• Applied Chemistry for Engineering
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• v.3 no.2
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• pp.207-212
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• 1992

Main disposal technology for industrial wasites in Korea has been landfilling, however, this is encountering serious problems such as the lack of landfill sites and objections of residents. Incineration, therefore, has become a final solution for this dilema. Various kinds of air pollutants generation are possible because of the variety of types and compositions of wastes generated in industry. In this paper, air pollutants produced while incinerating hazardous industrial wastes are discussed and some control technologies are surveryed with the purpose of optimal design of incinerators and emission reduction. From this initial stage of incinerator utilization, low-emission type should be developed and applied and intensive research on pollutant generation due to waste incineration and advanced control technologies should be also performed.

• 한국전산유체공학회:학술대회논문집
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• 2002.10a
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• pp.133-138
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• 2002

A 3-D axisymmetric computer program is developed to predict the NO behavior in SNCR system for the stoker incinerator with the waste treatment capacity, 200ton/day. To this end a turbulent reacting flow field calculation is made using proper assumption and empiricism. The stoker bed is assumed to be a homogeneous waste-volatilized gaseous state. The initial composition or reactants are assumed based on the data of the ultimate analysis. Turbulent is resolved by k-e model and turbulent reaction is handled by eddy-breakup model harmonized with empirical chemistry data for gaseous combustion, NO and urea reaction. The liquid droplet is traced by Lagrangian method incorporated by aerodynamic drag, Coriolis and crntrifugal forces. Radiation is treated by sensible heat loss model. Calculation results are in good agreement with experimental data at the outlet of post combustion chamber in Daejon 4th industrial complex. The flue gas shows the temperature range of $900\sim1000^{\circ}C$, velocity of 5m/s and NO concentration of 140ppm at the exit while the measured temperature, flue gas velocity and NO concentration are $967^{\circ}C$, $3\sim4m/s$ and $100\sim200ppm$respectively. Using the developed computer program a parametric study has been made with the variation of heat content of waste, castable length and SNCR variables for the determination of proper injector location. In general, the calculated results are consistent and physically acceptable.

• Journal of the Korea Organic Resources Recycling Association
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• v.21 no.4
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• pp.44-49
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• 2013

An establishment of dioxin-reduction operating skill for medium sized incineration facility is urgently needed in Korea with nearly 90% of medium sized incineration. Using lattice stoker incineration processing the capacity of 20 tons industrial general waste per day, similar properties of the household waste, dioxin-reduction is derived in optimum operating condition and parameters. As a result, CO haunting which is the minimization of frequency is found as the major parameter to minimize dioxin.

• Journal of Environmental Health Sciences
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• v.28 no.2
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• pp.99-108
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• 2002

This study was carried out to evaluate the Physicochemical characteristics of mined waste(separated waste and soil) and to predict environmental effect of an old landfill site located at north of Seoul. Municipal solid waster(MSW) had been disposed of at the old landfill site used in this study for about 2 years(1990-1992). The old landfill site selected for this study had accepted mainly municipal solid waste. The landfill-mined waste contained separated waste (40.9%) and soil(59.1%) by wet weight basis. The separated waste consisted of combustible(91.0%) and non-combustible(9.0%). The combustible waste was mainly non-biodegradable plastics. The low heating value of the separated combustible waste, which is calculated by Dulong's equation, was as high as 3,470kcal/kg. According to the Korean Extraction Procedure, separated waste and soil were proved to be not hazardous. The total content of heavy metal in the separated waste and soil met standard of California State, USA. Therefore the separated waste may be relandfilled at a sanitary landfill site and/or burned up at an incinerator, and the separated old soil may be used ad landfill cover-soil at a sanitary landfill site. Water quality of two streams was grade IV, of which water could be used as industrial and agricultural water. The streams near the landfill site might not be contaminated by leachate from the old landfill site. It was estimated that organic matter in the old landfill site would not be actively biodegraded within a short period of time.

