent has attracted strong interest from recycling and eco-friendly construction industries. This study aims to establish the production conditions of new hardening materials using clean bottom ash and an alkali activation process to evaluate the characteristics of newly manufactured hardening materials. The alkali activator for the compression process uses a NaOH solution. This study concentrated on strength development according to the concentration of the NaOH solution, the curing temperature, and the curing time. The highest compressive strength of a compressed body appeared at 61.24MPa after curing at $60^{\circ}C$ for 28 days. This result indicates that a higher curing temperature is required to obtain a higher strength body. Also, the degree of geopolymerization was examined using a scanning electron microscope, revealing a micro-structure consisting of a glass-like matrix and crystalized grains. The microstructures generated from the activation reaction of sodium hydroxide were widely distributed in terms of the factors that exercise an effect on the compressive strength of the geopolymer hardening bodies. The Si/Al ratio of the geopolymer having the maximum strength was about 2.41.

• The Journal of Korean Academy of Prosthodontics
• /
• v.33 no.1
• /
• pp.48-74
• /
• 1995

Since heat curing acrylic resins undergo unavoidable dimensional changes following polymerization, adaptation can be altered. Until recently, although numerous studies on the dimensional changes of denture base were based on a microscopic technic that measures the relative displacement of a limited reference points on the denture base, but there have been few studies on the distortions of resins using holographic interferometry. Purpose of this study was to determine and compare the dimensional changes and fringe patterns of 4 heat curing acrylic resins, and observe the distortions of acrylic resin denture base by temperature change with the aid of the holographic interferometry. Holographic interferograms were taken on the resin specimens and acrylic resin denture base with the 10mW He-Ne laser and double exposure method. Comparison and analysis of fringe pattern on the recorded object surface was performed. The following results were obtained. 1. The dimensional changes for the high impact resin Lucitone 199 were statistically the greatest of all resins, and the rapid heat curing resin Premium super 20 were the least. 2. The most polymerization shrinkage of all materials occured in initial period of measurements, at this time the difference of polymerization shrinkage properties between resins was founded. 3. The stress distribution of specimens was seen by various type of fringe pattern which had directionality. 4. The polymerization shrinkage of resins was greatly influenced by temperature change. 5. The partial deformations of resin denture base were observed in 70 C and 90 C water.

• Advances in concrete construction
• /
• v.11 no.5
• /
• pp.419-428
• /
• 2021

The pH of cement-based materials (CBMs) is an important factor for their durability, sustainability, and long service life. Currently, the use of supplementary cementitious materials (SCMs) is becoming mandatory due to economic, environmental, and sustainable issues. There is a decreasing trend in pH of CBMs due to incorporation of SCMs. The determination of numerical values of pH is very important for various low and high volume SCMs blended cement mortars for the better understanding of different defects and durability issues during their service life. In addition, the effect of cement hydration and pozzolanic reaction of SCMs on the pH should be determined at initial and later ages. In this study, the effect of low and high-volume fly ash (FA) and ground granulated ballast furnace slag (GGBFS) cement mortars in different curing conditions on their pH values has been determined. Thermal gravimetric analysis (TGA) was carried out to support the findings from pH measurements. In addition, thermal conductivity (k-value) and strength activity indices of these cement mortars were discussed. The results showed that pH values of all blended cement mortars were less than ordinary Portland cement (OPC) mortar in all curing conditions used. There was a decreasing tendency in pH of all mortars with passage of time. In addition, the pH of cement mortars was not only dependent on the quantity of Ca(OH)₂. The effect of adding SCMs on the pH value of cement mortar should be monitored and measured for both short and long terms.

• Journal of the Korean Crystal Growth and Crystal Technology
• /
• v.31 no.6
• /
• pp.247-257
• /
• 2021

This study was started to investigate why autoclave curing (AC) specimen showed an improvement in compressive strength after immersion in water for a long time, although AC specimen did not showed a high initial compressive strength unlike our expectations. Distilled water and alkaline solutions were used for immersion and three different curing methods were engaged. It was expected that the compressive strength would be improved after immersion in alkaline solutions; however, there was little difference in compressive strength after 21 day immersion because both new crystallites produced by additional geopolymerization and expansion caused by the alkaline aggregate reaction may prevent the additional improvement in compressive strength. It was concluded that in order to secure the long-term commonality and underwater stability of the geopolymers, it is desirable aging geopolymers while immersing it underwater for more than 21 days after curing using an autoclave.

