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Analysis of Chemical Compounds of Gaseous and Particulate Pollutants from the Open Burning of Agricultural HDPE Film Waste

  • Kim, Tae-Han;Choi, Boo-Hun;Kook, Joongjin
    • Journal of People, Plants, and Environment
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    • v.24 no.6
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    • pp.585-593
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    • 2021
  • Background and objective: Illegal open-air incineration, which is criticized as a leading source of air pollutants among agricultural activities, currently requires constant effort and attention. Countries around the world have been undertaking studies on the emission of heavy metal substances in fine dust discharged during the incineration process. A precise analytical method is required to examine the harmful effects of particulate pollutants on the human body. Methods: In order to simulate open-air incineration, the infrastructure needed for incineration tests complying with the United States Environmental Protection Agency (EPA) Method 5G was built, and a large-area analysis was conducted on particulate pollutants through automated scanning electron microscopy (SEM)-energy-dispersive X-ray spectroscopy (EDS). For the test specimen, high-density polyethylene (HDPE) waste collected by the DangJin Office located in Choongcheongnam-do was used. To increase the identifiability of the analyzed particles, the incineration experiment was conducted in an incinerator three times after dividing the film waste into 200 g specimens. Results: Among the metal particulate matters detected in the HDPE waste incineration test, transition metals included C (20.8-37.1 wt%) and O (33.7-37.9 wt%). As for other chemical matters, the analysis showed that metal particulate matters such as metalloids, alkali metals, alkaline earth metals, and transition metals reacted to C and C-O. Si, a representative metalloid, was detected at 14.8-20.8 wt%, showing the highest weight ratio except for C and O. Conclusion: In this study, the detection of metal chemicals in incinerated particulate matters was effectively confirmed through SEM-EDS. The results of this study verified that HDPE waste adsorbs metal chemicals originating from soil due to its own properties and deterioration, and that when incinerated, it emits particulate matters containing transition metals and other metals that contribute to the excessive production and reduction of reactive oxygen species.

Volume Reduction Ratio and Decontamination Factor of the Bench Scale Radwaste Incineration Process (실험용 방사성 폐기물 소각로의 감용비와 제염계수)

  • Seo, Yong-Chil;Yang, Hee-Chul;Kim, Joon-Hyung;Park, Hun-Hwee
    • Nuclear Engineering and Technology
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    • v.21 no.4
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    • pp.321-331
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    • 1989
  • A bench scale incineration process for the burnable radwaste has been constructed and operated at KAERI as a self-surpported development of incineration technology. The purposes of operating the process are to get experience in incineration, to analyze the characteristics of combustion and to test the performance of off-gas treatment units. Simulated paper and polyethylene wastes were incinerated. Volume reduction ratio and decontamination factor of the process have been determined to observe the economical efficiency and operational capability of the process. A methodology to estimate the acceptance limit of specific activity to an incineration facility by using a decontamination factor and to calculate the volume reduction ratio of the facility is introduced. The acceptance criteria for different radionuclides in the combustible waste at the bench scale incineration process are suggested using this methodology.

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Incineration of Waste Water Sludge and Coal In a Circulating Fluidized Bed Combustor (순환유동층에서 폐수슬러지와 석탄의 혼소 특성)

  • Bae, Dal-Hee;Shun, Do-Won;Park, Jae-Hyeon;Ryu, Ho-Jung;Park, Do-Hyun
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.165-172
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    • 2004
  • Co-incineration of coal and wastewater sludge was r;erfonn:rl in a O.lMWth bench scale circulating fluidized bed combustor(CFBC) Sludge was received from a wastewater treatment plant in a dye industrial complex in Busan. Metropolis. Moisture content of received sludge was 80%. Coal and sludge mixture was prepared with weight ratio of 90/10, 85/15 and 80/20. Co-combustion characteristics of the coal and sludge mixture demonstrated stable combustion conditions. Component analysis, incineration characteristics, boiler performance was measured before and after the test and application for commercial 59MWth CFBC boiler. The release of hazardous components such as $SO_2$ and Cl was suppressed by the presence of inherent minerals of Ca, Na, K in coal and sludge mixture. Pre-drying was not essential but it was recommended for the benefits of manageability of sludge.

