• Title/Summary/Keyword: hydration property

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Storeability and Cooking Property of Dried Oak Mushroom Treated with Ethylene Oxide and Gamma Radiation (감마선 조사와 훈증 처리된 건조 표고버섯의 저장성 및 조리 적성)

  • 김영재;김종군;조한옥;변명우;권중호
    • Journal of Food Hygiene and Safety
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    • v.2 no.1
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    • pp.29-34
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    • 1987
  • ABSTRACT$.$ Ethylene oxide (E.O) fumigation and gamma irradiation were applied to compar$.$ ative researches on the microbiological, physical and cooking quality of dried oak mushroom stored at $25^{\circ}C$ and different relative humidities. The equivalent moisture contents of dried oak mushroom for the limiting growth of general molds and xerophilic mold at $25^{\circ}C$ were shown to be 17% and 27% respectively. Total aerobic bacteria, molds and coliforms were sterilized at 5 kGy irradiation but E.O. fumigation was proved insufficient to eliminate the molds. The hydration rate of dried oak mushroom increased according to the increase of irradiation dose and soaking temperatures. and an irradiation by 5 kGy could shorten the hydration time of the sample as compared to E.O. treatment and control group. Sensory evaluation for the irradiated cooked sample was not significantly different in flavour but the texture of the gamma irradiated sample was significantly better(p < 0.01) than that of E. O. fumigated sample.sample.

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Hydration and Insulation Characteristics of a Ground Granulated Blast Furnace Slag Based Non-Sintered Cement Using Circulating Fluidized Bed Combustion Ash as a Activator (순환유동층 애시를 자극제로 사용한 고로슬래그 미분말 기반 비소성 시멘트의 수화 및 단열 특성)

  • Lee, Seung-Heun;Lee, Gang-Hyuk;Yoo, Dong-Woo;Ha, Ju-Hyung;Cho, Yun-Gu
    • Journal of the Korea Concrete Institute
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    • v.27 no.3
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    • pp.245-252
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    • 2015
  • As people have more interest in environment-friendly structures recently, many researchers are actively researching non-sintered cement in Korea and other countries. Non-sintered cement shows various characteristics of its reaction products and hardeners, depending on the kind of alkali activators. Thus, this study manufactures ground granulated blast furnace slag based non-sintered cement binder by using circulating fluidized bed combustion ash, which is a kind of industrial byproduct, as a stimulant, and investigated its hardening characteristics and hydration, depending on the rate of circulating fluidized bed combustion ash. Besides, this study investigated its insulation property according to the weight lightening of non-sintered cement. As a result, ettringite and C-S-H were mainly formed in the hydration, and it was possible to manufacture a non-sintered cement hardener over 50 MPa. Lastly, it was possible to manufacture a non-sintered cement hardener in a thermal conductivity level of $0.127W/m{\cdot}K$ when the compressive strength was 10 MPa for weight lightening.

Carbonation Characteristics of Alkali Activated Blast-Furnace Slag Mortar (알칼리활성 고로슬래그 모르타르의 탄산화 특성)

  • Song, Keum-Il;Yang, Keun-Hyeok;Lee, Bang-Yeon;Song, Jin-Kyu
    • Journal of the Korea Concrete Institute
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    • v.24 no.3
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    • pp.315-322
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    • 2012
  • Alkali-activated slag (AAS) is the most obvious alternative materials that can replace OPC. But, AAS industrial usage as a structural material should be evaluated for its durability. Carbonation resistance is one of the most important factors in durability evaluation. Test results for 18 slag-based mortars activated by sodium silicate and 6 OPC mortars were obtained in this study to verify the carbonation property. Main variables considered in the study were flow, compressive strength before and after carbonation, and carbonation depth. Mineralogical and micro-structural analysis of OPC and AAS specimens prior to and after carbonation was conducted using XRD, TGA, FTIR FE-SEM. Test results showed that CHS was major hydration products of AAS and, unlike OPC, no other hydration products were found. After carbonation, CSH of hydration product in AAS turned into an amorphous silica gel, and alumina compounds was not detected. From the analysis of the results, it was estimated that the micro-structures of CSH in AAS easily collapsed during carbonation. Also, the results showed that this collapse of chemical chain of CSH lowered the compressive strength of concrete after carbonation. By increasing the dosage of activators, carbonation resistance and compressive strength were effectively improved.

