• 분석과학
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• 제26권6호
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• pp.395-400
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• 2013

얇은 유리판 위에서 자동적으로 정렬되는 인지질 분자의 정렬도에 대한 수분 및 항균성 펩타이드의 효과를 고체 핵자기 공명 분광법을 이용하여 조사하였다. 순수한 1-palmitoyl-2-oleoyl-sn-glycero-3-phosphotidylcholine (POPC) 인지질 만을 유리판 위에서 정렬시킬 때에는 직접적인 물의 투입 없이 95% 상대 습도에서 수일간 수화시키는 것만으로 충분했다. 하지만, protegrin-1 (PG-1)과 같은 항균성 펩타이드가 혼합되어 있는 인지질의 경우에는 95%의 상대 습도에서 수일간 수화시키는 것과 약간의 물을 시료에 직접 투입하여 수화시키는 것이 크게 달라진다는 것을 확인하였다. 충분한 양의 물이 투입되었을 때, 지질 이중막 위에서 인지질 분자들의 표면 움직임이 매우 활발하였다. 순수한 POPC 분자들이 얇은 유리판 위에서 정렬되는 시간에 비해 항균성 펩타이드가 혼합되어 있는 경우에는 POPC 분자들이 평형상을 이루어질 때까지는 상당한 시간이 필요함을 확인하였다.

• 한국도로학회논문집
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• 제11권2호
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• pp.229-238
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• 2009

본 연구에서는 콘크리트지하차도 시공 시 수화열에 의한 열응력 분포 특성을 분석하여 시공 재료와 시공 과정에 따른 균열 발생 여부를 분석하여 설계 시에 균열을 억제할 수 있는 재료 특성과 시공 단계를 제시하는 방법에 대하여 연구하였다. 이러한 분석을 위해 열전달 이론을 도입하여 지하차도의 3차원 유한요소해석 모델을 개발하여 구조해석을 수행하였다. 1회 타설하는 콘크리트 부재의 부피가 지나치게 크면 매스콘크리트가 되기 때문에 수화열에 의한 균열이 발생하기 쉬우며 이러한 균열을 억제할 수 있는 방법으로는 크게 시공 단계를 적절하게 배치하는 것과 또는 이러한 균열을 방지 할 수 있도록 재료 특성을 바꾸어 시공하는 것으로 구분할 수 있다. 따라서 본 연구에서는 이를 위해 콘크리트 재료 성질의 시간에 따른 변화 특성 시멘트 종류 및 첨가제 유무에 따른 수화열 발생 특성, 시공 단계에 따른 구조물의 크기, 외부 환경조건 등을 고려하여 분석을 수행하였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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• pp.379-384
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• 2001

This Paper Presents field application test results of mass concrete using super retarding agent. The field test was carried out at mat foundation(thickness 1m) of newly constructed information center of Chongju university. Placing lift composed of 2 layers, and each layer is 50cm. Fly ash and flowing method is also applied. Difference of setting time of concrete between with super retarding agent and without super retarding agent is considered. Concrete without super retarding agent is placed at upper layer and with super retarding agent at lower layer According to test results, the reducing method of hydration heat considering difference of setting time with super retarding agent can reduce the highest temperature about 3~4$^{\circ}C$, and delay the peak time about 3~4days. Compressive strength using super retarding agent is somewhat higher than that of normal concrete. Accordingly, super retarding agent does not affect the strength development.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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• pp.347-350
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• 2005

The strength level for removal of lining concrete in tunnel is increased from 2.94MPa to 4.9MPa in 2004. This result in the increase of concrete curing time, and construction time would be delayed. In this study, in order to improve the efficiency of construction cycle and satisfy the strength criterion, a curing method is adopted, which is considering the hydration heat in the lining concrete member. As a result, it is shown that the concrete curing time for form removal is about 20hrs without the adjustment of concrete mix design. And construction cycle time is not changed compared to that before the change of strength criterion.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.369-374
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• 2002

In this paper, setting and hydration heat development characteristics with three binder types, type IV cement＋fly ash, type IV cement＋slag powder and type IV cement ＋ limestone powder. were investigate. As results, it was shown that the limestone powder decreased the initial setting time regardless of replacement ratio, especially the range of 20~50% replacement ratio, and the 2nd peak was shifted ahead when the limestone powder replacement ratio increased. But for the f1y ash and the limestone powder, contrary results were obtained compared with the limestone powder.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.789-794
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• 2002

The relationship is investigated between material modeling of concrete and the evaluation procedure of thermal stress by the hydration heat. In this respect, some important points are suggested to which special attention should be paid to reasonably evaluate the thermal stress using the widely-used structural analysis programs. This study indicates that proper material model should be used to draw incremental stress evaluation that takes into account the change of elastic modulus with time. Some correction techniques are also presented when using the program that don't have proper built-in procedure for the calculation of the thermal stress.