• Journal of the Korean Ceramic Society
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• v.53 no.6
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• pp.659-664
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• 2016

Ash deposition of heat exchange boiler, caused mainly by accumulation of particulate matter, reduces heat transfer of the boiler system. Heat and mass transfer through porous media such as ash deposits mainly depend on the microstructure of deposited ash. Therefore, in this study, we investigated microstructural and thermal properties of the ash deposited on the boiler tube. Samples for this research were obtained from the fuel economizer tube in an industrial waste incinerator. To characterize microstructures of the ash deposit samples, scanning electron microscope (SEM), energy-dispersive spectroscopy (EDS), inductively coupled plasma optical emission spectroscopy (ICP-OES), X-ray diffraction (XRD) and BET analysis were employed. The results revealed that it had a porous structure with small particles mostly of less than a few micrometers; the contents of Ca and S were 19.3, 22.6% and 18.5, 18.7%, respectively. Also, the results showed that it consisted mainly of anhydrite ($CaSO_4$) crystals. - The thermal conductivities of the ash deposit sample obtained from the economizer tube in industrial waste incinerator were measured to be 0.63 and 0.54 W/mK at $200^{\circ}C$, which were about 100 times less than the thermal conductivity (61.32 W/mK) of the boiler tube itself, indicating that ash deposition on the boiler tube was closely related to a decrease in boiler heat transfer.

• Applied Chemistry for Engineering
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• v.3 no.2
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• pp.201-206
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• 1992

Annual amount of plastics waste including rubber and leather waste, generated in 1990 was about 2,600,000 tons. Amount of generation of plastics waste has rapidly increased, but fractions of recycling and incineration have gradually decreased. Recently, two-stage incinerator, consisting of gasifier and gas combustor, draws much attention in Korea. Plastics are gasified in the starved air condition in the gasifier and produced gas is fired in the combustor. Combustion of produced gas is much easier than that of solid plastics, and produces a little pollutants. Standardzation of technology and process automation are still needed, but this incineration technology is in the commercial stage. Next topic concerned with this two-stage incineration will be how to treat complex plastics waste including toxic substances generated from automobiles and household appliances. Pyrolysis, realized by indirect heating in inert atmosphere, can provide high-quality products with minimum emissions. Many plastics are easily decomposed into oil in pyrolysis conditions, which can be utilized as chemical feedstocks, or gasoline or kerosene depending on feed materials and operating conditions. This has been demonstrated in several pilot-scale tests performed in Japan, Germany, etc. Easy removal of HCl from PVC is one of the most decisive merits of pyrolysis process. But in general, further efforts should be made for the process to obtain marketability. The future of pyrolysis process depends on public concern about environmental problems and oil prices.

• 한국지구물리탐사학회:학술대회논문집
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• 2003.11a
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• pp.573-580
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• 2003

In Taiwan there are 21 Municipal Solid Waste Incinerators (MSWI) built to treat 80% of the MSW nationwide. Approximately 2,000 tons of incineration ashes of municipal waste contain reaction ash and fly ash (3:1 by weight)will be produced daily, and this may cause a serious waste problem. According to EPA regulations, reaction ash and fly ash produced after incineration should be properly treated. Landfill capacity barely meets the general demands. More efficient actions should be planned and taken. The study found 'reclamation' should be the optimal solution to this problem. Only limited research and previous successful experiences are available among other countries. An incinerator in Northern Taiwan is chosen for this study to make environmental bricks from the reaction ash and fly ash. From the previous tests, the results of strength test were measured. From the previous test results, the fly ash products have not reached the desired strength; hence, reaction ash is chosen for further pilot study. In the experiment, incineration ashes, cement and gravel are mixed in the ratio of 1:1:1(by weight), to ground concretization aggregate and pelletization aggregate, the concrete products made from the aggregates were of the strength of 108 $kgf/cm^2$ and 142 $kgf/cm^2$ individually. For the purpose of making nonstructural walls which met the State Building Standards. In the study, 50 tons of concrete products was yielded from aggregate and environmental bricks. Further observation and supervision are recommended to ascertain the resource recycling and reclamation. EPA has planned to build three 'Recycling Plants' in northern, middle and southern Taiwan to develop efficient techniques to produce concrete products, sub-base course, soundproofing wall, gravel, artificial fishing reefs, tiles, drainage, bricks and etc. This experiment of the demonstrative plant solves the problem of the incineration ashes and opens another opportunity to reclaim them.

