• Title/Summary/Keyword: iPP

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The Study on the Properties of Polypropylene/Nylon6 with Various Compatibilizers (Polypropylene/Nylon6 블렌드에서 이종의 상용화제에 따른 물성연구)

  • Kim, H.C.;Lee, K.Y.;Kim, H.I.
    • Applied Chemistry for Engineering
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    • v.10 no.4
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    • pp.497-501
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    • 1999
  • The changes of properties were studied for the polypropylene(PP)/Nylon6 blends containing different kinds of compatibilizer made by either reactive extrusion of solution reaction. The compatibilizers were PP grafted with maleic anhydride (MAH) made by reactive extrusion and solution reaction. The grafted MAH contents were 0.3 wt %, and 2.7 wt %, respectively. The composition of the PP/nylon6 blend was fixed at 75/25 by weight. Blending was carried out with twin-screw extruder (L/D=30, ${\psi}=30$) at 300 rpm. As the content of PP-g-MAH was increased, the crystallization peak of Nylon6 decreased gradually then finally disappeared. Disappearance of crystallization peak of Nylon6 was mostly affected by grafted MAH content rather than the preparation method and the amount of compatibilizer. The portion of Nylon6 that could not crystallize in its normal crystallization temperature crystallized together with PP at the crystallization temperature of PP. So called concurrent crystallization was observed. Meanwhile two more peaks were observed during heating cycle. One was exothermic peak at $193^{\circ}C$ near to crystallization temperature of Nylon6, the other was endothermic peak at $215^{\circ}C$ that was $5^{\circ}C$ lower than normal endothermic peak of Nylon6. To analyze the peaks, nylon6 was annealed in the differential scanning calorimeter. As a result, the peak at $193^{\circ}C$ was crystallization peak of imperfect crystalline of Nylon6 and the other peak at $215^{\circ}C$ was melting peak of imperfect crystalline of nylon6.

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Effect of Chlorinated Polyethylene(cPE) on Morphology and Mechanical Properties of Polypropylene(PP) and Nitrile Rubber(NBR) Blends (염소화폴리에틸렌의 첨가가 폴리프로필렌-니트릴 고무 블렌드의 모폴로지 및 기계적물성에 미치는 영향)

  • Chang, Young-Wook;Won, Jong-Hoon;Joo, Hyun-Seok;Chung, Kyung-Ho
    • Elastomers and Composites
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    • v.40 no.3
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    • pp.204-211
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    • 2005
  • Effect of chlorinated polyethylene(cPE) on the morphology and mechanical properties of isotactic polypropylene(iPP) and nitrile rubber(NBR) blends was investigated. It was found that incorporation of a small amounts of cPE leads to a decrease in domain size of the dispersed phase, and uniform distribution of the dispersed phase in the blends. The PP/NBR/cPE ternary blends showed an improved tensile and tear strength as well as elongation-at-break as compared to binary PP/NBR blends. From the results on morphology and mechanical properties, optimum amount of the cPE is 5-10 wt% with repect to NBR in the blend.

Ultra Thin Film Encapsulation for Flexible OLED (플렉시블 유기 EL 소자를 위한 초박막 보호층)

  • Lim, J.S.;Shin, P.K.;Lim, K.B.;Song, J.H.;Kim, C.Y.;Lee, B.S.;Jeung, Y.S.;Lim, H.C.
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1412-1413
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    • 2006
  • In this research, an organic thin 13 passivation layer was newly adopted to prefect the organic layer from ambient moisture and oxygen. As the organic thin film passivation layer, poly methyl methacrylate thin films (ppMMA) were deposited using a plasma polymerization technique. In order to their passivation performance for OLEDs, water vapor transmission rate (WVTR) of the ppMMAs were analyzed and luminance-current-voltage (L-I-V)/luminance-time (L-T) characteristics of the OLEDs with and without ppMMA passivation layer were investigated. The OLEDs had a structure of ITO/TPD (HTL)/Alq3(EML&ETL)/Al. The OLED with ppMMA passivation layer showed improved L-T performance than that of without ppMMA passivation layer.

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Sandwich Intermediate Sitting-atop Complexation between Free Base meso-tetraarylporphyrins and Tellurium(IV) chloride

  • Dehghani, Hossein;Bakhshayesh, Sara;Shaterian, Maryam;Motamedi, Leila
    • Bulletin of the Korean Chemical Society
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    • v.31 no.4
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    • pp.815-818
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    • 2010
  • Free base meso-tetraarylporphyrins ($H_2T(X)PP$) react with tellurium(IV) chloride ($TeCl_4$) in mild conditions for formation sandwich intermediate sitting-atop (i-SAT) complexes, [$TeCl_4(H_2T(X)PP)_2$]. $^1H$ NMR, $^{13}C$ NMR, UV-vis, FT-IR and elemental analysis were used for characterization of the products. In the proposed structure of the i-SAT complexes, four pyrroles of each porphyrin ring are tilted alternatively up and down and this appropriates suitable orientation of lone pairs of two pyrrolenine nitrogens for electron donation to a tellurium center. $^1H$ NMR and FT-IR results showed that in the produced complex, hydrogen atoms of porphyrin macrocycles remained on the pyrrole nitrogens.

