• Title/Summary/Keyword: hydrogen vessel

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Improved prediction model for H2/CO combustion risk using a calculated non-adiabatic flame temperature model

  • Kim, Yeon Soo;Jeon, Joongoo;Song, Chang Hyun;Kim, Sung Joong
    • Nuclear Engineering and Technology
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    • v.52 no.12
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    • pp.2836-2846
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    • 2020
  • During severe nuclear power plant (NPP) accidents, a H2/CO mixture can be generated in the reactor pressure vessel by core degradation and in the containment as well by molten corium-concrete interaction. In spite of its importance, a state-of-the-art methodology predicting H2/CO combustion risk relies predominantly on empirical correlations. It is therefore necessary to develop a proper methodology for flammability evaluation of H2/CO mixtures at ex-vessel phases characterized by three factors: CO concentration, high temperature, and diluents. The developed methodology adopted Le Chatelier's law and a calculated non-adiabatic flame temperature model. The methodology allows the consideration of the individual effect of the heat transfer characteristics of hydrogen and carbon monoxide on low flammability limit prediction. The accuracy of the developed model was verified using experimental data relevant to ex-vessel phase conditions. With the developed model, the prediction accuracy was improved substantially such that the maximum relative prediction error was approximately 25% while the existing methodology showed a 76% error. The developed methodology is expected to be applicable for flammability evaluation in chemical as well as NPP industries.

A Study on the Fatigue Crack Growth Behavior of Cr-Mo- Steel for Pressure Vessel (압력용기용 Cr-Mo강의 균열진전거동에 관한 연구)

  • Choe, Byeong-Ik;Lee, Hak-Ju;Han, Seung-U;Kim, Chang-Uk;Cha, Jeong-Hwan;Kim, Jeong-Tae;Ji, Byeong-Ha
    • 연구논문집
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    • s.29
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    • pp.91-99
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    • 1999
  • Fatigue crack growth behaviors of Cr-Mo steels developed recently for thick-wall pressure vessel were investigated. Experiments in accordance with ASTM E647 standard were performed for 1/2 inch CT specimens of $2^(1/4)$Cr-1Mo and 3Cr-IMo steels in gaseous environments, hydrogen gas of 10 atm, 1 atm and argon gas of 1 atm. Fatigue crack growth rates were observed and effects of gaseous hydrogen and argon on the crack growth behavior were discussed.

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Development of the High Pressure Hydrogen Gas Cylinder(Type4) for Fuel Cell Vehicle;Design Qualification Tests (연료전지 차량용 고압기체수소 저장용기(Type4)개발;설계검증시험)

  • Yoo, Gye-Hyoung;Ju, Yong-Sun;Heo, Seok-Bong;Jeon, Sang-Jin;Kim, Jong-Lyul;Lee, Jong-Hee
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.193-196
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    • 2007
  • We developed and tested the high pressure hydrogen gas cylinder(type4) for fuel cell vehicle. The working pressure is 350bar. We conducted material tests, production tests and design qualification tests on the developed cylinders according to modified NGV2-2000(hydrogen). The high pressure hydrogen gas cylinder met all the design qualification requirements of ANSI/CSA NGV2-2000 and acquired NGV2 certification from independent inspection agency.

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Failure of Ammonia Synthesis Converter Due to Hydrogen Attack and Its On-Stream Assessment Using ToFD Method

  • Albiruni, Farabirazy;Lee, Joon-Hyun
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.132-137
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    • 2008
  • A failure analysis of ammonia converter which suffered hydrogen attack in two years since its initial operating time was presented. It is constructed from 2.25 Cr.1 Mo steel. Analysis showed that the failure on closing seam weld joint was due to local improper post weld heat treatment (PWHT). Improper PWHT can introduce high residual stresses in thick-walled pressure vessel. High residual stress level in weld joint is very prone to hydrogen attack for any components which are operating in hydrogen gas environment. The repair procedures based on the principle to decrease the residual stress then proposed. The repair was controlled very carefully by applying several nondestructive tests in the each stage of repair. To assure the successful of the proposed repair, after one year since repair time, high temperature ultrasonic and TOFD methods were applied on-stream to this equipment in order to evaluate its post repair condition. The two methods showed good results on the repaired area.

