• Title/Summary/Keyword: hydrogen bubbles

Search Result 40, Processing Time 0.026 seconds

Effect of Annealing on a-Si:H Thin Films Fabricated by RF Magnetron Sputtering (RF 스퍼터를 이용하여 제작된 a-Si:H 박막의 어닐링 효과에 관한 연구)

  • Kim, Do-Yun;Kim, In-Soo;Choi, Se-Young
    • Korean Journal of Materials Research
    • /
    • v.19 no.2
    • /
    • pp.102-107
    • /
    • 2009
  • The effect of annealing under argon atmosphere on hydrogenated amorphous silicon (a-Si:H) thin films deposited at room temperature and $300^{\circ}C$ using Radio Frequency (RF) magnetron sputtering has been investigated. For the films deposited at room temperature, there was not any increase in hydrogen content and optical band gap of the films, and as a result, quality of the films was not improved under any annealing conditions. For the films deposited at $300^{\circ}C$, on the other hand, significant increases in hydrogen content and optical band gap were observed, whereas values of microstructure parameter and dark conductivity were decreased upon annealing below $300^{\circ}C$. In this study, it was proposed that the Si-HX bonding strength is closely related to deposition temperature. Also, the improvement in optical, electrical and structural properties of the films deposited at $300^{\circ}C$ was originated from thermally activated hydrogen bubbles, which were initially trapped at microvoids in the films.

A Study on Effect of the Shape of Electrodes in Alkaline Water Electrolysis (알카리 수전해에서 전극 형상의 영향에 관한 연구)

  • CHOI, SOOKWANG;KIM, JONGSOO;HAN, JIN MOOK;YUN, SEONG-HO;KIM, SEWOONG;JUNG, YOUNGUAN
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.28 no.2
    • /
    • pp.121-128
    • /
    • 2017
  • For an investigation on the effect of the shape of electrodes in alkaline water electrolysis, two kinds of stack with circular and square electrode array are used to visualize both for behaviors of hydrogen bubble around the electrodes and for measurements of hydrogen production from these two stacks. The electrolytes for the hydrogen production experiment were applied for 20 wt%, 25 wt%, 30 wt% and 35 wt% of KOH alkaline aqueous solutions. As a result, the adhesion length of bubbles attached around the square electrode in the visualization experiment was found to be 1.7 times longer compared with the attached around the circular electrode. In the hydrogen production experiments, the volume of hydrogen production of the stack by using circular electrode array was approximately 3% more than that of the stack with square electrode array. These observations may be caused by the effect of the bubbles attached to the around the electrodes obstructing mass transfer such as hydrogen exhaust and electrolyte supply.

Experimental modelling of tunnel smoke flow using a fine-bubble technique (미세수소기포를 이용한 터널내의 연기거동 모사)

  • Park, Won-Hee;Jang, Yong-Jun;Kim, Dong-Hyeon;Park, Seung-Yil
    • Proceedings of the KSR Conference
    • /
    • 2007.05a
    • /
    • pp.444-447
    • /
    • 2007
  • The free flow of fine bubbles generated by electrolysis and smoke flow in a space enclosed by fire were recently found to show the same tendency thus leading to the introduction of a research technique. The research experimentally models smoke diffusion and flow in parallel and slanted tunnels using the fine hydrogen bubbles generated by electrolysis in a water tank. Visualization laser with wavelength of 532nm and output power of 1000mW is used to visualize effectively the cross section of fine hydrogen bubble flows generated in a model tunnel.

  • PDF

Shielding Gases for Welding Aluminum (알루미늄 용접을 위한 보호가스)

  • Steyer, Douglas;Jun, Baesoo
    • Journal of Welding and Joining
    • /
    • v.31 no.1
    • /
    • pp.38-42
    • /
    • 2013
  • In the welding of aluminum, it is important to provide a stable gas shield to exclude not only oxygen, but any sources of hydrogen, from the arc environment. Common sources of hydrogen are humidity in the air around the arc, moisture in the shielding gas, and residual lubricants on the surface of the welding consumable. Since molten aluminum can absorb seventy times more hydrogen than solid aluminum, as the aluminum cools, it releases hydrogen that then becomes trapped in the form of hydrogen bubbles in the solidifying metal.

