• Journal of Environmental Science International
• /
• v.3 no.1
• /
• pp.57-64
• /
• 1994

On the basis of the principle of Bratch's electronegativity equalization, we calculated group partial charges and group electronegativities for nonionic surfactants with Pauling's elecoonegativity parameters by using numerical calculation method. From calculated outputs we have investigated structural stability of micelle, characteristics of hydrophilic and hydrophobic groups, and relation between CMC(Critical Micelle Concentraion) and group partial charge and group electronegativity of hydrophilic and hydrophobic groups for nonionic surfactants. We have known that CMC by micelle formation depends upon group partial charge and group electronegativity of hydrophilic and hydrophobic groups for surfactants. Also, the structural stability of micelle in H2O solution is related to the electric double layer by the hydrophilic group of nonionic surfactants with H atoms in water CMC is diminished by the decrease of repeating units in hydrophilic group at constant hydrophobic group and is diminished by the increments of alkyl chains in hydrophobic group at constant hydrophilic group for nonionic surfactants. In conclusion, CMC is diminished because there is no electrostatic repulsion and is diminished of Debye length by the increments of partial charge of hydrophobic group.

• Applied Chemistry for Engineering
• /
• v.8 no.6
• /
• pp.914-919
• /
• 1997

On the basis of theory of Bratsch's electronegativity equalization, the electronegativity equalization, the group electronegativities and the group partial charges for anionic and nonionic surfactants could be calculated by using Pauling's electronegativity parameters. From calculated results, we have investigated how CMC, hydrophilic and hydrophobic groups, group partial charge, electronegativity of hydrophilic and hydrophobic groups, structural stability of micelle for anionic and nonionic surfactants are related. It was fround that CMC depends upon group partial charge and group electronegativity of hydrophilic and hydrophobic groups of surfactants. For the anionic surfactants, negative partial charge in hydrophobic group is delocalized as the carbon number in hydrophobic group increase. So negative partial charge of hydrophilic group has very large electronegativity that is decreased. And CMC decreases as hydration ability of hydrophilic groups which decreases relatively. For the nonionic surfactant, partial charge and electronegativity in hydrophobic group increases with the increment of carbon number in hydrophobic group. And CMC decreases because electronegativity of hydrophilic group is decreased with the increment of electronegativity of hydrophilic group. However, with the increase of repeating units in hydrophilic group, the negative partial charge of hydrophilic group increases. So CMC increases because surfactants hydrate rather than form micelles in aqueous solution by the increase of hydration ability.

• Journal of Environmental Science International
• /
• v.9 no.5
• /
• pp.403-408
• /
• 2000

On the basis of theory of Bratsch's electronegativity equalization the electronegativity equalization the group electronegativities and the group partial charges for cationic and amphoteric surface and amphoteric surfactants could be calculated using Pauling's electronegativity parameters. From calculated output we have investigated relationships between CMC(critical micelle concentration) and partial charge and group electronegativity of hydrophilic and hydrophobic groups structural stability of micelle for cationic and amphoteric surfactants. As a result CMC depends upon partial charge and electronegativity of hydrophilic group is decreased. With increasing the carbon number of hydrophilic group for cationic surfactant its partial charge is increased but CMC and its electronegativity are decreased. With increasing the carbon number of hydrophobic group for cationic and amphoteric surfactant its partial charge is increased but CMC andits electronegativity are decreased.

• Korean Journal of Chemical Engineering
• /
• v.35 no.11
• /
• pp.2256-2268
• /
• 2018

Hydrophilic and hydrophobic polyethersulfone (PES)-zinc oxide (ZnO) sublayers were prepared by loading of ZnO nanoparticles into PES matrix. Both porosity and hydrophilicity of the hydrophilic sublayer were increased upon addition of hydrophilic ZnO, while these were decreased for the hydrophobic sublayer. In addition, the results demonstrated that the hydrophilic membrane exhibited smaller structural parameter (S value or S parameter or S), which is beneficial for improving pure water permeability and decreasing mass transfer resistance. In contrast, a higher S parameter was obtained for the hydrophobic membrane. With a 2 M NaCl as DS and DI water as FS, the pure water flux of hydrophilic TFN0.5 membrane was increased from $21.02L/m^2h$ to $30.06L/m^2h$ and decreased for hydrophobic TFN0.5 membrane to $14.98L/m^2h$, while the salt flux of hydrophilic membrane increased from $10.12g/m^2h$ to $17.31g/m^2h$ and decreased for hydrophobic TFN0.5 membrane to $3.12g/m^2h$. The increment in pure water permeability can be ascribed to reduction in S parameter, which resulted in reduced internal concentration polarization (ICP). The current study provides a feasible and low cost procedure to decrease the ICP in FO processes.

• Textile Coloration and Finishing
• /
• v.13 no.3
• /
• pp.172-179
• /
• 2001

In order to improve dye uptime and wash fastness on dyeing of cotton fabrics with Amur cork tree, twitter ionic groups, acid groups, hydrophobic groups or cross linkage were introduced into cotton fabrics. Results obtained were as follows, 1 The optimum modification of cotton fabrics was carbosy methylation in the water solution containing 15% sodium chloroacetate and 15% sodium hydroxide and then introducing hydrophobic groups by treating in the solution containing $30m\ell$ DMSO and $3m\ell$ 2,4-TDI 2. Numbers of carbon, diisocyanate group than monoisocyanate group and aromatic compound than aliphatic compound in introduced hydrophobic groups were effective. 3. The dye uptake and wash fastness wore enhanced significantly by treating only with 2,4-TDI. 4. The wash fastness seems to correlate to the degree of swelling of the fabric during washing and also depend on the Interaction between dyes and acid groups as well as hydrophobic groups.

