• Title/Summary/Keyword: hydrophile

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Detergency and Liquid Wetting/Retention Properties of Soiled Polyester/Cotton(65/35) Cloth in Nonionic Surfactant Solutions (비이온계 계면활성제 수용액에서 Polyester/Cotton(65/35) 오염포의 습윤특성과 세척성)

  • Kim, Chun-Hee
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.140-145
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    • 2011
  • The effects of nonionic surfactant solutions of 0.1g/dL on detergency and liquid wetting/retention properties of soiled polyester/cotton(65/35) cloth were studied. Soiled polyester/cotton(65/35) cloth (EMPA 104) and 10 different nonionic surfactants (Span 20, Tween 20, 40, 60, 80, 21, 61, 81, 65, 85) were used in the study. The water retention and liquid retention capacity values of soiled cloth were decreased compared with those of unsoiled cloth. The wetting and water retention of soiled cloth improved with addition of surfactants, whereas water retention ratio(W/H) values didnot change markedly. Generally surfactants with low surface tension and high HLB (Hydrophile-lipophile balance) were more effective in improving the wetting/retention properties of soiled cloth. Nonionic surfactants having high ethylene oxide contents of 20 moles; i.e., Tween 20, 40, 60 & 80, showed better detergency than low ethylene oxide contents of 4 moles; i.e., Tween 21, 61 & 81. As HLB values of surfactants and $cos{\theta}$ of the soiled cloth increase, the detergency values of soiled cloth increased.

Surface Properties and Betergency of the Binary Surfactant Mixture (계면활성제 혼합용액의 계면특성 및 세척성에 관한 연구)

  • 심소희;박정희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.21 no.3
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    • pp.632-640
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    • 1997
  • Changes in surface properties and detergency of sunactant mixtures were investigated in order to study the optimum mixing ratio of anionic and nonionic surfactants by measuring surface tension, interfacial tension, suspendability, and emulsification as a Amction of mixing ratio. Also, surface tension and detergency of the surfactant mixtures were determined with the increase of water-hardness or temperature. The results were as follows: the addition of NPE to anionic surfactant solutions (LAS or SDS) by 0.1 mole fraction remarkably decreased surface tension. NPE (n=15)/anionic surfactant mixtures showed a synergistic effect in lowering interfacial tension and emulsification, but NPE (n=7.5)/anionic surfactant mixtures did not. In suspension stability, however, synergism appeared when LAS or 505 was mixed with both of NPE's. With respect to the hydrophile of NPE, NPE (n=15) was more effective than NPE (n=i.5) in improving suspension stability. Detergency of LAS/NPE mixture changed almost linearly with mixing ratio, but that of SDS/NPE mixture increased remarkably by the addition of 0.1 or 0.2 mole fraction of NPE at all temperatures. As the temperature increased, surface tension of surfactant mixtures decreased and detergency was improved, but their synergistic effect decreased. In hard water, the mixtures showed better detergency than single surfactuant solutions.

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A Study on the Thermal Degradation Properties of Epoxy Resin for Cast Resin Transformer (몰드변압기용 에폭시 수지의 열 열화특성에 관한 연구)

  • Lim, Kyung-Bum;Nam, Ki-Dong;Kim, Ki-Hwan;Park, Su-Hong;Hwang, Myung-Hwan
    • Fire Science and Engineering
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    • v.22 no.2
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    • pp.44-48
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    • 2008
  • In this paper, we measured a contact angle, surface resistivity and XPS to study the thermal aging characteristics of the epoxy resin for cast resin transformer. As a result of this experiment, we found that the contact angle increases up to $200^{\circ}C$ as it causes a re-crosslinking on the surface, but starts decreasing at $250^{\circ}C$ as it causes heat condensation. As a result of examining the oxygen/carbon peaks through the XPS analysis, we obtained a higher oxygen peak vs. carbon in the first untreated sample, but it showed the opposite trend after heat treatment. That rise in the carbon peak continued up to $200^{\circ}C$, but decreased again at the temperatures above. That's because it kept forming a stable surface structure up to $200^{\circ}C$ but its carbon combination got destroyed due to a rapid oxidization at $250^{\circ}C$. And a conduction path was formed easily with the hydrophile property caused by rapid surface activation.

Synthesis and Characteristics of PU Oil-Gelling Agents According to the Soft Segment Content (Soft Segment 조성에 따른 PU 유겔화제의 합성 및 특성)

  • Lee, Yong-Hun;Kim, Wook;Kim, Won-Ho
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.744-750
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    • 2000
  • Oil gelling agent was synthesized with PPG, PTMG and TDI at 7$0^{\circ}C$ for 4hours. PPGs and PTMGs having various average molecular weights (M$_{n}$: 1000, 2000, 3000) were employed to investigate the ratio of oil gelation and water gelation. As M$_{n}$ of PPG, in result, was decreased from 3000 to 1000, the ratio of oil gelation was increased from 130% to 290% for PPG and from 250% to 310% for PTMG. Ratio of oil gelation was increased approximately two times when EG was added. As the amount of hydrophilic compound in the prepolymer was increased, ratio of oil gelation was increased from 290% to 1120% for PPG and increased from 310% to 1310% for PTMG, due to the increased dispersion of prepolymer in the water/oil mixture.ure.

