• Elastomers and Composites
• /
• 제47권3호
• /
• pp.238-245
• /
• 2012

천연 흑연으로부터 Graphene oxide(GO)를 합성한 후 diisocyanatodicyclohexylmethane($H_{12}MDI$)를 이용하여 GO의 표면을 기능화하였고, hydrazine monohydrate에 의한 환원을 통해 isocyanate-graphene sheet(i-RGO)를 얻었다. 폴리우레탄과 적합한 나노복합체를 형성하기 위하여 GO, i-RGO, 천연흑연 및 열적환원된 graphene을 서로 비교분석하였으며, i-RGO가 가장 적합한 나노충전제로 선정되었다. 선정된 i-RGO의 함량에 따른 폴리우레탄의 물성 향상을 확인하기 위하여 충전제의 함량을 다르게 하여 PU/i-RGO 나노복합체를 합성하였다. 물성 평가에서, i-RGO의 함량이 증가할수록 열적 안정성, 경도 및 접촉각(발수력)이 향상되었는데, 이는 i-RGO의 물성 특성 및 가교점 작용에 기인한 것으로 판단되었다. 다만, 인장강도와 신장률의 경우 함량이 4 wt%를 넘어갈 경우 오히려 물성이 감소하는 것을 확인할 수 있었는데, 이는 과량의 가교점 형성이 원인인 것으로 해석되었다.

• 한국소음진동공학회논문집
• /
• 제13권1호
• /
• pp.10-18
• /
• 2003

This paper presented a design and control of a biped walking RGO(robotic gait orthosis) and its simulation. The biped walking RGO was distinguished from the other one by which had a very light-weight and a new RGO system will be made of 12-servo motors and 12-controllers. The vibration evaluation of the dynamic PLS(posterior leaf splint) on the biped walking RGO was used to access by the 3-axis accelerometer with a low frequency vibration of less than 30 Hz. The galt of the biped walking RGO depends on the constrains of mechanical kinematics and the initial posture. The stability of dynamic walking was investigated by analyzing the ZMP (zero moment point) of the biped walking RGO. It was designed according to the human wear type and was able to accomodate itself to the environments of S.C.I. Patients. The Joints of each leg were adopted with a good kinematic characteristics. To analyse joint kinematic properties. we made the strain stress analysis of the dynamic PLS and the analysis study of FEM with a dynamic PLS.

• 한국소음진동공학회:학술대회논문집
• /
• 한국소음진동공학회 2003년도 춘계학술대회논문집
• /
• pp.882-887
• /
• 2003

This paper presented a design and control of a new RGO(reciprocating gait orthosis)and its simulation. The new RGO was distinguished from the other one by which had a very light-weight and a new RGO(reciprocating gait orthosis) system. The vibration evaluation of the hip joint system on the new RGO(reciprocating gait orthosis)was used to access by the 3-axis accelerometer with a low frequency vibration of less than 30 ㎐. The gait of the new RGO depended on the constrains of mechanical kinematics and the initial posture. The stability of dynamic walking was investigated by analyzing the ZMP (zero moment point) of the new RGO. It was designed according to the human wear type and was able to accomodate itself to the environments of S.C.I. Patients. The joints of each leg were adopted with a good kinematic characteristics. To analyse joint kinematic properties, we made the hip joint system of FEM and the hip joint system by 1-axis and 3-axis Accelerometers.

• Journal of Electrochemical Science and Technology
• /
• 제10권3호
• /
• pp.313-320
• /
• 2019

In this study, cobalt diselenide ($CoSe_2$) and the composites ($CoSe_2@RGO$) of $CoSe_2$ and reduced graphene oxide (RGO) were synthesized by a facile hydrothermal reaction using cobalt ions and selenide source with or without graphene oxide (GO). The formation of $CoSe_2@RGO$ composites was identified by analysis with X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy and scanning electron microscopy (SEM). Electrochemical analyses demonstrated that the $CoSe_2@RGO$ composites have excellent catalytic activity for the reduction of $I_3{^-}$, possibly indicating a synergetic effect of $CoSe_2$ and RGO. As a consequence, the $CoSe_2@RGO$ composites were applied as a counter electrode in DSSC for the reduction of redox couple electrolyte, and exhibiting the comparable power conversion efficiency (7.01%) to the rare metal platinum (Pt) based photovoltaic device (6.77%).