• Title/Summary/Keyword: improving reaction

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Improvement of Photoelectrochemical Properties through Activation Process of p-type GaN (p-type GaN의 Activation을 통한 광전기화학적 특성 향상)

  • Bang, Seung Wan;Kim, Haseong;Bae, Hyojung;Ju, Jin-Woo;Kang, Sung-Ju;Ha, Jun-Seok
    • Journal of the Microelectronics and Packaging Society
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    • v.24 no.4
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    • pp.59-63
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    • 2017
  • The n-type GaN semiconductor has excellent properties as a photoelectrode, but it has disadvantage that its reliability is deteriorated due to the photocorrosion because the oxygen reaction occurs on the surface. For this reason, there are fundamental attempts to avoid photocorrosion reaction of GaN surfaces by using the p-type GaN as a photoelectrode where hydrogen generation reaction occurs on the surface. However, p-type GaN has a problem of low efficiency because of its high resistivity and low hole mobility. In this study, we try to improve the photocurrent efficiency by activation process for the p-type GaN. The p-type GaN was annealed for 1 min. at $500^{\circ}C$ in $N_2$ atmosphere. Hall effect measurement system was used for the electrical properties and potentiostat (PARSTAT4000) was used to measure the photoelectrochemical (PEC) characteristics. Consequently, the photocurrent density was improved more than 1.5 times by improving the activation process for the p-type GaN. Also, its reliability was maintained for 3 hours.

Fixation of Sericin of Silk Fabric by Epoxy Resin (Epoxy수지에 의한 견직물의 Sericin정착)

  • 문영배;남중희
    • Journal of Sericultural and Entomological Science
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    • v.26 no.2
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    • pp.16-25
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    • 1984
  • The sericin fixation of silk fabrics by epoxy resins was studied in the presence of aqueous salt solution in different solvents at the indicated temperature for the desired time. Heavy weight gains were obtained in the reaction with glycerol diglycidyl ether (EX-313) and ethylene glycol diglycidyl ether (EX-810) catalyzed by potassium thiocyanate in such solvents as carbon tetrachloride and p-chloroethylene. The obtained results were summarized as follows; 1) The tested resins were found similar in reaction behavior to silk fabric. The effect of fixation and weight gains was higher in EX-810 than EX-313. 2) The weight gains were increased with reaction time and temperature, and degumming ratio reached a constant value in 90 min at 70$^{\circ}C$. 3) The weight gains and the degumming ratio reached an equilibrium at 3-5% of epoxy concentration. 4) The weight gains were remarkably influenced and increased by the concentration of salt solution. The degumming ratio reached an equilibrium over 0.5N concentration of salt. 5) The weight gains were increased with the dipping time in gently-sloping. The degumming ratio reached an equilibrium over 15 min dipping. 6) The effect of sericin fixation of hydrophobic solvents, such as Carbon Tetrachloride, p-Chloroeth-ylene, Cyclohexane, Xylene and Toluene, was found suitable. 7) The effect of drying temperature was not remarkable on the weight gains and the degumming ratio. 8) There was a slight decrease in the moisture regain of sericin-fixed silk and it may be possible to maintain the moisture regain in the sericin-fixed silk by the epoxy resins. 9) The results on testing physical properties of sericin-fixed silk fabric were as follows; The crease recovery was almost not different from undegummed fabric, but inferior to degummed fabric. The tensile strength was improving in accordance with the effect of sericin fixation, either the elongation did.

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A Study on the Combustion Flow Characteristics of a Exhaust Gas Recirculation Burner with the Change of Outlet Opening Position (배기가스 재순환 버너에서 연소가스 출구 위치에 따른 연소 유동 특성에 관한 연구)

  • Ha, Ji-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.8
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    • pp.8-13
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    • 2018
  • Nitrogen oxides (NOx) have recently been very influential in the generation of ultrafine dust, which is of great social interest in terms of improving the atmospheric environment. Nitrogen oxides are generated mainly by the reaction of nitrogen and oxygen in air in a combustion gas atmosphere of high temperature in a combustion apparatus such as thermal power generation. Recently, research has been conducted on the combustion that recirculates the exhaust gas to the cylindrical burner by using a piping using a Coanda nozzle. In this study, three types of burners were carried out through computational fluid analysis. Case 1 burner with the outlet of the combustion gas to the right, Case 2 burner with both sides as gas exit, Case 3 burner with left side gas exit. The pressure, flow, temperature, combustion reaction rate and distribution characteristics of nitrogen oxides were compared and analyzed. The combustion reaction occurred in Case 1 and Case 2 burner in the right direction with combustion gas recirculation inlet and Case 3 burner in the vicinity of mixed gas inlet. The temperature at the outlet was about $100^{\circ}C$ lower than that of the other burners as the Case 2 burner was exhausted to both sides. The NOx concentration of Case 1 burner at the exit was about 20 times larger than that of the other burners. From the present study, it could be seen that it is effective for the NOx reduction to exhaust the exhaust gas to both side gas exits or to exhaust the exhaust gas to the opposite direction of inlet of recirculation gas.

