• Title/Summary/Keyword: iTS

Search Result 182, Processing Time 0.023 seconds

Mechanical and interfacial characterization of laser welded Co-Cr alloy with different joint configurations

  • Kokolis, John;Chakmakchi, Makdad;Theocharopoulos, Antonios;Prombonas, Anthony;Zinelis, Spiros
    • The Journal of Advanced Prosthodontics
    • /
    • v.7 no.1
    • /
    • pp.39-46
    • /
    • 2015
  • PURPOSE. The mechanical and interfacial characterization of laser welded Co-Cr alloy with two different joint designs. MATERIALS AND METHODS. Dumbbell cast specimens (n=30) were divided into 3 groups (R, I, K, n=10). Group R consisted of intact specimens, group I of specimens sectioned with a straight cut, and group K of specimens with a $45^{\circ}$ bevel made at the one welding edge. The microstructure and the elemental distributions of alloy and welding regions were examined by an SEM/EDX analysis and then specimens were loaded in tension up to fracture. The tensile strength (TS) and elongation (${\varepsilon}$) were determined and statistically compared among groups employing 1-way ANOVA, SNK multiple comparison test (${\alpha}$=.05) and Weibull analysis where Weibull modulus m and characteristic strength ${\sigma}_0$ were identified. Fractured surfaces were imaged by a SEM. RESULTS. SEM/EDX analysis showed that cast alloy consists of two phases with differences in mean atomic number contrast, while no mean atomic number was identified for welded regions. EDX analysis revealed an increased Cr and Mo content at the alloy-joint interface. All mechanical properties of group I (TS, ${\varepsilon}$, m and ${\sigma}_0$) were found inferior to R while group K showed intermediated values without significant differences to R and I, apart from elongation with group R. The fractured surfaces of all groups showed extensive dendritic pattern although with a finer structure in the case of welded groups. CONCLUSION. The K shape joint configuration should be preferred over the I, as it demonstrates improved mechanical strength and survival probability.

Michael-type Reactions of 1-(X-substituted phenyl)-2-propyn-1-ones with Alicyclic Secondary Amines in MeCN and H2O: Effect of Medium on Reactivity and Transition-State Structure

  • Kim, Song-I;Hwang, So-Jeong;Park, Yoon-Min;Um, Ik-Hwan
    • Bulletin of the Korean Chemical Society
    • /
    • v.31 no.5
    • /
    • pp.1199-1203
    • /
    • 2010
  • Second-order rate constants ($k_N$) have been measured spectrophotometrically for Michael-type reactions of 1-(X-substituted phenyl)-2-propyn-1-ones (2a-f) with a series of alicyclic secondary amines in MeCN at $25.0{\pm}0.1^{\circ}C$. The $k_N$ value increases as the incoming amine becomes more basic and the substituent X changes form an electron-donating group (EDG) to an electron-withdrawing group (EWG). The Br${\o}$nsted-type plots are linear with ${\beta}_{nuc}$ = 0.48 - 0.51. The Hammett plots for the reactions of 2a-f exhibit poor correlations but the corresponding Yukawa-Tsuno plots result in much better linear correlations with ${\rho}$ = 1.57 and r = 0.46 for the reactions with piperidine while ${\rho}$ = 1.72 and r = 0.39 for those with morpholine. The amines employed in this study are less reactive in MeCN than in water for reactions with substrates possessing an EDG, although they are ca. 8 pKa units more basic in the aprotic solvent. This indicates that the transition state (TS) is significantly more destabilized than the ground state (GS) in the aprotic solvent. It has been concluded that the reactions proceed through a stepwise mechanism with a partially charged TS, since such TS would be destabilized in the aprotic solvent due to the electronic repulsion between the negative-dipole end of MeCN and the negative charge of the TS. The fact that primary deuterium kinetic effect is absent supports a stepwise mechanism in which proton transfer occurs after the rate-determining step.

