• 한국수소및신에너지학회논문집
• /
• 제34권5호
• /
• pp.431-438
• /
• 2023

Recently, study on hydrogen is being conducted due to environmental pollution and fossil fuel depletion. High-pressure gas hydrogen commonly used is applied to vehicle and tube trailers. In particular, high-pressure hydrogen storage tank for vehicles must comply with the guidelines stipulated in SAE J2601. There is a charging temperature limitation condition for the safety of the storage tank material. In this study, numerical analysis method were verified based on previous studies and the nozzle angle was changed for thermal management to analyze the increase in forced convection effect and energy uniformity due to the promotion of circulation flow. The previously applied high-pressure hydrogen storage tank has a length/diameter ratio of about 2.4 and was analyzed by comparing the length/diameter ratio with 8. As a result, the circulation flow of hydrogen flowing into the high-pressure hydrogen storage tank is promoted at a nozzle angle of 30° than the straight nozzle and accordingly, the effect of suppressing temperature rise by energy uniformity and forced convection was confirmed.

• 한국수소및신에너지학회논문집
• /
• 제31권5호
• /
• pp.405-410
• /
• 2020

In this literature, we are introduce a basic design of multi energy hub based on natural gas governor station. Multi energy hub consists of turbo expender generator, phosphoric acid fuel cell, pressure swing adsorption, H₂ charging station, utilities and etc. We design a hybrid energy hub system that provides energy using these complex energies, and calculates the amount of electricity that can be produced and the amount of hydrogen charged through the process analysis. TEG and phosphoric acid fuel cell produce 2,290 to 2,380 kW and can supply electricity to 500 houses. In addition, By-product H₂ gas is refined to H₂ vehicle fuel. This will help maximize the balance of energy demand and supply and improve national energy efficiency by integrating unused decompression energy power generation technology and various power generation/heat source technologies.

• 한국재료학회지
• /
• 제33권7호
• /
• pp.302-308
• /
• 2023

The influence of specimen geometry and notch on the hydrogen embrittlement of an SA372 steel for pressure vessels was investigated in this study. A slow strain-rate tensile (SSRT) test after the electrochemical hydrogen charging method was conducted on four types of tensile specimens with different directions, shapes (plate, round), and notches. The plate-type specimen showed a significant decrease in hydrogen embrittlement resistance owing to its large surface-to-volume ratio, compared to the round-type specimen. It is well established that most of the hydrogen distributes over the specimen surface when it is electrochemically charged. For the round-type specimens, the notched specimen showed increased hydrogen susceptibility compared with the unnotched one. A notch causes stress concentration and thus generates lots of dislocations in the locally deformed regions during the SSRT test. The solute hydrogen weakens the interactions between these dislocations by promoting the shielding effect of stress fields, which is called hydrogen-enhanced localized plasticity mechanisms. These results provide crucial insights into the relationship between specimen geometry and hydrogen embrittlement resistance.

• 한국인터넷방송통신학회논문지
• /
• 제23권6호
• /
• pp.81-87
• /
• 2023

수소충전소와 수소전기차 간의 통신 프로토콜인 SAE J2601과 SAE J2799는 수소 충전에 관련된 내용만을 다루고 있다. 본 논문에서는 수소전기차의 수소검출, 전류, 전압을 측정하여, 수소충전소로 WiFi 프로토콜을 변화시켜 가면서 센서 데이터를 전송한다. 수소전기차의 센싱, 제어 및 센서 데이터 전송을 위해, 라즈베리파이를 이용하여 소규모 실험실 모델을 만들었다. 센서 데이터를 수소충전소의 데이터베이스에 저장하였고, 저장된 데이터 분석을 위해 그라파나를 이용하여 대쉬보드를 구성하였다. 수소가 검출되면 수소충전소의 디스펜서 밸브를 잠근다. 그리고 WiFi 프로토콜에 따른 평균 전송 지연을 측정하였다. 전송 지연 측정 결과, 수소충전소와 수소전기차간의 센서 데이터 전송을 위한 WiFi 프로토콜은 IEEE 802.11a가 가장 적합하였다.

• 한국재료학회지
• /
• 제32권11호
• /
• pp.466-473
• /
• 2022

The effect of Cr and Mo contents on the hydrogen embrittlement of tempered martensitic steels was investigated in this study. After the steels with different Cr and Mo contents were austenitized at 820 ℃ for 90 min, they were tempered at 630 ℃ for 120 min. The steels were composed of fully tempered martensite with a lath-type microstructure, but the characteristics of the carbides were dependent on the Cr and Mo contents. As the Cr and Mo contents increased, the volume fraction of film-like cementite and prior austenite grain size decreased. After hydrogen was introduced into tensile specimens by electrochemical charging, a slow strain-rate test (SSRT) was conducted to investigate hydrogen embrittlement behavior. The SSRT results revealed that the steel with lower Cr or lower Mo content showed relatively poor hydrogen embrittlement resistance. The hydrogen embrittlement resistance of the tempered martensitic steels increased with increasing Mo content, because the reduction in the film-like cementite and prior austenite grain size plays an important role in improving hydrogen embrittlement resistance. The results indicate that controlling the Cr and Mo contents is essential to achieving a tempered martensitic steel with a combination of high strength and excellent hydrogen embrittlement resistance.