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The pilot study on reclamation of incineration ashes of municipal waste in the demonstrative factory

  • Chang Hui-Lan;Liaw Chin-Tson;Leu Ching-Huoh
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.573-580
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    • 2003
  • In Taiwan there are 21 Municipal Solid Waste Incinerators (MSWI) built to treat 80% of the MSW nationwide. Approximately 2,000 tons of incineration ashes of municipal waste contain reaction ash and fly ash (3:1 by weight)will be produced daily, and this may cause a serious waste problem. According to EPA regulations, reaction ash and fly ash produced after incineration should be properly treated. Landfill capacity barely meets the general demands. More efficient actions should be planned and taken. The study found 'reclamation' should be the optimal solution to this problem. Only limited research and previous successful experiences are available among other countries. An incinerator in Northern Taiwan is chosen for this study to make environmental bricks from the reaction ash and fly ash. From the previous tests, the results of strength test were measured. From the previous test results, the fly ash products have not reached the desired strength; hence, reaction ash is chosen for further pilot study. In the experiment, incineration ashes, cement and gravel are mixed in the ratio of 1:1:1(by weight), to ground concretization aggregate and pelletization aggregate, the concrete products made from the aggregates were of the strength of 108 $kgf/cm^2$ and 142 $kgf/cm^2$ individually. For the purpose of making nonstructural walls which met the State Building Standards. In the study, 50 tons of concrete products was yielded from aggregate and environmental bricks. Further observation and supervision are recommended to ascertain the resource recycling and reclamation. EPA has planned to build three 'Recycling Plants' in northern, middle and southern Taiwan to develop efficient techniques to produce concrete products, sub-base course, soundproofing wall, gravel, artificial fishing reefs, tiles, drainage, bricks and etc. This experiment of the demonstrative plant solves the problem of the incineration ashes and opens another opportunity to reclaim them.

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A Study on the Enhancement of Inventories for Precursors (NOx, SOx) Released from Open Burning of Agricultural Waste Vinyl Causing the Secondary Generation of Particulate Matters

  • Kim, Tae-Han;Choi, Boo-Hun
    • Journal of People, Plants, and Environment
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    • v.24 no.2
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    • pp.195-207
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    • 2021
  • Background and objective: While response measures to particulate matters in rural areas are limited due to poor inventory record keeping in the agricultural sector, it is necessary to control agricultural waste vinyl and the emission of precursors released from open burning and the secondary generation of particulate matters. Currently, the open burning emission calculation method uses the definition prescribed in CAPSS by the National Institute of Environmental Research. Methods: This study presented an open burning emission calculation formula for agricultural waste vinyl, which is included as agricultural waste. As for activity data, the open burning ratio of agricultural waste vinyl, and the annual incineration volume provided in the Status Survey by the Ministry of Agriculture, Food, and Rural Affairs were applied. The emission factor was generated through incineration tests on three agricultural plastic film samples collected by the Korea Environment Corporation. Results: Among precursors, SOx and NOx were selected and their emission features were monitored with incineration experiment infrastructure based on the EPA 5G method. The highest emission concentration by agricultural waste type was concentrated in the first and second quarters. As for emission factor of SO2, it was calculated at 98.25 g/kg for mulching-use LDPE, 52.31 g/kg for greenhouse-use LDPE, and 14.40 g/kg for HDPE. As for NOx, it was calculated at 18.21 g/kg for mulching-use LDPE, 16.49 g/kg for greenhouse-use LDPE, and 10.67 g/kg for HDPE. Conclusion: This test confirmed the incineration features of PE-based plastics, ascertained the SOx emission factor that had not been included in open burning in the past, and established that low NOx emission concentration is interfered by soil mixed with livestock excretions. The findings from this study are expected to contribute to improving the system for controlling air pollutants in rural environments.

A feasibility study on the application of turtle boat form to the incinerating vessel (거북선 형상의 해상소각선 실용화 가능성에 관한 연구)

  • 이귀주;최영빈
    • Journal of Ocean Engineering and Technology
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    • v.11 no.3
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    • pp.95-99
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    • 1997
  • In these days, the pollution of marine environment near island at Korean coastal zone caused by the trash human waste and livestocks excreata become intensified. One of the most economic and efficient way to prevent this pollution problem is to set up island circulating incineration system. In this paper, the result of feasibility study on the application of turtle boat hull form to the incinerating vessel has been summarized especially for the resistance and course keeping point of view.

