• Title/Summary/Keyword: hydroxide

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Coating of Cobalt Over Tungsten Carbide Powder by Wet Chemical Reduction Method

  • Hong, Hyun-Seon;Yoon, Jin-Ho
    • 한국분말재료학회지
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    • 제21권2호
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    • pp.93-96
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    • 2014
  • Cobalt coated tungsten carbide-cobalt composite powder has been prepared through wet chemical reduction method. The cobalt sulfate solution was converted to the cobalt chloride then the cobalt hydroxide. The tungsten carbide powders were added in to the cobalt hydroxide, the cobalt hydroxide was reduced and coated over tungsten carbide powder using hypo-phosphorous acid. Both the cobalt and the tungsten carbide phase peaks were evident in the tungsten carbide-cobalt composite powder by X-ray diffraction. The average particle size measured via scanning electron microscope, particle size analysis was around 380 nm and the thickness of coated cobalt was determined to be 30~40 nm by transmission electron microscopy.

질산철을 이용하여 표면개질된 활성탄의 황화수소 흡착 (Adsorption of Hydrogen Sulfide on Surface Modified Activated Carbon using Ferric Nitrate)

  • 정문주;이성우;김대근
    • 한국대기환경학회지
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    • 제31권2호
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    • pp.173-180
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    • 2015
  • The purpose of this study was to fabricate a ferric nitrate impregnated activated carbon, and the performance for hydrogen sulfide by adsorption was evaluated. Sodium hydroxide was utilized to control pH in the process during generation of ferric hydroxide on the surface of the carbon. Critical mixing duration for generation of ferric hydroxide on the carbon was 48 hrs at pH 1 of the solution, in which the chemical adsorption of hydrogen sulfide was enhanced. The adsorption capacity of the impregnated carbon increased up to 0.10 g hydrogen sulfide/g carbon, which was 4.3 times higher than that of the raw carbon. Presence of FeOOH on the surface of the impregnated carbon was examined by X-ray diffraction.

중금속 산폐수 처리 후의 상등액을 이용한 염색폐수처리 연구 (A Study on the Treatment of Dyeing Wastewater Using the Supernatant after Treatment of Acidic Metal Wastewater)

  • 신진명;박장진;김미자;주소영
    • 환경위생공학
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    • 제18권1호
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    • pp.41-50
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    • 2003
  • Traditionally the supernatant after chemical treatment of metal acid wastewater is discharged in environment. The supernatant can be used as a coagulant as it contains effective metals. The aim of this study is to investigate the feasibility of treatment of dyeing wastewater using the supernatant after treatment by magnesium hydroxide and dolomite($Ca{\cdot}Mg(CO_3)_2$), of acidic metal wastewater. In dyeing wastewater treatment with the supernatant, optimum pH and dosage were determined. COD, turbidity and color were analyzed to evaluate the performance of treatment. In the case of magnesium hydroxide, the optimum dosage was 10%(v/v) for supernatant A and 3%(v/v) for supernatant B. Color, turbidity and COD removal was 99~100%, 85~97% and 43~53%, respectively. In the case of dolomite, the optimum dosage was 10%(v/v) for supernatant A and 3% for supernatant B. Color, turbidity and COD removal was 96~99%, 62~9l% and 52~53%, respectively.

고로슬래그를 사용한 재생 잔골재 모르타르의 초기강도 특성에 관한 연구 (A Study on the Early-Age Strength Properties of Recycled Fine Aggregate Mortar Using Blast Furnace Slag)

  • 심종우;이세현;서치호
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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    • pp.101-104
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    • 2006
  • This study aims to obtain technical data for improvement of utilization of Blast Furnace Slag(BFS), recycled aggregate in the future by complementing fundamental problems of BFS such as manifestation of initial strength and excessive alkali quantity as well as weakness of recycled fine aggregate through manufacturing of recycled fine aggregate mortar using BFS. Since hydroxide ion concentration of calcium hydroxide(Ca(OH)2) ion erupted from recycled fine aggregate newly produced is over 12. In recycled fine aggregate mortar transposing and using BFS powder, calcium hydroxide(Ca(OH)2) erupted from recycled fine aggregate played a role of stimulus from the day 3 and manifestation of compressive strength was slowly increased with mortar using natural fine aggregate and showed considerable increase from the day 7.

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금속이중층수산화물의 메모리효과를 이용한 항균 천연소재의 담지 및 항균소재의 개발 (Incorporation of Antibacterial Natural Extract into Layered Double Hydroxide through Memory Effect for Antibacterial Materials)

  • 김형준;정도각;오제민
    • 세라미스트
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    • 제22권3호
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    • pp.301-315
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    • 2019
  • We prepared hybrids between layered double hydroxide (LDH) and natural plant extract such as Peaonia suffruticosa Andrews (PS) and Peaonia Japonica (PJ) which was confirmed anti-bacterial activity through paper disc diffusion assay. According to X-ray diffractometer, scanning electron microscope, zeta-potential measurement and quantification of extract loading amount in hybrids, we confirmed that similar amount of PS and PJ loaded on inter-particle pore of LDH with partial adsorption on surface of LDH through reconstruction process. We also evaluated the bacterial colony forming inhibition of PS extract, PJ extract, PS-LDH and PJ-LDH hybrids against Escherichia coli as gram negative bacterium and Bacillus subtilis as gram positive bacterium, suggesting that both hybrids have enhanced anti-bacterial activity compared with extract itself.

