• Geophysics and Geophysical Exploration
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• v.12 no.1
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• pp.1-7
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• 2009

Airborne electromagnetics (AEM) is a useful tool for investigating volcanic structures because it can survey large and inaccessible areas. Disadvantages include lower accuracy and limited depth of investigation. The Grounded Electrical Source Airborne Transient Electromagnetic(GREATEM)survey system was developed to increase the depth of investigation possible using AEM. The method was tested in a survey at Mount Bandai in north-eastern Japan. Mount Bandai is an andesitic stratovolcano that rises 1819m above sea level. An eruption in July 1888 left a hoof-shaped collapsed wall in its northern crater and avalanche debris at its base. Previous surveys of Mount Bandai allow for comparisons of data on its structure and collapse mechanism as obtained by GREATEM and other geophysical methods. The results show resistive structures in recent volcanic cones and conductive structures in the collapsed-crater area. Conductive areas around the collapsed wall correspond to an alteration zone resulting from hydrothermal activity, supporting the contention that a major cause of the collapse associated with the 1888 eruption was hydrothermal alteration that structurally weakened the interior of the volcanic edifice.

• Economic and Environmental Geology
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• v.48 no.4
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• pp.325-335
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• 2015

This study examined the possibility to extract potential alteration zones and lithologic information based on ASTER band ratio techniques for mineralized area located in ${\ddot{O}}v{\ddot{o}}rkhangai$ province, Mongolia, and the effectiveness of remote sensing as a preliminary exploration tool for mineral exploration was tested. The results of ABRLO, PBRLO, and PrBRLO models indicated that the detection of argillic zone requires the verification of the samples to verify hydrothermal alteration minerals as clay minerals can formed by weathering process, whereas phyllic-propylitic zones were considerably related to the spatial distribution of the intrusive bodies, geological structures, and ore distribution. QI and MI results showed that QI is more useful for sedimentary rocks such as conglomerate and sandstone than meta-sedimentary like quartzite, and MI faced relatively uncertain in detection of felsic or mafic silicate rocks. QI and MI may require additional geologic information such as the characteristics of samples and geological survey data to improve extraction of lithologic information, and, if so, it is expected that remote sensing technique would contribute significantly as a preliminary geological survey method.

• Korean Journal of Mineralogy and Petrology
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• v.34 no.2
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• pp.147-156
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• 2021

We report fluid inclusion study results of copper-bearing quartz veins in Zogdor area, which is located within the Gurvansayhan island arc terrane of Southern Mongolia. At the Zogdor area, structurecontrolled copper mineralization is hosted in granodiorite-porphyry, which emplaced in the late Cretaceous formation. Within this granodiorite porphyry, copper-bearing quartz veins are associated with the hydrothermal alteration that includes quartz-epidote-magnetite, and quartz-magnetite in the propylitic zones. The veins are classified into two types, according to their mineral composition, which occur mainly as chalcopyrite, rare amounts of bornite, magnetite, and pyrite. Fluid inclusions in the quartz veins from the quartz-magnetite±chalcopyrite and quartz-epidote-magnetite veins are two-phase aqueous inclusions having bubble sizes of 5-30 vol.%, evident salinities of 2.0-22.6 wt.% NaCl, and homogenization temperatures of 107-270℃. Based on mineral assemblages of the observed veins, along with the geochemical properties and alteration faces of the host rock, fluid inclusion data show that the study area corresponds to propylitic alteration zone in the porphyry Cu related mineralization.

• Geophysics and Geophysical Exploration
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• v.11 no.3
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• pp.250-262
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• 2008

In order to assess the feasibility of the dipole-dipole electric method to the investigation of metallic ore deposit, both field data simulation and inversion are carried out for several simplified ore deposit models. Our interest is in a vein-type model, because most of the ore deposits (more than 70%) exist in a vein type in Korea. Based on the fact that the width of the vein-type ore deposits ranges from tens of centimeters to 2m, we change the width and the material property of the vein, and we use 40m-electrode spacing for our test. For the vein-type model with too small width, the low resistivity zone is not detected, even though the resistivity of the vein amounts to 1/300 of that of the surrounding rock. Considering a wide electrode interval and cell size used in the inversion, it is natural that the size of the low resistivity zone is overestimated. We also perform field data simulation and inversion for a vein-type model with surrounding hydrothermal alteration zones, which is a typical structure in an epithermal ore deposits. In the model, the material properties are assumed on the basis of resistivity values directly observed in a mine originated from an epithermal ore deposits. From this simulation, we can also note that the high resistivity value of the vein does not affect the results when the width of the vein is narrow. This indicates that our main target should be surrounding hydrothermal alteration zones rather than veins in field survey. From these results, we can summarize that when the vein is placed at the deep part and the difference of resistivity values between the vein and the surrounding rock is not large enough, we cannot detect low resistivity zone and interpret the subsurface structures incorrectly using the electric method performed at the surface. Although this work is a little simple, it can be used as references for field survey design and field data Interpretation. If we perform field data simulation and inversion for a number of models and provide some references, they will be helpful in real field survey and interpretation.