• 한국수소및신에너지학회논문집
• /
• 제8권4호
• /
• pp.161-171
• /
• 1997

$AB_2$ type Zr-based Laves phase alloys have been studied for potential application as negative electrode in Ni/MH batteries. However, They have a serious disadvantage of poor activation behavior in KOH solution. In this work, a new method of alloy design method was tried for improving Zr-based alloy activation. this method has focused on phase controlling to make multi-phase microstructure. In the case of multi-phase Zr-V-Mn-Ni shows good performance in activation, but activation mechanism has not been known. So, we were in search of elucidating this mechanism, Using morphological and electrochemical analysis, we could find that surface morphology and electocatalytic activity of the alloy change during immersion in KOH solution. V-rich second phases are selectively corroded and dissolved and then become Ni-rich phases. Resulting from these surface reaction in KOH solution, self-hydrogen charging occurs through Ni-rich phase. However, the alloy has poor cyclic durability because of such a corrosion mechanism. Therefore, finally we developed durable alloys by substitution of other alloying element.

• 한국수소및신에너지학회논문집
• /
• 제20권6호
• /
• pp.464-470
• /
• 2009

In order to analysis the possibility of high expansion and performance without backfire in a hydrogenfueled engine using external mixture injection, combustion characteristics and performance enhancement were analyzed in terms of retarding valve timing and increasing the boosting pressure. As the results, it was found that thermal efficiency increased by retarding intake valve timing with the same level of supplied energy is over 6.6% by the effect of high expansion including effect of combustion enhancement due to supercharging. It was also shown that the achievement of high power (equal to that of a gasoline engine), low brake specific fuel consumption and low emission (NOx of less than 16 ppm) without backfire in a hydrogen-fueled engine is possible around a boosting pressure of 1.5 bar, intake valve opening time of TDC and $\Phi$=0.35 in fuel-air equivalence ratio.

• 소성∙가공
• /
• 제33권1호
• /
• pp.5-11
• /
• 2024

The development of a next-generation hydrogen compressor, a key component in the expansion of hydrogen charging infrastructure, is in progress. In order to improve compression efficiency and durability, it is important to optimize the precision forming and shearing processes of the diaphragm, which is the bellows unit cell, as well as the optimization of diaphragm shape itself. In this study, we aim to show that die and process design technology that can synchronize the inner and outer shearing points of the diaphragm for the precision forming of product can be constructed based on a numerical simulation. First, the damage model that can predict the fracture points will be determined using the shear load and shear zone measurements obtained by performing a blanking test of AISI-633 stainless steel. Next, we will explain the overall procedure based on numerical analysis model how to determine the shearing points according to the deformation pattern of urethane die for various shearing die design.

• 한국수소및신에너지학회논문집
• /
• 제13권3호
• /
• pp.181-189
• /
• 2002

A series of multicomponent $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{1-x}Fe_{x}$ (x=0.00, 0.08, 0.15, 0.22, and 0.30) alloys are prepared and their oystal structure and P-C-T curves are examined. The electrochemical properties of these allqys such as activation conditions, discharge capacity, cycling performance are also investigated. $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{1-x}Fe_{x}$ (x=0.00, 0.08, 0.15, 0.22 and 0.30) have the C14 Laves phase hexagonal structure. The electrode was activated by the hot-charging treatment. The best activation conditions were the current density 120 mA/g and the hot-charging time 12h at $80^{\circ}C$ in the case of the alloy with x=0.00. The discharge capacity increased rapidly until the fourth cycle and then decreased. The discharge capacity increased again from the 13th cycle, arriving at 234 mAh/g at the 50th cycle. The discharge capacily just after activation decreases with the increase in the amount of the substituted Fe but the cycling performance is improved. The discharge capacity after activation of the alloy with x=0.00 is 157 mAh/g at the current density 120 mA/g. $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{0.85}Fe_{0.15}$ is a good composition with a medium quantity of discharge capacities and a good cycling performance. The ICP analysis of the electrolyte for these electrodes after 50 charge-discharge cycles shows that the concentrations of V and Zr are relatively high. Another series of multicomponent $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{0.85}M_{0.15}$ (M = Fe, Co, Cu, Mo and Al) alloys are prepared. They also have the C14 Laves phase hexagonal structure. The alloys with M = Co and Fe have relatively larger hydrogen storage capacities. The discharge capacities just after activation are relatively large in the case of the alloys with M = Al and Cu. They are 212 and 170 mAh/g, respectivety, at the current density 120mA/g. The $Zr_{0.8}Ti_{0.2}Mn_{0.4}V_{0.6}Ni_{0.85}Co_{0.15}$ alloy is the best one with a relatively large discharge capacity and a good cycling performance.

• 융합정보논문지
• /
• 제11권6호
• /
• pp.40-48
• /
• 2021

이 논문은 그린 딜로 인한 전기 에너지 수요가 급증을 될 수 있기 때문에 이를 제시하고자 한다. 그러나 미래의 전기자동차와 많은 전기 에너지의 조달은 여전히 화석 연료에 의존한다. 이에 IT 산업의 중요성이 부각되고 수소-전기차의 수요와 연관 산업으로 그 수요가 증가하게 된다. 본 연구의 방법은 IT 산업의 전기 에너지 수요보다 미래 차세대 동력으로 전기차의 충전과 연관성을 조사하였다. 이는 실증적 회귀 분석을 통해 경제 성장에 따른 산업용 전기와 가정용 에너지를 성장에 따른 PPP의 상관관계를 도출하였다. 그 결과 전기차와 차세대 전기차를 포함한 변화량은 GDP 대비 구매력 변화 국가의 1/3에서 유의미한 것으로 나타났다. 이는 전기차의 수요가 있는 32개국 중 12개 국가(이탈리아, 캐나다, 스위스, 폴란드, 슬로베니아, 독일, 슬로바키아, 핀란드, 스웨덴, 체코, 에스토니아, 덴마크)가 더 많은 전기 에너지에 더 민감하기에 전체 구매력에 영향을 미치게 된다. IT-전기 에너지원의 미사용 전력 낭비를 방지하고, 수소전기 충전-보존함으로써, 향후 성장을 위한 수급에 국가의 IT 산업 보존 완충 시설대비가 필수불가결하다.