• 제목/요약/키워드: industrial byproducts

검색결과 106건 처리시간 0.023초

고로슬래그 미분말을 혼입한 기포콘크리트의 물리적 특성 (Physical Properties of Foamed Concrete using Blast-Furnace Slag)

  • 조은석;임정준;송하영;이상수
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2019년도 추계 학술논문 발표대회
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    • pp.164-165
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    • 2019
  • Light-weight foamed concrete using cement as a raw material consumes a lot of energy and generates $CO_2$ because of the high temperature firing process in the manufacturing process of cement. This study was carried out to evaluate the use of blast furnace slag through the properties analysis by substituting a certain amount of blast furnace slag as an industrial by-product as a substitute for cement. The experimental results showed similar characteristics to those of using only cement when the blast furnace slag fine powder was used in an appropriate amount. Therefore, if a certain amount of cement is replaced with blast furnace slag powder, it can maintain similar quality, reduce natural resources and energy consumption, and reduce carbon dioxide emissions.

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건설폐기물을 활용한 이산화탄소 반응경화 시멘트 제조에 관한 연구 (Manufacturing of Calcium Silicate Cement Using Construction Waste)

  • 이향선;손배근;송훈
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2023년도 봄 학술논문 발표대회
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    • pp.47-48
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    • 2023
  • In the domestic industrial sector, greenhouse gases emitted from the cement industry account for about 10%, with most of them generated during the cement clinker calcination process. During the calcination process, 57% of carbon dioxide is emitted from the decarbonation reaction of limestone, 30% from fuel consumption, and 13% from electricity usage. In response to these issues, the cement industry is making efforts to reduce carbon dioxide emissions by developing technologies for raw material substitution and conversion, improving process efficiency by utilizing low-carbon alternative heat sources, developing CO2 capture and utilization technologies, and recycling waste materials. In addition, due to the limitations in purchasing and storing industrial byproducts generated from industrial facilities, many studies are underway regarding the recycling of construction waste. Therefore, this study analyzes the manufacture of calcium silicate cement (CSC), which can store carbon dioxide as carbonate minerals in industrial facilities, and aims to contribute to the development of environmentally friendly regenerated cement using construction waste.

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유전체 장벽 방전에 의한 벤젠의 분해 (Decomposition of Benzene by Dielectric Barrier Discharge)

  • 이용훈;이재호;박동화
    • 공업화학
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    • 제18권3호
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    • pp.213-217
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    • 2007
  • 본 연구에서는 유전체장벽방전을 이용하여 휘발성 유기화합물의 일종인 벤젠의 분해 경향과 분해 생성물의 선택성에 대해서 연구하였다. 유전체장벽방전의 공정변수에 따른 벤젠의 분해율과 분해 생성물의 선택성을 높이기 위해서 반응기 내부에 촉매(H-ZSM-5, Na-Y)를 사용하였다. 실험은 대기압에서 수행하였으며, 방전전압, 체류시간, 농도 등의 공정변수에 따른 분해율을 조사하였다. 유전체 장벽방전만을 사용하는 방법과 비교하여 여기에 촉매를 동시에 사용하는 하이브리드 방전이 같은 전압과 체류시간조건에서 보다 효과적인 벤젠의 분해 방법임을 확인하였다.

Effects of Feeding Different Protein Supplements on Digestibility, Nitrogen Balance and Calcium and Phosphorus Utilization in Sheep

  • Viswanathan, T.V.;Fontenot, J.P.
    • Asian-Australasian Journal of Animal Sciences
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    • 제22권5호
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    • pp.643-650
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    • 2009
  • Two metabolism trials were conducted with 24 wether lambs to investigate the effects of feeding crab meal and other protein supplements on N utilization, digestibility and Ca and P balance in sheep. The lambs (avg. BW, 25 kg) were randomly allotted to eight diets in each of two trials. The supplements were: i) none, negative control (NC); ii) soybean meal (SBM), control; iii) supplement based on industrial byproducts of both plant and animal origin (IPA); iv) experimental supplement based on byproducts of animal origin (ESA); v) hydrolyzed supplement No 4. (HESA); vi) commercial supplement based on animal protein (CS), $Pro-Lak^{(R)}$ vii) crab meal (CM); and viii) urea (U). The supplements supplied 33% of the total dietary N (CP, 9.8%; DM basis). Lambs fed the NC diet had lower (p<0.05) DM and OM digestibility. Lower (p<0.05) apparent absorption of N was recorded for the lambs fed the HESA and NC diets. Sheep fed CM had lower Ca absorption compared to SBM. Highest (p<0.05) P absorption was observed for lambs fed CS and CM and lowest for U and NC diets. Sheep fed CM had higher (p<0.05) total VFA concentration (65.7 ${\mu}mol/ml$), compared to those fed ESA, CS, and NC diets (47.3, 49.8, and 49.5 ${\mu}mol/ml$, respectively). Highest (p<0.05) ruminal $NH_3$ N (29.6 mg/dl) was observed in lambs fed the U diet, while those fed the NC diet had the lowest (p<0.05) average value (7.66 mg/dl). Lambs fed the U diet had the highest (p<0.05) blood urea N (10.67 mg/dl). The present study showed that N utilization of diets supplemented with experimental supplements based on feather meal and blood meal; commercial supplement based on animal protein, $Prolak^{(R)}$ supplement based on plant protein and blood meal; and crab meal are comparable with that of soybean meal.

