• Resources Recycling
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• v.24 no.1
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• pp.28-34
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• 2015

Generally, when using copper slag mixed into the concrete, due to higher weight of copper slag, a reduction in the compressive strength and durability of the hardened concrete to increased bleeding is caused. In this study, hence copper slag, a kind of by-product was used as an alternative to the fine aggregate, it was carried out in combination with the use of fly ash in eliminating disadvantage and recycling aspects. As a result of this study, the mixing of fly ash is decreased in the 50% of bleeding, 5% of drying shrinkage, 30% of carbonation test and improvement of 10% of compressive strength than that of copper slag only at most.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.10a
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• pp.5-21
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• 2005

Urbanization rates of population range from about 1% in the developed countries to about 4% in developing countries. For a global population that may reach 10 billion within the next 40 years, pressure has arisen for an increase in the large-scale use of wastes and byproducts in construction. Ironically, most of the wastes that need to be recycled are generated in large cities where the need for constructed facilities to serve large population is high. Waste and recycled materials (WRM) that are used in construction are required to satisfy material strength, durability and contaminant teachability requirements. These materials exhibit a wide variety of characteristics owing to the diversity of industrial processes through which they are produced. Several laboratory-based investigations have been conducted to assess the pollution potential and load bearing capacity of materials such as petroleum-contaminated soils, coal combustion ash, flue-gas desulphurization gypsum and foundry sand. For full-scale systems, although environmental pollution potential and structural integrity of constructed facilities that incorporate WRM are interrelated, comprehensive schemes have not been developed for integrated assessment of the relevant field-scale performance factors. In this presentation, a framework for such an assessment is proposed and presented in the form of a flowchart. The proposed scheme enables economic, environmental, worker safety and engineering factors to be addressed in a number of sequential steps. Quantitative methods and test protocols that have been developed can be incorporated into the proposed scheme for assessing the feasibility of using WRM as partial or full substitutes for earthen highway materials in the field.

• Journal of Microbiology and Biotechnology
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• v.4 no.3
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• pp.215-221
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• 1994

Two strains of yeast (RA-74-2 and RA-912) showing superior fermenting ability at a high temperature were isolated from soils and wastewaters by an enrichment culture method. Based on the morphological and physiological charateristics, the two strains were identified as Saccharomyces cerevisiae and Kluyveromyces marxianus, respectively. RA-74-2 was able to grow upto $43^{\circ}C$ and sustain similar fermenting ability in the temperatures range from 30 to $40^{\circ}C$. In addition, the sugar- and ethanol-tolerance of RA-74-2 were 30% (w/v) glucose and 10% (v/v) ethanol, which appeared to be higher than those of nine other industrial yeast strains currently being used in the alcohol factories. The thermotolerant ethanol fermenting yeast RA-912 showed identical growth in the temperatures range from 35 to $45^{\circ}C$ and was resistant to various heavy metals. The quality and quantity of byproducts of the isolated yeast strains in fermentation broth after fermentation at $40^{\circ}C$ and $45^{\circ}C$ were similiar with those obtained at $30^{\circ}C$. These results show that RA-74-2 can be adopted for the ethanol fermentation process where the expenses for cooling system is significant, and suggest that RA-912 may be applied in either SSF(simultaneous saccharification and fermentation) or Flash-fermentation process and RA-912 may be used as a gene donor for the development of thermotolerant ethanol-fermenting yeasts.