Skin Radioprotector (Diethone) Modifying Dermal Response of Radiation on Rats (방사선 보호제(Diethone)의 랫드 피부반응에 대한 수식작용)

  • Hong, Seong-Eon;Urahashi, Shingo;Kamata, Rikisaburo
    • Radiation Oncology Journal
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    • v.7 no.1
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    • pp.15-22
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    • 1989
  • Investigations were carried out into the time-and dose-related changes in acute skin reaction following graded single dose (20,30 and 40 Gy) of x-ray irradiation in Wistar rats, in order to evaluate the radioprotective effect of Diethon on skin. For the duration of skin response over 1. 5 score in dose of 40 Gy, the Diethone group of 24.7 days was significantly different (p<0.02) from that of control (29.8 days) and vaseline (29.2 days) groups, it was $17.1\%$ diminution of skin response period compared with that of control group. By the averaging daily scores for 10 days during peak skin reaction the mean scores were obtained. Mean score of Diethone group $(2.43\pm0.22)$ was significantly different (p<0.01) from that of control $(2.91\pm0.23)$ and vaseline $(2.81\pm0.18)$ groups of 40Gy dose. By iso-effect dose obtained at level of 2.5 score the dose reduction factor (DRF) was 1.41 which reduced radiation dose of $41\%$ by radioprotective effect of Diethone. From this experimental data, it may be possible to give higer radiation dose to large and/or radioresistant tumor mass rather than conventional treatment doses for improving therapeutic ratio by using topical application of skin radioprotector.

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Relationship between Subjective Oral Health Recognition and Dental Fear in Dental Clinic Patients (치과내원환자의 주관적 구강건강인식과 치과공포의 관련성)

  • Yoon, Hyun-Seo;Park, Ji-Hyun
    • The Journal of the Korea Contents Association
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    • v.12 no.6
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    • pp.371-379
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    • 2012
  • The purpose of this study is to develop basic data in improving quality of life along with the enhancement in oral health, by arranging a plan for being able to reduce dental fear given the dental treatment in the future by grasping the subjective oral health recognition & status, and the dental fear level of the dental treatment field targeting patients of visiting dental clinics in Busan and Gyeongnam area. In the whole items of DFS, a sense of fear was higher in women than men. A factor of avoiding dental treatment stood at 1.72 points in men and 2.10 points(p<0.001) in women. A factor of response to stimulation stood at 2.75 points in men and 3.20 points(p=0.001) in women. A fear level according to dental kind was high in a factor of avoiding implant treatment(p=0.015), a factor of avoiding orthodontic treatment(p=0.002), physiological reaction(p=0.009), a factor of avoiding prosthesis treatment(p=0.014), a factor of avoiding pulpectomy treatment(p=0.005), a factor of physiological reaction(p=0.017), a factor of avoiding periodontal therapy(p=0.013), a factor of physiological reaction(p=0.004), and a factor of avoiding treatment given not receiving regular checkup(p=0.027). In the above results, to reduce dental fear, there will be a need of developing diverse programs and oral health eduction for regular checkup and preventive treatment.

Effects of the Field Complexity and Type of Target Object on the Performance of the Baggage Screening Task for Improving Aviation Safety (항공 안전 증진을 위한 장 복잡성과 위험물품의 종류가 수화물 검사 수행에 미치는 효과)

  • Moon, Kwangsu
    • The Journal of the Korea Contents Association
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    • v.18 no.11
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    • pp.484-492
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    • 2018
  • This study examined the effects of field complexity and type of target objects on the performance in baggage screening task. A total of 62 participants(male: 45.2%, female: 54.8%) participated and their mean age was 22.88. The simulated baggage screening task was developed for this study and after the orientation and task exercises, main experiment session was conducted. Participants performed a total of 200 tasks and 40(20%) contained target object. The complexity was set at three levels: high, middle, and low levels and the number of background items contained 20, 14. and 8 respectively. The type of target was set as gun, knife, liquid, and righter. The dependent variables were hit ratio and reaction time. The results showed that the hit ratio decreased and reaction time increased significantly as field complexity increased, and they varied depending on the type of target. The hit ratio of the knife was the highest and liquid lowest and reaction time of the knife was the fastest and liquid slowest. In addition, the interaction effect was also significant. Knife was not affected by complexity, however, small item such as lighter was most affected by complexity.

The Effect of Supercritical Carbonation on Quality Improvement of Recycled Fine Aggregate (초임계 탄산화 반응이 순환잔골재의 품질개선에 미치는 영향)

  • Heo, Seong-Uk;Kim, Ji-Hyun;Chung, Chul-Woo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.1
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    • pp.33-40
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    • 2021
  • The objective of this work is to prove a possibility of void f illing through a carbonation f or the purpose of improving the quality of recycled aggregate. Carbonation can permanently immobilize CO2, which is a greenhouse gas, and thus provides additional benefit on environment. In this work, recycled fine aggregate was reacted using gaseous CO2 and supercritical CO2(scCO2) in a closed chamber, and the changes in physical properties of the recycled f ine aggregate bef ore and af ter carbonation were analyzed using the apparent density, skeletal density, pH, and FE-SEM measurements. Thereafter, a mortar specimen was prepared and a compressive strength was measured. According to the experimental results, it was found that the increase in the apparent density and the true density was higher by the reaction with scCO2, which was conducted at high temperature and high pressure compared to the reaction with gaseous CO2. In addition, the pH of the eluted water was found to have a larger initial decrease than that observed with samples from reaction by gaseous CO2. The shape and amount of calcium carbonate crystals were also found to be larger than that from gaseous CO2. The increase in compressive strength was the largest when using recycled fine aggregate reacted with scCO2. It was clear that quality improvement of recycled fine aggregate was higher with scCO2 than with gaseous CO2.

