• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.7
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• pp.1818-1832
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• 1994

Transport process during solidification of an AI-CU alloy in a vertical annular mold of which inner wall is cooled is numerically simulated. A model which can take account of local density dependence on the solute concentration is established and incorperated in the analysis. Results show that thermally and solutally induced convections are developed in sequence, so that there is little interaction between them. Thermal convection effectively removes the initial superheat from the melt and vanishes as solidification proceeds from the cooling wall. On the other hand, solutal convection which is developed later over the meshy and the pure liquid regions leads to large-scale redistribution of the consituents. The degree of the initial superheating hardly affects overall solidification behavior except the early stage of the process, when the cooling rate is kept constant. Macrosegregation is reduced remarkably with increasing cooling rate, because not only the liquidus interface advances so quickly that time available for the solute transport is not enough, but also the interdendritic flow is strongly damped by rapid crystal growth within the mushy region.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.22 no.2
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• pp.184-192
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• 1998

This paper deals with an extended analytical solution for the mixture solidification problem, in which temperature is inherently coupled with the solute transport due to the presence of volume contraction induced flow. A new exact solution to the energy equation accounting for the convection effect in the melt is successfully derived, which allows the present analysis to cover a high initial superheating. Difference in properties between the solid and liquid phases is rigorously incorporated into the model equations in the solid fraction weighted form. Taking advantage of linearized correction factors, a systematic and easy-to-implement algorithm for determining the solidus and liquidus positions is introduced, which proves not only to converge stably but also to be very efficient. For a specific case, the present results show excellent agreements with the existing solution. The effect of convection in the melt becomes appreciable with increasing the initial superheating. It is revealed that variable properties in the mushy region significantly affect the solidification behaviors. The present study is also capable of resolving the interaction between microsegregation and macrosegregation.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.1 no.4
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• pp.319-329
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• 1989

Heat transfer phenomena during inward melting and solidification process of the phase change material were studied expertimentally. The phase change medium was 99% pure n-docosane paraffin ($C_{22}H_{46}$). The solid-liquid interface motion during phase change was recorded photographically. Measurements were made on the temperature, the solid-liquid interface, the melted or frozen mass and the various energy components stored or extracted from the cylinder wall. For melting, the experimental results reaffirmed the dominant role played by the conduction at an early stage, by the natural convection at longer time. For solidification, natural convection effects in the superheated liquid were modest and were confined to short freezing time. Although the latent energy is the largest contributor to the total stored or extracted energy, the aggregate sensible energies can make a significant contribution, especially at large cylinder wall superheating or subcooling, large initial phase change material subcooling or superheating.

• Solar Energy
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• v.13 no.2_3
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• pp.53-64
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• 1993

This study investigated heat transfer phenomena during the freezing of an initially superheated or non-superheated liquid in a cooled cylinder tube. Numerical and experimental method were performed to obtatin the temperature and velocity distribution, the shape of interface. Natural convection effects in the superheated liquid were confined and moderated a short freezing time. After natural convection ceases, heat conduction dominated in the whole paraffin, so Crystal and much-zone were found out in PCM. Initial superheating of liquid tended to morderatly diminish the frozen layer thickness at short freezing times but little effect on the these quantities at longer times. On the amount of frozen mass, Iintial liquid superheating is less affected than tube wall subcooling.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.13 no.4
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• pp.223-229
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• 1984

Experiments were performed for freezing of an initially superheated or nonsuperheated liquid phase in a cooled vertical tube. The liquid was placed in a copper tube whose surface maintained a uniform temperature during the data run and the freezing occurred in a copper tube. The phase change medium was n-odtadecane, a paraffin which freezes at about $61^{\circ}C$. Measurements were made which yielded information about the time dependence of the freezing front, of the amount of frozen mass, and of the various energy components extracted from the tube. The time-wise decay of the initial liquid superheat was also measured. Initial superheat of the liquid tends to moderately diminish the rozen mass and associated latent energy extraction at small times but has lit tie effect on these quantities at large tiems. Natural convection in the liquid Plays a modest role only at small times and disappears when the superheat decay to zero. Although the latent energy constitutes the largest contributor to the total extracted energy, the sensible energy components can make a significant contribution, especially at large tube wall subcoolings, large initial liquid superheating and short freezing time.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.6 no.3
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• pp.182-192
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• 1994

This paper focuses on the investigation of the heat transfer phenomena that occur inside the cylindrical tube. The inclination of the tube is adopted as a principal parameter varying from vertical to horizontal. The phase change material employed in this experiment is 99 percent pure n-docosane paraffin($C_{22}$ $H_{46}$). It is found that the amount of solidified mass during a prescribed solidifying period is not sensitive to the inclination of the tube but to the local layer thickness. It is studied that the latent energy is the largest contributor to the total extracted energy. The sensible energy($E_{s1}$, $E_{s2}$, $E_{s3}$) may not be negligible at the large wall-subcooling and initial-liquid-superheating, also at the first step of solidifying.

• Analytical Science and Technology
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• v.30 no.3
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• pp.138-145
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• 2017

Microwave-assisted organic synthesis has gained a remarkable interest over the past years because of its advantages - (i) rapid energy transfer and superheating, (ii) higher yield and rapid reaction, (iii) cleaner reactions. Ionic liquids are well known for their unique properties such as negligible vapor pressure and high thermal stability. With these properties, ionic liquids have gained increasing attention as green, multi-use reaction media. Recently, ionic liquids have been applied as reaction media for biocatalysis. Lipase-catalyzed reactions in ionic liquids provide high activity and yield compared to conventional organic solvents or solvent free system. Since polar molecules are generally good absorbent to microwave radiation, ionic liquids were investigated as reaction media to improve activity and productivity. In this study, therefore, the effect of microwave irradiation in ionic liquids was investigated on lipase catalyzed reactions such as benzyl acetate synthesis and caffeic acid phenethyl ester synthesis. Comparing to conventional heating, microwave heating showed almost the same final conversion but increased initial reaction rate (3.03 mM/min) compared to 2.11 mM/min in conventional heating at $50^{\circ}C$.

• Solar Energy
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• v.15 no.1
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• pp.3-11
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• 1995

Heat transfer phenomena during inward freezing process of the water in a horizontal cylinder were experimentally studied. The cooling temperature of a wall more significantly affects the timewise average temperature than the initial superheating temperature of the water. In addition, it was absolved that the timewise average temperature was influenced by the initial volume ratio of the water($V_l/V_{tot}$) at the same temperature conditons. One the other hand, the freezing speed of the upper part in the water-ice interface was quickly progressed due to natural convection. Furthermore, experimental observation showed that the frozen mass fraction($M_s/M_{tot}$) was influenced by the initial volume ratio of the water($V_l/V_{tot}$). It was noted that the frozen mass fraction for each $V_l/V_{tot}$ represented by $Ste^*$ and Fo.