• 대한치과보철학회지
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• 제40권6호
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• pp.572-576
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• 2002

This investigation was designed to estimate the biaxial flexure strength and fracture toughness of lithium disilicate glass-ceramics of IPS Empress 2 system pressed with as-received ingots and their sprue buttons. Two groups of the lithium disilicate glass-ceramics were prepared as follows: group 1 is ingot-pressed group; group 2 is sprue button-pressed group. A ball-on-three-ball test was used to determine biaxial flexure strength (BFS) of disks in wet environment. Scanning electron microscopy(SEM) analysis was conducted to observe the microstructure of the ceramics. Unpaired t-test showed that there were no differences in the mean biaxial Hem strength (BFS) and KIC values between group 1 and 2 (p > 0.05). Two groups showed similar values in the KIC and the strength at 5% failure probability. The SEM micrographs of the IPS Empress 2 glass-ceramic showed a closely packed, multi-directionally interlocking pattern of numerous lithium disilicate crystals protruding from the glass matrix. The lithium orthophosphate crystals could not be observed on the fracture surface etched. There was no a marked difference of the microstructure between group 1 and 2. Although there were no tests including color stability, casting accuracy, etc., the results of this study implied that we could reuse the sprue button of the pressed lithium disilicate glass-ceramic of IPS Empress 2 system.

• 자원리싸이클링
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• 제6권4호
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• pp.24-30
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• 1997

최근 금속 스크랩의 재활용에 있어서 고품질의 2차지금을 제조하고자 하는 연구가 진행되고 있다. 본 연구에서는 알루미늄 주조품의 기계가공 후 발생하는 알루미늄 Chip을 보다 효율적이고 신속하게 재활용하기 위하여 vortex melting법을 수행하였다. Vortex melting 기술을 chip의 용해공정에 도입하였다. 최적의 vortex 깊이는 수모델 실험을 통하여 결정되었는데, 교반자의 형상, 위치, 회전속도 및 수위 등에 의해 결정된다. Chip의 용해전 상온, 200, 300, $400^{\circ}C$에서 예열하여 vortex의 중앙에 투입하엿다. 따라서, 온도에 따른 회수율을 결정할 수 있었다. 본 실험의 결과로서, 최적의 vortex 깊이는 교반자의 형상, 회전속도에 의해서만 영향을 받으며, 최고의 회수율, 97%는 chip의 예열온도가 $300^{\circ}C$일 경우 얻어졌다.

• 한국전기전자재료학회논문지
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• 제20권12호
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• pp.1099-1104
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• 2007

In order to develop non-heated STAl(super thermal resistant Aluminum alloy) for ampacity gain conductor, the systematic research was carried out. Especailly, the effect of a very small amount of Zr, Sc element in EC grade Al ingot on mechanical and electrical properties was our priority. As a result, it was found that the strength and recrystallization temperature of designed alloy was gradually increased with Zr, Sc addition up to 0.3 wt.%. However, the electric conductivity showed no drastic change. The tensile strength and recrystalliztion temperature, $17.75{\sim}20.05\;kgf/mm^2$ and $420{\sim}520\;^{\circ}C$, was obtained at 0.3 wt.% Zr, Sc addition, respectively. Particles of the $Al_3Zr$ and $Al_3Sc$ phase affected the ambient and elevated-temperature strength of the alloys.

• Journal of Magnetics
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• 제15권4호
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• pp.155-158
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• 2010

The HDDR (hydrogenation, disproportionation, desorption, and recombination) process can be used as an effective way of converting a no coercivity Nd-Fe-B ingot material, with a coarse $Nd_2Fe_{14}B$ grain structure, to a highly coercive one with a fine grain structure. Careful control of the HDDR process can lead to an anisotropic powder with good $Nd_2Fe_{14}B$ grain texture; the most critical step for inducing texture is disproportionation. The critical conditions (hydrogen pressure and temperature) for the disproportionation reaction of fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ (x = 0 or 0.3, y = 0 or 0.2) alloys, in different atmospheres of pure hydrogen and a mixed gas of hydrogen and argon, was investigated with TPA (thermopiezic analyser). From this, the hydrogen pressure-temperature diagram showing the critical conditions was established. The critical disproportionation temperature of the fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ alloys was slightly increased as the hydrogen pressure decreased in both pure hydrogen and mixed gas. The critical disproportionation temperature of the hydrogenated alloys was higher in the mixed gas than in pure hydrogen. Addition of Ga and Nb increased the critical disproportionation temperature of the fully hydrogenated Nd-Fe-B alloys.

• 한국태양에너지학회 논문집
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• 제33권5호
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• pp.24-33
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• 2013

Renewable energy industries, including sola cell plants, has been ever increasing ones for reducing fossil fuel consumption and strengthening national energy policy. In this paper we tried to identify occupational health hazards in solar cell-related industries operated in Korea. Poly silicon, silicon ingot and wafer, solar cell and module are major processes for producing solar cells. Poly silicon operations may cause hazards to workers from metal silicon, silanes, silicon, hydro fluoric acid and nitric acid. Solar cells could not be constructed without using metals such as aluminum and silver, acids such as hydrofluoric acid and nitric acid, bases such as sodium hydroxide and potassium hydroxide, and solvent and phosphorus chloride oxide. Workers in module assembly process may exposed to isopropanol, flux, solders that contain lead, tin and/or copper. To prevent occupational exposure to these hazards, it is essential to identify the hazards in each process and educate workers in industries with proper engineering and administrative control measures.