3D Modelling Shape Embodiment and Efficiency Analysis of Reservoir (저수지의 3D 모델링 형상 구현과 효율성 분석)

  • Song, Youn-Kyung;Hong, Soon-Hyun;Hong, Jung-Soo
    • Journal of the Korean Geophysical Society
    • /
    • v.9 no.2
    • /
    • pp.113-120
    • /
    • 2006
  • A lot of small-scale reservoirs that is extravagant in whole country are controlled state or real conditionthat correct data about the practice contents is not equipped all up to now. In this study, YungNam districts that region Gyeong-Ju city reservoir is distributed much of when flow speedily choose 23 peace among 73 small scale reservoir and experimented. Acquired data every 5 seconds, and user E/S and user value TS for orthocenter to 1 second interval and executes present ondition measurement using RTK-GPS. Could was wave and state that reservoir of 15 places (about 65%) gives protective care that do 3D modelling with acquired data, and now correct contents about reservoir state past through comparative analysis with data. Also, area of full water and wave that analyze effective storage and area of full water of 23 places reservoir could know that 20.63%, effective storage decreased as 3.34%. I wish to contribute about analysis about present reservoir state through this and method the adminstration direction.

  • PDF

Analysis of Characteristics of Coupled Phosphorus in the Sewage (하수 중 인의 결합 특성 분석)

  • Choi, Hee-Jeong;Lee, Seung-Mok
    • Journal of Korean Society on Water Environment
    • /
    • v.23 no.1
    • /
    • pp.97-102
    • /
    • 2007
  • The present investigation deals to achieve an accurate determination of the phosphorous present in the wastewater samples using the membrane reactor. The study may enable to quantify the dissolved (DP) and adsorbed phosphorous (AP), also the adsorbed phosphorous categorically identified as inorganic coupled phosphorous (DRP) and organic coupled phosphorous (NRP). Moreover, the study has been conducted separately in anaerobic and aerobic chamber. The results obtained showed that dissolved phosphorous only can occur in anaerobic chamber with ca. 25%. The study conducted for adsorbed phosphorous showed that the DRP has the percent composition in anaerobic and aerobic chamber respectively 33% and 40% i.e., 7% more in aerobic chamber. The similar values obtained for NRP was found to be 42% and 60% i.e., 18% more in aerobic chamber. On the other hand while comparing the results for NRP and DRP, it has to be noted that NRP has 9% and 20% more percent composition than DRP respectively in anaerobic and aerobic chamber. Further, the adsorbed phase showed the species Al-P, Fe-P in the aerobic chamber with the quotient of 7.73 mg/g TS (total solid) whereas in the anaerobic chamber it showed the species Fe-P and $Fe(OH)_3$-P with the 7.16 mg/g TS.

Time Stamp Compression in RTP Protocols using Enhanced Negotiation Bits Decision Algorithm (RTP 프로토콜에서 Time Stamp필드의 압축을 위한 향상된 협상비트 결정 알고리즘)

  • Kim, Kyung-Shin
    • Journal of the Korea Society of Computer and Information
    • /
    • v.18 no.10
    • /
    • pp.55-61
    • /
    • 2013
  • The important issue in header compression would be how to compress the dynamic field increasing constantly between consecutive packets in the head of IP wireless networks. Existent header compression scheme that can eliminated repeated field in header are RFC2507, RFC3095 and E-ROHC scheme. In this paper, I propose a new method of compressing TS fields, which are the Dynamic fields of the RTP packet, into BCB (Basic Compression Bits) basic bits or NCB (Negotiation Compression Bits, BCB + additional bits) bits. In order to verify the proposed header compression method, I have simulation about proposed video packets of IP wireless networks. using Visual SLAM.

Ecophysiological Studies on the Population Dynamics of Two Toxic Dinoflagellates Alexandrium tamarense and Alexandrium catenella Isolated from the Southern Coast of Korea -I. Effects of Temperature and Salinity on the Growth (남해연안해역에서 분리한 유독와편모조류 Alexandrium tamarense와 Alexandrium catenella의 개체군 변화에 관한 생리.생태학적 연구 -I. 수온과 염분의 변화에 따른 성장 특성)

