• Journal of the Korean Society of Safety
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• v.39 no.2
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• pp.38-43
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• 2024

Recently, with the expanding market for electronic devices and electric vehicles, secondary battery usage has been on the rise. Lithium-ion batteries are particularly popular due to their fast charging times and lightweight nature compared to other types of batteries. A secondary battery consists of four components: anode, cathode, electrolyte, and separator. Generally, the positive and negative electrode materials of secondary batteries are composed of an active material, a binder, and a conductive material. Acetylene Black (AB) is utilized to enhance conductivity between active material particles or metal dust collectors, preventing the binder from acting as an insulator. However, when recycling waste batteries that have been subject to high usage, there is a risk of fire and explosion accidents, as accurately identifying the characteristics of Acetylene Black dust proves to be challenging. In this study, the lower explosion limit for Acetylene Black dust with an average particle size of 0.042 ㎛ was determined to be 153.64 mg/L using a Hartmann-type dust explosion device. Notably, the dust did not explode at values below 168 mg, rendering the lower explosion limit calculation unfeasible. Analysis of explosion delay times with varying electrode gaps revealed the shortest delay time at 3 mm, with a noticeable increase in delay times for gaps of 4 mm or greater. The findings offer fundamental data for fire and explosion prevention measures in Acetylene Black waste recycling processes via a predictive model for lower explosion limits and ignition delay time.

• Journal of the Society of Disaster Information
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• v.18 no.1
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• pp.182-193
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• 2022

Purpose: By measuring and evaluating the risk of biodiesel through non-volatile residue (NVR) and flash point and explosion limit measurement at a specific temperature according to ASTM test standards, the risk of chemical fire causative substances is identified and a universal evaluation method By derivation and securing the risk-related data of the material, it can be used for the identification and analysis of the cause of the fire, and it can be applied to the risk assessment of other chemical substances Method: In order to measure the risk of biodiesel, it was measured using the non-volatile residue(NVR) measurement method, which measures how much flammable liquid is generated at a specific temperature. Heating was tested by applying KS M 5000: 2009 Test Method 4111. In addition, the flash point was measured using the method specified in ASTM E659-782005, and the energy supply method was measured using the constant temperature method. In addition, the explosion limit measurement was conducted in accordance with ASTM E 681-04 「Standard test method for concentration limits of flammability of chemicals(Vapors and gases)」 test standard. Result: As a result of checking the amount of combustible liquid by the non-volatile residue (NVR)measurement method, the non-volatile residue(NVR) of general diesel when left at 105±2℃ for 3 hours was about 30% (70% of volatile matter) and about 4% of biodiesel. In addition, similar results were obtained for the non-volatile residue(NVR)heating temperature of 150±2℃, 3 hours and 200±2℃ for 1 hour, and white smoke was generated at 200℃ or higher. In addition, similar values were obtained as a result of experimentally checking the explosion (combustion) limits of general diesel, general diesel containing 20% biodiesel, and 100% biodiesel. Therefore, it was confirmed that the flammability risk did not significantly affect the explosion risk. Conclusion: The results of this study suggested the risk judgment criteria for mixtures through experimental research on flammable mixtures for the purpose of securing the effectiveness, reliability, and reproducibility of the details of the criteria for determining dangerous substances in the existing Dangerous Materials Safety Management Act. It will be possible to provide reference data for the judgment criteria for flammable liquids that are regulated in the field. In addition, if the know-how for each test method is accumulated through this study, it is expected that it will be used as basic data in the research on risk assessment of dangerous substances and as a basis for research on the determination of dangerous substances.

• Fire Science and Engineering
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• v.15 no.4
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• pp.1-9
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• 2001

The purpose of this study is to set up disaster prevention plan and risk assessment system considering combustion velocity at traditional housing zone. The combustion velocity analysis could contribute to build in disaster prevention technique through the potential risk analysis of the area, such analysis also able to set up comprehensive disaster prevention management system. Following results have achieved through the combustion velocity calculation. \circled1 The combustion velocity was calculated in order of the below winds, the above winds and the side winds. \circled2 It must be careful to set up disaster prevention plan in case of the below winds. \circled3 The combustion velocity was calculated at the density Bone where neighboring Distance and Length was small. \circled4 It proved that factors of each parameter not mostly effect to analyse the combustion velocity in limit of the 30 minutes after ignition. \circled5 At the density zone where Distance and Length is small the duration of transfer to neighboring house takes up to 4 minutes, it is required to set up of emergency response plan to minimize the fire dispersion.

• Journal of Mechanical Science and Technology
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• v.17 no.10
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• pp.1563-1571
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• 2003

A fast response NO analyzer was applied to investigate the relation between cycle-by-cycle NO emissions and combustion chamber pressure. NO emissions were sampled at an isolated exhaust manifold of 4-stroke spark ignition engine to avoid the interference of exhaust gas from other cylinders. The linear correlation analysis was performed with collected data of NO emissions and combustion chamber pressure with respect to the various air-fuel mixture ratios and engine loads. The sampled data sets were obtained during 200 cycles at each operating condition. The results showed that there was a typical pattern in NO emissions from an exhaust port through a cycle. It was possible to set a block of crank angle in which the linear correlation coefficient between NO emissions and combustion chamber pressure was high. As the engine load increased, NO emissions were more dependent on combustion chamber pressure after TDC. It was also analyzed that the correlation between two parameters with respect to air-fuel mixture ratio tended to increase as mixture went leaner. Furthermore, this correlation coefficient for the mixture near the lean limit seemed to be kept high even though combustion was unstable.