ON THE ORIGIN OF THE NEUTRAL HYDROGEN SUPERSHELLS

  • Elias, Federico;Silich, Sergiy;Franco, Jose
    • Journal of The Korean Astronomical Society
    • /
    • v.40 no.4
    • /
    • pp.141-145
    • /
    • 2007
  • Here we analyze if the ionized shells associated with giant HII regions represent the progenitors of the larger neutral hydrogen supershells detected in the Milky Way and other spiral and dwarf irregular galaxies. We calculate the evolutionary tracks that 12 HII shells found by Relano et al. (2005, 2007) would have if they expanded into the interstellar medium because of multiple supernovae explosions occurring inside the cavity. We find, contrary to Relano et al. (2007), that the evolutionary tracks of these HII shells are inconsistent with the observed parameters of the largest and most massive neutral hydrogen supershells. Thus, an additional energy source to the multiple supernovae explosions is required in order to explain the origin of the most massive neutral hydrogen shells.

A Study on the Electrochemical Characteristics of Hydrogen Storage Alloy Electrodes for Secondary Batteries (축전지용 수소저장합금 전극의 전기화학적 특성에 관한 연구)

  • KIM, Chan-Jung;LEE, Jae-Myoung;CHOI, Byung-Jin;KIM, Dai-Ryong
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.4 no.2
    • /
    • pp.29-40
    • /
    • 1993
  • Intensive studies on the electrochemical characteristics of TiFe type alloy electrodes have been carried out to clarify the mechanism of electrochemical hydrogen absorption and desorption. It was found that electrochemical activation of the TiFe type alloys is difficult and that charge efficiencies are very low even after a decade of activation cycles. However, by the pretreatment of the powders such as gas activation and/or Ni chemical plating, charge efficiencies fairly increased, especially for the $TiFe_{0.8}Ni_{0.2}$ alloy. It was considered that difficulties to activation and lower charge efficies of the alloys are due to the presence of the passivation films, which prohibit inward diffusion of hydrogen and promote the combination of adsorbed hydrogen atom to gas bubbles during the electrochemical charge. In addition, lower diffusivity of hydrogen in the alloys may be played an important role lowering the charge efficiencies.

  • PDF

Numerical Simulation of Cavitating Flows on a Foil by Using Bubble Size Distribution Model

  • Ito, Yutaka;Nagasaki, Takao
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2004.03a
    • /
    • pp.216-227
    • /
    • 2004
  • A new cavitating model by using bubble size distribution based on bubbles-mass has been proposed. Both liquid and vapor phases are treated with Eulerian framework as a mixture containing minute cavitating bubbles. In addition vapor phase consists of various sizes of vapor bubbles, which are distributed to classes based on their mass. The bubble number-density for each class was solved by considering the change of the bubble-mass due to phase change as well as generation of new bubbles due to heterogeneous nucleation. In this method, the bubble-mass is treated as an independent variable, and the other dependent variables are solved in spatial coordinates and bubble-mass coordinate. Firstly, we employed this method to calculate bubble nucleation and growth in stationary super-heated liquid nitrogen, and bubble collapse in stationary sub-cooled one. In the case of bubble growth in super-heated liquid, bubble number-density of the smallest class based on its mass is increased due to the nucleation. These new bubbles grow with time, and the bubbles shift to larger class. Therefore void fraction of each class is increased due to the growth in the whole class. On the other hand, in the case of bubble collapse in sub-cooled liquid, the existing bubbles are contracted, and then they shift to smaller class. It finally becomes extinct at the smallest one. Secondly, the present method is applied to a cavitating flow around NACA00l5 foil. Liquid nitrogen and liquid oxygen are employed as working fluids. Cavitation number, $\sigma$, is fixed at 0.15, inlet velocities are changed at 5, 10, 20 and 50m/s. Inlet temperatures are 90K in case of liquid nitrogen, and 90K and 1l0K in case of liquid oxygen. 110K of oxygen is corresponding to the 90K of nitrogen because of the same relative temperature to the critical one, $T_{r}$=$T/T_c^{+}$. Cavitating flow around the NACA0015 foils was properly analyzed by using bubble size distribution. Finally, the method is applied to a cavitating flow in an inducer of the LE-7A hydrogen turbo-pump. This inducer has 3 spiral foils. However, for simplicity, 2D calculation was carried out in an unrolled channel at 0.9R cross-section. The channel moves against the fluid at a peripheral velocity corresponding to the inducer revolutions. Total inlet pressure, $Pt_{in}$, is set at l00KPa, because cavitation is not generated at a design point, $Pt_{in}$=260KPa. The bubbles occur upstream of the foils and collapse between them. Cavitating flow in the inducer was successfully predicted by using the bubble size distribution.

