• 제목/요약/키워드: improving reaction

검색결과 438건 처리시간 0.028초

아크릴 공중합체형 발수제로 처리된 P/C 혼방직물의 물성연구 (The Properties of P/C Blended Fabrics Treated with the Water Repellent of Acrylic Copolymer and Additives)

  • 박홍수;김영근;정영숙;최봉종;이기창
    • 한국응용과학기술학회지
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    • 제8권1호
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    • pp.9-20
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    • 1991
  • In the preparation of acrylic water repellent(EDLWC). quaternized 2-diethylarrunoethylmethacrylate-stearylmethacrylate copolymer (DSACC) and quaternized 1-Iaurovlbis(aminoethyl)-2-dodecylimidazoline(LDDIC) were selected as a basic resin and the improving agent such as softening effect and hydrostatic pressure of the water repellent. EDLWC was prepared by blending waxes and emulsifier for waxes with various ratio to DSACC and LDDIC. As the results of the measurement of water repellency, washable, tear strength and crease recovery to polyester-cotton(P/C) blended fabrics treated with EDLWC only or addition of textile finishing resin, the physical properties were increased. Sodium acetate was the most effective catalyst in the water repellency among the various kinds of catalyst. and the reasonable concentration of the catalyst was 1. 4 wt%. EDLWC was confirmed as durable water repellent with the results of making little difference of water repellency as ${\pm}5$ point after and before washing. The reaction mechanism between P/C blended fabrics and EDLWC in the presence of catalyst was proposed. And also, the longitudinal view of the P/C blended fabrics treated with water repellent was observed with scanning electron microscope.

Polarity-tuned Gel Polymer Electrolyte Coating of High-voltage LiCoO2 Cathode Materials

  • Park, Jang-Hoon;Cho, Ju-Hyun;Kim, Jong-Su;Shim, Eun-Gi;Lee, Yun-Sung;Lee, Sang-Young
    • 전기화학회지
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    • 제14권2호
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    • pp.117-124
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    • 2011
  • We demonstrate a new surface modification of high-voltage lithium cobalt oxide ($LiCoO_2$) cathode active materials for lithium-ion batteries. This approach is based on exploitation of a polarity-tuned gel polymer electrolyte (GPE) coating. Herein, two contrast polymers having different polarity are chosen: polyimide (PI) synthesized from thermally curing 4-component (pyromellitic dianhydride/biphenyl dianhydride/phenylenediamine/oxydianiline) polyamic acid (as a polar GPE) and ethylene-vinyl acetate copolymer (EVA) containing 12 wt% vinyl acetate repeating unit (as a less polar GPE). The strong affinity of polyamic acid for $LiCoO_2$ allows the resulting PI coating layer to present a highly-continuous surface film of nanometer thickness. On the other hand, the less polar EVA coating layer is poorly deposited onto the $LiCoO_2$, resulting in a locally agglomerated morphology with relatively high thickness. Based on the characterization of GPE coating layers, their structural difference on the electrochemical performance and thermal stability of high-voltage (herein, 4.4 V) $LiCoO_2$ is thoroughly investigated. In comparison to the EVA coating layer, the PI coating layer is effective in preventing the direct exposure of $LiCoO_2$ to liquid electrolyte, which thus plays a viable role in improving the high-voltage cell performance and mitigating the interfacial exothermic reaction between the charged $LiCoO_2$ and liquid electrolytes.

Socioeconomic impact of traditional Korean medicine, Pyeongwee-San (KMP6) as an anti-allergic inflammatory drug