• Analytical Science and Technology
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• v.18 no.5
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• pp.419-424
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• 2005

In recent years, dioxins which were designated as persistent organic pollutants and endocrine disrupters are treated as substance of environmental pollution and studied about human health risk assessment, emission pollutants estimation, analytical methods and so on. It is easy that dioxins are accumulated to soil because of the atmosphere circulation of burning up the waste. This is the comparative studies on the distribution relationship of dioxin isomers in exhausted gas of industrial waste and urban waste incinerators, ambient air and soil. A basis of PCDDs and PCDFs based on OCDD was drawn up to the curve and they correspond to dioxin isomers in exhausted gas of industrial waste and urban waste incinerators and ambient air. On comparing these results, It was found that the ambient air and exhausted gas of industrial waste incinerators were very similar in curve and ratio. Consequently, environmental by exposed dioxin depends on the exhausted gas of industrial waste incinerators than urban waste incinerators. In case of soil, even though we can not completely rule out the possibility of pollution source bring on pesticide and other factors, and naturally biological dissociations, the curve shape is very similar to exhausted gas of industrial waste incinerators and ambient air. So, we inform here that it was mainly caused by these environmental factors.

• Journal of Environmental Health Sciences
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• v.35 no.3
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• pp.226-234
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• 2009

The main objective of this study was to evaluate the effects on shape and size, compressive strength, water absorption and heavy metals leaching with various weight mixing ratios in waste ash brick products using waste recycling MSWI(Municipal Solid Waste Incinerator) bottom ash, steel slag and waste building material. The manufacturing processes for the waste ash brick consist of screening, mixing, conveyor transmission, compaction.forming, and curing steps of raw materials. The weight mixing ratios of steel slag around bottom ash were adjusted within the ranges of 10% to 30%. The reported results show that the width and thickness of the manufactured waste ash brick could be satisfied with $90{\pm}2mm\;and\;57{\pm}2mm$, respectively which are K.S. standards of products qualities. And in case of length, only 20-Ba50Ss30, 20-Ba60Wb20 and 20-Ba50Wb30 for the mixing ratios could be satisfied with $190{\pm}2mm$ that is K.S. standards of products quality. The compressive strength and water absorption for 20-Ba50Ss30 and 20-Ba70Wb10 were over $8N/mm^2$ and below 15% respectively that are K.S. standards of manufactured waste ash brick. The results of tests for the heavy metals leaching in the all manufactured waste ash bricks are also passed to the wastes management regulations. The cost analysis of 20-Ba50Ss30 is evaluated. The manufacturing cost is evaluated 34.3 won/brick with 8 hours and 20tons of raw material per day. Incinerators with problems in bottom ash disposal can therefore derive significant benefits from the application of waste ash brick production.

• Applied Chemistry for Engineering
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• v.8 no.5
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• pp.790-795
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• 1997

Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofuransfurans are the archetype of toxic chemicals. So it has absorbed public attention. The majors primary sources of PCDDS and PCDFs are chemical, thermal and photochemical reactions. Municipal solid waste incinerator facilities has been reported as the major contributors of dioxins to the environment. In this paper, Dioxins and furans were examined emission gas and fly ash produced during combustion in municipal solid waste incinerator. More effective method for sampling, extraction was described. The sample was extracted using a soxhlet method and purified using silicagel, alumina and carbon fibre HPLC to remove interfering compound. The extract was then analyzed by HRGC/HRMS. The result of this study showed recovery standard was good and the data resembled those of thermal processes. Total dioxins and furans were $1076.20pg/Nm^3$ and $1452.34pg/Nm^3$ respectively. The amount of highly chlorinated compound was more than that of lowly chlorinated compound. The 2,3,7,8-substituted TCDD was Just 0.34% of the total dioxins/furans amount.