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Otical Properties of P3HT-$TiO_2$ Hybrid Photovoltaic Cell (P3HT-$TiO_2$ 복합형 태양전지의 광학적 특성)

  • Her, Hyun-Jung;Baek, Un-Hyuk;Kim, Jae-Wan;Choi, Y.J.;Kang, C.J.;Kim, Yong-Sang
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1243-1244
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    • 2007
  • 전자주개물질 (elelctron donating material)인 poly(3-hexylthiophene) (P3HT)와 전자받개물질 (electron accepting material)인 티타니아 ($TiO_2$)를 이용한 복합형 태양전지에 대해 연구하였다. 유기물 태양전지에 응용되는 전도성 고분자의 여기자 (exiton)의 확산거리가 매우 짧기 때문에 그것을 보완하기 위해 전자주개물질과 받개물질의 표면적을 넓힐 필요가 있다. 비교적 패턴을 형성하기 쉬운 무기물인 티타니아를 이용해 표면적을 증가시켰으며 그렇지 않은 태양전지에 비해 효율이 두 배 증가하는 것을 볼 수 있었다. 티타니아의 표면적을 증가시킨 태양전지의 개방회로전압 ($V_{oc}$), 단락회로전류 ($I_{sc}$), FF (fill factor) 및 효율 (${\eta}$)은 각각 560 mV, 0.657 mA, 48.3 %, 0.18% 이다.

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High-performance photovoltaics by double-charge transporters using graphenic nanosheets and triisopropylsilylethynyl/naphthothiadiazole moieties

  • Agbolaghi, Samira;Aghapour, Sahar;Charoughchi, Somaiyeh;Abbasi, Farhang;Sarvari, Raana
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.293-300
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    • 2018
  • Reduced graphene oxide (rGO) nanosheets were patterned with poly[benzodithiophene-bis(decyltetradecyl-thien) naphthothiadiazole] (PBDT-DTNT) and poly[bis(triiso-propylsilylethynyl) benzodithiophene-bis(decyltetradecyl-thien) naphthobisthiadiazole] (PBDT-TIPS-DTNT-DT) and used in photovoltaics. Conductive patternings changed via surface modification of rGO; because polymers encountered a high hindrance while assembling onto grafted rGO. The best records were detected in indium tin oxide (ITO):poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS):PBDTDTNT/rGO:PBDT-DTNT:LiF:Al devices, i.e., short current density $(J_{sc})=11.18mA/cm^2$, open circuit voltage $(V_{oc})=0.67V$, fill factor (FF) = 62% and power conversion efficiency (PCE) = 4.64%. PCE increased 2.31 folds after incorporation of PBDT-DTNT into thin films. Larger polymer assemblies on bared-rGO nanosheets resulted in greater phase separations.

Change in radiation characteristics outside the SNF storage container as an indicator of fuel rod cladding destruction

  • Rudychev, V.G.;Azarenkov, N.A.;Girka, I.O.;Rudychev, Y.V.
    • Nuclear Engineering and Technology
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    • v.53 no.11
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    • pp.3704-3710
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    • 2021
  • The characteristics of the external radiation on the surface of the casks for spent nuclear fuel (SNF) storage by dry method are investigated for the case when the spatial distribution of SNF in the basket changes due to the destruction of the fuel rod claddings. The surface areas are determined, where the changes in fluxes of neutrons, produced by 244Cm actinide, and γ-quanta, produced by long-lived isotopes, are maximum in the result of the decrease in the height of the SNF area. Concrete (VSC-24) and metal (SC-21) casks are considered as examples. The procedure of periodic measurement of the dose rate of neutrons or γ-quanta at the specified points of the cask surface is proposed for identifying the fuel rod cladding destruction. Under normal operation, the decrease in the dose rate produced by neutrons as the function of SNF storage duration is determined by the half-life of 244Cm, and for γ-quanta - by the half-lives of long-lived SNF isotopes. Consequently, a stepwise change in the dose rate of neutrons or γ-quanta, detected by the measurements, as compared to the previous one, would indicate the destruction of the fuel rod claddings.

Factory Production Management of Modular Units Using MFD 2019 (MFD 2019를 활용한 모듈러 유닛의 공장생산 관리)

  • Lee, Doo-Yong;Nam, Sung-Hoon;Lee, Jae-Sub;Jung, Dam-I;Kim, Kyoung-rai;Cho, Bong-Ho
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.6
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    • pp.139-146
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    • 2019
  • The modular building system is a type of prefabricated construction method, and is an industrialized building system that transports, assembles, and completes a three-dimensional module manufactured in a factory to the site. The economics of a modular building system where 50 to 80% of the entire process takes place in a modular factory is dominated by productivity of the factory manufacturing process. Since the building of the module is finished by the combination of unit parts produced by each material, it is necessary to manage the process in each module unit. However, currently marketed process control programs do not reflect the features of these modular methods. In this paper, we introduce Modular Factory Design software(MFD 2019) that can make modular unit production plan which reflects production base(modular factory) and production target(application and number of modular units). In order to verify software compatibility and reliability, two production plans with different production methods were formulated and simulated.