• 한국세라믹학회지
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• 제52권1호
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• pp.28-32
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• 2015

In this article, the influence of a hydrolyzed wheat protein retarder on the hydration process, ion concentration in liquid phase, degree of supersaturation, and crystal morphology of plaster was investigated. Furthermore, the retarding mechanism and the strength loss of gypsum were also studied by scanning electron microscopy (SEM). The results indicate that the use of the hydrolyzed wheat protein retarder for plaster achieved a better retarding effect and lower strength loss. The combination of gypsum plaster with the retarder not only decreased the plaster's early hydration rate and prolonged its setting time efficiently, but also militated against the crystal morphology of dihydrate gypsum. For example, the crystal dimensions changed little, but the proportion of needle-shaped crystals decreased. Combination with calcium ions on the surface of dihydrate gypsum crystal nuclei may form a chemisorbed layer, reduce the surface energy of the crystal nuclei, and inhibit the growth of the crystal nuclei of dihydrate gypsum. Consequently, the hydration process of building gypsum becomes greatly extended and is slowed down significantly.

• Architectural research
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• 제20권1호
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• pp.27-34
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• 2018

To improve the chloride ingress resistance of concrete, slag is widely used as a mineral admixture in concrete industry. And currently, most of experimental investigations about non steady state diffusion tests of chloride penetration are started after four weeks standard curing of concrete. For slag blended concrete, during submerged chloride penetration tests periods, binder reaction proceeds continuously, and chloride diffusivity decreases. However, so far the dependence of chloride ingress on curing ages are not detailed considered. To address this disadvantage, this paper shows a numerical procedure to analyze simultaneously binder hydration reactions and chloride ion penetration process. First, using a slag blended cement hydration model, degree of reactions of binders, combined water, and capillary porosity of hardening blended concrete are determined. Second, the dependences of chloride diffusivity on capillary porosity of slag blended concrete are clarified. Third, by considering time dependent chloride diffusivity and surface chloride content, chloride penetration profiles in hardening concrete are calculated. The proposed prediction model is verified through chloride immersion penetration test results of concrete with different water to binder ratios and slag contents.

• 토지주택연구
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• 제3권1호
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• pp.83-88
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• 2012

In this study, physical characteristics of cement and/or concrete materials that are typically used for energy-foundation (EF) structures have been studied. The thermal conductivity and structural integrity of the cement-based materials were examined, which are commonly encountered in backfilling a vertical ground heat exchangers, cast-in-place concrete piles and concrete lining in tunnel. For this purpose the thermal conductivity and unconfined compression strength of cement-based materials with various curing conditions were experimentally estimated and compared. Hydration heat generated from massive concrete in the cast-in-place concrete energy pile was observed for 4 weeks to estimate its dissipation time in the underground. The hydration heat may mask the in-situ thermal response test (TRT) result performed in the cast-in-place concrete energy pile. It is concluded that at least two weeks are needed to dissipate the hydration heat in this case. In addition, a series of numerical analysis was performed to compare the effect of thermal property of the concrete material on the cast-in-place pile.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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• pp.85-88
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• 1999

We tested the limestone powder as a filler powder for the effective use of slag cement. Hydration process were investigated by measuring the thermal differential analysis(DTA), compressive strength, XRD patterns, calorimeter of slag cement-limestone powder paste prepared by mixing limestone powder-slag cement. The results obtained in this study, there were no significant difference between the cases of adding up to 5% limestone powder, but the reaction time was accelerated. Also the compressive strength was increased for adding up to 5% limestone powder. The min hydrated paste products were Ca(OH)2 and calcium silicate hydrates. In the case of mixed limestone powder peak appear tricalcium carboaluminate hydrate in the sample of 7 days hydration.