• Journal of the Optical Society of Korea
• /
• 제7권4호
• /
• pp.240-244
• /
• 2003

Simultaneous determination of concentrations for four major components in human blood serum was investigated using a Fourier-transform mid-infrared spectroscopy. Infrared spectra of human blood serum were measured in 8.404 ∼ 10.25 ${\mu}m$ range where the highest absorption peaks of glucose are located. A partial least square (PLS) algorithm was utilized to establish a calibration model for determining total protein, albumin, globulin and glucose levels which are commonly measured metabolites. The standard error of cross validation obtained from our multivariate calibration model was 0.24 g/dL for total protein, 0.15 g/dL for albumin, 0.17 g/dL for globulin, and 6.68 mg/dL for glucose, which are comparable with or meet the criteria for clinical use. The results indicate that the infrared absorption spectroscopy can be used to predict the concentrations of clinically important metabolites without going through a chemical process with a reagent.

• 한국염색가공학회:학술대회논문집
• /
• 한국염색가공학회 2009년도 제41차 학술발표회
• /
• pp.115-116
• /
• 2009

In this study, near-infrared absorbing dyes, namely, new rigidified heptamethine cyanine dyes were synthesized and investigated their properties. The cyanine dyes have been synthesized by a condensation reaction between a quanternary salt containing as activated methyl group and an unsaturated bisaldehyde or its equivalent. We were investigated the synthesis of new rigidified heptamethine cyanine and related the compounds with near infrared absorption. The full spectroscopic characterization of all cyanine were described. Absorption properties in the near-infrared region may cause these dyes to the potential used in bio-probe, optical recording media materials.

• 한국재료학회지
• /
• 제6권6호
• /
• pp.555-560
• /
• 1996

The vibrational behavior and the molecular dynamics of the high Tc superconductor Ba0.6K0.4BiO3 have been studied experimentally and by atomistic computer simulation methods. For Ba0.6K0.4BiO3, the vibrational spectrum is dominated by oxygen ion modes from 150cm-1 to 820cm-1 including infrared absorption bands at 330, 480, 640 and 830cm-1including infrared absorption bands at 330, 480, 640 and 830cm-1at room temperature. Band assignments are discussed in relation to those bands predicted by simulations, and the infrared and Raman measurements reported in the literature.

• Bulletin of the Korean Chemical Society
• /
• 제22권8호
• /
• pp.833-836
• /
• 2001

Infrared absorption spectra of $\alpha\omega-diphenylpolyenyl$, anions Ph(CH)nPh- (DPn-, n=7, 9, and 13) in the tetrahydrofuran-d6 solutions was measured in the range of 1700 and 1200 cm-1 . The infrared spectra obtained from anions (DPn) showed considerable difference from their neutral species (DPn); their intensities were enhanced at least two orders of magnitude stronger than their neutral species. The in-plane CH bending modes at 1464 and 1375 cm-1 are correspondingly strengthened with the chain length increased, but the C=C stretching at 1541 cm-1 is weakened and frequencies are not changed. We provide an IR evidence for the first time that the bond order or bond alternations of the anions (soliton) are different from those of radical anions (polaron) as well as neutral species.

• 약학회지
• /
• 제13권2_3호
• /
• pp.51-56
• /
• 1969

In quantitative analysis of sulfonamide drugs by means of infrared Spectrophotometry, the author tried to analyse Sulfamethoxydiazine and Sulfamethoxypyridazine in their Pharmaceutical Preparations. By the survey of infrared absorption spectra of Sulfamethoxydiazine and Sulfamethoxypyridazine. We found quantitative properties at the peaks of wave number 1150 cm$^{-1}$ (Sulfamethoxydiazine) and 1090 cm$^{-1}$ (Sulfamethoxypyridazine) in the spectra. These peaks obey Beer's Law in a range of 50-150 ug for Sulfamethoxydiazine and 70-350 ${\mu}$g for Sulfamethoxypyridazine in 300 mg KBr disc. By this method, Sulfamethoxydiazine and Sulfamethoxypyridazine could be analyzed less than 2% error.