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A Study on Quantitative Supply of Sewage Sludge for Co-Incineration of Municipal Solid Waste and Sewage Sludge (하수슬러지와 생활폐기물 혼합소각시 하수슬러지 정량공급에 관한 연구 - Batch Test 중심으로)

  • Cho, Jae-Beom;Kim, Woo-Gu;Yeon, Kyeong-Ho;Shin, Jung-Hun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.1
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    • pp.64-69
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    • 2013
  • The various promotion countermeasures such as solidification, carbonization, and the creation of cement materials have been considered to existing treatment methods such as incineration and the creation of composts, since direct landfill was prohibited for encouraging the recycling based on the sludge treatment on land. The Main objective of this study is to investigate the feasibility of co-incineration for MSW (municipal solid waste) and SS (sewage sludge) through the quantitative supply of sewage sludge. In this study, optimum water content to operate normally incinerator is 85%. In order to increase the workability of sewage sludge, it is necessary to supply properly water. In the case study of sites, optimum water content is 87% due to the water evaporation. Therefore, it was found that the water content up to 87% would be reached the stable operation of co-incinerator on the mixture of municipal waste solid and sewage sludge.

An Study on Compressive Strength Properties of Mortar with Municipal Solid Waste Incineration Ash Melted Slag Powder (쓰레기 소각재 용융슬래그 미분말을 혼입한 모르타르의 압축강도 특성에 대한 연구)

  • Lee, Yong-Moo;Kim, Young-Su
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.1
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    • pp.53-58
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    • 2016
  • In order to investigate the feasibility of municipal solid waste incineration ash melted slag powder as admixture, an experimental study was performed on cement mortar with municipal solid waste incineration ash melted slag powder. Fresh mortar properties and strength properties with various municipal solid waste incineration ash melted slag powder replacement ratios were estimated. There replacement ratio adopted in this study was 0, 10, 20, 30, 40, 50%. After then flow properties was considered as properties of fresh mortar. And compressive strength was determined 3, 7, 14, 28, 56 days for the hardened mortar specimens. According to the test results, the flow of mortar was increased with in replacement amount of municipal solid waste incineration ash melted slag powder. Furthermore, compressive strength at early age was decreased, whereas the compressive strength at the age of 28, 56day was increased.

Analysis of Heavy Metal Concentration on Working Clothes for Waste Incinerating Workers (생활폐기물 소각장 작업복의 중금속 분석)

  • Park, Soon-Ja
    • The Korean Journal of Community Living Science
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    • v.18 no.1
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    • pp.39-53
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    • 2007
  • The purpose of this study was to determine the characteristics of an experimental protective clothing material with regard to comfort and isolation from the hazardous heavy metals produced in municipal waste incineration. An analysis was conducted on the total concentrations of heavy metals in some parts such as surface, middle layer, and interior for the treated fabric, and the untreated one, and working clothes. We conclude that the processed fabric with charcoal for working clothes showed the least exposure to heavy metals of the three. Working clothes worn by workers during waste incineration were much more contaminated than the untreated and treated materials. The material of working clothes could be chosen according to the function with regard to its original chemical characteristics, which are the proper results of the dyeing process. The processed fabric material has high degrees of moisture regain, thermal insulation, water vapor penetration, and antibacterial function; consequently, it is much more comfortable to wear. The fabric material proposed in this research contributed much more to blocking heavy metal concentrations (such as Cd, Pb, Cu, Cr, Zn, Mn) than did the fabric of working clothes at present. Consequently, we strongly suggest that the material of working clothes be upgraded by adopting the above-mentioned charcoal-processed fabric. Materials of working clothes must be improved to increase comfort and prevent harmful gas, flying dust, and heavy metals from permeating the fabrics.

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The Development of Turtle Boat Hull Formed Floating Type Multi-purpose Incinerating Vessel (거북선 형상의 다목적 부유식 해상쓰레기 소각선 개발)

  • 이귀주;류태호;박원미
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2000.04a
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    • pp.117-122
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    • 2000
  • In these days, the pollution of marine environment near island at Korean coastal zone caused by the trash, human waste and livestocks excreta become series problem. One of the most economic and efficient way to prevent this pollution problem is to set up island circulating incineration system. In this paper, the results of feasibility study on the application of turtle boat hull form to the incinearting vessel has been summarized especially for the resistance and course keeping point of view.

  • PDF