• 한국재료학회지
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• 제12권5호
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• pp.398-406
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• 2002

VAR process is required to control its various operating parameters. Heat transfer simulation has been accomplished to understand development of solidification micro and macro-structures during VAR process in Ti alloys. Optimum VAR process parameters could be also estimated in this study. It was found that macro-structures were closely related to the shape and depth of liquid pool, and solidification parameters, such as temperature gradient, heat flux, solid fraction. The cooling rates were higher at bottom, top, and center part respectively. As cooling rates increased, the $\alpha$ phase decreased in length, width and fraction. In order to evaluate which parameter affects the result of heat transfer calculation most sensitively, the sensitivities of input parameters to the simulation result were examined. The pool depth and cooling rate showed more sensitive to the temperature of the molten metal, heat transfer coefficient, and liquidus respectively. Also, these thermal properties became more sensitive at higher temperatures.

• 한국수소및신에너지학회논문집
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• 제21권2호
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• pp.123-128
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• 2010

Hydriding combustion synthesis (HCS) can produce full hydrides of alloys and in a short time. The conventional process based on ingot metallurgy cannot produce Mg-based alloy easily with the desired composition and the cast product needs a ling activation process for the practical use of hydrogen storage. In this study, the hydriding properties of Mg-xNi (x=5, 13.5, 54.7wt.%) alloys prepared by hydriding combustion synthesis were evaluated. The hydrogen storage capacity and kinetics of HCS Mg-xNi alloys were strongly dependent on the content of Ni. The HCS Mg-13.5wt.%Ni alloy shows the hydriding behavior to reach the maximum capacity within 30 min. and the reversible $H_2$ storage of 5.3wt.% at 623 K.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2013년도 추계 학술논문 발표대회
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• pp.152-153
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• 2013

Based on the Fire Service Act of mandatory provision, new buildings are strictly forced to use fire protection materials. Flame resistant EPS is one of those materials. Unlike conventional EPS that can be fused to make EPS ingot and be recycled for various purposes, flame resistant EPS waste cannot be recycled due to the presence of protective coating that is applied to increase the fire protection properties of EPS. A suitable alternative that can process large amount of flame resistant EPS wastes needs to be developed, and one of the possible alternative is to use them as construction materials. In this research, experiments were designed to observe whether the flame resistant EPS wastes can be utilized as partial replacements of fine aggregates in cement mortar. The replacement ratio of waste EPS was varied, and its effect on compressive strength and absorption capacity was investigated. According to the experimental results, both compressive strength and absorption capacity met the Korean Standard specification for cement bricks and blocks, indicating that flame resistant EPS wastes can be used for construction purposes.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1992년도 춘계학술대회 논문집
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• pp.50-53
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• 1992

The GaP crystals are growth by Synthesis Solute Diffusion(SSD) method and its properties are investigated. Etch pits density along vertical direction of ingot is increased from 3.8${\times}$10$^4$cm$\^$-2/ of first freeze to 2.3${\times}$10$\^$5/cm$\^$-2/ of last freeze part. The carrier concentration and mobilities are measured to 197.49$\textrm{cm}^2$/V. sec and 6.75${\times}$10$\^$15/cm$\^$-3/ at room temperature. The temperature dependence of optical energy gap is empilically fitted to E$\_$g/(T)=2.3383-(6.082${\times}$10$\^$-4/T${\times}$/(373.096+T)[eV]. Photo-luminescence spectra measured at low temperature are consist with sharp line-spectra near band-gap energy and radiative recombination between shallow Si-donor to Zn-acceptor and its phonon reprica, and broad emission. The infrared absorption in GaP is cause to phonon coupling modes of TO, LO, LA, TA$_1$, TA$_2$and vibration modes of Ga$_2$O, Si-donor and Zn-acceptor, respectively.

• 한국주조공학회지
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• 제25권3호
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• pp.115-122
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• 2005

In the present study, an EMC (Electromagnetic Casting) process, using a segmented Cu cold crucible under a high frequency alternating magnetic field of 20 kHz, was practiced for the fabrication of poly-crystalline Si ingot of 50 mm diameter. The effects of Joule heating and electromagnetic pressure in molten Si were systematically investigated with various processing parameters such as electric current and crucible configuration. A preliminary experimental work was initiated with the pure Al system for the establishment of a stabilized non-contact working condition, and further adapted to the semiconductor-off-grade Si system. A commercialized software such as Opera-3D was utilized in order to simulate electromagnetic pressure and Joule heating. In order to evaluate the meniscus shape of the molten melts, shape parameter was used throughout the research. A segmented graphite crucible, which was attached at the upper part of the cold crucible, was introduced to enhance significantly the heating efficiency of Si melt keeping non-contact condition during continuous melting and casting processes.