• Metals and materials international
• /
• 제24권6호
• /
• pp.1262-1274
• /
• 2018

The inhibition of gravity segregation has been a long-standing challenge in fabrication and applications of homogeneous immiscible alloys. Therefore, the effect of rare-earth La on the gravity segregation of Al-Bi immiscible alloys was investigated to understand the homogenization mechanism. The results showed that the addition of La can completely suppress the gravity segregation. This is attributed to the nucleation of Bi-rich liquid phase on the in-situ produced $LaBi_2$ phase and the change of the shape of $LaBi_2@Bi$ droplets. In addition, a novel strategy is developed to prepare the homogeneous immiscible alloys through the addition of rare-earth elements. This strategy not only is applicable to other immiscible alloys, but also is conducive to finding more elements to suppress the gravity segregation. This study provided a useful reference for the fabrication of the homogeneous immiscible alloys.

• 한국재료학회:학술대회논문집
• /
• 한국재료학회 2007년도 추계학술발표대회 및
• /
• pp.74.2-74.2
• /
• 2007

• 한국가시화정보학회지
• /
• 제15권2호
• /
• pp.41-47
• /
• 2017

Microring/nanoring structure has high applicability for nano-antenna and biosensor thanks to its superior optical characteristics. Although coiling nanowires manufactured using immiscible emulsion droplets have an advantage in mass production, this process also forms nanowire bundles. In this study, we solved the nanowire bundle problem by size-selective sorting of the emulsion droplets in a pinched flow fractionation microchannel. Utilizing silver nanowires and immiscible emsulsion droplets, we investigated the correlation between the size of ring droplets and bundle droplet. We visualized the sorting process for glass particles and microring-containing emulsion droplets. Droplets were sorted based on their size, and the ratio of bundle droplets in solution decreased. This droplet-sorting strategy has potential to help the printing and coating process for manufacturing of ring structure patterns and developing of functional materials.

• 한국전산유체공학회지
• /
• 제12권3호
• /
• pp.41-46
• /
• 2007

Dynamic behavior of immiscible gas bubble attached to the wall in channel flow plays very important role in many engineering applications. Special attention has been paid to micro direct methanol fuel cell(${\mu}$DMFC) where surface tension becomes dominant factor with minor gravitational effect due to its reduced size. Therefore, displacement of $CO_2$ bubble generating on a cathode side in ${\mu}$DMFC can be very difficult and efficient removal of $CO_2$ bubbles will affect the overall machine performance considerably. We have focused our efforts on studying the dynamic behavior of immiscible bubble attached to the one side of the wall on 2D rectangular channel subject to external shear flow. We used Level Contour Reconstruction Method(LCRM) which is the simplified version of front tracking method to track the bubble interface motion. Effects of Reynolds number, Weber number, advancing/receding contact angle and property ratio on bubble detachment characteristic has been numerically identified.

• Fibers and Polymers
• /
• 제2권2호
• /
• pp.81-85
• /
• 2001

The effects of rate of phase separation to ester interchange reactions and the repulsive pair interaction energy on the phase behavior in a phase-separated immiscible polyester blend are investigated using a Monte Carlo simulation method. The time evolution of structure factor and the degree of randomness are monitored as a function of homogenization time. When the phase separation is dominant over ester interchange reactions, the domain size slowly increases with homogenization time. However, when the pair interaction becomes less repulsive, the domain size does not significantly change with homogenization time. On the other hand, when ester interchange reactions are dominant over the phase separation, the homogenization proceeds without a change in the domain size. The higher the extent of phase separation, the lower the increasing rate of the DR. However, when the phase separation is sufficiently dominant, the effect of the extent of phase separation on the increasing rate of the degree of randomness become less significant.

• 한국지하수토양환경학회지:지하수토양환경
• /
• 제23권1호
• /
• pp.1-13
• /
• 2018

A series of experiments using transparent micromodels with an artificial pore network etched on glass plates was performed to investigate the effects of flow rate on the migration and distribution of resident wetting porewater (deionized water) and injecting non-wetting fluid (n-hexane). Multicolored images transformed from real RGB images were used to distinguish n-hexane from porewater and pore structure. Hexane flooding followed by immiscible displacement with porewater, migration through capillary fingering, preferential flow and bypassing were observed during injection experiments. The areal displacement efficiency increases as the injection of n-hexane continues until the equilibrium reaches. Experimental results showed that the areal displacement efficiency at equilibrium increases as the flow rate increases. Close observation reveals that preferential flowpaths through larger pore bodies and throats and clusters of entrapped porewater were frequently created at lower flow rate. At higher flow rate, randomly oriented forward and lateral flowpaths of n-hexane displaces more porewater at an efficiency close to stable displacement. It may resulted from that the pore pressure of n-hexane, at higher flow rate, increases fast enough to overcome capillary pressure acting on smaller pore throats as well larger ones. Experimental results in this study may provide fundamental information on migration and distribution of immiscible fluids in subsurface porous media.