• Journal of the Korean Wood Science and Technology
• /
• v.48 no.2
• /
• pp.136-153
• /
• 2020

In this paper, the influence of initial formaldehyde/urea (F/U) molar ratios on the performance of low molar ratio (1.0) urea-formaldehyde (UF) resin adhesives has been investigated. Two initial F/U molar ratios, i.e., the first and second initial molar ratios were used for the alkaline addition reaction. Three levels of the first initial F/U molar ratios (2.0, 3.0, and 4.0) and two levels of the second initial molar ratios (2.0 and 1.7) were employed to prepare a total of six UF resins with an identical final molar ratio (1.0). The basis properties, functional groups, molecular weight, crystallinity, and thermal curing properties of the UF resins were characterized in detail. Higher levels (3.0 and 4.0) of the first initial F/U molar ratio provided the UF resins with better properties (non-volatile solids content, viscosity, gelation time, pH, and specific gravity) than those of the resins prepared with the conventional level F/U molar ratio of 2.0. Statistical analysis suggested that combining the first and second initial molar ratio of 4.0 with 1.7 would result in UF resins with greater adhesion strength and lower formaldehyde emission than those of the resins prepared with other molar ratios. The results showed that higher levels of the first initial molar ratio resulted in a more branched structure, as indicated by GPC, FTIR, DSC, XRD, and greater adhesion strength than those of the other UF resins with an identical final molar ratio of 1.0.

• Restorative Dentistry and Endodontics
• /
• v.34 no.5
• /
• pp.450-459
• /
• 2009

The aim of this study was to measure the initial dynamic modulus changes of light cured composites using a custom made rheometer. The custom made rheometer consisted of 3 parts: (1) a measurement unit of parallel plates made of glass rods, (2) an oscillating shear strain generator with a DC motor and a crank mechanism, (3) a stress measurement device using an electromagnetic torque sensor. This instrument could measure a maximum torque of 2Ncm, and the switch of the light-curing unit was synchronized with the rheometer. Six commercial composite resins [Z-100 (Z1), Z-250 (Z2), Z-350 (Z3), DenFil (DF), Tetric Ceram (TC), and Clearfil AP-X (CF)] were investigated. A dynamic oscillating shear test was undertaken with the rheometer. A certain volume ($14.2\;mm^3$) of composite was loaded between the parallel plates, which were made of glass rods (3 mm in diameter). An oscillating shear strain with a frequency of 6 Hz and amplitude of 0.00579 rad was applied to the specimen and the resultant stress was measured. Data acquisition started simultaneously with light curing, and the changes in visco-elasticity of composites were recorded for 10 seconds. The measurements were repeated 5 times for each composite at $25{\pm}0.5^{\circ}C$. Complex shear modulus G*, storage shear modulus G', loss shear modulus G" were calculated from the measured strain-stress curves. Time to reach the complex modulus G* of 10 MPa was determined. The G* and time to reach the G* of 10 MPa of composites were analyzed with One-way ANOVA and Tukey's test ($\alpha$ = 0.05). The results were as follows. 1. The custom made rheometer in this study reliably measured the initial visco-elastic modulus changes of composites during 10 seconds of light curing. 2. In all composites, the development of complex shear modulus G* had a latent period for $1{\sim}2$ seconds immediately after the start of light curing, and then increased rapidly during 10 seconds. 3. In all composites, the storage shear modulus G" increased steeper than the loss shear modulus G" during 10 seconds of light curing. 4. The complex shear modulus of Z1 was the highest, followed by CF, Z2, Z3, TC and DF the lowest. 5. Z1 was the fastest and DF was the slowest in the time to reach the complex shear modulus of 10 MPa.

• Journal of Industrial Technology
• /
• v.29 no.B
• /
• pp.73-80
• /
• 2009

This paper is to investigate effect of B.G.I (Best Grouting Innovation) method on reinforcing ground. In this thesis, extensive literature review was performed to summarize theoretical backgrounds of grouting and to compare the applicability of different grouting methods. Unconfined compression test with specimen prepared by injecting different grouts of B.G.I, S.G.R and L.W methods and by changing the curing time were carried out to figure out characteristics of initial unconfined compression strength mobilized in the early stage. As results of test, the compression strength increases with curing times and specimen prepared with grouts of B.G.I method show greater values than others. On the other hands, the measured values of pH are in the range of 7-10 during tests. In field, preliminary construction to main construction at several sites were performed to confirm the effect of reinforcing the ground by application of B.G.I method. From the results of permeability test in field, SPT test and phenol reaction test, it was found that N values after grouting are greater than those before grouting and values of permeability in grouted ground is reduced significantly.

• Journal of the Korea Institute of Building Construction
• /
• v.2 no.4
• /
• pp.177-182
• /
• 2002

The purpose of this study is to develope the strength prediction model by Maturity Method. A maturity function is a mathematical expression to account for the combined effects of time and temperature on the strength development of a cementious mixture. The method of equivalent ages is to use Arrhenius equation which indicates the influence of curing temperature on the initial hydration ratio of cement. For the experimental factors of this study, we selected the concrete mixing of W/C ratio 45, 50, 55 and 60% and curing temperature 5, 10, 20 and $30^{\circ}C$. And we compare and evaluate with logistic model that is existing strength prediction model, because we have to verify adaption possibility of new strength prediction model which is proposed by maturity method. As the results, it is found that investigation of the activation energy that are used to calculate equivalent age is necessary, and new strength prediction model was proved to be more accurate in the strength prediction than logistic model in the early age. Moreover, the use of new model was more reasonable because it has low SSE and high decisive factor.