Inhibition of Side Reactions Forming Dimers of Diols in the Selective Hydrogenation of Methacryl Aldehyde (메타아크릴 알데히드의 선택적 수소화에서 2가 알코올의 이합체 형성 부반응 억제효과)

  • Kook-Seung Shin;Mi-Sun Cha;Kyoung-Ku Kang;Chang-Soo Lee
    • Clean Technology
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    • v.29 no.2
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    • pp.79-86
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    • 2023
  • The homogeneous catalyst, Ru-MACHO-BH, selectively performs hydrogenation reactions only on the carbonyl group of α, β-unsaturated aldehyde compounds with extremely high reactivity and selectivity. However, the hydrogenation of α, β-unsaturated aldehydes involves a heterogeneous Diels-Alder reaction, resulting in the formation of significant amounts of byproducts, such as dimers. In this study, we used the Ru-MACHO-BH catalyst (Carbonyl hydrido (tetrahydroborato) [bis (2-diphenyl phosphino ethyl) amino] ruthenium(II)) to selectively hydrogenate the carbonyl group of a specific type of α, β-unsaturated aldehyde called methacryl aldehyde, leading to the synthesis of methallyl alcohol. Simultaneously, we applied diols to inhibit the formation of byproducts. The results demonstrate that monoethylene glycol can significantly reduce the formation of diols. Based on these results, we effectively suppressed the formation of dimers containing vinyl groups in methacryl aldehyde by using hydroquinone, which can efficiently inhibit the chemical interaction of vinyl groups. Consequently, the conversion rate of methacryl aldehyde was increased. Ultimately, by reducing the amount of the expensive homogeneous catalyst Ru-MACHO-BH to 1/10, we achieved a selectivity of over 90% and a yield of over 80% for the desired product, methallyl alcohol. These results provide a method to minimize yield reduction while reducing the usage of expensive catalysts, thereby improving cost-effectiveness. We expect that the reaction could be applied to various kinds of selective hydrogenation and has been successfully run on an industrial scale.

Study on The Regulation on Poisonous Medicinal Herbs (독성 한약재의 법적 규제에 관한 연구)

  • Kweon, Kee-Tae
    • The Korean Society of Law and Medicine
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    • v.11 no.1
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    • pp.271-296
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    • 2010
  • Objective: Poisonous Medicinal herbs can be considered as a risk factor to public health unless they are prescribed by Doctor of traditional Korean medicine. The proper method to manage them should be prepared to prevent risk factors caused by misuse and abuse of the poisonous medicinal herbs and enhance public health. Methods: In this dissertation (paper), the definition, scope, management status, data about pharmacology and toxicity and media release regarding adverse reaction were understood after organizing documents, laws and regulations concerning poisonous medicinal herbs. Also, management methods are suggested by analyzing related examples and regulations in China, Japan and Hong Kong, where the use of herbal medicine is general. Results: Methods for items for poisonous medicinal herbs, safety information management, management based on standardization of traditional processing methodology and reorganization and revision of related laws and regulations are established. Conclusion: Proper laws and regulations are not yet established to manage poisonous medicinal herbs in Korea. In this regard, it is urgent to establish laws and regulations which can apply independently. The purpose of the laws and regulations should be to enhance management of poisonous medicinal herbs and prevent incidence of addiction and death, improving the public health.

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Mother-Child Interactions in a Stressful Situation by Mother's Emotional Regulation Level (스트레스 상황에서 어머니의 정서조절 수준에 따른 어머니-자녀 간 상호작용 분석)

  • Nahm, Eun Young;Park, So Eun
    • Korean Journal of Child Studies
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    • v.38 no.1
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    • pp.251-262
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    • 2017
  • Objective: This study analyzed mother-child interactions in a stressful situation each second by mother's emotional regulation level. Methods: The study was conducted with 16 mothers and their 5-year-old children playing a teaching task for 15 min. During the interactions, the participants were videotaped and examined. Furthermore, qualitative analysis was used for analyzing mother-child interactions in detail by creating a situation that maximizes the stress and frustration of the mother and child. Results: The results showed that maternal humor and affection were significantly related to child positive emotion and that maternal coaching closely correlated with the child pride, pleasure, and whining. Additionally, maternal intrusive behavior showed a positive correlation with child anger. Lastly, mothers with higher levels of emotional regulation more often expressed affection to their children. They were more actively involved in the tasks and used fewer positive or negative directive expressions. Therefore, children of this group expressed more positive emotions. Conclusion: These findings suggests that programs improving parental emotional reaction and emotion regulation should be developed.