• Title/Summary/Keyword: immersion time

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An Evaluation of Moisture Susceptibility on Asphalt Mixtures by Rainfall Intensity (강우강도에 따른 아스팔트 혼합물 종류의 수분민감도 평가)

  • Jung, Jong Suk;Kim, Yong Rak;Lee, Sang Hyeog;Kim, hyo Jin
    • International Journal of Highway Engineering
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    • v.16 no.5
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    • pp.29-38
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    • 2014
  • PURPOSES : The purpose of this study is to evaluate moisture susceptibility of a dense graded and an open graded asphalt mixtures by the method of AASHTO T-283. METHODS : To simulate moisture damage of asphalt pavements with continuously rainfall during summer rainy season, the dense graded and the open graded asphalt mixtures were immersed in water for 15 days and were measured the weight and the change of strength. Also, the mixtures were performed five freeze-thaw cycles to simulate moisture damage of the mixtures by freeze-thaw during winter and were measured the change of strength. The degradation characteristics model was used to analyze the relationship between strength and moisture damage. RESULTS : According to the results, the dense graded and the open graded asphalt mixtures were shown in the similar trends of the strength changes by immersion time and freeze-thaw cycle. However, the moisture damage reduction of open graded asphalt mixture was more sensitive in early phase than that of dense graded asphalt mixture.

A study on the effect of alumina coating on NiO dissolution in molten carbonate fuel cell (용융탄산염형 연료전지의 NiO 공기극의 용해거동에 미치는 알루미나 코팅효과에 대한 연구)

  • Ryu B. H.;Yoon S. P.;Han J;Nam S. W.;lim T.-H.;Hong S.-A.
    • New & Renewable Energy
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    • v.1 no.1 s.1
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    • pp.64-71
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    • 2005
  • The stability of alumina-coated NiO cathodes was studied in $Li_{0.62}/K_{0.38}$ molten carbonate electrolyte. Alumina was effectively coated on the porous Ni plate using galvanostatic pulse plating method. The deposition mechanism of alumina was governed by the concentration of hydroixde ions near the working electrode, which was controlled by the temperature of bath solution. Alumina-coated NiO cathodes were formed to $A1_2O_3-NiO$ solid solution by the oxidation process and their Ni solubilities were were than that of NiO up to the immersion time of 100h. However, their Ni solubilities increased and were similar to that of the bare NiO cathode after 100h. It was because aluminum into the solid solution was segregated to $\alpha-LiAlO_2$ on the NiO and its Product did not Play a role of the Physical barrier against NiO dissolution.

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Comparative analysis for the corrosion susceptibility of copper alloys in sandy soil

  • Galai, Mouhsine;Benqlilou, Hanane;Touhami, Mohamed Ebn;Belhaj, Tounsi;Berrami, Khalifa;El Kafssaoui, Hassan
    • Environmental Engineering Research
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    • v.23 no.2
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    • pp.164-174
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    • 2018
  • Corrosion of copper alloys (copper, bronze and brass) in soil was evaluated at ambient temperature using various methods such as electrochemical impedance spectroscopy (EIS), polarization curves and Scanning Electron Microscopy (SEM) coupled with Energy Dispersive Spectroscopy microanalysis measurements. Three equivalent circuits were separately used to interpret the obtained impedance spectra. The EIS measurements indicated that the polarization resistance of all electrodes increases with increasing the immersion time. SEM showed a presence of three layers of corrosion products with various composition and morphology covering each electrode. In addition, it was found that at 20% of moisture content the $R_p$ values and the current density of all electrodes in the studied soil give the following order: copper > bronze > brass. Good consistency between the data obtained from EIS and PP measurements was observed.

The Role of Aquaporin-4 in Cerebral Edema Formation after Focal Cerebral Ischemia in Rats