Characteristics on the Motion of Purse Seine(I) -The Sinking Behaviour of Model Purse Seine by Different Netting Material- (건착망의 운동특성(I) -그물감이 다른 건착망의 침강거동-)

  • Kim, Suk-Jong;ImaiI, Takehiko;Park, Jeong-Sik
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.31 no.4
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    • pp.362-371
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    • 1995
  • This study describes with the sinking behaviour for the purse seine. The experiment was carried out using three model purse seines of knotless netting. The nettings were woven in same leg length(10.5mm) of polypropylene 170 denier, polyamide 210 denier and polyester 250 denier two thread ply twine, each of the seines were named PP seine, PA seine and PES seine. Dimension of Purse seine models were 420cm for corkline and 85cm for seine depth, each models rigged 65.8g, 50.6g and 35.8g(weight in water) of lead for a leadline, seine models will have the same weight in water. Experiments carried out in the observation channel in a flume tank under still water conditions. Sinking motion was recorded by the one set of TV-camera for VTR, and reading coordinate carried out by the video digitization system. The results obtained were as follows: 1) Netting bundle for PP seine was existence on the surface of the water, spread out a netting by sinking force of sinkers. 2) Netting bundle for PES seine was existence in the middle of corkline and leadline. 3) Average sinking speed of seine margin was fastest for 10.7cm/s of PP seine, followed by 9.7cm/s of PA and 9.2cm/s of PES seines. 4) In all seines, the force of horizontal movement for the seine setting was values of ranged in disregard.

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Uterine Involution and Ovarian Follicular Growth during Early Postpartum Period of Murrah Buffaloes (Bubalus bubalis)

  • Lohan, I.S.;Malik, R.K.;Kaker, M.L.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.3
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    • pp.313-316
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    • 2004
  • Ultrasonographic studies were conducted on eight Murrah buffaloes daily from day 6 postpartum (pp) onwards till day 77 pp to monitor changes in the cervix, uterine horn and ovarian follicular growth and development. The mean size of horn and cervix on day six ($9.07{\pm}0.74$ and $8.58{\pm}0.00cm$) decreased significantly to $4.09{\pm}0.09$ and $3.56{\pm}0.08cm$ by day 27 pp, respectively. Follicles in 50% of the buffaloes ovulated within 24 to 54 days pp and the size of the largest follicle on different days increased to more than 5 mm. The remaining 50 percent of animals ovulated after 65 days postpartum. Large size follicles (>8.5 mm) appeared in six out of eight buffaloes between 10 to 30 days pp and five animals had ovulated during early postpartum period. Waves pattern of follicular growth was observed during early postpartum period. Ovulatory follicles growth rate was more than the anovulatory follicles and increase in size was more as compared to the subordinate follicle. Anovulatory follicles persisted for longer period. Mean size of large follicle was more from day 6 to 41 pp and again from 50 to 65 pp in cyclic animals. Second large follicle were large during early postpartum (18days), thereafter, its size was more in acyclic animals. Small follicles population was less in cyclic animals upto day 50 postpartum. Mean medium size follicle growth pattern did not differ in cyclic and acyclic groups. Large size follicle number was more in cyclic group (5/8) during 14 to 20 days postpartum. Presence of large follicles (>8.5 mm) showed initiation of ovarian activity.

Positive implicative and associative filters of lattice implication algebras

  • Jun, Young-Bae;Yang Xu;Keyun Qin
    • Bulletin of the Korean Mathematical Society
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    • v.35 no.1
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    • pp.53-61
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    • 1998
  • We introduce the concepts of a positive implicative filter and an associative filter in a lattice implication algebra. We prove that (i) every positive implicative filter is an implicative filter, and (ii) every associative filter is a filter. We provide equivalent conditions for both a positive implicative filter and an associative filter.

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Spalling Properties of High Strength Concrete Mixed with Various Mineral Admixtures Subjected to Fire

  • Han, Cheon-Goo;Han, Min-Cheol;Heo, Young-Sun
    • International Journal of Concrete Structures and Materials
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    • v.2 no.1
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    • pp.41-48
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    • 2008
  • This study investigates the spalling properties of high strength concrete designed with various types of mineral admixture and diverse content ratios of polypropylene (PP) fiber. Experimental factors considered in series I are four pozzolan types of mineral admixture and series II consists of three shrinkage reducing types of mineral admixture. PP fiber was added 0.05, 0.10 and 0.15vol. % in each mixture of series I and series II, so that totally 27 specimens including control concretes in each series were prepared. Test results showed that the increase of fiber content decreased the slump flow of fresh concrete and increased or decreased the air content depending on the declining ratio of slump flow. For the properties of compressive strength, all specimens were indicated at around 50 MPa, which is high strength range; especially all specimens in series II were 60 MPa. Fire test was conducted in standard heating curve of ISO 834 with ${\phi}100{\times}200\;mm$ size of cylinder moulds for 1 hour. The specimens incorporating silica fume exhibited severe spalling and most specimens without the silica fume could be protected from the spalling occurrence in only 0.05vol % of PP fiber content. This fire test results demonstrated that the spalling occurrence in high strength concrete was not only affected by concrete strength related to the porosity of microstructure but also, even more influenced by micro pore structure induced by the mineral admixtures.