• Title/Summary/Keyword: hydrocarbon reserves

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Performance Analysis of WHR-ORC Using Hydrocarbon Mixtures for 20kW Gross Power at Low Temperature

  • Kwakye-Boateng, Patricia;Yoon, Jung-In;Son, Chang-Hyo;Hui, Kueh Lee;Kim, Hyeon-Uk
    • Journal of Power System Engineering
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    • v.18 no.6
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    • pp.140-145
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    • 2014
  • Exploitation of renewable energies is on the increase to mitigate the reliance on fossil fuels and other natural gases with rocketing prices currently due to the depletion of their reserves not to mention their diverse consequences on the environment. Divergently, there are lots of industries "throwing" heat at higher temperatures as by products into the environment. This waste heat can be recovered through organic Rankine systems and converted to electrical energy with a waste heat recovery organic Rankine cycle system (WHR-ORC). This study uses the annual average condenser effluent from Namhae power plant as heat source and surface seawater as cooling source to analyze a waste heat recovery organic Rankine cycle using the Aspen HYSYS simulation software package. Hydrocarbon mixtures are employed as working fluid and varied in a ratio of 9:1. Results indicate that Pentane/Isobutane (90/10) mixture is the favorable working fluid for optimizing the waste heat recovery organic Rankine cycle at the set simulation conditions.

Marine Controlled-source Electromagnetic Surveys for Hydrocarbon Exploration (탄화수소 탐지를 위한 해양 인공송신원 전자탐사)

  • Kim, Hee-Joon;Han, Nu-Ree;Choi, Ji-Hyang;Nam, Myung-Jin;Song, Yoon-Ho;Suh, Jung-Hee
    • Geophysics and Geophysical Exploration
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    • v.9 no.2
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    • pp.163-170
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    • 2006
  • The shortage of proven hydrocarbon reserves has resulted in exploration progressing from the offshore into progressively deeper water of the continental shelf. Despite the success of seismic acquisition at ever greater depths, there are marine geological terrenes in which the interpretation of seismic data is difficult, such regions dominated by scattering or high reflectivity that is characteristic of carbonate reefs, volcanic cover and submarine permafrost. A marine controlled-source electromagnetic (CSEM) method has recently been applied to the oil and gas exploration thanks to its high-resistivity characteristics of the hydrocarbon. In particular, this method produces better results in terms of sensitivity under the deep water environment rather than the shallow water. Only in the last five years has the relevance of CSEM been recognized by oil companies who now use it to help them make exploration drilling decisions. Initial results are most promising and several contractors now offer magnetotelluric and CSEM services.

Effect of Catalyst Type and Reaction Medium on Fischer-Tropsch Synthesis for Production of Hydrocarbon from Syngas (합성가스로부터 탄화수소제조를 위한 피서트롭스 반응에 관한 촉매 종류 및 반응매체의 영향)

  • Kim, Chul-Ung;Jeong, Soon-Yong;Jeong, Kwang-Eun;Koh, Jae-Cheon;Chae, Ho-Jeong;Kim, Tae-Wan;Park, Hyun-Joo;Lee, Sang-Bong;Han, Jeong-Sik;Jeong, Byung-Hun
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.658-663
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    • 2010
  • With petroleum reserves dwindling, interest has been increasing worldwide in Fischer-Tropsch synthesis (FT) as a method of producing synthetic liquid fuels and chemicals from coal, natural gas or biomass. In general, FT synthesis is operated through the gas phase fixed-bed reaction system. Recently, there are lots of study in supercritical fluid due to unique characteristics such as the quick diffusion of reactant gas, effective removal of reaction heat, and the in-situ extraction of high molecular weight hydrocarbon, such as wax. In this study, our major aim is to obtain a deeper insight into the effect of the type of support on the reaction performance over a supported cobalt catalyst in a fixed bed reactor.

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A Study on the Fischer-Tropsch Synthesis for Production of Hydrocarbon from Syngas under Gas Phase and Supercritical Phase (가스 및 초임계반응하에서 합성가스로부터 탄화수소 제조를 위한 피서트롭스 반응에 관한 연구)

  • Kim, Chul-Ung;Jeong, Soon-Yong;Jeong, Kwang-Eun;Chae, Ho-Jeong;Kim, Tae-Wan;Park, Hyun-Joo;Lee, Sang-Bong;Kim, Jung-Hyun;Han, Jeong-Sik;Jeong, Byung-Hun
    • Journal of the Korean Society of Propulsion Engineers
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    • v.15 no.3
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    • pp.15-21
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    • 2011
  • With petroleum reserves dwindling, interest has been increasing worldwide in Fischer-Tropsch synthesis (FT) as a method of producing synthetic liquid fuels and chemicals from coal, natural gas or biomass. In general, FT synthesis is operated through the gas phase fixed-bed reaction system. Recently, there are lots of study in supercritical fluid due to unique characteristics such as the quick diffusion of reactant gas, effective removal of reaction heat, and the in-situ extraction of high molecular weight hydrocarbon, such as wax. In this study, our major aim is to obtain a deeper insight into the effect of the type of support on the reaction performance over a supported cobalt catalyst in a fixed bed reactor.