• International Journal of Industrial Entomology and Biomaterials
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• v.7 no.1
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• pp.1-4
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• 2003

Sericulture is a traditional agro-industry, which involves mulberry cultivation and silkworm rearing, has made great contributes to the human civilization. With the development of national economy and modem technology, mulberry and silkworm are being used to develop products with functionality besides the traditional cocoon production in China. In this paper, we brief the current developing situation of sericultural byproducts with functionality in the following aspects. (1) Functional products from silkworm larvae: silkworm powder, white muscardine silkworm, isolation and purification of anti-bacterial proteins from the larvae and production of medically valuable substances by Bombyx mori nuclear polyhedrosis virus (BmNPV) vector. (2) Utilization of silkworm feces: for pillow and for isolation of chlorophyll etc. (3) Production of valuable Chinese traditional medicine like Cordyceps sinensis with pupae, functional utilization of pupa protein and chitin. (4) Silk as additives to cosmetics, silk food and medical materials. (5) Functional utilization of mulberry: cultivation of edible fungus on mulberry shoots as medium, mulberry fruit drinks, mulberry tea, etc. The prospect of sericultural byproduct industry in China is also discussed.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.290-292
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• 2004

Heavy metal contamination has been increased in aqueous environments near many industrial facilities, such as metal plating facilities, mining operations, and tanneries. The soils in the vicinity of many military bases are also reported to be contaminated and pose a risk of groundwater and surface water contamination with heavy metals. The biological removal of metals through bioaccumulation has distinct advantages over conventional methods; the process rarely produces undesirable or deleterious chemical byproducts, it is highly efficient, easy to operate and cost-effective in the treatment of large volumes of wastewater containing toxic heavy metals. In addition, a recent development of molecular biology shed light on the enhancing the microorganism's natural remediation capability as well as improving the current biological treatment. In this study, characteristics of the cell growth and heavy metal accumulation by Saccharomyces cerevisiae strains expressing phytochelatin syntahse (PCS) gene were studied in batch cultures. The AtCRFI gene was demonstrated to confer substantial increases in metal tolerance in yeast. PCS-expressing cells tolerated more Cd$^{2＋}$ than controls.

• Applied Chemistry for Engineering
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• v.25 no.6
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• pp.645-647
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• 2014

We synthesized $TiO_2$ ($Ru_x/TiO_2$) incorporating $TiO_2$ and Ru via an one-step hydrothermal method. The physical properties were characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS) and transmission electron microscopy (TEM). The prepared samples were applied as a catalyst for the oxidation of benzyl alcohol to benzaldehyde using molecular oxygen ($O_2$). Especially, the catalytic activities increased as the contents of ruthenium in $TiO_2$ increased without the formation of any byproducts.

• Membrane and Water Treatment
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• v.2 no.4
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• pp.207-223
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• 2011

Supported Liquid Membranes (SLMs) have been widely studied as feasible alternative to traditional processes for separation and purification of various chemicals both from aqueous and organic matrices. This technique offers various advantages like active transport, possibility to use expensive extractants, high selectivity, low energy requirements and minimization of chemical additives. SLMs are not yet used at large scale in industrial applications, because of the low stability. In the present paper, after a brief overview of the state of the art of SLM technology the facilitated transport mechanisms of SLM based separation is described, also introducing the small and the big carrousel models, which are employed for transport modeling. The main operating parameters (selectivity, flux and permeability) are introduced. The problems related to system stabilization are also discussed, giving particular attention to the influence of membrane materials (solid membrane support and organic liquid membrane (LM) phase). Various approaches proposed in literature to enhance SLM stability are also reviewed. Modification of the solid membrane support, creating an additional layer on membrane surface, which acts as a barrier to LM phase loss, increases system stability, but the membrane permeability, and then the flux, decrease. Stagnant Sandwich Liquid Membrane (SSwLM), an implementation of the SLM system, results in both high flux and stability compared to SLM. Finally, possible large scale applications of SLMs are also reviewed, evidencing that if the LM separation process is opportunely carried out (no production of byproducts), it can be considered as a green process.