  • Song, Young-Hoon;Nam, Sun-Young;Choi, Young-Jin;Kim, Jeong-Hwa;Kim, Young-Sick;Jeong, Hyun-Ja
    • 셀메드
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    • 제2권3호
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    • pp.29.1-29.9
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    • 2012
  • The prevalence of allergic disease has been increasing over the past few decades in the majority of Western industrialized nations. There are some socioeconomic disparities regarding allergic disease status and management. Pyeongwee-San (KMP6) is Korean medicine for the treatment of gastrointestinal tract disease. It is known that KMP6 has an improving effect on the spleen and stomach functions in traditional Korean medical theory. Here, we hypothesized that KMP6 could be used to regulate the inflammatory reaction. We show the molecular mechanisms of Pyeongwee-San (KMP6) on inflammatory reactions. A molecular docking simulation showed that hesperidin, component of KMP6, regulate the enzymatic activity by interaction in the active site of caspase-1. KMP6 control the activity of caspase-1 in activated human mast cell line (HMC-1 cells). KMP6 reduced the expression of receptor interacting protein (RIP)-2 in HMC-1 cells. Thymic stromal lymphopoietin protein production and mRNA expression were inhibited by KMP6. In the activated HMC-1 cells, KMP6 suppressed the activation of mitogen-ativated protein kinase and nuclear factor-kappaB. In addition, KMP6 significantly inhibited the expression of inflammatory cytokines. Our findings indicate that KMP6 may attenuate allergic reactions via the regulation of caspase-1/RIP-2 signaling pathway. These studies will help advance the social welfare system.

마이크로 열 센서용 측온저항체 온도센서의 제작 및 특성 (The Fabrication and Characteristics of RTD(Resistance Thermometer Device) for Micro Thermal Sensors)

  • 정귀상;홍석우
    • 센서학회지
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    • 제9권3호
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    • pp.171-176
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    • 2000
  • 반응성 스퍼터링과 고주파 마그네트론 스퍼터링으로 각각 증착된 MgO 박막과 그 위에 증착된 백금박막의 열처리 온도 및 시간에 따른 물리적, 전기적 특성을 4침 탐침기, 주사전자현미경 및 X선 회절법을 이용하여 분석하였다. $1000^{\circ}C$, 2시간의 열처리 조건하에서 MgO 박막은 백금박막과 화학적 반응없이 백금박막의 열산화막에 대한 부착특성을 개선시켰으며, 그 위에 증착된 백금박막의 면저항 및 비저항은 각각 $0.1288\;{\Omega}/{\square}$, $12.88\;{\mu}{\Omega}{\cdot}cm$이었다. Lift-off 방법을 이용하여 $SiO_2$/Si기판상에 백금 저항체를 만들었으며, 백금 와이어, 백금 페이스트 그리고 SOG를 이용하여 마이크로 열 센서용 박막형 Pt-RTD를 제작하였다. $25{\sim}400^{\circ}C$의 온도범위에서 $1.0{\mu}m$의 두께를 갖는 제작된 Pt-RTD의 저항온도계수는 벌크 백금에 가까운 $3927ppm/^{\circ}C$로 측정되었다. 측정온도범위내에서 저항값은 선형적인 변화를 보였다.

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토양수분과 경도가 동력경운기의 견인성능에 미치는 영향 (Effects of the Soil Moisture and Hardness on the Drawing Performance of a Two-Wheel Tractor.)

  • 박호석;차균도
    • Journal of Biosystems Engineering
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    • 제2권1호
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    • pp.25-32
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    • 1977
  • This experiment was conducted in order to find out the drawing performance of a two-wheel tractor under different levels of the soil moisture and hardness, so as to obtain some basic data for improving their drawing performance. With fairly homogeneous soil, 5 levels of soil moisture contents (8, 13, 17, 20 and 23%) and 3 levels of soil hardness (0 , 2 and 4kg/$cm^2$) were selected for this experiment.The summerized results are as follows ;1. The draft force, on the hard soil (hardness ; 4kg/$cm^2$), had a distinct tendency to decrease with the increasing soil moisture. On the medium soil (hardness ; 2 kg/$cm^2$), and the soft soil (hardness ; 0kg$cm^2$), the draft force showed the highest when the moisture contents were within the range of 16-19%.But the maximum draft force, on the soft soil, was higher than that on the medium soil by 10 %. 2. The driving axle torque increased with increasing soil by 10 %. 3.The values of horizontal distance between the soil reaction point and axle shaft were within the range of 0~10cm , and it had the tendency to increase with the increasing soil moisture. Also, it s value was the largest on the hard soil and the smallest on the soft soil. 4.The tractive efficiency decreased with the increasing soil moisture. On the hard soil, the average value of tractive efficiency was higher than that on the medium soil by 19.0% and that on the soft soil was lower than that on the medium soil. 5.The traction ratio were within the range of 30 ~45%, and their changing tendency with respect to the soil moisture was similar to that in the case of the draft force. 6. The travel resistance ratio tended to increased with increasing soil moisture, and the highest value was found on the soft soil, and the lowest on the hard soil.