어류 프레임 농축액과 시판 사골 농축액의 위생적 및 영양적 특성 비교 (Comparison on Sanitary and Nutritional Characteristics Between Skipjack Tuna Ktsuwonus pelamis Frame and Commercial Beef Bone Extract Concentrates)

  • 임치원;성상욱;허민수;이태기;김진수
    • 한국수산과학회지
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    • 제50권5호
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    • pp.467-472
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    • 2017
  • There is increasing interest in developing flavor-enriched concentrate using byproducts of skipjack tuna Ktsuwonus pelamis as a replacement for commercial beef bone extract concentrate (CBB-EC). This study was compared on sanitary and nutritional characteristics between skipjack tuna frame extract concentrate (ST-EC) and CBB-EC as a control of skipjack tuna frame extract concentrate. The moisture contents of CBB-EC and ST-EC 41.4-4.9% and 45.3%, respectively. The results of viable cell counts and E. coli assays suggested that CBB-EC and ST-EC is a safe and sanitary for use in food. There were no differences in peroxide values among CBB-ECs. The total amino acid contents in CBB-EC and ST-EC were 25.6-29.3 g/100 g and 37.9 g/100 g, respectively, and the major amino acids present glutamic acid, proline, glycine, alanine and arginine. Regardless of kinds of the mineral, mineral contents of ST-EC higher than those of CBB-EC. The major fatty acids were 16:0, 18:0 and 18:1n-9 in CBB-EC, 16:0, 18:1n-9 and 22:6n-3 in ST-EC. These results can be used as background information to develop flavor-enriched concentrates from byproducts of skipjack tuna as replacement for CBB-EC.

ECH 생산공정 개선을 위한 Hypochlorination 반응에 관한 연구 : 부반응 억제 (A Study on the Hypochlorination Reaction for Improvement of Epichlorohlydrin Production Process : Reduction of Side Reacion)

  • 이철행;전상준;이태용;홍원희;윤창한;김영섭;조병남;김연석
    • 청정기술
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    • 제9권1호
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    • pp.29-35
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    • 2003
  • 기존의 Epichlorohydrin의 생산 공정을 개선하기 위해 중간 생성물인 dichlorohydrin생성 반응인 hypochlorination 반응에 대한 실험을 통해 개선방안을 조사하였다. 첫 번째로 이 반응에서 사용되고 있는 공업용수를 PVC 공장으로부터 방출된 폐수를 재활용하여 사용하였을 경우 반응 수율에 미치는 영향에 대해 실험하였고 실제적인 반응 생성물 조성에는 크게 영향을 미치지 않는 것으로 나타났다. 부반응물 중 거의 대부분을 차지하고 있는 TCPA를 정제공정 이전에 "추출제 A"를 사용하여 제거할 수 있다. 이를 이용하여 TCPA에 의한 부가적인 부반응을 억제하고 후단의 정제공정에서 분리하는데 소요되는 에너지를 절감할 수 있을 것이다. 또한 Allyl chloride와 반응하는 염소기체의 양을 감소시키면서 생성물의 조성변화를 관찰하였다. 주반응 생성물의 수율에 는 거의 영향을 미치지 않으면서 부반응물의 비율이 다소 감소하는 경향을 확인할 수 있었다.

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반도체 가공 작업환경에서 부산물로 발생되는 주요 금속산화물의 입자 크기, 형상, 결정구조에 따른 독성 고찰 (Size, Shape, and Crystal Structure-dependent Toxicity of Major Metal Oxide Particles Generated as Byproducts in Semiconductor Fabrication Facility)

  • 최광민
    • 한국산업보건학회지
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    • 제26권2호
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    • pp.119-138
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    • 2016
  • Objectives: The purpose of this study is to review size, shape, and crystal structure-dependent toxicity of major metal oxide particles such as silicon dioxide, tungsten trioxide, aluminum oxide, and titanium dioxide as byproducts generated in semiconductor fabrication facility. Methods: To review the toxicity of major metal oxide particles, we used various reported research and review papers. The papers were searched by using websites such as Google Scholar and PubMed. Keyword search terms included '$SiO_2$(or $WO_3$ or $Al_2O_3$ or $TiO_2$) toxicity', 'health effects $SiO_2$(or $WO_3$ or $Al_2O_3$ or $TiO_2$). Additional papers were identified in references cited in the searched papers. Results: In various cell lines and organs of human and animals, cytotoxicity, genotoxicity, hepatoxicity, fetotoxicity, neurotoxicity, and histopathological changes were induced by silicon dioxide, tungsten trioxide, aluminium oxide, and titanium dioxide particles. Differences in toxicity were dependent on the cell lines, organs, doses, as well as the chemical composition, size, surface area, shape, and crystal structure of the particles. However, the doses used in the reported papers were higher than the possible exposure level in general work environment. Oxidative stress induced by the metal oxide particles plays a significant role in the expression of toxicity. Conclusions: The results cannot guarantee human toxicity of the metal oxide particles, because there is still a lack of available information about health effects on humans. In addition, toxicological studies under the exposure conditions in the actual work environment are needed.