  • Song, Young-Jin;Bae, Hae-Rahn;Ha, Se-Un;Huh, Jae-Taeck
    • Journal of Korean Neurosurgical Society
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    • v.41 no.1
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    • pp.30-38
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    • 2007
  • Objective : To elucidate the role of aquaporin-4[AQP4] in cerebral edema formation, we studied the expression and subcellular localization of AQP4 in astrocytes after focal cerebral ischemia. Methods : Cerebral ischemia were induced by permanent middle cerebral artery[MCA] occlusion in rats and estimated by the discoloration after triphenyltetrazolium chloride[TTC] immersion. Change of AQP4 expression were evaluated using western blot. Localization of AQP4 was assessed by confocal microscopy and its interaction with ${\alpha}-syntrophin$ was analyzed by immunoprecipitation. Results : After right MCA occlusion, the size of infarct and number of apoptotic cells increased with time. The ratio of GluR1/GluR2 expression also increased during ischemia. The polarized localization of AQP4 in the endfeet of astrocytes contacting with ventricles, vessels and pia mater was changed into the diffuse distribution in cytoplasm. The interactions of AQP4 and Kir with ${\alpha}-syntrophin$, an adaptor of dystrophin complex, were disrupted by cerebral ischemia. Conclusion : The deranged spatial buffering function of astrocytes due to mislocalized AQP4/Kir4.1 channel as well as increased assembly of $Ca^{2+}$ permeable AMPA receptors might contribute to the development of edema formation and the excitotoxic neuronal cell death during ischemia.

A Study on the Estimation of Adhesive Stability of the Improved Direct Setting Method using Tile Bond for Application of Porcelain Tile under 1 percent absorptance (흡수율이 1% 이하인 자기질 타일의 타일접착제를 사용한 벽체 개량 떠붙임 공법의 부착안정성 평가 연구)

  • Jung, Yang-Hee;Jung, Eun-Hye;Seo, Sin-Seok;Kim, Ook-Jong;Lee, Do-Bum
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.11a
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    • pp.13-16
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    • 2008
  • This paper is to present the performance data for improved direct setting method using tile bond for application of porcelain tile under 1 percent absorptance. For this purpose, improved direct setting method type 1 & 2(tile bond curing time 0, 24H) were compared with the conventional setting methods(including direct setting method and improved pressure setting method) in the sight of the adhesive stability of porcelain tile. It tested for tiles after 14, 28days under standard condition and severe conditions. The severe conditions were water immersion, heat ageing(70℃) and freeze-thaw cycle. On the basis of test results, the adhesive strength of direct setting method was lowest for the conventional setting methods. But improved direct setting method using tile bonds(A, B) came close to the result of improved pressure setting method using tile bonds.

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A.c. Impedance Measurement of CP-Ti in 0.1 M NaOH Solution

  • Moon, Sungmo;Kwon, Mikyung;Kim, Jusuk
    • Journal of Electrochemical Science and Technology
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    • v.3 no.4
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    • pp.185-189
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    • 2012
  • A.c. impedances of mechanically polished CP-Ti specimens were measured at open-circuit potential (OCP) with immersion time and under applied anodic potentials between -0.2 and 1 $V_{Ag/AgCl}$ in 0.1 M NaOH solution. Capacitances of native oxide films ($C_{ox,na}$) grown naturally and capacitances of anodic oxide films ($C_{ox,an}$) formed under applied anodic potentials were obtained to examine the growth of native and anodic oxide films in 0.1 M NaOH solution and how to use $C_{ox,na}$ for the surface area measurement of Ti specimen. $1/C_{ox,na}$ and $1/C_{ox,an}$ appeared to be linearly proportional to OCP and applied potential ($E_{app}$), with proportional constants of 0.086 and 0.051 $uF^{-1}\;V^{-1}$, respectively. The $C_{ox,na}$ also appeared to be linearly proportional to geometric surface area of the mechanically polished CP-Ti fixture specimen, with proportional constants of 11.3 and $8.5{\mu}F\;cm^{-2}$ at -0.45 $V_{Ag/AgCl}$ and -0.25 $V_{Ag/AgCl}$ of OCPs, respectively, in 0.1 M NaOH solution. This linear relationship between $C_{ox,na}$ and surface area is suggested to be applicable for the measurement of real surface area of Ti specimen.

Sonochemical Synthesis of Closed [5,6]-bridged Aziridino[70]fullerene Derivative and Self-assembled Multilayer Films

