• Title/Summary/Keyword: hydroxide

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Hydrolysis of Silk Fibroin with Boiling Water, Hydrochloric Acid, and Sodium Hydroxide -On the Quantitative Change in Terminal Amino Group Content- (견피브로인의 비등수 염산 및 수산화나트륨에 의한 가수분해 -말단아미노기의 정양적변화를 중심으로-)

  • Park Chan Hun;Dho Seong Kook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.11 no.1
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    • pp.63-69
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    • 1987
  • Silk fibroin is likely to be hydrolyzed by acids or alkalies at high temperature, and the degree of the hydrolysis has been inferred from the changes in tensile strength and elongation. But, in this experiment, it was intended to infer that from the quantitative changes in terminal aminp group content as well as in tensile strength and elongation. Silk yarn was treated with boiling water, hydrochloric acid, and sodium hydroxide under various conditions. The boiling water somewhat degraded silk fibroin. Silk yarn treated with sodium hydroxide contained more terminal amino group than that treated with hydrochloric acid. This result agreed fairly well with the loss in weight, tensile strength, and elongation: the terminal amino group content increased with the decrease of tensile strength, elongation, and weight. The damage by sodium hydroxide to the silk fibroin was greater than that by hydrochloric acid.

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A Literature Study on the Development of Cementitious Materials using a Layered Double Hydroxide (층상이중수산화물(Layered Double Hydroxides)을 활용한 시멘트계 재료 개발에 관한 문헌조사 연구)

  • Lee, Seung-Yeop;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.107-108
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    • 2015
  • Layered Double Hydroxides is known as a hydrotalcite-like material. It is a type of anionic clay with planar structure. It is composed of layer structure which is able to exchange anion between two layers which includes divalent ion and trivalent ion. Therefore, layered double hydroxide is applicable for eliminating harmful heavy metals and anionic substances which exist in the concrete. Because it is also able to be used as catalyst and has high possibility of utilization, It is getting an large amount of attention recently. In this study, an analysis on the structure of the layerd double hydroxide (LDH) which is possible to bind the anion was carried out.

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Fabrication of High-Density Nickel Hydroxide Powder-I (고밀도 수산화니켈 분말의 제조에 관한 연구-I)

  • 신동엽;조원일;신치범;조병원;강탁;윤경석
    • Journal of the Korean institute of surface engineering
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    • v.28 no.2
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    • pp.92-100
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    • 1995
  • To increase the capacity of positive electrode materials for matching the high capacity negative electrode materials in alkaline rechargeable batteries, high-density nickel hydroxide powders were made through a continuous process from nickel sulfate reacted with ammonia and sodium hydroxidc. The effect of operating conditions on structure, shape, size distribution, apparent density and tap density of powders were investigated. Crystal structure of nickel hydroxide powder was hcp according to Bravais Lattice. The increase of mean residence time promoted the growth of (101) plane. The shape of powder was nearly spherical. Their size was in the range of $2~50\mu\textrm{m}$. The size distribution of the powders prepared was narrower than that of commercially obtained nickel hydroxide. Apparent density and tap density were 1.6~1.7g/cc and 2.0~2.1g/cc, respectively.

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Study on Neutralization Progress Model of Concrete with Coating Finishing Materials in Outdoor Exposure Conditions Based on the Diffusion Reaction of Calcium Hydroxide

  • Park, Jae-Hong;Hasegawa, Takuya;Senbu, Osamu;Park, Dong-Cheon
    • International Journal of Concrete Structures and Materials
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    • v.6 no.3
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    • pp.155-163
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    • 2012
  • In order to predict the neutralization of concrete which is the reaction of carbonation dioxide from the outside and cement hydration product, such as calcium hydroxide and C-S-H, it was studied the numerical analysis method considering change of the pore structure and relative humidity during the neutralization reaction. Diffusion-reaction neutralization model was developed to predict the neutralization depth of concrete with coating finishing material. In order to build numerical analysis models considering outdoor environment and finishing materials, the adaption of proposed model was shown the results of existing outdoor exposure test results and accelerated carbonation test.

The structure of intercalation compound between a layered double hydroxide and an ethyl orange (층상이중수산화물과 에틸오렌지의 삽입화합물의 구조)

  • Jung, Woo-Chan;Huh, Young-Duk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.137-142
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    • 1997
  • We synthesized the intercalation compound between a layered double hydroxide and an ethyl orange. The orientation of the intercalated ethyl orange into the layered double hydroxide was investigated. The molecular plane of the ethyl orange and its N=N axis lie nearly perpendicular to the hydroxide layers with an antiparallel pattern.