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Effect of pH, Chemical Composition and Additives on Stability of Soymilk Suspension (pH, 화학적 조성 및 첨가제가 두유(豆乳)의 현탁안정성에 미치는 영향)

  • Kim, Eun-Soo;Chung, Seong-Soo;Jo, Jae-Sun
    • Korean Journal of Food Science and Technology
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    • v.22 no.3
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    • pp.319-324
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    • 1990
  • The effects of pH, protein and fat content, addition of emulsifiers, stabilizer, sugar, salt and calcium salt on the stability of soymilk suspension were investigated by analyzing the cream separated and precipitates of soymilk which is prepared by various conditions. In the alkaline region of pH, soymilk showed a good stability of the suspension and particularly, above pH 10, precipitates were not formed. When 1.5% of palm oil with 0.4% of glycerine monostearate was added to soymilk in the hydrophile-lipophile balance (HLB) value of 4 to 7, resulted maximal emulsion stability occured below H LB 6. The stability was decreased with increasing the fat concentration and soy oil showed better emulsion stability than that of palm oil. Among the commercial stabilizers, 0.03% of carrageenan was most effective. The stability was not decreased by addition of sugar up to 3% while it was decreased by addition of sodium salt and calcium salt at low level.

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A Study on the Preparation of PBAST/PVA Double Layered Hollow Microspheres (PBAST/PVA 이중층 중공미세구의 제조에 관한 연구)

  • Song, Myung-Sook;Woo, Je-Wan
    • Clean Technology
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    • v.14 no.4
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    • pp.256-264
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    • 2008
  • In this study, using PBAST (poly(butylene adipate-co-succinate-co-terephthalate)) which was eco-friendly biodegradable aliphatic polyester, PBAST/PVA (poly(vinyl alcohol)) double-layered hollow microspheres were prepared with the water/oil/water multiple emulsion ($W_1/O/W_2$) method. The double-layered hollow microspheres were manufactured with the yield of 30.92% when the concentration of polymer PBAST in organic phase was 5 wt%, the concentration of PVA in inner aqueous phase was 5 wt%, the volume ratio of $W_1/O$ emulsion to outer aqueous phase was 1:4.5, and when co-surfactants that had large gap in HLB (hydrophile-lipophile balance) value were used. The bulk density of prepared hollow microsphere was 0.180 g/ml and particle size was $1.5{\sim}3\;{\mu}m$.

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A Study on the Improvement and Networking for the Natural leisure areas in Gyeonggi-do (경기도 내 자연 휴식공간의 네트워크화 및 개선방안 연구)

  • Sung, Hyun-Chan;Seo, Jung-Young
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.12 no.3
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    • pp.116-129
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    • 2009
  • This study is to enhance the provincial leisure plans through various programs and infrastructure facilities and to establish a network of natural leisure areas in Gyeonggi-do. According to the result, first, in terms of analyzing the locations of natural leisure areas by types, the rest of urban parks is formed in the Capital area outside Seoul as centering around the central area. Moreover, with regard to the rest of forest and the rest of natural ecology learning, the area of the detention exceeds the total area of Gyeonggi-do. The rest of valleys and swamps showed a dotted pattern of the detention area while the rest of tideland and fishing village experience indicated a distribution of the detention area along the West Coast as an axis. Second, according to result of analyzing the accessibility of natural leisure areas by types, the rest of valleys and swamps showed the highest accessibility among the natural leisure areas : the rest of natural ecology learning had the medium level of accessibility; the rest of forest indicated the lowest accessibility. Therefore, it is necessary to create more leisure areas concerning the futures demands. In addition, they should be constructed in the places adjacent to the urban district area exhibiting higher usability and accessibility. In the places where there are many natural leisure area with higher utility, management plans should be deliberated as well. Based on the result of analyzing the rest of valleys and swamps and the rest of tideland and fishing village experience, it was found that the natural leisure area should improve the quality of water intensively and hydrophile property and create hydrophilic spaces. The development of natural leisure areas need to be carried out under the principle of environmental protection while considering historic sites and nearby rivers and lakes. Moreover, water leisure programs should be developed actively as well with further utilization of water resources in order to enhance the usability of natural leisure.