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흑삼의 화학성분 및 생리활성에 대한 최근 연구 (Recent Advances in Studies on Chemical Constituents and Biological Activities of Korean Black Ginseng(Panax ginseng C. A. Meyer))

  • 남기열;김영수;손미례;박종대
    • 생약학회지
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    • 제46권3호
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    • pp.173-188
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    • 2015
  • We have conducted a comprehensive literature review regarding the chemical constituents and biological activities of Korean black ginseng(Panax ginseng C. A. Meyer), three to nine times-steamed and dried ginseng, which shows strong black color through Maillared browning reaction. It has been reported that some chemically deglycosylated and transformed saponins are obtained from black ginseng as artifacts produced during intensive steaming. They have been known to be ginsenosides Rg3, Rg4, Rg5, Rg6, Rh1, Rh2, Rh4, Rk1 and Rk3, quite different from those of red ginseng, among which ginsenosides Rg3, Rg5 and Rk1 are considered to be major components. And also, black ginseng has been recently found to demonstrate anticancer, recovery from learning and memory damages, hypontensive, antidiabetic, antiobesitic, tonic and antiatopic activities, together with antioxidative and exercise performance improving activities, exhibiting their effects to be a little bit stronger than those of red ginseng. These findings suggest that black ginsng might play an important role in the development of promising functional foods and drugs from the viewpoint of the chemical composition and biological activities of black ginseng with a distinction from those of white and red ginsengs. In this review, the authors will survey and evaluate further functions of black ginseng with a focus on its physicochemical properties and biological activities.

태권도 품새 우수·비 우수선수 간 앞차고 몸돌아 옆차기의 성·패에 따른 균형성 비교 (Comparison between the Balance of Skilled and Less-Skilled Players during Successful and Failed Front Kick and Turning Side Kick Motions)

  • 류시현;류지선
    • 한국운동역학회지
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    • 제22권3호
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    • pp.285-293
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    • 2012
  • The aim of this study is to identify the appropriate movement for maintaining postural balance during Front Kick and Turning Side Kick motions. To do so, ten Taekwondo athletes: five skilled players(S, body mass: $65.0{\pm}5.8kg$, height: $172.3{\pm}3.7cm$, age: $20.0{\pm}1.2yrs$, career: $9.0{\pm}1.9yrs$) and five less-skilled players(LS, body mass: $67.1{\pm}5.5kg$, height: $173.2{\pm}5.1cm$, age: $19.4{\pm}1.7yrs$, career: $9.6{\pm}1.7yrs$) participated in this study. A three-dimensional motion analysis was performed on the participants using eight infrared cameras and two force plate(sampling frequency of 200 Hz and 2000 Hz for S and LS players, respectively). The participants' motions were divided into: a front-kick phase(P1) and a turning-side-kick phase(P2). For P2(p<.05), the range and root mean square(RMS) of the ground reaction torque and the M-L mean velocity of COP were greater for LS than for S; similarly, for P2(p<.05), the M-L range, A-P range, and velocity of the COP were greater for LS than for S. Further, the M-L range and maximum velocity of the COP was greater for failure than for success(p<.05). The femoral biceps muscle for bending the knee joint was significantly stronger in S than in LS(p<.05). It is expected that these results will be useful in developing a training program for improving the balance and stability of Taekwondo poomsae athletes and improve their front-kick and turning-side-kick motions.