  • Oh, Seok-Jin;Park, Ji-A;Kwon, Hyeong-Kyu;Yang, Han-Soeb;Lim, Weol-Ae
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.15 no.2
    • /
    • pp.133-141
    • /
    • 2012
  • Effects of temperature and salinity on the growth of the toxic dinoflagellate $Alexandrium$ $tamarense$ and $A.$ $catenella$ isolated from the southern coast of Korea were examined in the laboratory. Growth experiment was conducted under the following combinations of temperature and salinity; 10, 15, 20, 25 and $30^{\circ}C$, 10, 15, 20, 25, 30 and 35 psu at a constant irradiance of 300 ${\mu}mol$ photons $m^{-2}s^{-1}$. Temperature and salinity conditions for maximum growth rate were indicated as follows: temperature $15^{\circ}C$ and salinity 30 psu (0.31 $d^{-1}$) in $A.$ $tamarense$, temperature $25^{\circ}C$ and salinity 30 psu (0.36 $d^{-1}$) in A. catenella. Temperature and salinity ranges for optimum growth condition of two species were $10{\sim}20^{\circ}C$, 25~35 psu and $120{\sim}30^{\circ}C$, 25~35 psu, respectively. The result of two-factor ANOVA indicated significant effects (P<0.001) of temperature and salinity on the growth rate, and two species were more effected by a temperature than a salinity on the growth. In addition, prediction equations were obtained through the multiple regressions of the specific growth rates as ${\mu}=0.04+0.0193T-0.0339S- 0.0005T^2+0.0021S^2+0.00073TS-0.000022T^3-0.000038S^3+0.00000086TS^2-0.0000255T^2S$ in $A.$ $tamarense$ and ${\mu}=1.01-0.1288T-0.0778S+0.0067T^2+0.0038S^2+0.00204TS-0.0001T^3-0.000059S^3-0.0000131TS^2-0.0000392T^2S$ in $A.$ $catenella$. Correlation coefficient between experimental values and simulated values was highly indicated. These results seem to provide information for understanding the spreading mechanism of $A.$ $tamarense$ and $A.$ $catenella$.

A Tabu Search Algorithm to Optimal Weight Selection in Design of Robust $H_{\infty}$ Power System Stablilizer

  • Dechanupaprittha, S.;Ngamroo, I.
    • Proceedings of the IEEK Conference
    • /
    • 2002.07a
    • /
    • pp.486-489
    • /
    • 2002
  • This paper proposes a tabu search (TS) algorithm to optimal weight selection in design of robust H$_{\infty}$ power system stabilize. (PSS), In H$_{\infty}$ control design, the weight selection and the representation of system uncertainties are the major difficulties. To cope with these problems, TS is employed to automatically search for the optimal weights. On the other hand, the normalized coprime factorization (NCF) is used. The H$_{\infty}$ controller can be directly developed without ${\gamma}$-iteration. Also, the pole-zero cancellation phenomena are prevented. The performance and robustness of the proposed PSS under different loading conditions are investigated in comparison with a robust tuned PSS by examining the case of a single machine infinite bus (SMIB) system. The simulation results illustrate the effectiveness and robustness of the proposed PSS.

  • PDF

Theoretical Studies on the Acyl Transfer Reactions Involving a Tetrahedral Intermediate$^\dag$

  • 이도영;김창곤;이본수;이익준
    • Bulletin of the Korean Chemical Society
    • /
    • v.16 no.12
    • /
    • pp.1203-1208
    • /
    • 1995
  • Theoretical studies of the effect of the nonleaving group (RY) on the breakdown mechanism of the tetrahedral anionic intermediate, T-, formed by the addition of a less basic phenoxide nucleophile (X) to phenyl benzoates with a more basic phenoxide leaving group (Z) have been carried out using the PM3 MO method. The identity acyl transfer reactions (X=Z) are facilitated by an electron-withdrawing RY whereas they are inhibited by an electron-donating RY group. The results of non-identity acyl transfer reactions indicate that a more electron-donating RY group leads to a greater lowering of the higher barrier, TS2, with a greater degree of bond cleavage, and a greater negative charge development on the phenoxide oxygen atom, whereas the opposite is true for a more electron-withdrawing RY group, i.e., leads to a greater lowering of the lower barrier, TS1. The results provide theoretical basis for the signs of ρXY(>0) and ρYZ(<0) observations.

