• 한국지하수토양환경학회지:지하수토양환경
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• 제11권5호
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• pp.35-42
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• 2006

본 논문에서는 황화철($FeS,\;FeS_{2}$) 유기 용매의 환원적 분해 반응과의 표면특성의 관계에 대해서 다음과 같은 결과를 얻었다. hexachloroethane(HCA)은 수소첨가반응, 탈염소제거반응과 탈수소탈염소화반응으로 pentachloroethane(PCA), tetrachloroethylene(PCE), trichloroethylene(TCE)와 cis-1,2-dichloroethylene(cis-1,2-DCE)로 분해되었다. FeS와 $FeS_{2}$를 반응 매개물로 HCA에 대한 반응에서 FeS는 $FeS_{2}$보다 분해반응 속도가 빠르게 나타났다. FeS와 $FeS_{2}$의 표면 특성 연구에서 각 광물질에 대한 친수성 표면 자리(Ns)를 정량적으로 계산하기 위해서 비표면적 값($107.0470m^{2}/g$와 $92.6374m^{2}/g$)과 표면 전위를 측정에 측정된 $PH_{ZPC}(FeS,\;PH_{ZPC}=7.42,\;FeS_{2},\;PH_{ZPC}=7.80)$ 값을 이용해서 계산한 결과 FeS와 $FeS_{2}$의 $N_{s}$값은 각각 $0.053\;site/nm^{2},\;0.205\;site/nm^{2}$으로 나타났다. 그리고 0.2 g/L Fe광물질에 대한 실질적인 친수성 표면 농도는 각각 $3.303{\times}10^{-6}\;mol/L$와 $1.102{\times}10^{-5}\;mol/L$ 나타났다. $FeS_{2}$는 FeS에 비해 훨씬 친수성 표면임을 실험 결과 확인하였다. FeS와 $FeS_{2}$의 두 광물질 중에서 유기 용매의 환원 반응 속도는 FeS가 훨씬 빠르게 나타났다.

• 한국수자원학회논문집
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• 제41권10호
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• pp.983-993
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• 2008

근래에 이상기상과 지구 온난화로 인한 해수면 상승과 해사채취, 난개발에 의해 국내외 연안역에 여러 형태의 침식피해가 발생되고 있다. 이에 대한 침식방지 및 보호대책 공법이 적용되고 있으나 큰 실효를 거두지 못하고 있다. 연안보호 구조물로 PC 콘크리트 호안블럭이 국내외 연안에 시공되고 있으나 대부분의 기존 구조물들은 사람의 접근성이 어려운 구조물로 시공되어 있어 친수성이 부족한 실정이다. 본 연구에서는 이런 점들을 보완하여 사람들의 접근성이 좋으면서 연안침식 방지 보호 능력이 우수한 친수성 호안공을 개발하고자 한다. 개발한 호안공의 성능과 기능의 확보를 위해 모형실험이 반사율, 파량, 월파고에 대해 수행되었다. 그 결과는 일반 계단형 보다 훨씬 좋은 결과를 나타냈다. 또한 호안공의 실용화를 위해 현장실험은 노출부 일단면의 식생실험과 해안역의 침식구간에 시공실험을 실시하였다. 후자의 경우는 실험구간에서 많은 양의 모래가 짧은 시간에 퇴적되어 연안침식 방지 및 보호용 친수 호안공으로서의 현장 적용성을 확인하였다.

• 방사선산업학회지
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• 제8권1호
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• pp.53-57
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• 2014

The kenaf is quickly developing as a renewable resource. Kenaf can be grown under a wide range of weather conditions. Modification of kenaf fiber by graft polymerization provides a significant route to alter the chemical properties, including surface hydrophilicity or hydrophobicity. In this study, kenaf fiber surfaces were grafted with acrylic acid as a hydrophilic group using electron beam irradiation. The grafting rate increased with an increase in grafting time. The FT-IR results confirmed that acrylic acid was successfully grafted onto the kenaf fibers. The wettability of the kenaf fiber was increased, accompanied by acylic acid grafting on the fiber surface. According to the permeability test result, it was found that acrylic acid grafted kenaf fiber reinforced cement composite was more reduced than non-grafted kenaf fiber reinforced cement composite.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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• pp.51-52
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• 2003

In order to understand the buffering behavior of hygroscopic fabric under subzero conditions, microclimates of the wool and PET clothing system were measured and compared. Vertical type Man-Clothing-Environment simulator was used to measure the microclimate at the environmental temperature of -10$^{\circ}C$. Buffering capacity was quantified by calculating from the depth and width of the hyperbolic curve of the graph. Hydrophilic wool fabrics showed better buffering capacity at the transient state than hydrophobic PET fabrics; which is attributed to the heat of sorption.

