• Title/Summary/Keyword: impedance

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Preparation of Poly(propylene) Membrane Supported Gel Electrolyte Membranes for Rechargeable Lithium Ion Batteries through Thermal Polymerization of Di(ethylene glycol) Dimethacrylate (Di(ethylene glycol) Dimethacrylate의 열중합에 의한 Poly(propylene) 분리막으로 지지한 리튬이온 이차전지의 겔 전해질막 제조)

  • Yun, Mi-Hye;Kwon, So-Young;Jung, Yoo-Young;Cho, Doo-Hyun;Koo, Ja-Kyung
    • Membrane Journal
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    • v.20 no.3
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    • pp.259-266
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    • 2010
  • Porous poly(propylene) supported gel polymer electrolytes (GPE) were synthesized by thermal polymerization of DEGDMA [Di(ethylene glycol) dimethacrylate] in electrolyte solutions (1 M solution of $LiPF_6$ in EC/DEC 1 : 1 mixture) at $70^{\circ}C$. AC impedance spectroscopy and cyclic voltammetry were used to evaluate its ionic conductivity and electrochemical stability window of the GPE membranes. Lithium ion battery (LIB) cells were also fabricated with $LiNi_{0.8}Co_{0.2}O_2$/graphite and GPE membranes via thermal polymerization process. Through the thermal polymerization, self sustaining GPE membranes with sufficient ionic conductivities (over $10^{-3}\;S/cm$) and electrochemical stabilities. The LIB cell with 5% monomer showed the best rate-capability and cycleability.

Analysis of Inverter Circuit with External Electrode Fluorescent Lamps for LCD Backlight (LCD 백라이트용 외부전극 형광램프의 인버터 회로 해석)

  • Jeong, Jong-Mun;Shin, Myeong-Ju;Lee, Mi-Ran;Kim, Ga-Eul;Kim, Jung-Hyun;Kim, Sang-Jin;Lee, Min-Kyu;Kang, Mi-Jo;Shin, Sang-Cho;Ahn, Sang-Hyun;Gill, Do-Hyun;Yoo, Dong-Gun;Koo, Je-Huan
    • Journal of the Korean Vacuum Society
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    • v.15 no.6
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    • pp.587-593
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    • 2006
  • The circuit of the EEFL system and the inverter has been analyzed into the resistance RL, the capacitance C of the EEFL-backlight system, and the inductance of transformer in the inverter. The lamp resistance and capacitance are deter-mined from the phase difference is between the lamp current and voltage and from the Q-V diagram, respectively. The single Lamp of EEFL for 32' LCD-BLU has the resistance of $66\;k\Omega$ and the capacitance of 21.61 pF. The resistance, which is connected by parallel in the 20-EEFLS BLU, is $3.3\;k\Omega$ and the capacitance is 402.1 pF. The matching frequency in the operation of lamp system is noted as $\omega_M=1/\sqrt{L_2C(1-k^2)}$, where $L_2$ is the inductance of secondary coil and k is the coupling coefficient between primary and secondary coil. The lamp current and voltage has maximum value at the matching frequency in the LCD BLU system. The results of analytic solutions are in good agreement with the experimental results.

Synthesis and Conductive Properties of Li1+xAlxTi2-x(PO4)3 (x = 0, 0.3, 0.5) by Sol-Gel Method (Sol-Gel법에 의한 Li1+xAlxTi2-x(PO4)3 (x = 0, 0.3, 0.5)의 합성 및 전도특성)

  • Moon, Jung-In;Cho, Hong-Chan;Song, Jeong-Hwan
    • Korean Journal of Materials Research
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    • v.22 no.7
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    • pp.346-351
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    • 2012
  • $Li_{1+x}Al_xTi_{2-x}(PO_4)_3$(LATP) is a promising solid electrolyte for all-solid-state Li ion batteries. In this study, LATP is prepared through a sol-gel method using relatively the inexpensive reagents $TiCl_4$. The thermal behavior, structural characteristics, fractured surface morphology, ion conductivity, and activation energy of the LATP sintered bodies are investigated by TG-DTA, X-ray diffraction, FE-SEM, and by an impedance method. A gelation powder was calcined at $500^{\circ}C$. A single crystalline phase of the $LiTi_2(PO_4)_3$(LTP) system was obtained at a calcination temperature above $650^{\circ}C$. The obtained powder was pelletized and sintered at $900^{\circ}C$ and $1000^{\circ}C$. The LTP sintered at $900{\sim}1000^{\circ}C$ for 6 h had a relatively low apparent density of 75~80%. The LATP(x = 0.3) pellet sintered at $900^{\circ}C$ for 6 h was denser than those sintered under other conditions and showed the highest ion conductivity of $4.50{\times}10^{-5}$ S/cm at room temperature. However, the ion conductivity of LATP (x = 0.3) sintered at $1000^{\circ}C$ decreased to $1.81{\times}10^{-5}$ S/cm, leading to Li volatilization and abnormal grain growth. For LATP sintered at $900^{\circ}C$ for 6 h, x = 0.3 shows the lowest activation energy of 0.42 eV in the temperature range of room temperature to $300^{\circ}C$.