  • Yoon, Shin-Sook;Hwang, Sung-Ho;Hong, Sung-Kyu;Lee, Jeong-Ho;Ko, Weon-Bae
    • Carbon letters
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    • v.10 no.4
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    • pp.325-328
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    • 2009
  • This cycloaddition of [70]fullerene with methyl azidoacetate in benzene under ultrasonic irradiated condition afforded the closed [5,6]-bridged aziridino[70]fullerene derivative, which was unusual product of cycloaddition to the 5,6-junction of fullerene. Its structure was determined by FAB-MS, UV-vis, $^1H-$ and $^{13}C$-NMR spectral data. The closed [5,6]-bridged aziridino[70]fullerene-functionalized gold nanoparticle films were self-assembled using the layer-by-layer method on the reactive of glass slides functionalized with 3-mercaptopropyl trimethoxysilane. The functionalized glass slides were alternately soaked in the solution containing closed the [5,6]-bridged aziridino[70]fullerene and 4-aminothiophenoxide/hexanethiolate-protected gold nanoparticles. The closed [5,6]-bridged aziridino[70]fullerene-functionalized gold nanoparticle films have grown up to 5 layers depending on the immersion time. The self-assembled nanoparticle multilayer films were characterized using UV-vis spectroscopy showed that the surface plasmon band of gold at 527 nm gradually became more evident as successive layers were added to the films.

Service Life Prediction of Concrete Structures Exposed to a Sulfuric Acid Environment

  • Jeon, Joong-Kyu;Moon, Han-Young;Jeon, Chan-Ki;Song, Jong-Hwa
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.385-389
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    • 2007
  • In this study, it was investigated the resistance of OPC, 60% GGBS, 20% PFA and 10% SF mortar specimens against sulfuric acid corrosion. As an index for degree of acid corrosion, the corrosion depth was evaluated. Then, it was found that an increase in the duration of immersion and a decrease in the pH, as expected, resulted in a more severe corrosion irrespective of binders; 60% GGBS mortar specimen was the most resistant to sulfuric acid corrosion. From the laboratory testing of sulfuric acid corrosion, an empirical prediction model was suggested as a power function of time and the pH of sulfuric acid, and was applied to an assessment of concrete structures exposed to an acidic environment. It was found that the empirical model gave a more precise prediction of sulfuric acid deterioration of concrete rather than a conventional model, mostly used for predicting carbonation of concrete.

Corrosion Behavior of Zn and Zn-AI Alloy Coated Steels under Cyclic Wet-dry Environments

  • Nishikata, Atsushi;Yadav, Amar Prasad;Tsutsumi, Yusuke;Tsuru, Tooru
    • Corrosion Science and Technology
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    • v.2 no.4
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    • pp.165-170
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    • 2003
  • Atmospheric corrosion behaviors of Zn, Zn-5%Al and Zn-55%A l coated steels have been investigated under cyclic wet-dry environments containing chloride ions. The wet-dry cycle was carried out by alternate exposure to immersion in 0.5 M (or 0.05 M) NaCl solutions and drying at $25^{\circ}C$ and 60 %RH. The polarization resistance $R_p$ and solution resistance $R_s$ were monitored by AC impedance technique. From the obtained $1/R_p$ and $1/R_s$ values, the corrosion rate of the coatings and the Time of Wetness (TOW) were estimated, respectively. Effects of chloride ions and TOW on the corrosion rates of Zn, Zn-5%Al, Zn-55%Al coatings and appearance of red rust (onset of underlying steel corrosion) under wet-dry cycles are discussed on the basis of the corrosion monitoring data.

High-resolution Optical and Near-infrared Spectra of 2MASS J06593158-0405277

  • Park, Sunkyung;Lee, Jeong-Eun;Pyo, Tae-Soo;Sung, Hyun-Il;Lee, Sang-Gak;Kang, Wonseok;Yoon, Tae Seog;Park, Won-Kee
    • The Bulletin of The Korean Astronomical Society
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    • v.42 no.1
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    • pp.54.2-54.2
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    • 2017
  • We present the results of high-resolution optical (R ~ 30,000) and near-infrared (R ~ 45,000) spectroscopic monitoring observations of a new FU Orionis-like young stellar object, 2MASS J06593158-0405277. FU Orionis objects (FUors) are well-studied examples of episodic accretion because of their outburst phenomenon. Recently, 2MASS J06593158-0405277 exhibited an outburst and was identified as an FUor. It provides an important opportunity to investigate the whole FUors phenomenon from its pre-outburst to its post-outburst phase. We observed 2MASS J06593158-0405277 with the Bohyunsan Optical Echelle Spectrograph (BOES) of the Bohyunsan Optical Astronomy Observatory (BOAO) and the Immersion GRating INfrared Spectrograph (IGRINS) of Harlan J. Smith Telescope (HJST) at the McDonald observatory since December 24, 2014. We detected a number of lines and present here our analysis for time variations of those spectral lines.

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