• 한국지하수토양환경학회지:지하수토양환경
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• 제23권4호
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• pp.42-47
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• 2018

E. coli TG1 pBS TOM Green was cultured to produce toluene-o-monooxygenase (TOM). A biosensor system was successfully constructed using purified TOM to effectively detect trichloroethene (TCE) and tetrachloroethene (PCE), which represent some of the major contaminants in groundwater and soil. In order to utilize TOM as a sensor, NADH, a biological oxidizer, was replaced with hydrogen peroxide which is a chemical oxidizing agent. A three-layered sandwich-type sensing tip was fabricated on the outside of the hydrophilic polyvinylidene fluoride membrane. TCE and PCE were applied to the sensor and the hydrogen ions were measured by a fiber optic fluorometer using fluoresceinamine. Calibration curves were obtained for TCE and PCE in the concentration range of 0.2-100 mg/l, and the detection limit of the system was $10{\mu}g/l$ for TCE and PCE.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2001년도 총회 및 춘계학술발표회
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• pp.15-18
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• 2001

Sorption/desorption studies were conducted to determine sorption/desorption characteristics of phenolic compounds (phenol and 4-chlorophenol) in organically modified natural bentonite. The cationic exchange capacity (CEC) of bentonite was exchanged with a cationic surfactant, hexadecyltrimethylammonium (HDTMA), to enhance the removal capacity of organic phenol contaminants dissolved in aqueous solution. This modification produces a change of the surface property of bentonite from hydrophilic to organophilic. The single-solute and bi-solute competitive adsorptions were performed In batch mode to investigate the removal of two toxic organic Phenols, chlorophenol and 4-chlorophenol on the HDTMA-bentonite. The adsorption affinity of the 4-chlorophenol was higher than phenol due to higher octanol:water partition coefficient (Kow). The single-solute and bi-solute competitive desorptions were also performed investigate the competitive desorption of the phenolic compounds from HDTMA-bentonite. Freundlich model was used to analyze the single-solute adsorption/desorption results, while the IAST model predicted the hi-solute adsorption/desorption equilibria. The IAST model well predicted hi-solute competitive adsorption/desorption behaviors.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2005년도 학술발표논문집
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• pp.690-694
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• 2005

It is necessary that the construction of submerged breakwater could minimize and compensate the negative effect on the marine environment and ecosystem caused by the Saemangeum reclamation. The important merit of this proposal is that the space between Saemangeum embankment and submerged breakwater is expected to become nursery ground for fish and shellfishes. The purpose of this study was investigated hydraulic characteristic of submerged breakwater to investigate the possibility of mitigation in the fisheries ground by hydraulic experiment.

• 한국포장학회지
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• 제11권1호
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• pp.41-46
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• 2005

For both economic and ecological reasons corrugated box manufacturers are seeking to produce acceptably strong boxes while using more recycled paper. This study was to develop hydrophilic coating agents in order to improve overall physical properties of recycled corrugated fiberboard liners. Two coating agents were developed and applied to 'S' corrugating medium. The results showed that compression strength of new liners, named 'S-A' and 'S-B', were increased significantly both standard humidity and high humidity environment and it was as much as 'SK' liner. New developed liners were also economically advantageous since new liners were estimated about one hundred fifty dollars per ton cheaper than SK liner. The study indicated that further work is needed on the coating technology and machine development.

• 한국환경과학회지
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• 제32권2호
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• pp.89-97
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• 2023

The purpose of this study is to examine the possibilities of use as a factor of the water landscape in modern urban spaces such as parks and, apartments, through a case study of the concept, functions, and culture of moats in the East and West from ancient times to the Middle Ages. This study aimed to examine the concept, origin, and function of the moat as a theoretical consideration. Asian castles with moats, including those in Korea, China and Japan, and Western castles with moats in Britain, France, Belgium, and Germany were investigated and analyzed. By reflecting on these cultures and the functions of the moat in modern urban spaces and converting the environment damaged due to industrialization and urbanization into an eco-friendly and environment symbiotic city the quality of life can be improved, and sustainable development can be achieved. This study was conducted through a literature survey and field investigation.

• 한국물환경학회지
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• 제30권1호
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• pp.80-86
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• 2014

Unlike to natural organic matters (NOMs), effluent organic matters (EfOMs) are not well understood due to their complexity and heterogeneity. In this study, EfOMs from sewage and industrial wastewater treatment effluents and Suwannee River NOM (SRNOM) were isolated into hydrophobic (HPO), transphilic (TPI) and hydrophilic (HPI) fractions. Specific ultraviolet absorbance (SUVA) and fluorescence excitation emission matrix (FEEM) analyses were used to characterize physicochemical properties. In addition, acute toxicity and oxidative stress to Daphnia magna were evaluated to characterize toxicological properties. EfOMs showed similar properties to microbially derived organic matters having low hydrophobicity, which are totally different from SRNOM having high hydrophobicity. Moreover, acute toxicity and antioxidant enzyme activity in D. magna was largely dependent on fraction types of EfOMs. These findings suggest that EfOMs have different physicochemical and toxicological properties compared with those of NOMs, which needs to be further identified with various sources of EfOMs.