Development of a Multichannel Eddy Current Testing Instrument(I) (다중채널 와전류탐상검사 장치 개발(I))

  • Lee, Hee-Jong;Nam, Min-Woo;Cho, Chan-Hee;Yoon, Byung-Sik;Cho, Hyun-Joon
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.2
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    • pp.155-161
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    • 2010
  • Recently, the electromagnetic techniques of the eddy current testing(ECT), alternating current field testing, magnetic flux leakage testing and remote field testing have been used as a nondestructive evaluation method based on the electromagnetic induction. The eddy current testing is now widely accepted as a NDE method for the heat exchanger tube in the electric power industry, chemical, shipbuilding, and military. The ECT system mainly consists of the synthesizer module, analog module, analog-to-digital converter, power supplier, and data acquisition and analysis program. In this study, the synthesizer module and the analog module which are essential to the ECT system were primarily developed. The developed ECT system is basically a multifrequency type which is able to inject the maximum four frequencies based on the frequency and time domain multiplexing method. Conclusively, we confirmed that the EC signal was processed appropriately in each circuit modules, and the Lissajous EC signal was displayed in the impedance plane.

Development of Disposable Immunosensors for Rapid Determination of Sildenafil and Vardenafil in Functional Foods

  • Vijayaraj, Kathiresan;Lee, Jun Hyuck;Kim, Hyung Sik;Chang, Seung-Cheol
    • Journal of Food Hygiene and Safety
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    • v.32 no.2
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    • pp.83-88
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    • 2017
  • We introduced disposable amperometric immunosensors for the detection of Sildenafil and Vardenafil (SDF/VDF) based on screen printed carbon electrodes. The developed immunosensors were used as a non-competitive sandwich-type enzyme immunoassay with a horseradish peroxidase label. The sensors were constructed on screen printed carbon electrodes by the simple electrochemical deposition of a reduced graphene oxide and chitosan (ErGO-CS) composite. To evaluate the sensing chemistry and optimize the sensor characteristics, a series of electrochemical experiments were carried out including electrochemical impedance spectroscopy, cyclic voltammetry and amperometry. The sensors showed a linear response to SDF/VDF concentrations in a range from 100 pg/mL to 300 ng/mL. The lower detection limit was calculated to be 55 pg/mL, the sensitivity was calculated to be $1.02{\mu}Ang/mL/cm^2$, and the sensor performance exhibited good reproducibility with a relative standard deviation (RSD) of 7.1%. The proposed sensing chemistry strategy and the sensor format can be used as a simple, cost-effective, and feasible method for the in-field analysis of SDF/VDF in functional or health supplement food samples.

Assessment of Nutritional Status and Factors Related to Smoking in Adolescent Males -1.Dietary Intakes and Nutritional Assessment of Serum Lipids and Antioxidant Vitamins in Adolescent Male Smokers- (남자 고등학생 흡연장의 영양상태 판정 및 흡연관련 요인분석 -1.식이 섭취 실태와 체내 지질 및 항산화 비타민 영양상태-)