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Effect of Sodium Hydroxide Treatment on Nutritive Value of Pelleted Rye Hay (호밀건초 Pellet 조제시 NaOH 처리가 사료가치에 미치는 효과)

  • 한성윤;김대진
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.20 no.3
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    • pp.155-160
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    • 2000
  • This syudy was conducted to increase the utility of forage rye which are suitable to be cultivated at high altitude Taekwllyong area. For that purpose two cultivars of rye (winter-more, kool-glazer) were cultivated for 3years using a randomized block design with 3 replications. The dry matter digestibility (DMD) was evaluated with the pelleted rye hay produced by adding sodium hydroxide and then the TDN value was calculated by the DMD. By adding NaOH, DMD and TDN value of rye pellets (Y=46.92+ 1.8X, ~ 0 . 9 7 )w ere increased significantly (p<0.05) and NDF (neutral detergent fiber) decrease significantly. However, ADF (acid detergent fiber) and lignin did not significantly decrease (p<0.05). Rye could be cultivated as a second crop after com at high altitude area in the same year and pelleted with NaOH in order to increase the nutritive values (p< 0.05). (Key words : Dry matter digestibility (DMD), Forage rye, NDF, ADF, Sodium hydroxide)

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A Study on the Efficiency of Dye Sensitized Solar Cell Employing TiO2 Photoelectrode Synthesized Using Basic Catalyst (염기성 촉매제를 이용한 염료감응 태양전지의 효율에 관한 연구)

  • Ki, Hyun-Chul;Jung, Haeng-Yun;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.10
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    • pp.736-740
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    • 2013
  • In this study, the influence of electrochemical properties by mixing Tetrabutylammonium hydroxide (TBAOH) and ammonium hydroxide (NH4OH) electrode on the dssc. The titanias were prepared using a sol-gel method by mixing Tetrabutylammonium hydroxide and Ammonium hydroxide. The $TiO_2$ nanopowder prepared by sol-gel methode, and to improve the distributed properties of $TiO_2$ nanopowder, the TBAOH and NH4OH was added. The I-V values of cells show that the Tetrabutylammonium has 6.51% efficiency.

Studies on Magnesia Production. Production of Magnesium Hydroxide from Bittern and Sea Water (마그네시아 製造에 關한 硏究 간수, 海水로 부터 水酸化마그네슘 製造)

  • Maeng, Jung-Jae;Chang, In-Soon
    • Journal of the Korean Chemical Society
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    • v.9 no.1
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    • pp.49-54
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    • 1965
  • One of the difficult and time consuming problems in the production of magnesia from sea water is a settling rate of magnesium hydroxide. In this experiments, authors attempted to accelerate its settling rate by addition of various sedimenting agents as C.M.C., Separan and Starch, and sought for optimum calcination temperature for domestic dolomite, as alkali source, mole ratio of dolomite milk to bittern. It is observed through experiments that the small amounts of sedimenting agents, C.M.C., Separan, starch, 20 mg/l, 40 mg/l, 400mg/l, respectively increase the settling rate of magnesium hydroxide by 8 times or more. The following conditions resulted in good yield of magnesium hydroxide from sea water with relatively tolerable calcium oxide contaminated for the magnesium clinker. Calcinating temperature, $1,100{\sim}1,200^{\circ}C$, mole ratio of 10% dolomite milk to magnesium salts in sea water or bittern, 1. 2 : 1.

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Formation of Magnetite Using $Fe^{2+}$ and $Fe^{3+}$ Hydroxide ($Fe^{2+}$$Fe^{3+}$ 수산화물을 이용한 마그네타이트 합성)

  • Oh, Jae-Hyun;Hong, Young-Ho;Park, Jung-Hoon;Kim, Mahn
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1346-1354
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    • 1994
  • In this study, the formation of magnetite using Fe(II) and Fe(III) hydroxides was investigated; The effects of hydroxide synthesizing pH and temperature, reaction temperature, and total water volume of hydroxide suspensions on the magnetite formation were studied. And the basic reaction behaviors of magnetite formation was discussed in the view of hydroxide formation reaction of Fe(II) and Fe(III) by titration. The characteristics of products were examined by TEM, VSM, XRD. From these experimental data, solid-solid reaction between Fe(II) and Fe(III) hydroxides is proposed as a new ferrite formation mechanism.

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The Saw Damage Etching Characteristics of Silicon Wafer for Solar Cell with Alkaline Solutions (염기용액을 이용한 태양전지용 실리콘 기판의 절삭손상층 식각 특성)

  • Kwon, Soon-Woo;Yi, Jong-Heop;Yoon, Se-Wang;Kim, Dong-Hwan
    • New & Renewable Energy
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    • v.5 no.1
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    • pp.26-31
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    • 2009
  • The surface etching characteristics of single crystalline silicon wafer were investigated using potassium hydroxide (KOH) and tetramethylammonium hydroxide (TMAH). The saw damage layer was removed after 10min by KOH 45wt% solution at $80^{\circ}C$. The wafer etched at high temperature ($90^{\circ}C$) and in low concentration (4wt%) of TMAH solution showed an increased etch rate of silicon wafer and wavy patterns on the surface. Especially, pyramidal textures were formed in 4wt% TMAH solution without alcohol additives.

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