• 한국재료학회지
• /
• 제19권2호
• /
• pp.111-114
• /
• 2009

For the fabrication of core-shell structure bimetallic lead-free solder balls, both the critical temperature ($T_{cr}$) for the phase separation of two immiscible liquid phases and the temperature coefficient of the interfacial tension between the two separated liquid phases are required. In order to obtain this information, the temperature dependence of the surface tension of 60%Bi-24%Cu-16%Sn(-REM) alloys was measured using the constrained drop method. The slope of the temperature dependence of the surface tension changed clearly at a critical temperature for the separation of two immiscible liquid phases. The critical temperature of the 60%Bi-24%Cu-16%Sn alloy was estimated to be 1097K. An addition of 0.05% Ce decreased the critical temperature to 1085K, whereas that of 0.05% La increased it to 1117K. It was found that the surface tension and its temperature coefficient of the 60%Bi-24%Cu-16%Sn alloy were slightly increased by the addition of 0.05% Ce and 0.05% La. In addition, additions of Ce and La increased the temperature coefficient of the interfacial tension.

• KSBB Journal
• /
• 제15권1호
• /
• pp.55-59
• /
• 2000

생난황으로부터 시알산 함유 올리고당을 직접 생산하기 위한 biphasic system(water-immiscible hexane system)의 최적 조건을 조사하였다. Biphasic system I은 II보다 생산수율이 높았으며, 온도, 함수율 및 반응 시간의 최적조건은 각각 $30^{\circ}C$, 20%, 12시간이었다. Biphasic system I 에서, 난황을 가수분해하기 위한 3종류의 효소(protease A, corolase 7089, neutrase 0.5L)의 활성은 함수율과 온도에 강하게 영향을 받았으나, biphasic system II에서는 온도($30^{\circ}C$와 $50^{\circ}C$)의 영향을 거의 받지 않았다. 두 종류의 biphasic system에서 반응시간 12시간까지는 시알산 함유 올리고당의 생산량이 증가되었으나, 15시간 이후에는 거의 증가하지 않았다.

• 한국재료학회지
• /
• 제14권5호
• /
• pp.348-352
• /
• 2004

The mechanical alloying (MA) effect in immiscible V-Cu system with positive heat of mixing was studied by not only the neutron and X-ray diffraction but also the analysis of DSC spectra. The total energy, ΔHt accumulated during MA for the mixture of $V_{50}$ $Cu_{50}$ / powders increased with milling time and approached the saturation value of 14 kJ/mol after 120 h of milling. It can be seen that the free energy difference between the amorphous phase and the pure V and Cu powders with an atomic ratio 5:5 is estimated to be 11 kJ/mol by Miedema et al. This is thermodynamically taken as one of the evidences for the amorphization. The structural changes of V-Cu MA powders were characterized by the X-ray diffraction and neutron diffraction. We take a full advantage of a negligibly small scattering length of the V atom in the neutron diffraction measurement. The neutron diffraction data definitely indicate that the amorphization proceeds gradually but incompletely even after 120 h of MA and bcc-Cu Bragg peaks appears after 60 h of MA.

• 한국분말재료학회지
• /
• 제28권4호
• /
• pp.287-292
• /
• 2021

In this study, the layered structures of immiscible Fe and Cu metals were employed to investigate the interface evolution through solid-state mixing. The pure Fe and Cu powders were cold-consolidated by high-pressure torsion (HPT) to fabricate a layered Cu-Fe-Cu structure. The microstructural evolutions and flow of immiscible Fe and Cu metals were investigated following different iterations of HPT processing. The results indicate that the HPT-processed sample following four iterations showed a sharp chemical boundary between the Fe and Cu layers. In addition, the Cu powders exhibited perfect consolidation through HPT processing. However, the Fe layer contained many microcracks. After 20 iterations of HPT, the shear strain generated by HPT produced interface instability, which caused the initial layered structure to disappear.