  • 김정희;임재연;김경원
    • Korean Journal of Community Nutrition
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    • v.3 no.3
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    • pp.349-357
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    • 1998
  • This study was done to investigate the effect of adolescent smoking on dietary intakes and nutritional status of serum lipids and antioxidant vitamins. Subjects were 82 somkers whose average pack-year was 0.73, and 85 nonsmokers of male technical high school students in Seoul. Anthropometric measurement was performed and % body fat was also analyzed by Bioelectrical Impedance Fatness Analyzer(GIF-891). Dietary intakes and habits were examined through questionnaires and nutrient intakes were analyzed by Computer Aided Nutritional (CAN) analysis programs. Serum TG and total cholesterol levels were measured by Spotchem sp-4410 and serum HDL-cholesterol levels were measured by test kit. serum vitamin C level was measured by 2,4-dinitrophenylhydrazine method and serum levels of vitamin A and vitamin E were measured by HPLC. All data were statistically analyzed by SAS PC package program. There was a significant difference in body fat percentage and systolic blood pressure while other anthropometric measurements were not different between smokers and monsmokers. Caloric intakes(2335㎉) in adolescent smokers tended to be higher than that of nonsmokers (2,175㎉) but the difference was not statistically significant. Intakes of protein(76.67g) and niacin(16.49㎎) in adolescent male smokers were significantly higher(P<0.05) than those of nonsmokers although other nutrient intakes were not significantly different. Analysis of serum lipids showed that serum HDL-cholesterol level of smokers was significantly different. Analysis of serum lipids showed that serum HDL-cholesterol level of smokers was significantly lower(p<0.05) than that of nonsmokers, whereas other lipid levels were not significantly different. Serum vitamin C level was also significantly lower(p<0.05) in adolescent smokers than in nonsmokers. In addition, serum vitamin E level, which was 7.85㎎/1 in smokers, was lower than that of 9.20㎎/1 in nonsmokers(p<0.05) while serum vitamin A level was not significantly different between the two groups. These results indicate that cigarette smoking in adolescence decreases serum levels of HDL-cholesterol, vitamin C and vitamin E even thoughth their smoking history is very short. (Korean J Community Nutrition 3(3) : 349∼357, 1998)

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Comparative Study on Body Fat Distribution in Korean and Japanese Young Female Subjects (한국과 일본여자의 체지방 분포에 관한 연구)

  • 김향숙
    • Journal of Nutrition and Health
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    • v.26 no.5
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    • pp.615-624
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    • 1993
  • The body fat distribution and nutritional state of the Korean and Japanese young female subjects were compared. Three-day individually weighed, dietary intakes and anthropometric measurements were determinded in 48 Korean and 60 Japanese female students. 19 to 23 yr of age, from the divisions of nutritions. The body composition estimates were measured by bioeletrical impedance-total body water(BI-TBW) method. There were no significant difference between the Korean and Japanese young females in body size and body shape. The Korean young females had lower estimated total body fat and internal fat that calculated by BI-TBW method, but there was no great difference between the Korean and the Japanese in subcutaneous fat. In contrast, the Korean young females are reported to have the same total energy expenditure per day as the Japanes young females and the total energy intakes and carbohydrate energy intake ratio per day were significantly higher than those of the Japanese young females. The difference in body fat distribution and energy intakes in Korean, and the role of capsaicin in red pepper are discussed as a possible determinant of the internal fat in the Korean vs the Japanese.

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Dietary factors affecting bone mineral density in Korean rural postmenopausal women (농촌지역 폐경후 여성의 골밀도 변화에 영향을 미치는 식이 요인 연구)

  • Choe, Jeong Sook;Ahn, Eun Mi;Kwon, Sung Ok;Park, Young Hee;Lee, Jinyoung
    • Journal of Nutrition and Health
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    • v.45 no.5
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    • pp.470-478
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    • 2012
  • This study was conducted to investigate dietary factors, bone status, and bone loss in postmenopausal women in rural areas. A total of 189 women participated in the follow-up study after two years. Radius, Tibia, and Phalanx SOS (Speed of Sound) was measured on two occasions 2 years apart by ultra-sonic-metry, and % body fat was measured by bioelectrical impedance analysis at the baseline and after 2years. Dietary intake data were collected 4 times at different season by 24-hour recall method, and then calculated as average. Bone density of radius decreased by 4.2% during the two year period. When the subjects were divided into three groups, by bone decline level during two years, the lowest bone loss group had higher potassium and vegetable intake than other groups. Age and calcium intakes showed significant correlation with bone decline rate at tibia. In multiple regressions, the baseline SOS, vitamin A, vegetables and eggs intakes were found to be significant factors for tibia bone decline. In conclusion, dietary factors, such as higher vegetable intake, seem to affect the changes in bone mineral density in more favorable way. Therefore, efforts are needed to enhance the access to nutritional care for rural elderly postmenopausal women.