• Journal of the Optical Society of Korea
• /
• 제13권2호
• /
• pp.279-285
• /
• 2009

Prediction of glucose concentration in the interstitial fluid (ISF) based on mid-infrared absorption spectroscopy was examined at the glucose fundamental absorption band of 1000 - 1500/cm (10 - 6.67 um) using multi-component analysis. Simulated ISF samples were prepared by including four major ISF components. Sodium lactate had absorption spectra that interfere with those of glucose. The rest NaCl, KCl and $CaCl_2$ did not have any signatures. A preliminary experiment based on Design of Experiment, an optimization method, proved that sodium lactate influenced the prediction accuracy of glucose. For the main experiment, 54 samples were prepared whose glucose and sodium lactate concentration varied independently. A partial least squares regression (PLSR) analysis was used to build calibration models. The prediction accuracy was dependent on spectrum preprocessing methods, and Mean Centering produced the best results. Depending on calibration sample sets whose sodium lactate had different concentration levels, the standard error prediction (SEP) of glucose ranged $17.19{\sim}21.02\;mg/dl$.

• 천문학회보
• /
• 제44권1호
• /
• pp.42.3-42.3
• /
• 2019

The high-resolution near-infrared (NIR) spectroscopy can reveal the evidence of the accretion burst (e.g., the broadened absorption features produced by the Keplerian disk motion) although the moment of the outburst was not caught. The embedded protostar IRAS 16316-1540 observed with the Immersion Grating Infrared Spectrograph (IGRINS, $R={\Delta}{\lambda}/{\lambda}{\sim}45000$) shows the broad absorption features in atomic and CO transitions, as seen in FU Orionis objects (FUors), indicative of an outburst event. We examine whether the spectra of IRAS 16316-1540 arise from the rotating inner hot gaseous disk. Using the IGRINS spectral library, we show that the line profiles of IRAS 16316-1540 are more consistent with an M1.5 V template spectrum convolved with a disk rotation profile than the protostellar photosphere absorption features with a high stellar rotation velocity. We also note that the absorption features deviated from the expected line profile of the accretion disk model can be explained by a turbulence motion generated in the disk atmosphere. From previous observations that show the complex environment and the misaligned outflow axes in IRAS 16316-1540, we suggest that an impact of infalling clumpy envelope material against the disk induces the disk precession, causing the accretion burst from the inner disk to the protostar.

• 한국식품과학회지
• /
• 제35권2호
• /
• pp.302-305
• /
• 2003

본 연구는 원적외선 저장쌀의 급여가 흰쥐의 생존능력에 미치는 영향을 조사하기 위하여 수행되었다. 원적외선 저장쌀은 수침시간에 따른 수분흡수량이 일반쌀에 비해 1.3배정도 많았으며, 취반후와 저장에 따른 백색도가 높게 유지되었다. 원적외선 쌀의 급여는 흰쥐의 체중변화에는 유의한 영향을 미치지 못하였다. 흰쥐의 생존능력에 미치는 영향을 조사한 결과 6주령의 경우는 일반쌀과 원적외선 저장쌀간의 생존율에 따른 유의적인 차이는 확인하지 못하였으나, 7주령과 8주령의 경우, 원적외선 저장 쌀의 급여에 따른 생존능력의 유의적인 차이를 나타낸 것으로 확인되었다.

• 전자공학회논문지D
• /
• 제34D권3호
• /
• pp.34-40
• /
• 1997

Intervalence subband absroption of normally incident infrared radiation in p-type InGaAs-InAlAs coupled quantum well (CQW) is theoretically investigated by the multiband effective mass formalism. By solving a 4*4 luttinger-kohn hamitonian, we calculate valence subband structures, intervalence subband transition matrix elements, and absorption coefficient spectrum in the CQW which consists of a wider well, a thinner well and a barreir between them. Using the flexible design parameters given to the valence band CQW structure, we show that the absorption coefficient profile can be tailored. For a carefully designed CQW, theabsorption coefficient cn be made to maintain a large value over a wider wavelength range of incident infrared radiation compared with that shown in intersubband absorption in usual single quantum well.

• 천문학회보
• /
• 제46권1호
• /
• pp.57.1-57.1
• /
• 2021

The icy mantles of interstellar grains are developed by the freeze-out of interstellar molecules and atoms onto grain surfaces. The ice molecules become more complex by surface chemistry induced directly by high energy photons or by the thermal energy diffused over heated grain surface. Therefore, the ice composition is an important tracer of physical conditions where the ices form. Ices have been studied via their absorption features against continuum sources, such as young stellar objects or evolved background stars, in infrared wavelengths. The Spitzer IRS was the most sensitive spectrometer for the observations of infrared ice absorption features. We has been developing an automated analysis tool for the Spitzer IRS spectra, especially for the 15 ㎛ CO₂ bending mode. The 15 ㎛ CO₂ absorption feature is very useful for the study of accretion process in star formation since its spectral shape varies with thermal condition of the dust grains. Eventually, this tool will cover the whole range of the Spitzer IRS spectrum (5~20 ㎛).