• Computers and Concrete
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• v.24 no.5
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• pp.453-458
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• 2019

Today, concrete remains the most important, durable, and reliable material that has been used in the construction sector, making it the most commonly used material after water. However, cement continues to exert many negative effects on the environment, including the production of carbon dioxide (CO2), which pollutes the atmosphere. Cement production is costly, and it also consumes energy and natural non- renewable resources, which are critical for sustainability. These factors represent the motivation for researchers to examine the various alternatives that can reduce the effects on the environment, natural resources, and energy consumption and enhance the mechanical properties of concrete. Geopolymer is one alternative that has been investigated; this can be produced using aluminosilicate materials such as low calcium (class F) FA, Ultra-Fine GGBS, and high calcium FA (class C, which are available worldwide as industrial, agricultural byproducts.). It has a high percentage of silica and alumina, which react with alkaline solution (activators). Aluminosilicate gel, which forms as a result of this reaction, is an effective binding material for the concrete. This paper presents an up-to-date review regarding the important engineering properties of geopolymer formed by FA and slag binders; the findings demonstrate that this type of geopolymer could be an adequate alternative to ordinary Portland cement (OPC). Due to the significant positive mechanical properties of slag-FA geopolymer cements and their positive effects on the environment, it represents a material that could potentially be used in the construction industry.

• Steel and Composite Structures
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• v.49 no.6
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• pp.645-666
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• 2023

Due to the steadily declining supply of natural coarse aggregates, the concrete industry has shifted to substituting coarse aggregates generated from byproducts and industrial waste. Oil palm shell is a substantial waste product created during the production of palm oil (OPS). When considering the usage of OPSC, building engineers must consider its uniaxial compressive strength (UCS). Obtaining UCS is expensive and time-consuming, machine learning may help. This research established five innovative hybrid AI algorithms to predict UCS. Aquila optimizer (AO) is used with methods to discover optimum model parameters. Considered models are artificial neural network (AO - ANN), adaptive neuro-fuzzy inference system (AO - ANFIS), support vector regression (AO - SVR), random forest (AO - RF), and extreme gradient boosting (AO - XGB). To achieve this goal, a dataset of OPS-produced concrete specimens was compiled. The outputs depict that all five developed models have justifiable accuracy in UCS estimation process, showing the remarkable correlation between measured and estimated UCS and models' usefulness. All in all, findings depict that the proposed AO - XGB model performed more suitable than others in predicting UCS of OPSC (with R², RMSE, MAE, VAF and A_15-index at 0.9678, 1.4595, 1.1527, 97.6469, and 0.9077). The proposed model could be utilized in construction engineering to ensure enough mechanical workability of lightweight concrete and permit its safe usage for construction aims.

• Applied Chemistry for Engineering
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• v.25 no.5
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• pp.531-537
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• 2014

A catalytic plasma reactor was employed for the oxidation of isopropyl alcohol (IPA) classified as a volatile organic compound (VOC). Copper oxide (Cu : 0.5% (w/w)) supported on a multichannel porous ceramic consisting of ${\alpha}-Al_2O_3$ was used as a catalyst, which was directly exposed to the plasma created in it. The effects of discharge voltage and reaction temperature on the concentrations of IPA and its byproducts were examined to understand the behavior of the catalytic plasma reactor. Without thermal insulation, the reactor temperature increased up to $120^{\circ}C$ at an applied voltage of 17 kV (discharge power : 28 W), and the IPA at a flow rate of $1L\;min^{-1}$ ($O_2$ : 10% (v/v); IPA : 1000 ppm) was completely removed. At temperatures below $120^{\circ}C$, however, besides the desirable product $CO_2$, several unwanted byproducts such as acetone, formaldehyde and CO were also formed from IPA. On the other hand, when the reactor was thermally insulated, the plasma discharge increased the temperature up to $265^{\circ}C$ under the same condition and most of IPA was oxidized to $CO_2$. Without loading CuO on the ceramic support, the plasma discharge in the thermally insulated reactor produced nearly equal amounts of $CO_2$ and CO. On comparison, with the catalyst alone (temperature : $265^{\circ}C$), more than 70% of the removed IPA was simply converted into another type of VOC (acetone), indicating that the catalyst assisted by the plasma is more effective in the oxidation of IPA than that of the catalyst-alone process.