Seismic Performance Evaluation of Non-seismic T-bar type Steel-Panel Suspended Ceiling using Shaking Table Test (비내진 상세를 갖는 금속마감패널 천장시스템의 진동대 실험을 통한 내진성능평가)

  • Lee, Jae-Sub;In, Sung-Woo;Jung, Dam-I;Lee, Doo-Yong;Lee, Sang-Hyen;Cho, Bong-Ho
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.35 no.10
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    • pp.171-180
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    • 2019
  • In Korea, the seismic design of non-structural elements was interested by Earthquake of the 2016 Gyeong-ju and 2017 Po-hang. Among the non-structural elements, the ceiling system with steel panel used in Po-hang station showed failure examples of non-seismic design ceiling. In this study, the seismic performance of suspended ceiling with steel-panel, such as those used in Po-hang Station, was evaluated by shaking table tests. The shaking table tests were performed in accordance with the ICC-ES AC156 standard with floor acceleration being applied horizontally in one direction using a $3.3{\times}3.3m^2$ frame. The ceiling system consists of steel-panels, carrying channels, main and cross T-bars, and anti-falling clips. The anti-falling clip prevents the steel panel falling completely. The shaking table test confirmed that the damage at the previous stage had a direct impact on the damage state at the next stage. Through the shaking table test, the damage state of the T-bar type steel-panel suspended ceiling system was defined.

Characterization of Wavelength Effect on Photovoltaic Property of Poly-Si Solar Cell Using Photoconductive Atomic Force Microscopy (PC-AFM)

  • Heo, Jinhee
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.3
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    • pp.160-163
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    • 2013
  • We investigated the effect of light intensity and wavelength of a solar cell device by using photoconductive atomic force microscopy (PC-AFM). The $POCl_3$ diffusion doping process was used to produce a p-n junction solar cell device based on a Poly-Si wafer and the electrical properties of prepared solar cells were measured using a solar cell simulator system. The measured open circuit voltage ($V_{oc}$) is 0.59 V and the short circuit current ($I_{sc}$) is 48.5 mA. Also, the values of the fill factors and efficiencies of the devices are 0.7% and approximately 13.6%, respectively. In addition, PC-AFM, a recent notable method for nano-scale characterization of photovoltaic elements, was used for direct measurements of photoelectric characteristics in local instead of large areas. The effects of changes in the intensity and wavelength of light shining on the element on the photoelectric characteristics were observed. Results obtained through PC-AFM were compared with the electric/optical characteristics data obtained through a solar simulator. The voltage ($V_{PC-AFM}$) at which the current was 0 A in the I-V characteristic curves increased sharply up to 1.8 $mW/cm^2$, peaking and slowly falling as light intensity increased. Here, $V_{PC-AFM}$ at 1.8 $mW/cm^2$ was 0.29 V, which corresponds to 59% of the average $V_{oc}$ value, as measured with the solar simulator. Also, while light wavelength was increased from 300 nm to 1,100 nm, the external quantum efficiency (EQE) and results from PC-AFM showed similar trends at the macro scale, but returned different results in several sections, indicating the need for detailed analysis and improvement in the future.

Conversion Efficiency Enhancement of a-Si:H Thin-Film Solar Cell Using Periodic Patterned Substrate (주기적인 패턴 유리 기판을 사용한 비정질 실리콘 박막 태양전지의 효율 향상에 관한 연구)

  • Son, C.H.;Kim, K.M.;Kim, J.H.;Hong, J.;Kwon, G.C.
    • Journal of the Korean Vacuum Society
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    • v.21 no.1
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    • pp.55-61
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    • 2012
  • We fabricated a-Si:H thin-film solar cell using the two-dimensional (2D) periodic patterned glass substrate. The use of a 3D periodic texture rather than a randomly texture at surface of TCO can result in higher short circuit current densities ($J_{sc}$). In order to analyze the optical effect of patterning glasses, ray-tracing simulations were performed. Also, p-i-n cells were deposited on patterned glasses as substrate by PECVD. UV-Vis spectroscopy, light I-V measurement were carried out for the optoelectronic characterization. The anti-reflective and light-trapping performance of patterning glass substrate was investigated by a comparison of experimental results with numerical simulations.