Nutritional Status of Chronic Obstructive Pulmonary Disease Patients according to the Severity of Disease (만성 폐쇄성 폐질환 환자에서 병기에 따른 영양상태 평가)

  • Park, Young-Mi;Yoon, Ho-Il;Sohn, Cheong-Min;Choue, Ryo-Won
    • Journal of Nutrition and Health
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    • v.41 no.4
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    • pp.307-316
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    • 2008
  • The purpose of the study was to investigate nutritional status of chronic obstructive pulmonary disease (COPD) patients and to find out the differences according to the stages of disease. From March to October, 2006, 41 stable male patients of mild to severe COPD patients were recruited from Seoul National University hospital. The patients' of body weight and fat free mass were assessed by bioelectrical impedance analysis. The nutritional status of the patients was also assessed by 3-day recall, index of nutritional quality (INQ), dietary diversity score (DDS), dietary variety score (DVS), food group index pattern and dietary quality index (DQI). The total of 41 patients were classified into three groups, stage I, stage II and stage III groups according to the classification of Global Initiative for Chronic Obstructive Lung Disease (GOLD) standard. The mean age of the patients in each stage were 67.2-66.9 years showing no significant difference. The ratio of $FEV_1$/FVC were $57.5{\pm}7.3$, $46.9{\pm}7.6$ and $38.2{\pm}6.8%$, respectively showing significant differences according to the stages of disease. The fat free mass of the stage II ($48.2{\pm}4.7kg$) and III ($47.3{\pm}4.5kg$) was significantly lower than that of stage I ($53.1{\pm}6.9kg$) patients. There were significant correlation of fat free mass with $FEV_{1}$, and BMI (body mass index) with $FEV_{1}$/FVC ratio (p < 0.05). COPD patients showed the diet-related clinical symptoms of anorexia, dyspnea, dyspepsia, and chewing difficulty. Daily intakes of calorie, K, vitamin $B_2$ and folate of the patients were very low ($83.8{\pm}20.7%$, $58.9{\pm}14.4%$, $70.7{\pm}19.6%$ and $74.4{\pm}10.2%$, respectively) however, they did not significantly different according to the stages of disease. Daily intake of calcium was significantly lower in the stage III patients (p < 0.05). The mean scores of dietary variety score was significantly lower in the stage III patients (p < 0.001). Dietary quality index of the patients were not different among the stages of disease and the scores indicated poor quality of diet. As a summary, we found that body fat free mass, regularity of exercise, frequency of having snacks and dietary variety score were significantly associated with the severity of chronic obstructive pulmonary disease.

Effect of Period of Immersion on Corrosion Potential, Anodic Polarization, and Impedance Characteristics of Reinforced Steel in Mortar (W/C: 0.6) (모르타르(W/C:0.6)의 철근의 부식전위와 양극분극 및 임피던스 특성에 미치는 재령 년수)

  • Jeong, Jae-Hyun;Moon, Kyung-Man;Lee, Sung-Yul;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Journal of Ocean Engineering and Technology
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    • v.30 no.4
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    • pp.327-333
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    • 2016
  • Reinforced concrete structures have found wide usage in land and maritime applications. However, the corrosion of reinforced concrete has been recognized as a serious problem from economic and safety standpoints. In previous studies, the corrosion behavior of the inner steel bar embedded in mortar (W/C: 0.4, 0.5) was investigated using electrochemical methods. In this study, multiple mortar test specimens (W/C: 0.6) with six different cover thicknesses were prepared and immersed in flowing seawater for five years. Subsequently, equations related to the cover thickness, period of immersion, and corrosion characteristics of the embedded steel bar were evaluated using electrochemical methods. Prior to immersion, the corrosion potentials indicated an increase with increasing cover thickness, and after five years, all corrosion potentials demonstrated a trend in the positive direction irrespective of the cover thickness. However, the relationships between the corrosion potential and cover thickness were not in complete agreement. Furthermore, after five years, all of the corrosion potentials indicated values that were nobler compared to those obtained prior to immersion, and their corrosion current densities also decreased compared to their values obtained prior to immersion. It was considered that the embedded steel bar was easily corroded because of the aggression of water, dissolved oxygen, and chloride ions; a higher W/C ratio also assisted the corrosion process. The corrosive products deposited on the surface of the steel bar for five years cast a resistance polarizing effect shifting the corrosion potential in the nobler direction. Consequently, it was considered that the W/C ratio of 0.6 showed nearly same results as those of W/C of 0.4 and 0.5. Therefore, the corrosion potential as well as various parameters such as the cover thickness, period of immersion, and W/C ratio must be considered at once for a more accurate evaluation of the corrosion property of reinforced steel exposed to marine environment for a long period.