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Preliminary Structural Sizing of the Co-axial Double-tube Type Primary Hot Gas Duct for the Nuclear Hydrogen Reactor (수소생산용 원자로에서 동심축 이중관형 1차 고온가스덕트의 예비 구조정산)

  • Song, Kee-nam;Kim, Y-W
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.4 no.2
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    • pp.1-6
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    • 2008
  • Very High Temperature Gas Cooled Reactor (VHTR) has been selected as a high energy heat source for nuclear hydrogen generation. The VHTR can produce hydrogen from heat and water by using a thermo-chemical process or from heat, water, and natural gas by steam reformer technology. A co-axial double-tube primary hot gas duct (HGD) is a key component connecting the reactor pressure vessel and the intermediate heat exchanger (IHX) for the VHTR. In this study, a preliminary design analysis for the primary HGD of the nuclear hydrogen system was carried out. These preliminary design activities include a determination of the size, a strength evaluation and an appropriate material selection. The determination of the size was undertaken based on various engineering concepts, such as a constant flow velocity model, a constant flow rate model, a constant hydraulic head model, and finally a heat balanced model.

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Analyses of hydrogen risk in containment filtered venting system using MELCOR

  • Choi, Gi Hyeon;Jerng, Dong-Wook;Kim, Tae Woon
    • Nuclear Engineering and Technology
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    • v.54 no.1
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    • pp.177-185
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    • 2022
  • Hydrogen risk in the containment filtered venting system (CFVS) vessel was analyzed, considering operation pressure and modes with the effect of PAR and accident scenarios. The CFVS is to depressurize the containment by venting the containment atmosphere through the filtering system. The CFVS could be subject to hydrogen risk due to the change of atmospheric conditions while the containment atmosphere passes through the CFVS. It was found that hydrogen risk increased as the CFVS opening pressure was set higher because more combustible gases generated by Molten Core Concrete Interaction flowed into the CFVS. Hydrogen risk was independent of operation modes and found only at the early phase of venting both for continuous and cyclic operation modes. With PAR, hydrogen risk appeared only at the 0.9 MPa opening pressure for Station Black-Out accidents. Without PAR, however, hydrogen risk appeared even with the CFVS opening set-point of 0.5 MPa. In a slow accident like SBO, hydrogen risk was more threatening than a fast accident like Large Break Loss-of-Coolant Accident. Through this study, it is recommended to set the CFVS opening pressure lower than 0.9 MPa and to operate it in the cyclic mode to keep the CFVS available as long as possible.

Simulation Experiment of PEMFC Using Insulation Vessel at Low Temperature Region (저온영역에서 단열용기를 이용한 연료전지 모의 실험)

  • Jo, In-Su;Kwon, Oh-Jung;Kim, Yu;Hyun, Deok-Su;Park, Chang-Kwon;Oh, Byeong-Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.5
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    • pp.403-409
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    • 2008
  • Polymer electrolyte membrane fuel cell (PEMFC) is very interesting power source due to high power density, simple construction and operation at low temperature. But it has problems such as high cost, improvement of performance, effect of temperature and initial start at low temperature. These problems can be approached to be solved by using experiment and mathematical method which are general principles for analysis and optimization of control system for heat and hydrogen detecting management. In this paper, insulation vessel and control system for stable operation of fuel cell at low temperature were developed for experiment. The constant temperature capability and the heating time at sub-zero temperatures with insulation control system were studied by using a heating bar of 60W class. PEMFC stack which was made by 4 cells with $50\;mc^2$ active area in each cell is a thermal source. Times which take to reach constant temperature by the state of insulation vacuum were measured at variable environment temperatures. The test was performed at two conditions: heating mode and cooling mode. Constant temperature capability was better at lower environment temperature and vacuum pressure. The results of this experiment could be used as basis data about stable operation of fuel cell stack in low temperature zone.