• Economic and Environmental Geology
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• v.26 no.1
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• pp.11-20
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• 1993

In the present study, three representative hydrothermal clay deposits, named the Seongsan, Ogmaesan and Haenam deposits, were selected for oxygen and hydrogen isotope studies. Oxygen and hydrogen isotopic compositions of quartz, sericite, alunite and kaolin minerals from Seongsan, Ogmaesan, Haenam deposits and surrounded rocks of clay deposits have been measured. The ${\delta}^{18}O$ values of quartz, kaolin, sericite and alunite in the Seongsan mine are +8.4 to +11.1‰, +3.6 to 5.4‰, +4.8 to +5.8‰ and + 3.0 to +6.6‰, respectively. In the Ogmaesan mine, the ${\delta}^{18}O$ values of quartz, kaolin, sericite and alunite are +8.0 to +13.6‰, +2.8 to +6.7‰, +4.8 to +8.4‰ and +0.9 to +2.4‰, respectively. The ${\delta}^{18}O$ values of the Haenam mine range from +7.9 to +10.1‰ for quartz and from +4.5 to +6.5‰ for sericite. The ${\delta}^{18}O$ values of the whole-rocks range from + 3.0 to + 7.8‰ for the granitic rocks. The ${\delta}^{18}O$ values of the whole-rocks range from + 3.2 to + 10.7‰ for the volcanic rocks. The 8D values of kaolin, sericite and alunite in the Seongsan mine are -78 to -86‰, -71 to -90‰ and -43 to -77‰, respectively. In the Ogmaesan mine, the ${\delta}D$ values of kaolin, sericite and alunite are -73 to -80‰, -74 to -88‰ and -57 to -98‰, respectively. The ${\delta}D$ values of the Haenam mine range from -76 to -85‰ for sericite. The ${\delta}D$ values of the whole-rocks range from -77 to -105‰ for the granitic rocks. The ${\delta}D$ values of the wholerocks range from -76 to -100‰ for the volcanic rocks. The main result obtained oxygen and hydrogen isotope data can lead to the following interpretations on the origin of hydrothermal fluids in the clay deposits: Through the oxygen isotopic study, the formation temperature of the clay deposits was estimated from the coexisting minerals such as quartz-kaolin minerals and -sericite. Formation temperature of the acidic alteration zone is 165 to $280^{\circ}C$ in the Seongsan deposits, 175 to $250^{\circ}C$ in the Ogmaesan deposits and 250 to $350^{\circ}C$ in the Haenam deposits. Three clay deposits has been formed by magmatic water mixed with meteoric water. Furthermore, from this isotopic data, it is clarified that kaolin minerals and alunite are hypogene in origin, and has been formed by oxidation of hydrogen sulfide in the steam-heated environment, and that alunite has been produced in the spectacular solfataric alteration observed at the surface of some present-day hydrothermal systems. Oxidation of the $H_2S$ is thought to be generated when the vapor phase generated by boiling of the deep-seated water under the water table.

• Korean Journal of Mineralogy and Petrology
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• v.35 no.2
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• pp.83-100
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• 2022