농업부산물 크라프트펄프의 혼합에 따른 판지의 물성변화 (Application Evaluation of Physical and Strength Properties of Paperboard by Kraft Pulp Mixing Made from Agricultural Byproducts)

  • 이지영;임기백;김선영;박종혜;김은혜;성용주;허영준;김영훈;김연오;이세란
    • 펄프종이기술
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    • 제46권5호
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    • pp.43-50
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    • 2014
  • The cultivation of agricultural crops results in the generation of agricultural byproducts. Researchers have reported that these materials can be useful in a variety of applications. However, over 50% of them are currently discarded because of the lack of specific technologies in industrial applications. Therefore, effective and specific applications must be developed in order to manufacture high-quality materials using discarded lignocellulosic resources. In this study, we determined the possibility of using kraft pulp from major agricultural byproducts as a raw material for the manufacture of paperboard. Rice husks, peanut husks, and garlic stems were obtained and used to prepare many kinds of kraft pulps by controlling the active alkali, sulfidity, reaction time, and liquor ratio. After the production of these kraft pulps, handsheets were manufactured by mixing them with KOCC. After preconditioning, the physical properties and strengths of the handsheets were measured according to the TAPPI test methods. The shapes, lengths, and widths of the pulp fibers varied according to the type of agricultural byproduct and the kraft pulping conditions. Rice husk and garlic stem pulps manufactured under mild pulping conditions resulted in handsheets of higher bulk than other pulps. Garlic stem pulps manufactured under mild pulping conditions were stronger than rice husk pulps and peanut husk pulps.

산업부산물인 순환골재 및 순환골재/제강슬래그 조합을 이용한 수용액상에서의 중금속 제거 특성 (Removal Characteristics of Heavy Metals from Aqueous Solution by Recycled Aggregate and Recycled Aggregate/Steel Slag Composites as Industrial Byproducts)

  • 신우석;김영기
    • 공업화학
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    • 제26권4호
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    • pp.477-482
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    • 2015
  • 본 연구에서는 순환골재와 순환골재/제강슬래그 조합을 이용하여 수용액상에서 $Cr^{6+}$$As^{3+}$ 흡착 특성을 평가하였다. 순환골재와 제강슬래그의 주요 성분(CaO, $SiO_2$, $Al_2O_3$, $Fe_2O_3$)이 각각 91%와 86.9% 함유되어 흡착제로서 유리한 조성을 가지고 있다. 순환골재와 순환골재/제강슬래그 조합에 있어서 $Cr^{6+}$$As^{3+}$의 동역학적 평형은 각각 180 min과 360 min 이후에 도달하였다. 동적흡착결과를 유사 1차 모델과 유사 2차 모델로 분석한 결과 두 모델 모두 더딘 평형 결과를 나타냈다. 순환골재와 순환골재/제강슬래그 조합에 있어서, 평형흡착 실험은 Freundlich 모델에 잘 부합했고, $Cr^{6+}$보다 $As^{3+}$의 흡착량이 더 높았다. 용액의 pH가 6에서 10으로 증가함에 따라서 $As^{3+}$의 흡착률은 증가하는 것으로 나타났다. 한편, $Cr^{6+}$는 감소를 나타냈다. 본 연구 결과를 통해 순환골재 및 순환골재/제강슬래그 조합은 중금속($Cr^{6+}$, $As^{3+}$)을 효율적으로 제거할 수 있는 흡착제로 판단된다.

폐석회를 이용한 매립지 차수재 개발 (A Development of Landfill Liner by Utilizing Waste Lime)

  • 김준섭;이승학;박준범
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 1999년도 봄 학술발표회 논문집
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    • pp.521-528
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    • 1999
  • As the size of our industry and population inclose, the byproducts such as municipal solid wastes, industrial wastes are in the increasing phase. The treatment of such things is rising as a social problem. Today, the final disposal of these wastes depends mostly on the landfill, and the sanitary landfill is required and designed for preventing soil and groundwater contamination. Clays have been used for a liner material of a sanitary landfill, however, the high quality clay is hard to come by and quite expensive as a lining material in our country. Using the waste lime produced abundantly every year from chemical processes was studied here, made from the proper mixing of the bentonite and the waste lime meets the regulations from the USEPA. The soil property index tests (sieve analysis, specific gravity test Atterberg limit test) were performed, and at last to confirm the sorption characteristics of the bentonite and the waste lime the sorption isotherm equilibrium test and the sorption isotherm were performed with Toluene and Ethylbenzene which are the main components of the leachate from the landfill.

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