  • PDF

Fundamental evaluation of hydrogen behavior in sodium for sodium-water reaction detection of sodium-cooled fast reactor

  • Tomohiko Yamamoto;Atsushi Kato;Masato Hayakawa;Kazuhito Shimoyama;Kuniaki Ara;Nozomu Hatakeyama;Kanau Yamauchi;Yuhei Eda;Masahiro Yui
    • Nuclear Engineering and Technology
    • /
    • v.56 no.3
    • /
    • pp.893-899
    • /
    • 2024
  • In a secondary cooling system of a sodium-cooled fast reactor (SFR), rapid detection of hydrogen due to sodium-water reaction (SWR) caused by water leakage from a heat exchanger tube of a steam generator (SG) is important in terms of safety and property protection of the SFR. For hydrogen detection, the hydrogen detectors using atomic transmission phenomenon of hydrogen within Ni-membrane were used in Japanese proto-type SFR "Monju". However, during the plant operation, detection signals of water leakage were observed even in the situation without SWR concerning temperature up and down in the cooling system. For this reason, the study of a new hydrogen detector has been carried out to improve stability, accuracy and reliability. In this research, the authors focus on the difference in composition of hydrogen and the difference between the background hydrogen under normal plant operation and the one generated by SWR and theoretically estimate the hydrogen behavior in liquid sodium by using ultra-accelerated quantum chemical molecular dynamics (UA-QCMD). Based on the estimation, dissolved H or NaH, rather than molecular hydrogen (H2), is the predominant form of the background hydrogen in liquid sodium in terms of energetical stability. On the other hand, it was found that hydrogen molecules produced by the sodium-water reaction can exist stably as a form of a fine bubble concerning some confinement mechanism such as a NaH layer on their surface. At the same time, we observed experimentally that the fine H2 bubbles exist stably in the liquid sodium, longer than previously expected. This paper describes the comparison between the theoretical estimation and experimental results based on hydrogen form in sodium in the development of the new hydrogen detector in Japan.

Study on optimum structure of air-lift bio-reactor using numerical analysis of two-phase flow (이상 유동 수치해석을 이용한 기포 구동 생물 반응기 내부 최적 구조에 관한 연구)

  • Kim, San;Chung, Ji Hong;Lee, Jae Won;Sohn, Dong Kee;Ko, Han Seo
    • Journal of the Korean Society of Visualization
    • /
    • v.17 no.3
    • /
    • pp.24-31
    • /
    • 2019
  • Recently, an air-lift bio-reactor operated by micro bubbles has been utilized to product hydrogen fuel. To enhance the performance, characteristics of hydrodynamics inside the bio-reactor were analyzed using a numerical simulation for two-phase flow. An Eulerian model was employed for both of liquid and gas phases. The standard k-ε model was used for turbulence induced by micro bubbles. A Population Balance Model was employed to consider size distribution of bubbles. A hollow cylinder was introduced at the center of the reactor to reduce a dead area which disturbs circulation of CO bubbles. An appropriate diameter of the draft tube and hollow cylinder were optimized for better performance of the bio-reactor. The optimum model could be obtained when the cross-sectional area ratio of the hollow cylinder to the reactor, and the width ratio of the riser to the downcomer approached 0.4 and 3.5, respectively. Consequently, it is expected that the optimum model could enhance the performance of the bio-reactor with the homogeneous distribution and higher density of CO, and more effective mixing.

Images of Decomposition of Hydrogen Peroxide Demonstration Represented in New Media Contents: Focusing on Simulacra and Simulation (뉴미디어 콘텐츠에서 재현되는 과산화수소 분해 실험의 이미지 -시뮬라크르와 시뮬라시옹을 중심으로-)

  • Shin, Sein;Ha, Minsu;Lee, Jun-Ki
    • Journal of The Korean Association For Science Education
    • /
    • v.40 no.1
    • /
    • pp.13-28
    • /
    • 2020
  • This study attempted to understand the characteristics of images of scientific experiments represented and consumed on YouTube, a representative of today's new media. In particular, this paper analyzes the case studies of YouTube's hydrogen peroxide decomposition experiment based on Baudrillard's theory of Simulation and Simulacra, which discusses the strong status of images and the ambiguity of the boundary between virtual and reality. A total of 14 YouTube videos related to hydrogen peroxide decomposition experiments were analyzed. In those videos, hydrogen peroxide decomposition experiments were typically conducted with several signs representing scientific experiments, but the most important sign in the videos were bubbles produced through experiments. For more public consumption of the content, the bubbles resulted from hydrogen peroxide decomposition reproduced in YouTube have been transformed into a more spectacular image as 'super-huge' and 'explosive' bubble. Considering the influence of new media that can be accessed by students anytime and anywhere, it is positive that science experiments in new media enhance students' intimacy and access to science. At the same time, however, it is also important to note the danger that the purpose of scientific experiments will be limited to only 'showing specular images', due to the nature of new media, which mainly deals with immediate and superficial images. Furthermore, this study argues that improving students' science media literacy is required to critically examine the science-related images represented in the new media based on understanding the characteristics and limitations of new media that deeply affect daily life.