The Zhenzigou Pb-Zn deposit, which is one of the largest Pb-Zn deposit in the northeast of China, is located at the Qingchengzi mineral field in Jiao Liao Ji belt. The geology of this deposit consists of Archean granulite, Paleoproterozoinc migmatitic granite, Paleo-Mesoproterozoic sodic granite, Paleoproterozoic Liaohe group, Mesozoic diorite and Mesozoic monzoritic granite. The Zhenzigou deposit which is a strata bound SEDEX or SEDEX type deposit occurs as layer ore and vein ore in Langzishan formation and Dashiqiao formation of the Paleoproterozoic Liaohe group. White mica from this deposit are occured only in layer ore and are classified four type (Type I : weak alteration (clastic dolomitic marble), Type II : strong alteration (dolomitic clastic rock), Type III : layer ore (dolomitic clastic rock), Type IV : layer ore (clastic dolomitic marble)). Type I white mica in weak alteration zone is associated with dolomite that is formed by dolomitization of hydrothermal metasomatism. Type II white mica in strong alteration zone is associated with dolomite, ankerite, quartz and alteration of K-feldspar by hydrothermal metasomatism. Type III white mica in layer ore is associated with dolomite, ankerite, calcite, quartz and alteration of K-feldspar by hydrothermal metasomatism. And type IV white mica in layer ore is associated with dolomite, quartz and alteration of K-feldspar by hydrothermal metasomatism. The structural formulars of white micas are determined to be (K_0.92-0.80Na_0.01-0.00Ca_0.02-0.01Ba_0.00Sr_0.01-0.00)_0.95-0.83(Al_1.72-1.57Mg_0.33-0.20Fe_0.01-0.00Mn_0.00Ti_0.02-0.00Cr_0.01-0.00V_0.00Sb_0.02-0.00Ni_0.00Co_0.02-0.00)_1.99-1.90(Si_3.40-3.29Al_0.71-0.60)_4.00O₁₀(OH_2.00-1.83F_0.17-0.00)_2.00, (K_1.03-0.84Na_0.03-0.00Ca_0.08-0.00Ba_0.00Sr_0.01-0.00)_1.08-0.85(Al_1.85-1.65Mg_0.20-0.06Fe_0.10-0.03Mn_0.00Ti_0.05-0.00Cr_0.03-0.00V_0.01-0.00Sb_0.02-0.00Ni_0.00Co_0.03-0.00)_1.99-1.93(Si_3.28-2.99Al_1.01-0.72)_4.00O₁₀(OH_1.96-1.90F_0.10-0.04)_2.00, (K_1.06-0.90Na_0.01-0.00Ca_0.01-0.00Ba_0.00Sr_0.02-0.01)_1.10-0.93(Al_1.93-1.64Mg_0.19-0.00Fe_0.12-0.01Mn_0.00Ti_0.01-0.00Cr_0.01-0.00V_0.00Sb_0.00Ni_0.00Co_0.05-0.01)_2.01-1.94(Si_3.32-2.96Al_1.04-0.68)_4.00O₁₀(OH_2.00-1.91F_0.09-0.00)_2.00 and (K_0.91-0.83Na_0.02-0.01Ca_0.02-0.00Ba_0.01-0.00Sr_0.00)_0.93-0.83(Al_1.84-1.67Mg_0.15-0.08Fe_0.07-0.02Mn_0.00Ti_0.04-0.00Cr_0.06-0.00V_0.02-0.00Sb_0.02-0.01Ni_0.00Co_0.00)_2.00-1.92(Si_3.27-3.16Al_0.84-0.73)_4.00O₁₀(OH_1.97-1.88F_0.12-0.03)_2.00, respectively. It indicated that white mica of from the Zhenzigou deposit has less K, Na and Ca, and more Si than theoretical dioctahedral mica. Compositional variations in white mica from the Zhenzigou deposit are caused by phengitic or Tschermark substitution [(Al³⁺)^VI+(Al³⁺)^IV <-> (Fe²⁺ or Mg²⁺)^VI+(Si⁴⁺)^IV] substitution. It means that the Fe in white mica exists as Fe²⁺ and Fe³⁺, but mainly as Fe²⁺. Therefore, white mica from layer ore of the Zhenzigou deposit was formed in the process of remelting and re-precipitation of pre-existed minerals by hydrothermal metasomatism origined metamorphism (greenschist facies) associated with Paleoproterozoic intrusion. And compositional variations in white mica from the Zhenzigou deposit are caused by phengitic or Tschermark substitution [(Al³⁺)^VI+(Al³⁺)^IV <-> (Fe²⁺ or Mg²⁺)^VI+(Si⁴⁺)^IV] substitution during hydrothermal metasomatism depending on wallrock type, alteration degree and ore/gangue mineral occurrence frequency.

• Economic and Environmental Geology
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• v.29 no.4
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• pp.455-470
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• 1996

Mesozoic granitic rocks in the Korean peninsula contain $H_2$, $CH_4$, CO and rare $C_2H_6$. The Jurassic Daebo granites mostly belonging to the ilmenite series are predominated in $CH_4$. Meanwhile, the magnetite series Bulguksa granites of Cretaceous age in the Kyongsang basin and Okchon zone are relatively enriched in $CO_2$. The older granites have a wide variation of $CH_4/CO_2$ ratios (0.1~1.0) compared to those of the younger ones (0.1~0.5). This characteristics of gas compositions suggest that the Jurassic granites are principally derived from the partial melting of metasedimentary rocks with much reducing materials in the lower continental crust. On the other hand, the mantle source granitic magmas might be responsible for the Cretaceous granites characterized by dominant and homogeneous $CO_2$ gas compositions. Liquid-vapor homogenization temperatures of quartz in the Jurassic and Cretaceous granites range from 108 to $539^{\circ}C$ (av. $324^{\circ}C$) and 160 to $556^{\circ}C$ (av. $358^{\circ}C$), respectively. Their salinities are between 0.2 and 16.3 wt.% NaCl for the Jurassic granites and 0.4, and 15.6 wt.% NaCl for the Cretaceous ones. Fluid inclusions with solid daughter minerals lying on or near the halite equilibrium curve represent inclusion fluids from the magmatic stage. The type I and II fluid inclusions which are plotted apart from the equilibrium curve are considered to trap in late hydrothermal alteration stage with a increasing influx of metedric water.