Upgrading of Heavy Oil or Vacuum Residual Oil : Aquathermolysis and Demetallization (중질유 혹은 감압잔사유의 개질 반응 : Aquathermolysis와 Demetallization)

  • Lee, Hoo-Cheol;Park, Seung-Kyu
    • Applied Chemistry for Engineering
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    • v.27 no.4
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    • pp.343-352
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    • 2016
  • It has been estimated that the Earth has nearly 1.688 trillion barrels of crude oil, which will last 53.3 years at current extraction rates. The organization of petroleum exporting countries (OPEC) group forecasted that the oil prices will not jump to triple-digit territory within a decade, but it can quickly increase as the political issue for reducing oil production appears. With the potential of serious shortage of conventional hydrocarbon resources, the heavy oil, one of unconventional hydrocarbon resources including oil sand and natural bitumen has attracted worldwide interest. The heavy oil contains heavy hydrocarbon compounds, commonly called as resins and asphaltenes, with long carbon chains more than sixty carbon atoms. The high content of heavier fraction corresponds with the high molecular weight, viscosity, and boiling point. Physicochemical properties of residues from vacuum distillation of conventional oil, referred to as vacuum residues (VR) were similar to those of heavy oil. For the development of heavy oil reserves, reducing the heavy oil viscosity is the most important. In this article, commercially employed aquathermolysis processes and their application to VR upgrading are discussed. VR contains transition metals such as Ni and V, but these metals should be eliminated in advance for further refining. Recent studies on demetallization technologies for VR are also reviewed.

Supercritical Water Gasification of Low Rank Coal with High Moisture Content (고함수 저등급 석탄의 초임계수 가스화 특성)

  • Yoon, Sang Jun;Lee, Jae Goo;Ra, Ho Won;Seo, Myung Won
    • Journal of Hydrogen and New Energy
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    • v.24 no.4
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    • pp.340-346
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    • 2013
  • Study on clean and efficient utilization technology for low rank coal with high moisture content is actively ongoing due to limited reserves of petroleum and of high grade coal and serious climate change caused by fossil fuel usage. In the present study, supercritical water gasification of low rank coal was performed. With increasing reaction temperature, content of combustible gases such as $H_2$ and $CH_4$ in the syngas increased while the $CO_2$ content decreased. As the reaction pressure increased from 210 to 300 bar, the $CO_2$ content in the syngas increased while the hydrocarbon gas content decreased. The $H_2$ and $CH_4$ content in the syngas increased slightly with pressure. With the addition of Pd, Pt, and Ru catalysts, it was possible to improve the production of $H_2$. Moreover, the increase of active metal content in the catalyst increased the $H_2$ productivity. The Ru catalyst shows the best performance for increasing the $H_2$ content in the syngas, while decreasing the $CO_2$ content.

A Study on the Ways to Joint Marine Development and Joint Marine Environmental Protection in Northeast Asia (동북아 해역 권원중첩수역 공동개발합의와 공동환경보호합의 도출 방안)

  • Kim, Ki-Sun
    • Strategy21
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    • s.37
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    • pp.193-241
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    • 2015
  • China, Japan and Korea are the world's top 10 energy consumers, and so very interested in the development of seabed hydrocarbon resources in order to meet their energy demands. The East China Sea is the tri-junction area where three countries' entitlements on the maritime boundaries are overlapped. There are abundant oil reserves in the East China Sea, and therefore competitions among countries are growing to get control of them. Although these countries have concluded the bilateral agreements to jointly develop resources in the East China Sea, they do not function as well. Because joint development and management of seabed petroleum resources can lead to stable development system, and to lower possibility of legal and political disputes, the needs for joint development agreement among three countries are urgent. Meanwhile, Northeast Asian seas are semi-closed seas, which are geographically closed and vulnerable to marine pollution. Moreover there are a lot of nuclear power plants in coastal area, and seabed petroleum resources are being developed. So it is likely to occur nuclear and oil spill accidents. Fukushima nuclear disaster and Bohai Bay oil spill accident in 2011 are the cases to exhibit the potential of major marine pollution accidents in this area. It is anticipated that the risks become higher because power plants and offshore oil platforms are extending gradually. Therefore, the ways to seek the joint marine environmental protection agreement focused on regulation of nuclear power plant and offshore oil platform have to be considered. In this paper, we try to find the way to make joint development and joint environmental protection agreement in Northeast Asian seas. We concentrate on the measure to drive joint development of seabed petroleum deposits in East China Sea's overlap area, despite of maritime delimitation and territorial disputes, and we try to drive joint marine environmental protection system to respond to marine pollution and accidents due to offshore oil platform and nuclear power plants. Through these consideration, we seek solutions to deal with lack of energy, disputes of maritime territorial and boundary delimitation, and marine pollution in Northeast Asia.