Comparison of Surface Passivation Layers on InGaN/GaN MQW LEDs

  • Yang, Hyuck-Soo;Han, Sang-Youn;Hlad, M.;Gila, B.P.;Baik, K.H.;Pearton, S.J.;Jang, Soo-Hwan;Kang, B.S.;Ren, F.
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.5 no.2
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    • pp.131-135
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    • 2005
  • The effect of different surface passivation films on blue or green (465-505 nm) InGaN/GaN multi-quantum well light-emitting diodes (LEDs) die were examined. $SiO_2$ or $SiN_x$ deposited by plasma enhanced chemical vapor deposition, or $Sc_2O_3$ or MgO deposited by rf plasma enhanced molecular beam epitaxy all show excellent passivation qualities. The forward current-voltage (I-V) characteristics were all independent of the passivation film used, even though the MBE-deposited films have lower interface state densities ($3-5{\times}10^{12}\;eV^{-1}\;cm^{-2}$) compared to the PECVD films (${\sim}10^{12}\;eV^{-1}\;cm^{-2}$), The reverse I-V characteristics showed more variation, hut there was no systematic difference for any of the passivation films, The results suggest that simple PECVD processes are effective for providing robust surface protection for InGaN/GaN LEDs.

Antioxidant, Anti-Wrinkle Activity and Whitening Effect of Fermented Mixture Extracts of Angelica gigas, Paeonia Lactiflora, Rehmannia chinensis and Cnidium officinale (당귀, 작약, 지황, 천궁 혼합 발효물의 항산화, 항주름 및 미백 효과)

  • Um, Ji Na;Min, Jin Woo;Joo, Kwang Sik;Kang, Hee Cheol
    • Korean Journal of Medicinal Crop Science
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    • v.25 no.3
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    • pp.152-159
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    • 2017
  • Background: In this study, examined the effects of an extract of a mixture of Angelica gigas, Cnidium officinale, Paeonia lactiflora, and Rehmannia glutinosa fermented by Leuconostoc mesenteroides, with enhanced value and functionality. In oriental medicine, a mixture of these herbs is called Samultang. Methods and Results: In this study, we evaluated the effects of a fermented extract of Samultang on oxidative stress, procollagen type I expression, and melanin production. Samultang was extracted with 70% ethanol, followed by inoculation with Leuconostoc mesenteroides to obtain the fermented extract. The evaluation of viability of B16F10 cells and human foreskin fibroblast (HHF) revealed that both ethanol and fermented extracts of Samultang were non-toxic. The results of 1,1-diphenyl-2-picrylhydrazyl (DPPH) test showed that the fermented extract of Samultang ($SC_{50}value=100{\mu}g/m{\ell}$) was a more effective DPPH free radical scavenger than its ethanol extract. In addition, procollagen type I expression was higher in cells treated with the fermented extract of Samultang than in cells treated with ethanol. In the non-toxic concentration range, the fermented extract of Samultang showed strong inhibitory effect on melanin production in ${\alpha}-melanocyte$ stimulatin hormone-stimulated B16F10 cells ($IC_{50}=37.9{\mu}g/m{\ell}$). Conclusions: These results suggest that the fermented extract of Samultang has considerable protential as a cosmetic ingredient owing to its antioxidant, anti-wrinkle, and whitening effects.

Flow and Strength Properties of Cement Mortar mixed with Naphthalene Superplasticizers (나프탈렌계 고성능감수제를 첨가한 시멘트 모르터의 유동성 및 강도특성)

  • 김화중;강인규;김성훈;권영도;황재현
    • Magazine of the Korea Concrete Institute
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    • v.6 no.4
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    • pp.85-91
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    • 1994
  • In the previous study, naphthalene and /or naphthol were sulfonated wlth sulfuric acid and they were condensated with formaldehyde. The condensates prepared are subjected to the flow and strength tests of cement rnortnr to examine the chemcal effects of cement adrnlxtures. As the results of flow test, the flow of cement mortar mxed wth naphthol condensates(TSC) and naphthol naphthalene cocondensates( NT5) was larger than those mxed with synthetic naphtha lene condensate (NSS). In the experiments of compressive strength after 28 days curing, the hardned cement mortar containing naphthalene naphthol condensates(N1'5) showed a higher compressive strength than those contairung naphthalene condensates(NSS) and naphthol condensates('I'SC). As a results, the synthetic naphthalene condensates(NT5, TSC 1, whlch used i n this study, are greatly expected as good superplasticizers for the concrete.