• Economic and Environmental Geology
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• v.43 no.5
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• pp.443-453
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• 2010

The Samsung gold-silver deposit consists of quartz veins that fill along the fault zone within Cretaceous shale and sandstone. Mineralization is occurred within fault-breccia zones and can be divided into two stages. Stage I is main ore mineralization and stage II is barren. Stage I is associated with wall-rock alteration minerals(sericite, pyrite, chlorite, quartz), rutile, base-metal sulfides(pyrrhotite, pyrite, sphalerite, chalcopyrite, galena), and electrum. Stage II occur quartz, calcite and pyrite. Fluid inclusion data indicate that homogenization temperatures and salinities of stage I range from 145 to $309^{\circ}C$ and from 0.4 to 12.4 wt.% NaCl, respectively. It suggests that hydrothermal fluids were cooled and diluted with the mixing of meteoric water. The main deposition of base-metal sulfides and electrum occurred as a result of cooling and dilution at temperature between $200^{\circ}C$ and $300^{\circ}C$. Sulfur(9.3~10.8‰) isotope composition indicates that ore sulfur was mainly derived from a magmatic source as well as the host rocks. The calculated oxygen[-2.3~0.9‰(quartz: 0.3‰, 0.9‰, calcite: -2.3‰)] and hydrogen[-86~-76‰(quartz: -86‰, -82‰, calcite: -76‰)] isotope compositions indicate that hydrothermal fluids may be meteoric origin with some degree of mixing of another meteoric water for paragenetic time.

• Economic and Environmental Geology
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• v.42 no.6
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• pp.513-525
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• 2009

The Buyeong gold-silver deposit consists of quartz veins that fill along the NS fault zone within Cretaceous Goseong formation. Mineralization can be divided into hypogene and supergene stages. Hypogene stage is associated with hydrothermal alteration minerals such as sericite, pyrite, chlorite, epidote and sulfides such as pyrite, pyrrhotite, marcasite, sphalerite, chalcopyrite, galena and galenobismutite. Supergene stage is composed of malachite, goethite, chalcocite, and sphalerite oxide. Fluid inclusion data indicate that homogenization temperatures and salinities range from 112 to $340^{\circ}C$ and from 0.2 to 7.9 wt.% NaCl, respectively. Sulfur(3.2~3.9‰) isotope composition indicates that ore sulfur was derived from mainly magmatic source as well as partly host rocks. The calculated oxygen(4.3~6.0‰) and hydrogen(-60~-64‰) isotope compositions indicate that hydrothermal fluids may be meteoric origin with some degree of mixing of another meteoric water for paragenetic time.

• Economic and Environmental Geology
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• v.39 no.5 s.180
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• pp.583-595
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• 2006

Quartz veins from the Hwawon area are an epithermal quartz vein that is filling the fault zone within Precambrian metasedimentary rocks and Jurassic granite. Mineralization can be divided into hypogene and supergene stages. Hypogene stage is associated with hydrothermal alteration minerals(propylitic and argillic zones) such as epidote, chlorite, illite, sericite and sulfides such as pyrite, sphalerite, chalcopyrite, galena, bornite, cubanite, argentian tetrahedrite, Pb-Ag-S system and Pb-Te-S system. Supergene stage is composed of Fe-Mn oxide, Zn-Fe oxide and Pb oxide. Fluid inclusion data indicate that homogenization temperatures and salinity of hypogene stage range from $291.2^{\circ}C$ to $397.3^{\circ}C$ and from 0.0 to 9.3 wt.% eq. NaCl, respectively. It suggests that ore forming fluids were cooled and diluted with the mixing of meteoric water. Oxygen($-0.7{\sim}3.5%_{\circ}$(white quartz: $-0.7{\sim}3.5%_{\circ}$, transparent quartz: $2.4%_{\circ}$)) and hydrogen($-70{\sim}55%_{\circ}$(white quartz: $-70{\sim}55%_{\circ}$, transparent quartz: $-62%_{\circ}$)) isotopic composition indicates that hydrothermal fluids were derived from magmatic and evolved by mixing with meteoric water during mineralization.