Generation of Pseudo Porosity Logs from Seismic Data Using a Polynomial Neural Network Method (다항식 신경망 기법을 이용한 탄성파 탐사 자료로부터의 유사공극률 검층자료 생성)

  • Choi, Jae-Won;Byun, Joong-Moo;Seol, Soon-Jee
    • Journal of the Korean earth science society
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    • v.32 no.6
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    • pp.665-673
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    • 2011
  • In order to estimate the hydrocarbon reserves, the porosity of the reservoir must be determined. The porosity of the area without a well is generally calculated by extrapolating the porosity logs measured at wells. However, if not only well logs but also seismic data exist on the same site, the more accurate pseudo porosity log can be obtained through artificial neural network technique by extracting the relations between the seismic data and well logs at the site. In this study, we have developed a module which creates pseudo porosity logs by using the polynomial neural network method. In order to obtain more accurate pseudo porosity logs, we selected the seismic attributes which have high correlation values in the correlation analysis between the seismic attributes and the porosity logs. Through the training procedure between selected seismic attributes and well logs, our module produces the correlation weights which can be used to generate the pseudo porosity log in the well free area. To verify the reliability and the applicability of the developed module, we have applied the module to the field data acquired from F3 Block in the North Sea and compared the results to those from the probabilistic neural network method in a commercial program. We could confirm the reliability of our module because both results showed similar trend. Moreover, since the pseudo porosity logs from polynomial neural network method are closer to the true porosity logs at the wells than those from probabilistic method, we concluded that the polynomial neural network method is effective for the data sets with insufficient wells such as F3 Block in the North Sea.

Development of a Pressure Core Sampler with Built-in Data Logging System (데이터 기록 장치가 내장된 PCS (Pressure Core Sampler)의 개발)

  • Kim, Sang Il;Cho, Young Hee;Ki, Jung Seck;Kim, Dong Wook;Lee, Kye Kwang;Kim, Hae Jin;Choi, Kook Jin
    • The Journal of Engineering Geology
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    • v.24 no.3
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    • pp.423-429
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    • 2014
  • Development of a reservoir pressure core sampler (PCS) with a built-in data logging system (DLS) for recording real-time temperature and pressure observations is critical in domestic hydrocarbon production to accurately measure and monitor reserves of shale gas, coalbed methane, and gas-hydrate. Another purpose of this new technology is to minimize the loss of gas from the core as the drill core is collected. This is accomplished by maintaining the pressure of the sample from the moment the drill core is obtained at depth, thus allowing an accurate analysis of shale gas, coalbed methane gas, and gashydrate within the core. Currently, the United States and European countries have monopolized the development and marketability of PCS technologies. We are thus developing a reservoir PCS by analyzing the operating principle and mechanisms of the existing PCS, and by conducting tests on the existing PCS. We further aim to develop a PCS with a maximum operating pressure of 100 bar, a maximum operating temperature of $-20^{\circ}C$ to $40^{\circ}C$, and a pressure loss rate of 10%.

Suggestion of the Modified Archie's Formula for Calculating Water Saturation of Clean Sandstone and Carbonate Rocks (청결 사암 및 탄산염암의 물 포화도 산출을 위한 수정 Archie 경험식의 제안)

  • Lee, Sang-Hee;Ko, Eun-Ji;Kim, Jin-Hoo
    • Geophysics and Geophysical Exploration
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    • v.18 no.3
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    • pp.125-132
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    • 2015
  • The water saturation ($S_w$), which is very important to estimate hydrocarbon reserves in the reservoir, has been determined from resistivity index (RI) by using the Archie's formula. However, in many cases, it has been reported that n is not constant for a given formation and it could be varied with water saturation. In addition, it frequently happens that the line obtained by linear regression analysis on log-log scale does not pass through the origin. In order to overcome these drawbacks, we suggested a modified Archie's formula, which can handle almost all the RI vs. $S_w$ cross-plots whether the trend is straight or curved and whether it passes through the origin or not. We also demonstrated that how to determine conductivity exponent ${\mu}$, critical water saturation $S_c$, and saturation distribution factor b in the laboratory to use the modified Archie's formula. Since the modified Archie's formula takes into account pore structure, pore water distribution, and wettability of reservoir such as clean sandstone and carbonate rocks, it might improve field applicability.