• Journal of the Korean Society of Propulsion Engineers
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• v.15 no.1
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• pp.69-75
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• 2011

Firing tests have been carried out for a technology demonstration model of 75-tonf-class combustor which is to be used on the liquid rocket engine of a Korean space launch vehicle. Firing tests were done at 50% of the nominal flow rate because of incapability of the test facility and limit of the test bed strength. Through the low pressure firing tests of 75-tonf-class channel cooling thrust chamber, operability and stability at the ignition and combustion phases were confirmed. Additionally it was foreseen that the 75-tonf-class thrust chamber would satisfy the performance requirements.

• Proceedings of the KIEE Conference
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• 1994.07a
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• pp.110-113
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• 1994

In the hazardous areas where explosive substances in the form of gases, vapor or mists exist, electrical apparatus and installations must be of explosion-proof construction to prevent or limit the danger of the ignition of potentially explosive atmosphere. In Korea, six types of protection have been specified in the government regulations at present: flameproof enclosure, pressurization, oil immersion, increased safety, intrinsic safety, and special types. If electrical apparatus are made of explosion-proof construction in a way other than five above-mentioned types, and their performance is tested and approved by the reponsible authorities, they may be categorized as special type apparatus. In this paper, we introduced a special type of explosion-proof electrical apparatus, called non-incendive type, and presented its constructional requirements. We also investigated evaluation methods of non-incendive type apparatus to assure the explosion-proof performance, and proposed a new classification method of hazardous areas using probabilistic concept.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.05a
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• pp.71-74
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• 2010

Using the technology demonstration model of 75-tonf-class combustor which is expected to be used to the rocket engine of a korean space launch vehicle, 2 times of firing tests were carried out. Firing tests were done at 50% of the nominal flow rate because of incapability of the test facility and limit of the test bed strength. Through the low pressure firing tests of 75-tonf-class channel cooling thrust chamber, reliability and stability at the ignition and combustion phases were confirmed. Additionally it was foreseen that the 75-tonf-class thrust chamber would satisfy the performance requirements.

• Transactions of the Korean Society of Mechanical Engineers
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• v.11 no.3
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• pp.386-394
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• 1987

The method of methanol using in diesel engines hasn't been established yet because of it's low ignition characters. But many studies about it with many methods have been doing recently. If alcohol can be used in diesel engines, smoke and NO$\sub$x/, which is a big problem in diesel engines, can be reduced large. The purpose of this study is to establish using method of alcohol, as a substitute fuel. In this study, Combustion characters, engine performance and exhaust gas emissions are checked by using gasfication diesel method. Concluding remarks of this study are as follows. (1) Methanol can be used within 30% of total inducing energy, if above that rate, it can't be used because of knocking and bad operating condition. (2) Under the low load, the effect of methanol inducing of fuel consumption is somewhat bad, but under the high load, the effect is very good. (3) Under the high load, smoke limit is a marked improvement with methanol inducing.

• Journal of the Korean Society of Safety
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• v.29 no.4
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• pp.23-27
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• 2014

The use of electromagnetic energy and non-equilibrium plasma for enhancing ignition and combustion stability is receiving increased attention recently. The conventional technologies have adapted the electrical devices to make the electromagnetic field, which resulted in various safety issues such as high-maintenance, additional high-cost system, electric shock and explosion. Therefore, an electrodeless microwave technology has an advantage for economic and reliability compared with conventional one because of no oxidation. However, the application of microwave has been still limited because of lack of interaction mechanism between flame and microwave. In this study, an experiment was performed with jet diffusion flames induced by microwaves to clarify the effect of microwave on the combustion stability and pollutant emissions. The results show that microwave induced flames enhanced the flame stability and blowout limit because of abundance of radical pool. However, NOx emission was increased monotonically with microwave intensity except 0.2 kW, and soot emission was reduced at the post flame region.

• Journal of the Architectural Institute of Korea Structure & Construction
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• v.34 no.3
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• pp.37-42
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• 2018

The use of fly ash in construction materials is increasing worldwide due the various advantages of using it, such as to produce durable concrete, or to use less cement and thus lower carbon dioxide emissions. The quality of fly ash is often determined by loss on ignition value (LOI), where an upper limit of LOI is set in each country for quality control purpose. However, due to many reasons, production of high LOI fly ash is increasing that cannot be utilized in concrete, ending up in landfill. In this study, the effect of fly ash use in cementitious materials on nitrogen oxides adsorption is examined. In particular, the effect of using high LOI, and thus high carbon content fly ash on nitrogen oxides adsorption is investigated. The results suggest that the higher carbon content fly ash is related to higher nitrogen dioxide adsorption, although normal fly ash was also more effective in nitrogen dioxide adsorption than ordinary portland cement. Also, higher replacement rate of up to 40% of fly ash is beneficial for nitrogen dioxide adsorption. These results demonstrate that high carbon fly ash can be used as construction materials in an environmentally friendly way where strength requirement is low and where nitrogen oxides emissions are high.