• Journal of the Korean Physical Society
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• v.73 no.9
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• pp.1329-1333
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• 2018

We investigated the mechanism of mobility enhancement after the dehydrogenation process in polycrystalline silicon (poly-Si) thin films. The dehydrogenation process was performed by using an in-situ CVD chamber in a $N_2$ ambient or an ex-situ furnace in air ambient. We observed that the dehydrogenated poly-Si in a $N_2$ ambient had a lower oxygen concentration than the dehydrogenated poly-Si annealed in an air ambient. The in-situ dehydrogenation increased the (111) preferred orientation of poly-Si and reduced the oxygen concentration in poly-Si thin films, leading to a reduction of the trap density near the valence band. This phenomenon gave rise to an increase of the field-effect mobility of the poly-Si thin film transistor.

• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.427-432
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• 2005

This study treats the advantage of in situ line source method measuring the heat transfer capacity of a borehole, using mobile equipment, to determine the thermal properties of the entire borehole system such as thermal conductivity, diffusiveity. volumetric heat capacity, and borehole thermal resistance. The results from the response test include not only the thermal properties of the ground and the borehole, but also conditions that are difficult to estimate, e,g. natural convection in the boreholes, asymmetry in the construction, etc. In this study, 1) theoretical in situ methods for assessing working fluid temperature variation in V-type PE tube have been introduced, and 2) TRTE(Thermal Response Test Equipment) has been built based on these kinds of theoretical in situ methods. Basically TRTE consists of a pump, a heater and temperature sensors for measuring the inlet and outlet temperatures of the borehole. In order to make equipment easily transportable it is set up on a small trailer. Since the response test takes above two days to execute, the test was fully automatic in recording measured data using Labview DAS(Data acquisition system) program. The test was demonstrated in the course of intensive research in this field through the one site at Ulsan city in Korea. From this kind of thermal properties test of borehole systems in situ, the design of the borehole system can be optimized regarding the total geological, hydro-geological and technical conditions at the location.

• Textile Coloration and Finishing
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• v.15 no.3
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• pp.127-131
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• 2003

Acrylonitrile(AN) was solution-polymerized in dimethyl sulfoxide(DMSO) and tertiary butyl alcohol(TBA) at 30, 40, $50^\circ{C}$ using a low temperature initiator, 2,2'-azobis(2,4-dimethylvaleronitrile) (ADMVN). The low temperature polymerization using ADMVN, DMSO, and TBA is to be successful in obtaining high molecular weight polyacrylonitrile(PAN) with less branches by solution polymerization. Throug a polymerization of AN in DMSO at $30^\circ{C}$, PAN having viscosity-average molecular weight$(M_v)$ of 931,000 was obtained. And then, during AN solution polymerization in DMSO and TBA using a cosolvent system the in-situ formation of microfibrillar structure has been discovered at the cosolvent composition of 24/1$(V_{DMSO}/V_{TBA})$. The simultaneous process of gelation and phase separation of long chain molecules may explain the in-situ formation of PAN fibers during polymerization.

• Proceedings of the Materials Research Society of Korea Conference
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• 2012.05a
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• pp.70.1-70.1
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• 2012

In-situ X-ray photoelectron spectroscopy (XPS) and infrared (IR) spectroscopy studies of SOFC cathode materials will be discussed in this presentation. The mixed conducting perovskites (ABO3) containing rare and alkaline earth metals on the A-site and a transition metal on the B-site are commonly used as cathodes for solid oxide fuel cells (SOFC). However, the details of the oxygen reduction reaction are still not clearly understood. The information about the type of adsorbed oxygen species and their concentration is important for a mechanistic understanding of the oxygen incorporation into these cathode materials. XPS has been widely used for the analysis of adsorbed species and surface structure. However, the conventional XPS experiments have the severe drawback to operate at room temperature and with the sample under ultrahigh vacuum (UHV) conditions, which is far from the relevant conditions of SOFC operation. The disadvantages of conventional XPS can be overcome to a large extent with a "high pressure" XPS setup installed at the BESSY II synchrotron. It allows sample depth profiling over 2 nm without sputtering by variation of the excitation energy, and most importantly measurements under a residual gas pressure in the mbar range. It is also well known that the catalytic activity for the oxygen reduction is very sensitive to their electrical conductivity and oxygen nonstoichiometry. Although the electrical conductivity of perovskite oxides has been intensively studied as a function of temperature or oxygen partial pressure (Po2), in-situ measurements of the conductivity of these materials in contact with the electrolyte as a SOFC configuration have little been reported. In order to measure the in-plane conductivity of an electrode film on the electrolyte, a substrate with high resistance is required for excluding the leakage current of the substrate. It is also hardly possible to measure the conductivity of cracked thin film by electrical methods. In this study, we report the electrical conductivity of perovskite $La_{0.6}Sr_{0.4}CoO_{3-{\delta}}$ (LSC) thin films on yttria-stabilized zirconia (YSZ) electrolyte quantitatively obtained by in-situ IR spectroscopy. This method enables a reliable measurement of the electronic conductivity of the electrodes as part of the SOFC configuration regardless of leakage current to the substrate and cracks in the film.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.11a
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• pp.124-124
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• 2009