국산 고령토로 합성한 제올라이트 A의 이온교환성 (The Ion-Exchange Properties of Synthetic Zeolite A from Domestic Kaolin)

  • 김영대;김면섭
    • 한국세라믹학회지
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    • 제18권2호
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    • pp.91-98
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    • 1981
  • Synthetic zeolite A was prerared from domestic Hadong kaolin with sodium hydroxide solution and their ion exchange isotherms of $K^+$, $NH^{4+}$, $Li^+$ and $Ag^+$ ion were presented. The optimum reaction conditions for synthetic zeolite A from calcinated kaolin were 2 fold excess of 2N sodium hydroxide solution, 10$0^{\circ}C$ and 8 hours. It was observed that before the crystallization of zeolite A the samples reacted with sodium hydroxide solution had rather higher ion exchange capacities than zeolite A. The $K^+$-$Na^+$ and $Ag^+$$Na^+$ ion exchange isotherms were signoidal. The initial selectivity series was in the order $Ag^+$$K^+$>$Na^+$>$NH_4$>$Li^+$. Between approximately 33 and 67% replacement of soium ions the selectivity series became $Na^>$ and above 67% became $Ag^+$>$K^+$. Evidence were also presented to demonstrate that 8 out of 12 sodium ions per pseudo unit cell were not easily replaceable by lithium ions and 4 out of 12 not easily replaceable by ammonium ions.

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수산화물과 옥살산염의 열분해에 의한 $SnO_2$미분말의 합성 ($SnO_2$ Powder Preparation from Hydroxide and Oxalate and its Characterization)

  • 이종흔;박순자
    • 한국세라믹학회지
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    • 제27권2호
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    • pp.274-282
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    • 1990
  • SnO2 powder was prepared by hydroxide method and oxalate method. In hydroxide method, the pH dependence of powder characteristics was investigated by using buffer solution. As increasing the pH of solution, SnO2 powder size was decreased because nucleation rate was inctreased by more supersaturation of solution. Also, we found that the powder by our method has larger specific surface area in comaprison with other method. And the degree of agglomeration of precipitate with the change of precipitation temperature was investigated in oxalate method. The SnC2O4 was angular shape precipitate, and the size of the SnC2O4 was increased with the increase of precipitation temperature in methanol solvent.

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$A\;\ell\;(OH)_3$를 첨가(添加)한 PVC의 내(耐)Tracking성(性)과 열분석(熱分析)에 관한 연구(硏究) (A Study on Thermegravimetry and Tracking Resistance of PVC Doped with $A\;\ell\;(OH)_3$)

  • 강성화;임기조;신용덕;박대희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1995년도 추계학술대회 논문집 학회본부
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    • pp.389-391
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    • 1995
  • Using as an alternate of insulating material for outdoor and cable, however, it has still many problems to be solved in the field of material such as resistances of environment and tracking. In this paper, Tracking property of PVC filled with aluminum hydroxide have been investigated by ASTM D 2303 method. It was found that time to track of PVC filled aluminum hydroxide was longer than that of unfilled PVC. Tensile strength and elongation of PVC were decreases increased with aluminum hydroxide contents. On the other hand, Thermegravimetry of PVC decreased. Therefore, the increase of time to tracking breakdown by antitracking additive can be explained by increased degradation temperature of polymer.

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Chemical characteristics of mineral trioxide aggregate and its hydration reaction

  • Chang, Seok-Woo
    • Restorative Dentistry and Endodontics
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    • 제37권4호
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    • pp.188-193
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    • 2012
  • Mineral trioxide aggregate (MTA) was developed in early 1990s and has been successfully used for root perforation repair, root end filling, and one-visit apexification. MTA is composed mainly of tricalcium silicate and dicalcium silicate. When MTA is hydrated, calcium silicate hydrate (CSH) and calcium hydroxide is formed. Formed calcium hydroxide interacts with the phosphate ion in body fluid and form amorphous calcium phosphate (ACP) which finally transforms into calcium deficient hydroxyapatite (CDHA). These mineral precipitate were reported to form the MTA-dentin interfacial layer which enhances the sealing ability of MTA. Clinically, the use of zinc oxide euginol (ZOE) based materials may retard the setting of MTA. Also, the use of acids or contact with excessive blood should be avoided before complete set of MTA, because these conditions could adversely affect the hydration reaction of MTA. Further studies on the chemical nature of MTA hydration reaction are needed.

Effects of Calcium Hydroxide as an Intracanal Medicine on Sealers.

  • Hosoya, N.;Takahashi, G.;Kurayama, H.;Tahata, K.;Arai, T.
    • 대한치과보존학회:학술대회논문집
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    • 대한치과보존학회 2001년도 추계학술대회(제116회) 및 13회 Workshop 제3회 한ㆍ일 치과보존학회 공동학술대회 초록집
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    • pp.565.2-565
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    • 2001
  • Calcium hydroxide is unavoidably left on the root canal wall when used as an intracanal medicament, and is assumed to have some undesirable influence on the canal sealers. The purpose of this study was to determine whether the $Ca(OH)_2$ change physical properties (Exp. I) and sealing ability (Exp. II) of root canal sealers. Exp. I: As calcium hydroxide agents, $Calcipex^{\circledR}, {\;}Vitapex^{\circledR}, {\;}Calxyl^{\circledR}, {\;}and{\;}Ca(OH)_2$ were used.(omitted)

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