Effects of polysaccharide fractions from phellodendron chinese SCHNEID on tumor progression and immunopontentiation

  • Jun, Kya-I;Lee, Tae-Kyun;Kim, Cheorl-Ho
    • Advances in Traditional Medicine
    • /
    • v.1 no.1
    • /
    • pp.37-44
    • /
    • 2000
  • In the previous paper (Kim et al., Glycoconjugate Journal 16, 247-252, 1999), heteropolysaccharides from Korean medicinal plant, Phellodendri cortex (Hwangbek) showed a poten B-Iymphocyte-stimulating activity in a system using polyclonal antibody forming cells in C57BL/6XC3H mice at dosages of 2-10 mg. In a series of biolgical active polysaccharides from natural medicinal plants, the polysaccharide fractions were isolated and purified from Phellodendron chinese SCHNEID, and antitumor activities were examined at dosages of 2, 5 and 10 mg/100 g. F-7 and F-8 showed the highest tumor inhibitory activities (inhibition ratio 96.4 and 98.2% in 2 mg/100 g), and in dose of 5 mg/100 g, the inhibitory ratios were 95.3 and 97.5%, respectively. Furthermore, 10 mg/100 g of intraperitoneal (i.p.) injection gave 97.3 and 98.7% of inhibition. In oral administration, the inhibitory activities were not markedly observed, indicating that the polysaccharides are directly acting to immune system. When the effects on TS and TK activities were determined, TS activities in the F-2 and F-7-treated mice were markedly suppressed to 73.7% and 79.5% of that in the control (p<0.01), while there was little difference in TK activity with a slight decrease in F-2 only. However, in i.p. injection, TS activities in the F-2, F-5, F-7 and F-8-treated mice were markedly suppressed to 83% to 85% of that in the control (p<0.01). Furthermore, there was also significant differences in TK activities in F-2, F-5, F-7 and F-8-treated mice (p<0.05). Therefore, polysaccharide fraction F-8 was further purified to active fractions of F-9 and F-11 by gel permeation chromatography using TSK Gel HW50S. The purified polysaccharides of F-9 and F-11 were composed of GlcNAc (47.3%), Gal (24.7%) and Man (28.0%). These results clearly indicated that the i.p. injection is much effective to suppress tumor growth than oral administration.

  • PDF

A Study of the Academic Perspective of Chang Seok Sun (장석순(張錫純)의 학술사상에 관한 연구)

  • Woo, Ho;Park, Hyun-kuk
    • The Journal of Dong Guk Oriental Medicine
    • /
    • v.7 no.1
    • /
    • pp.1-32
    • /
    • 1998
  • I found following idea, as a result of researching his Science idea, mainly, by translation of the "$Zh\bar{a}ng$ xi $ch\acute{u}n$ $Xu\acute{e}$ $Sh\acute{u}$ ssu $hsi\acute{a}ng$ "(張錫純 學術硏究). $Zh\bar{a}ng$ xi $ch\acute{u}n$ regarded $ch\tilde{u}ng$ $ch\bar{u}ng$ $ts'\bar{a}n$ $hs\bar{l}$' (衷中參西) as the core idea of The Chinese-Western medical combination. He didn't segregate philosophy of the West from One of the Orient. He persued to harmonize each other and thought that the Western medicint theory is included in the Chinese one in many parts. besides, He recognized that it is bad to reject each other, for the medical science's purpose is to save a life, and united The Chinese-Western medicine theory, by $ch\acute{u}ng$ $ch\tilde{u}ng$ $ch\bar{u}ng$ $ts'\bar{a}n$ $hs\bar{l}$'(衷中參西) idea which refers to consult the Western medicine on the basis of the Chinese one. Medical basic theory of $Zh\bar{a}ng$ xi $ch\acute{u}n$ brought up new views of the theory : Dae-gi(大氣), gi-Hwa(氣化) theory, Nongangubgan byung juing chi(論肝及肝病證治), Eum her chijung ja bi(陰虛治重滋脾). Lim Sangeung yong(臨床應用) of Hyul Her gub(血虛及)-Hwal Hyul Hwa $\breve{u}$ bub(活血化瘀法), on the basis of classics, such as, "$N\breve{e}i$ Ching"(內經), "Chin Kue $\breve{i}$ $y\bar{a}o$ $l\ddot{u}{\bar{e}}h$, "Shen $n\acute{u}ng$ $p\breve{e}n$ $t\acute{s}{\check{a}}o$ ching"(新農本草經) etc. I'll sum up $Zh\bar{a}ng$ xi $ch\acute{u}n's$ clinical idea now He unified Sang Han(像寒)-On Byung(溫病) with Yuk Kyung Byung Jung(六經辨證) and It was noticiable to utilize a kinds of Baek Ho Tang(白虎湯). He gave a detailed description about a method of grasp the symptoms of the cause of the internal medicine diseases and pathology and, he left abundant views of theory about using remedy and experience of clinic.

  • PDF