We observed the changes of crystal structure of Rubrene (5,6,11,12-tetraphenylnaphthacene) polycrystal thin films at various in situ substrate temperature and process by scanning electron microscope(SEM), x-ray diffraction (XRD) and near-field microwave microprobe (NFMM). Amorphous rubrene thin film was initially obtained on 200 nm thick $SiO_2/Si$ substrate at 35 $^{\circ}C$ in a vacuum evaporation but in situ long time postannealing at the temperature 80 $^{\circ}C$ transformed the amorphous phase into crystalline. Four heating conditions are followed : (a) preheating (b) annealing (c) preheating, annealing (d) preheating, cooling(35 $^{\circ}C$), annealing. We have obtained the largest polycrystal disk in sample (c). But the highest crytallity and conductivity of the rubrene thin films were obtained in sample (d).

• Korean Journal of Optics and Photonics
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• v.4 no.3
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• pp.260-265
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• 1993

An in-situ stress measurement interferometer is constructed and used to measure the intrinsic stress in Ti$O_2$ thin films during their growth by ion-assisted deposition. It is found that the stress increases with the momentum transferred by the ion beam to the growing film and is fairly well agreed with Windischmann's model. The variation of the stress with thickness is qualitatively explained in terms of the balance between the compressive stress produced by the ion beam and the surface diffusion determined by the surface temperature.

• Corrosion Science and Technology
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• v.3 no.5
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• pp.198-208
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• 2004

Although there has been no general agreement on the mechanism of primary water stress corrosion cracking (PWSCC) as one of major degradation modes of Ni-base alloys in pressurized water reactors (PWR's), common postulation derived from previous studies is that the damage to the alloy substrate can be related to mass transport characteristics and/or repair properties of overlaid oxide film. Recently, it was shown that the oxide film structure and PWSCC initiation time as well as crack growth rate were systematically varied as a function of dissolved hydrogen concentration in high temperature water, supporting the postulation. In order to understand how the oxide film composition can vary with water chemistry, this study was conducted to characterize oxide films on Alloy 600 by an in-situ Raman spectroscopy. Based on both experimental and thermodynamic prediction results, Ni/NiO thermodynamic equilibrium condition was defined as a function of electrochemical potential and temperature. The results agree well with Attanasio et al.'s data by contact electrical resistance measurements. The anomalously high PWSCC growth rate consistently observed in the vicinity of Ni/NiO equilibrium is then attributed to weak thermodynamic stability of NiO. Redox-induced phase transition between Ni metal and NiO may undermine the integrity of NiO and enhance presumably the percolation of oxidizing environment through the oxide film, especially along grain boundaries. The redox-induced grain boundary oxide degradation mechanism has been postulated and will be tested by using the in-situ Raman facility.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2013.05a
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• pp.601-602
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• 2013

• Journal of the Korean Association of Geographic Information Studies
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• v.21 no.3
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• pp.162-175
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• 2018

The purpose of this study was to analyze the surface temperature of surface fabrics using UAV TIR images, to mitigate problems in the thermal environment of urban areas. Surface temperature values derived from UAV images were compared with those measured in-situ during the similar period as when the images were taken. The difference in the in-situ measured and UAV image derived surface temperatures is the highest for gray colored concrete roof fabrics, at $17^{\circ}C$, and urethane fabrics show the lowest difference, at $0.3^{\circ}C$. The experiment power of the scatter plot of in-situ measured and UAV image derived surface temperatures was 63.75%, indicating that the correlation between the two is high. The surface fabrics with high temperature are metal roofs($48.9^{\circ}C$), urethane($43.4^{\circ}C$), and gray colored concrete roofs($42.9^{\circ}C$), and those with low temperature are barren land($30.2^{\circ}C$), area with trees and lawns($30.2^{\circ}C$), and white colored concrete roofs($34.9^{\circ}C$). These results show that accurate analysis of the thermal characteristics of surface fabrics is possible using UAV images. In future, it will be necessary to increase the usability of UAV images via comparison with in-situ data and linkage to satellite imagery.

• Proceedings of the KSRS Conference
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• 1998.09a
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• pp.58-63
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• 1998

The aim of the present study is to define and tentatively to interpret the distribution of polluted water released from Lake Sihwa into Yellow Sea using Landsat TM. Since the region is an extreme case 2 water, empirical algorithms for chlorophyll-a and suspended sediments have limitations. This work focuses on the use of multi-temporal Landsat TM. We applied PCA to detect evolution of spatial feature of polluted water after release from the lake. The PCA results were compared with in situ data, such as chlorophyll-a, suspended sediments, Secchi disk depth (SDD), surface temperature, radiance reflectance at six bands. The in situ remote sensing reflectance was analysed with PCA. On the basis of these In situ data we found good correlation between first Principal Component and Secchi disk depth ($R^2$=0.7631), although other variables did not result in such a good correlation. The problems in applying PCA techniques to multi-spectral remote sensed data are also discussed.