Effect on Nonionic Surfactant Solutions on Wetting and Absorbancy of Cotton Fabrics (비이온계 계면활성제 수용액이 면직물의 습윤특성에 미치는 영향)

  • 김천희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.25 no.8
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    • pp.1444-1452
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    • 2001
  • Textile materials are frequently in contact with surfactant solutions during their manufacturing or finishing processes as well as cleaning processes in use. Liquid wetting, wicking and absorbency of textile materials, and the liquid properties, surface characteristics and pore geometry of textile materials, and the liquie-solid interactions, In this paper, 10 different nonionic surfactants, including Span 20, Twen 20, 40, 60, 80, 21, 61, 81, 65, 85, were used. The surfactants were characterized by their hydrophile-lipophile-balance (HLB) values, structures, and surface tensions. The 0.1g/dL and 1.0g/dL surfactant solutions, which were both above critical micelle concentration (CMC), were used to see the concentration effects on the wetting and absorbency of cotton fabrics. The wetting behavior and liquid retention properties of hydrophobic cotton fabrics with different nonionic surfactant solutions are reported. The contact angles are greatly decreased and the water retention values are greatly increased by adding most of the surfactants studied into the system. The extents of this effects are influenced by the characteristics of surfactants and its solutions. Hydrophilic surfactants which have low number of carbon atoms or unsaturated hydrophobe structures are more effective in improving the wetting and absorbancy of hydrophobic cotton fabrics. The water retention of hydrophobic cotton fabrics has positive relations with $cos{\theta}$, adhesion tension and work of adhesion. The 1.0g/dL surfactant solutions show similar, but slightly improved wetting and absorbency characteristics of hydrophobic cotton fabrics compared to the 0.1g/dL surfactant solutions.

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Change master cast by hardening method to position of tray after impression taking (인상채득 후 경화시 트레이의 위치에 따른 주모형의 변화)

  • Lee, Jung Ae
    • Journal of Korean society of Dental Hygiene
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    • v.8 no.2
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    • pp.53-66
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    • 2008
  • There was to purpose of this study improves analyzing cause that prosthesis brings bite engaging that is inaccurate in patient's mouth, when supposed that all conducts that do in operatory and dental laboratory are perfect. Impression did check bite by alginate impression material and polymerization style silicon impression material that use usually in presence at a sickbed Irreversibility, hydrocolloid, alginate impression material washed in flowing water and poured anhydrite after wait about 8 minutes so that region that charge interest after impression check bite may become undoing. And hydrophile property addition polymerization style impression material poured anhydrite after blow 30 considering impression material dwell time and H2 gas occurrence time (5~15 minute) after have washed in flowing water. I got each 7 models, result that manufactures total 28 and measures by third dimension measuring instrument (Meteo, Korea) following sequence curing in tray holder and floor 1, By Alginate impression when is hardened in tray holder and when is hardened in the floor after do check bite, SPH 4, SPH5 all as there is synonymy appeared(P<0.05). By in case do not use average 0.1741 in case use tray holder in 0.0447 SPH5s in case do not use average 0.2838 pastas in case use tray holder in SPH4 0.0309, When did not use both SPH4 and SPH5 tray holder, when used tray holder, 1 appeared more greatly. 2. By amity sex addition polymerization style silicon impression when is hardened in tray holder after do check bite and when is hardened in the floor SPH 4, a11 of the SPH5s very big synonymy be(P>0.05). And in case use tray holder in 0.000657 pasta SPH5s in case do not use average 0.000129 pastas in case use tray holder in SPH4 average 0.000114 pastas, by in case do not use 0.000757, I appeared more greatly when used tray when did not use both SPH4 and SPH5 tray holder, but 1 appeared is not level to keep in mind(Table 8~9). 3 SPH4 was looked very big mindfulness in model that manufacture doing impression check bite by Alginate and model that do impression check bite by amity sex accessory penalty silicon without using tray holder(P< 0.001). I use tray holder and SPH4 did not appear synonymy in model that manufacture doing impression check bite by Alginate and model that do impression check bite by amity sex accessory penalty silicon(P>0.05). Study finding of above when see synthesis Alginate certainly tray holder use must and I could know that hardening method does not exert big influence on volume stability if remove impression sieve of excess because amity sex accessory penalty silicon passes over tray, Also, Alginate impression material previewed can get heading a conspiracy style that volume stability of accessory penalty silicon impression material degree is if use tray holder.

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Property Studies of PAN/PVdF Composite Nanofiber Manufactured from Electrospinning (전기방사법으로 제조된 PAN/PVdF 복합나노섬유의 특성연구)

  • Yun, Jung-Hyun;Choi, Dong-You
    • 전자공학회논문지 IE
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    • v.46 no.3
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    • pp.6-11
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    • 2009
  • In this paper, manufactured composite nanofiber by electrospinning that make spinning solvent according to weight of PAN/PVdF. PVdF content of composite nanofiber decreases, diameter of fiber decreased. Result that measure contact angle to confirm hydrophile property of PAN/PVdF composite nanofiber, PVdF content increases, could confirm that contact angle with water increases. After leave filter measurement sample for 25 hours in temperature of $40^{\circ}C$, humidity of 85%, result PAN/PVdF composite nanofiber that estimate efficiency could confirm that display performance of HEPA more than 99.95% and ULPA more than 99.999%. And fiber diameter is small, could confirm that filter performance increases. Tensile strength of bulk of PAN/PVdF composite nanofiber was 5-8MPa, expansion 100-300%. And strength and expansion could know that increase according as PVdF's content increases. Tensile strength was 3-8MPa degree after annealing PAN/PVdF composite nanofiber during 2 hours in 120t. Tensile strength was no change almost by annealing, and expansion could know that decrease.