• Title/Summary/Keyword: ignition hazards

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Measurement of Flash Point for Binary Mixtures of Methanol, Ethanol, 1-propanol and Toluene (Methanol, Ethanol, 1-propanol 그리고 Toluene 이성분 혼합계에 대한 인화점 측정)

  • Hwang, In Chan;Kim, Seon Woo;In, Se Jin
    • Fire Science and Engineering
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    • v.32 no.1
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    • pp.1-6
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    • 2018
  • The flash point is one of the most important parameters used to characterize the ignition and explosion hazards of liquids. Flash points were measured for several binary systems containing toluene, including {methanol+toluene}, {ethanol+toluene}, and {1-propanol+toluene}. Experiments were performed according to the standard test method using a SETA closed cup flash point tester. The measured flash points were compared with the predicted values calculated using the following $G^E$ models: Wilson, NRTL, and UNIQUAC. The average absolute deviation between the predicted and measured lower flash point was less than 1.69 K.

A Study on the Characteristics & Fire Hazard of Electric Range (전기레인지의 특성과 화재 위험성에 관한 연구)

  • Lee, Jung-Il;Ha, Kag-Cheon;Kim, Ji-Myong
    • Journal of the Society of Disaster Information
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    • v.15 no.3
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    • pp.380-390
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    • 2019
  • Purpose: Recently, in addition to increase in the use of electric ranges, fires have also been increasing. Method: To find out the fire risk of induction and highlights range, looked at the structure and operation methods. Combustion tests, heat transfer tests, and ignition tests were performed on both types. Results: The highlight electric range burned the towel two minutes later, takes about 25 minutes for the residual heat to cool down after cooking, and the energy of the red color disappeared in three to four minutes and no sparks were seen. Conclusion: Experiments have shown that burn and fire hazards exist, especially if there is cracks in the top, there is a risk of fire and explosion.

A Study on the Vented Gas Explosion Characteristics of Indoor Leakage of the LPG (실내 LPG 누출시 폭발특성에 관한 연구)

  • Oh Kyu-hyung;Kim Hong;Kim Sang-sub;Jo Yoong-do;Jo Jee-whan;Oh Shin-kyu
    • Journal of the Korean Institute of Gas
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    • v.3 no.3 s.8
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    • pp.51-57
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    • 1999
  • A study on the vented gas explosion characteristics were carried out with the liquified petroleum gas(LPG) which is used in domestics and industries fuel. To evaluate a damage by gas explosion and to predict a explosion hazards, a series of experiment have been performed in the regular hexahedron vessel of 270${\iota}$. A side of the vessel was made to setting a polyester diaphragm which was ruptured by explosion to simulate an accidental explosion which ruptured the window by explosion. Experimental parameters were LPG concentration, ignition position, venting area, a strength of diaphragm which was ruptured and distances from venting, Experimental results showed that vented gas explosion pressure was more affected by the diaphragm strength than the gas concentration, and the vented gas explosion pressure and blast wave pressure was increased with decreasing the venting area and increasing the strength of diaphragm. In this research we can find that a damage by vented explosion at the outside can be larger than the inside by blast wave pressure near the venting.

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Risk Assessment of Fire and Explosion of Methane (메탄의 화재 및 폭발 위험성 평가)

  • Ha Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.9 no.2 s.27
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    • pp.1-7
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    • 2005
  • The thermochemical parameters for safe handling, storage, transport, operation and process design of flammable substances are explosive limit, flash point, autoignition temperature, minimum oxygen concentration, heat of combustion etc.. Explosive limit and autoignition temperature are the major physical properties used to determine the fire and explosion hazards of the flammable substances. Explosive limit and autoignition temperature of methane fur LNG process safety were investigated. By using the literatures data, the lower and upper explosive limits of methane recommended 4.8 vol$\%$ and 16 vol$\%$, respectively. Also autoignition temperatures of methane with ignition sources recommended $540^{\circ}C$ at the electrically heated cruicible furnace (the whole surface heating) and recommended about $1000^{\circ}C$ in the local hot surface. The new equations for predicting the temperature dependence and the pressure dependence of the lower explosive limits for methane are proposed. The values calculated by the proposed equations were a good agreement with the literature data.

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Applying Fire Risk Analysis to Develop Fire-safe Modular Walls: Guidance to Material Selection, Design Approach and Construction Method

  • Lim, Seokho;Chung, Joonsoo;Kim, Mihyun Esther
    • Architectural research
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    • v.24 no.2
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    • pp.21-27
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    • 2022
  • For the past decade, South Korea had experienced catastrophic building fires, which resulted in consider-ably high number of casualties. This motivated research to develop fire-safe wall assemblies. In this study Fire Risk Analysis (FRA) is conducted as part of the project designing phase to ensure fire safety of the final product. Traditional approach was to consider fire performance at the end of the designing stage, when PASS/FAIL fire test results are required to be submitted to the Authority Having Jurisdiction (AHJ). By applying a fire risk analysis to guide the designing phase, overall fire safety of a wall assembly can be achieved more systematically as conducting FRA allows designers to clearly identify elements that are more vulnerable to fire and simply replace them with other practical options. Severity of fire risk is determined by considering the fire hazards of a wall assembly such as the exterior layer, insulation, vertical connectivity, and external ignition sources (e.g., photovoltaic panels). Frequency of fire risk is assessed based on the factors affecting fire likelihood, which are air cavity and fire-stopping applied in the design, and random design changes occurring during on-site construction. Fire risk matrix is proposed based on these fire risk factors and efforts to reduce the fire risk level associated with the wall assembly are given by systematically assessing the fire risk factors identified from fire risk analysis. Current study demonstrates how fire risk analysis can be applied to develop fire-safe walls by reducing the relevant fire risks- both severity and frequency.

