• Title/Summary/Keyword: hydrogen extraction

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Reactive Extraction of Succinic Acid by Amino Extractants and Comparison of Extraction Characteristics of Maleic Acid (아민계 추출제를 이용한 숙신산의 반응추출 및 말산과의 추출특성 비교)

  • 홍원희;홍연기
    • KSBB Journal
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    • v.19 no.1
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    • pp.33-37
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    • 2004
  • Succinic acid is of interested as the raw material of biodegradable polymer. In this study, succinic acid was separated by reactive extraction using amine extractants such as TOA (trioctylamine) and Aliquat 336. The extractability of TOA for succinic acid was higher than that of Aliquat 336. The distribution of succinic acid into organic phase was decreased with increasing pH in aqueous phase. However, the effect of pH on the extractability of Aliquat 336 was little. In the case of maleic acid which has similar structure to succinic acid, the extractability for maleic acid was higher than that for succinic acid. It was mainly due to the difficulty of deprotonation of second carboxylic group by intramolecular hydrogen bonding.

Ion-Pair Extraction of Cs Radionuclides by Dicyclohexyl-24-crown-8 and Tetraphenylborate for Their Determination in Reactor Coolant (Dicyclohexyl-24-crown-8과 Tetraphenylborate에 의한 원자로 냉각수로부터 세슘 핵종의 이온쌍 용매추출)

  • Ihn-Chong Lee;Si-Joong Kim;Chul Lee
    • Journal of the Korean Chemical Society
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    • v.27 no.4
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    • pp.262-267
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    • 1983
  • A study has been carried out for a scheme of the selective extraction and determination of cesium, sodium and nuclides by the ion association with dicyclohexyl-24-crown-8 and sodium tetraphenylborate from primary coolant of a pressurized water reactor. For that purpose, the effects of hydrogen, cesium and borate ions on the extraction have been investigated. Interferences of iodine and xenon nuclides were found but could be removed by reducing with sodium thiosulfate and back extraction with 1 N hydrochloric acid solution, respectively.

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Antioxidant, Anti-acetylcholinesterase and Composition of Biochemical Components of Russian Deer Velvet Antler Extracts

  • Je, Jae-Young;Park, Pyo-Jam;Lim, Dong-Hwan;Jeon, Byong-Tae;Kho, Kang-Hee;Ahn, Chang-Bum
    • Food Science of Animal Resources
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    • v.31 no.3
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    • pp.349-355
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    • 2011
  • Russian deer velvet antlers were divided into three parts and subjected to a extraction process using hot water at 100, 110, and $120^{\circ}C$ or an extraction with 70% ethanol. Each extract was analyzed for its biochemical components, including uronic acid, sulfated-glycosaminoglycans (sulfated-GAGs), and sialic acid, and the antioxidant and anti-acetylcholinesterase activities were investigated. Different levels of uronic acid and sulfated-GAGs were observed in the extracts according to the water temperature used for the extraction, and contents decreased with increasing extraction temperature. The upper layer of each extract showed high amounts of uronic acid and sulfated-GAGs, followed by the middle and base layers. Ethanol extraction was more effective for recovering uronic acid than sulfated-GAGs. Sialic acid content was the highest in the $110^{\circ}C$ extracts but was not observed in the ethanol extracts. Velvet antler extracts showed strong antioxidant activities against DPPH and hydrogen peroxide as well as strong reducing power in a dose-dependent manner. However, the antioxidant activities were different in each layer and according to the extraction method. Additionally, velvet antler extracts exhibited inhibitory activity against acetylcholinesterase, which is associated with Alzheimer's disease, in a dose-dependent manner. These results suggest that velvet antler extracts are useful as a functional food ingredient and/or a pharmaceutical.

Effect of Debinding and Sintering Conditions on the Tensile Properties of Water-atomized STS 316 L Parts by Powder Injection Molding (수분무 STS 316L 분말사출성형체의 탈지 및 소결공정에 따른 인장 특성)

  • 윤태식;성환진;안상호;이종수
    • Journal of Powder Materials
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    • v.9 no.4
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    • pp.218-226
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    • 2002
  • The purpose of the present study is to investigate the influence of thermal debinding and sintering conditions on the sintering behavior and mechanical properties of PIMed 316L stainless steel. The water atomized powders were mixed with multi-component wax-base binder system, injection molded into flat tensile specimens. Binder was removed by solvent immersion method followed by thermal debinding, which was carried out in air and hydrogen atmospheres. Sintering was done in hydrogen for 1 hour at temperatures ranging from 1000℃ to 1350℃ The weight loss, residual carbon and oxygen contents were monitored at each stage of debinding and sintering processes. Tensile properties of the sintered specimen varied depending on the densification and the characteristics of the grain boundaries, which includes the pore morphology and residual oxides at the boundaries. The sinter density, tensile strength (UTS), and elongation to fracture of the optimized specimen were 95%, 540 MPa, and 53%, respectively.

Analysis of droplet formation under sloshing phenomena in liquid fuel tank (액체 연료 탱크 내 슬로싱 현상에서의 액적 형성 분석)

  • Sungwoo Park;Jinyul Hwang
    • Journal of the Korean Society of Visualization
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    • v.21 no.2
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    • pp.102-110
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    • 2023
  • With the global shift from a carbon-based economy to a hydrogen-based economy, understanding the sloshing phenomenon and its impact on boil-off rate (BOR) in liquid hydrogen (LH2) tank trailers is crucial. Here, we analyze the primary breakup process under sloshing phenomena in a liquid fuel tank. We observe the growth of multiple holes on the sheet-like structures and the formation of ligament structures reminiscent of jet atomization. Through the extraction of three-dimensional liquid regions, we analyze the geometrical characteristics of these regions, enabling the classification of sheets, ligaments, and droplets. The present findings could contribute to understanding the breakup mechanism and hold potential for the development of strategies aimed at minimizing BOR.