오일팜 바이오매스의 자원화 연구 II - 오일팜 바이오매스의 펠릿 제조 특성 - (Study of Oil Palm Biomass Resources (Part 2) - Manufacturing Characteristics of Pellets Using Oil Palm Biomass-)

  • 성용주;김철환;조후승;김성호;심성웅;임수진;이지영;김세빈
    • 펄프종이기술
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    • 제45권1호
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    • pp.42-51
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    • 2013
  • In this study, oil palm biomass such as empty fruit bunch (EFB) and palm kernel shell (PKS) was used as raw materials for making pellets. Hardwood sawdusts were also mixed with EFB and PKS for making pellets. For improving a bad forming behavior in a pelletizer, 1 to 3 per cent of corn starch based on oven-dried weight biomass was added. The starch contributed to the decrease of dust generation in addition to the improvement of forming capability during pellet forming. Heating values of every pellets made of EFB and PKS were higher than 4,300 kcal/kg for the first grade pellet, irrespective of addition of sawdusts. However, the pellets made of EFB and PKS had ash contents over 3 per cent, which made it impossible to be applied for home use. Instead, they could be applied for industrial use. For studying their combustion characteristics, the pellets from the mixtures of EFB, PKS and sawdusts were analyzed using thermal gravimetric analyzer (TGA). From the TGA results, thermal decomposition of EFB and PKS occurred following three including endothermic reaction and dehydration, devolatilization of the major chemical components, and finally combustion of residual lignin and char.

Polymer materials for enzyme immobilization and their application in bioreactors

  • Fang, Yan;Huang, Xiao-Jun;Chen, Peng-Cheng;Xu, Zhi-Kang
    • BMB Reports
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    • 제44권2호
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    • pp.87-95
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    • 2011
  • Enzymatic catalysis has been pursued extensively in a wide range of important chemical processes for their unparalleled selectivity and mild reaction conditions. However, enzymes are usually costly and easy to inactivate in their free forms. Immobilization is the key to optimizing the in-service performance of an enzyme in industrial processes, particularly in the field of non-aqueous phase catalysis. Since the immobilization process for enzymes will inevitably result in some loss of activity, improving the activity retention of the immobilized enzyme is critical. To some extent, the performance of an immobilized enzyme is mainly governed by the supports used for immobilization, thus it is important to fully understand the properties of supporting materials and immobilization processes. In recent years, there has been growing concern in using polymeric materials as supports for their good mechanical and easily adjustable properties. Furthermore, a great many work has been done in order to improve the activity retention and stabilities of immobilized enzymes. Some introduce a spacer arm onto the support surface to improve the enzyme mobility. The support surface is also modified towards biocompatibility to reduce non-biospecific interactions between the enzyme and support. Besides, natural materials can be used directly as supporting materials owning to their inert and biocompatible properties. This review is focused on recent advances in using polymeric materials as hosts for lipase immobilization by two different methods, surface attachment and encapsulation. Polymeric materials of different forms, such as particles, membranes and nanofibers, are discussed in detail. The prospective applications of immobilized enzymes, especially the enzyme-immobilized membrane bioreactors (EMBR) are also discussed.

주철 - 알루미늄 합금의 Hot Dip Aluminizing시 흑연 및 금속간화합물 층의 형성 거동 (Behavior of Graphite and Formation of Intermetallic Compound Layer in Hot Dip Aluminizing of Cast Iron)

  • 한광식;강용주;강문석;강성민;김진수;손광석;김동규
    • 한국주조공학회지
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    • 제31권2호
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    • pp.66-70
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    • 2011
  • Hot dip aluminizing (HDA) is widely used in industry for improving corrosion resistance of material. The formation of intermetallic compound layers during the contact between dissimilar materials at high temperature is common phenomenon. Generally, intermetallic compound layers of $Fe_2Al_5$ and $FeAl_3$ are formed at the Al alloy and Fe substrate interface. In case of cast iron, high contact angle of graphite existed in the matrix inhibits the formation of intermetallic compound layer, which carry with it the disadvantage of a reduced reaction area and mechanical properties. In present work, the process for the removal of graphite existed on the surface of specimen has been investigated. And also HDA was proceeded at $800^{\circ}C$ for 3 minutes in aluminum alloy melt. The efficiency of graphite removal was increased with the reduction of particle size in sanding process. Graphite appears to be present both in the region of melting followed by re-solidification and in the intermetallic compound layer, which could be attributed to the fact that the surface of cast iron is melted down by the formation of low melting point phase with the diffusion of Al and Si to the cast iron. Intermetallic compound layer consisted of $Fe(Al,Si)_3$ and $Fe_2Al_5Si$, the layer formed at cast iron side contained lower amount of Si.