• Journal of Environmental Science International
• /
• v.1 no.2
• /
• pp.93.1-104
• /
• 1992

Because of varied functions and characteristics, water soluble polymers have lone attracted much intrest in both academic and industrial fields, especially now in pollution problems such as wastewater treatment through ployrneric flocculants. In this regard, the main objective of this study is to synthesize polymeric floccuants containning hydrophobic group in presence of the potassium persulfate/sodium thiosulfate redox system and to estimate their flocculating ability on the kaolin suspension. In order to test the flocculating power of flocculant prepared on the kaolin suspension system, turbidity of the supernatant liquid, residence time, filtration rate of flocculated samples, have additionally been measured from the flocculation experiments and analysed In comparision with the theoretical background.

• Proceedings of the Korean Society of Applied Pharmacology
• /
• 1994.04a
• /
• pp.182-182
• /
• 1994

Angiotensin converting enzyme (ACE)을 비가역적으로 불활성화시킴으로써 오랫동안 작용할 수 있는 고혈압치료제로서의 ACE억제제를 개발하기 위하여pseudomechanism-based inhibition이라는 새로운 억제기전을 가질 것으로 추정되는 아래 그림과 같은 기본 분자구조를 갖는 epoxide 유도체들을 합성하여 in vitro에서 ACE활성 억제효과를, HPLC법을 이용하여 측정하였다. 그 결과 합성되어진 epoxide 유도체들은, epoxide group대신에 sulfhydryl 또는 carboxyl group으로 치환되어져 있는 기존의 ACE 억제제들보다도 효능이 현저히 저하됨으로써, ACE의 $Zn^{2+}$ binding site와는 배위결합력이 미약하다는 것을 의미하여 준다. 또한 유도체들의 phenylring에 chloride, hydroxyl, nitro group과 같은 polar group 의 도입으로 말미암아 ACE 억제효과가 저하됨으로써 이 부위에서의 hydrophobic interaction이 ACE를 억제하는데 중요하다는 것을 시사해 주며 이외에도 이미 알려진 바와같이 carbonyl carbon과 인접한 carbon atom에 methyl group의 도입이 억제효과에 중요한 역활을 하였다. 따라서 향후에는 ACE의 $Zn^{2+}$ binding site와 강력한 배위결합을 하는 carboxyl group을 도입하고 epoxide의 위치를 변경시키며 또한 hydrophobic interaction하는 부위의 구조를 변화시켜 보다 효능이 우수한 새로운 기전의 ACE억제제를 개발해 나가고자 한다.

• Journal of the Korean Society for Precision Engineering
• /
• v.29 no.1
• /
• pp.13-18
• /
• 2012

In this study, silicone injection molding technology with curved thermoplastic insert was developed to produce super-hydrophobic surface. Thermoplastic insert part and injection mold design of base plastic cover were performed to produce cost effective hydrophobic surface part. An optimization process of part thickness for thermoplastic insert part was performed with transient thermal analysis under silicone over-molding process condition. Structural thermal analysis of silicone injection mold was also performed to obtain uniform temperature condition on the surface of micro-patterned mold core. Super-hydrophobic surface for the silicone injection molded part with thermoplastic insert could be verified from the measurement of contact angle. It was shown that the averaged contact angle was over $140^{\circ}$.

• Korean Journal of Food Science and Technology
• /
• v.19 no.2
• /
• pp.89-96
• /
• 1987

The denaturation mechanism of the protein during heating of myosin and paramyosin extracted from the ordinary muscle of yellowtail (Seriola qrinqueradits) and the adductor muscle of whelk (Neptunea arthritica cuming) were investigated by analyzing the hydrophobicity, solubility, SH group and protein-protein interaction. The free hydrophobic residue of the two proteins were increased by increase of heating temperature up to $65^{\circ}C$ and then decreased for further temperature raise. The protein-protein interaction was proportional to the increment of the free hydrophobic residue. The aggregation of protein was begun from $65^{\circ}C$ with the decrease of the free hydrophobic residues. The results of Arrhenius equation for the data on proteinprotein interaction showed that the denaturation course was made up with multi-steps in the myosin and two-steps in the paramyosin. The number of free hydrophobic residue and SH group, solubility and protein-protein interaction were significantly differed with the denaturation temperature (p<0.01).

• Proceedings of the Polymer Society of Korea Conference
• /
• 2006.10a
• /
• pp.266-266
• /
• 2006

The cell spheroid (multicellular mass) is enhanced cell functions because of the cell-cell interaction compared with the individual cell. The objective of this study is synthesis, characterization and evaluation of novel crosslinkers to form spheroid in a short time. Our approach to bridge cells is based on the crosslinking of the cell membrane via the hydrophobic interaction. The crosslinker was prepared by the reaction between ethylenediamine and poly(ethylene glycol) (PEG) derivative with oleyl group as hydrophobic group at the terminal group. The product was characterized with gel permeation chromatography (GPC) and FT-IR. Furthermore, cell culture experiment was also performed to confirm spheroid formation. The function of prepared spheroids was evaluated.