A Study on the Heat Release Characteristics of Fire Load for Performance Based Design of Multiplexes: A Focus on the Heat Release Rate and Fire Spread Rate of Cinema Seats (복합영상관의 성능위주설계를 위한 가연물의 연소발열특성 연구: 객석의자의 열발생률 및 연소확산속도를 중심으로)

  • Nam, Dong-Gun;Jang, Hyo-Yeon;Hwang, Cheol-Hong;Lim, Ohk-Kun
    • Fire Science and Engineering
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    • v.34 no.1
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    • pp.11-17
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    • 2020
  • As performance-based design (PBD) has a direct impact on evacuation safety assessments, designing fire scenarios based on real fire tests is essential. To improve the reliability of the PBD for fire safety in multiplexes, information on fire behavior, such as heat release rate (HRR) and fire spread rate, are provided in this study by conducting a standard fabric flammability test. To this end, several chairs were arranged in a pattern that resembled a theater-style seating. The peak HRR and heating value per unit mass for each chair ranged from 415 kW to 988 kW and 15.2 MJ/kg to 23.8 MJ/kg, respectively. The heating values per unit mass of the new and old chairs were 23.6 MJ/kg and 16.7 MJ/kg, respectively. As the quantity of plastic and cushioning materials in the new chairs was more than that of the old ones, the new chairs were more vulnerable to fire hazards. Furthermore, when the chairs were arranged in a line, the fire spread rate was observed to be 0.39-0.42 m/min, regardless of the ignition location. Finally, a fire growth curve showing the peak HRR and fire spread rate was also demonstrated.

Dust Explosion Characteristics of Multi-Walled Carbon Nano Tube (다중벽 탄소나노튜브의 분진폭발 특성)

  • Han, In Soo;Lee, Keun Won;Choi, Yi Rac
    • Korean Chemical Engineering Research
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    • v.55 no.1
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    • pp.40-47
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    • 2017
  • Dust explosion hazards are always present when combustible dusts are manufactured or handled in the process. However, industries is experiencing difficulty in establishing chemical accident prevention measures because of insufficiency of information on dust explosion characteristics of combustible dust handled in industry. In this study, we investigated experimentally dust explosion characteristics of two kinds of multi-walled carbon nano tubes (MWCNT) different in particle size distribution and examined classification of dust explosion hazardous area for MWCNT manufacturing or handling process by applying the NFPA 499 code. As a result, $P_{max}$, $K_{st}$, LEL, MIE and MIT of MWCNT 1 having $124.2{\mu}m$ median diameter are obtained 6.3 bar, $56bar{\cdot}m/s$, $125g/m^3$, over 1000 mJ, and over $650^{\circ}C$. $P_{max}$, $K_{st}$, LEL, MIE and MIT of MWCNT 2 having $293.5{\mu}m$ median diameter are 6.2 bar, $42bar{\cdot}m/s$, $100g/m^3$, over 1000 mJ, and over $650^{\circ}C$, respectively. MWCNT 1, 2 are not categorized as combustible dust listed in the NFPA 499 Code for classification of dust explosion hazardous area because explosion severity and ignition sensitivity of MWCNT 1, 2 are below 0.35 and 0.01, respectively.

Measurement of flash point for binary mixtures of Ethanol, 1-propanol, 2-propanol and 2,2,4-trimethylpentane (Ethanol, 1-propanol, 2-propanol 그리고 2,2,4-trimethylpentane 이성분 혼합계에 대한 인화점 측정)

  • Hwang, In Chan;In, Se Jin
    • Clean Technology
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    • v.25 no.2
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    • pp.140-146
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    • 2019
  • Flammable substances, such as organic solvents, are commonly used in laboratories and industrial processes. The flash point of flammable liquid mixtures is a very important parameter for characterizing the ignition and explosion hazards, and the flash points of mixtures of $C_2{\sim}C_3$ alcohols and 2,2,4-trimethylpentane were measured in the present study. The 2,2,4-trimethylpentane is an important component of gasoline and is frequently used in the petroleum industry as a solvent. Lower flash point data were measured for the binary systems {ethanol + 2,2,4-trimethylpentane}, {1-propanol + 2,2,4-trimethylpentane}, and {2-propanol + 2,2,4-trimethylpentane}. The flash point measurements were carried out according to the standard test method (ASTM D3278) using a Stanhope-Seta closed cup flash point tester. The measured flash points were compared with the predicted values calculated using Raoult's law and also following $G^E$ models: Wilson, Non-Random Two Liquid (NRTL) and UNIversal QUAsiChemical (UNIQUAC). These models were able to predict the experimental flash points for different compositions of {$C_2{\sim}C_3$ alcohols + 2,2,4-trimethylpentane} mixtures with minimal deviations. The average absolute deviation between the predicted and measured lower flash point was less than 1.28 K. A minimum flash point behaviour was observed in all of the systems as in the many observed cases for the hydrocarbon and alcohol mixtures.