Estimation of the Concentration of HF in the Atmosphere Using Plant Leaves Exposed to HF in the Site of the HF Spill (불산 누출 사고 시 불산에 노출된 식물잎을 이용한 대기 중 불화수소 농도 추정)

  • Yim, Bongbeen;Kim, Sun-Tae
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.3
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    • pp.248-255
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    • 2016
  • The leaves of three plant species, such as soybean, raspberry, and kudzu, exposed to hydrogen fluoride was collected in an area surrounding an emission source where the release accident occurred. The ultrasonic-assisted extraction and analysis of fluoride by ion chromatography was carried out. The mean concentration of fluoride in the leaves of three plant species exposed to hydrogen fluoride was $5,409{\pm}1,198mg\;F/kg\;dry\;wt$ and $788{\pm}339mg\;F/kg\;dry\;wt$, respectively. The mean fluoride concentration in ambient air were estimated to be $2.36{\pm}0.65mg/m^3$ ($2.89{\pm}0.79ppm$) and $0.35{\pm}0.15mg/m^3$ ($0.43{\pm}0.19ppm$) in exposed and unexposed sites, respectively. It seems likely that the passive monitoring using plant leaves could identify with respect to plant risk by fluoride in atmosphere.

Immobilization of Arsenic in Tailing using the Hydmgen-Peroxide (과산화수소를 이용한 광미중 비소의 불용화)

  • 정익재;최용수;박흥목
    • Journal of Korea Soil Environment Society
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    • v.4 no.3
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    • pp.67-75
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    • 1999
  • It is difficult to remedy tailings and soils including arsenic because arsenic compounds show anionic behaviour in natural condition and have chemical diversity by Eh/pH. This study was carried out to develop immobilization method of arsenic and iron in tailings and soils into ferric arsenate using hydrogen peroxide. According to experimental results, concentrations of arsenic and iron extracted from tailing of closed Gubong mine were reduced up to 84% and 93%, respectively. in this experiment. arsenic concentration decreased with an increase of hydrogen peroxide dosage. It was also showed that only 10% of arsenic and 20% of iron were extracted from the re-extraction experiments. Therefore, soil and tailing remedied by this method will be able to maintain long-time stability.

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Role of Plant Extracts to Remove Hydrogen Sulfide in the Air-Lifter Reactor (Air-lift 반응기내 황화수소제거시 식물정유추출물의 역할)

  • Park, Jong-Woo;Park, Young-G.;Kim, Jeong-In
    • KSBB Journal
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    • v.25 no.5
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    • pp.421-428
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    • 2010
  • This paper reports on the experimental investigation carried out to evaluate the physical optimal conditions in the absorption column to remove odorous hydrogen sulfide gas. Hydrogen sulfide gas, as a highly undesirable contaminant, is most widely emitted from environmental treatment facilities. The absorbent mixed with natural second metabolites extracted from conifer trees and chemical absorbent of 2-aminoethanol was applied to remove it via chemical neutralization. The absorbent of natural second metabolites was achieved by a removal efficiency of 20-40% by itself depending on the treatment conditions, but the complex absorbent mixed with 0.1% amine chemical provides the removal efficiency of 98%. The optimal removal efficiencies have been examined against the two major parameters of temperature and pH. This study shows that the aqueous solution by natural second metabolites can be used as an appropriate absorbent in the column absorbed for the removal of hydrogen sulfide gas.

Extraction of Vanadium Powder by Metallothermic Reduction (금속환원법에 의한 바나듐 분말 추출)

  • Lee, Dong-Won;Heo, Sang-Hyun;Yeom, Jong-Taek;Wang, Jei-Pil
    • Journal of Powder Materials
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    • v.20 no.1
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    • pp.43-47
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    • 2013
  • The extraction of metallic pure vanadium powder from raw oxide has been tried by Mg-reduction. In first stage, $V_2O_5$ powders as initial raw material was reduced by hydrogen gas into $V_2O_3$ phase. $V_2O_3$ powder was reduced in next stage by magnesium gas at 1,073K for 24 hours. After reduction reaction, the MgO component mixed with reduced vanadium powder were dissolved and removed fully in 10% HCl solution for 5 hours at room temperature. The oxygen content and particle size of finally produced vanadium powders were 0.84 wt% and 1 ${\mu}m$, respectively

Anaerobic digestate as a nutrient medium for the growth of the green microalga Neochloris oleoabundans

  • Abu Hajar, Husam A.;Guy Riefler, R.;Stuart, Ben J.
    • Environmental Engineering Research
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    • v.21 no.3
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    • pp.265-275
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    • 2016
  • In this study, the microalga Neochloris oleoabundans was cultivated in a sustainable manner using diluted anaerobic digestate to produce biomass as a potential biofuel feedstock. Prior to microalgae cultivation, the anaerobic digestate was characterized and several pretreatment methods including hydrogen peroxide treatment, filtration, and supernatant extraction were investigated and their impact on the removal of suspended solids as well as other organic and inorganic matter was evaluated. It was found that the supernatant extraction was the most convenient pretreatment method and was used afterwards to prepare the nutrient media for microalgae cultivation. A bench-scale experiment was conducted using multiple dilutions of the supernatant and filtered anaerobic digestate in 16 mm round glass vials. The results indicated that the highest growth of the microalga N. oleoabundans was achieved with a total nitrogen concentration of 100 mg N/L in the 2.29% diluted supernatant in comparison to the filtered digestate and other dilutions.