A Study on the Strength Property of Recycled Fine Aggregate (Wet Type) Mortar with Blast Furnace Slag (고로슬래그를 사용한 습식 순환 잔골재 모르타르의 강도 특성에 관한 연구)

  • Shim, Jong-Woo
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.5
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    • pp.153-160
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    • 2010
  • This study aims to obtain technical data for improvement of utilization of Blast Furnace Slag(BFS), recycled aggregate in the future by complementing fundamental problems of BFS such as manifestation of initial strength and excessive alkali quantity as well as weakness of recycled fine aggregate through manufacturing of recycled fine aggregate mortar using BFS. The recycled aggregate includes the cement paste hardened as the surface and the type of the aggregate, which contains plenty of calcium hydroxide($Ca(OH)_2$) as well as the unhydrated cement. Accordingly, the objectives of this study are to inspect the manufacturing the recycled fine aggregate mortar used with blast furnace slag, to consider the effects of the recycled aggregate on the strength development of ground granulated blast furnace slag, and then to acquire the technical data to take into consideration the further usages of the recycled aggregate and blast furnace slag. In eluted ions from recycled aggregate, it showed that there were natrium($Na^+$) and kalium($K^+$), expected to be flown out of unhydrated cement, as well as calcium hydroxide($Ca(OH)_2$). Application of this water to mix cement mortar with ground granulated blast furnace slag was observed to expedite hydration as calcium hydroxide($Ca(OH)_2$) and unhydrated cement component were expressed to give stimuli effects on ground granulated blast furnace slag. The results of the experiment show that the recycled aggregate mixed with blast furnace slag has comparatively higher hydration activity in 7 day than the mortar not mixed with one in 3 day mortar does, causing the calcium hydroxide in the recycled fine aggregate to work on as a stimulus to the hydration of ground granulated blast furnace slag.

Hydration Property of Electric Arc Furnace Reduction Slag (전기로(電氣爐) 환원(還元) 슬래그의 수화반응(水和反應) 특성(特性) 연구(硏究))

  • An, Yong-Jun;Han, In-Kyu;Choi, Jae-Seok;Bae, Kwang-Hyun;Kim, Hyung-Seok
    • Resources Recycling
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    • v.19 no.6
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    • pp.93-101
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    • 2010
  • In this study, we have studied hydration properties and compressive strength of the electric arc furnace reduction slag as a cement admixture. The reduction slag is mainly consisted of 17.1% of f-CaO and rapid curing clinker minerals, 37.1% of $C_{11}A_7CaF_2$, and 21.0% of $C_3A$. When the substitution rate of the slag on OPC was 30%, the initial setting time and final setting time has been shortened from 305 min. and 425 min. to 10min. and 30min. When the substitution rate of the slag on OPC was 7%, the compressive strength of mixed cement mortars has been increased than that of OPC during all period. When the substitution rate of the slag on OPC was over 20%, the compressive strength of mortars has been reduced than that of OPC at initial and final compressive strength. As a result of hydration properties of reduction slag, $C_{11}A_7CaF_2$ transfer to $C_3AH_6$ but as the substitution rate of slag on OPC increases, increased f-CaO and the metastable hydrates $C_4AH_{13}$ increased. Therefore, we should control the substitution rate of the slag on OPC was under 7% in order to use EAF reduction slag as a cement admixture.

Carbonation Resistance Property of Mortar using Electrolysis Aqueous (전기분해수를 배합수로 활용한 모르타르의 탄산화 저항 특성)

  • Jeong, Su-Mi;Park, Sun-Gyu
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.3
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    • pp.204-210
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    • 2022
  • Cement is pointed out as the main cause of carbon dioxide emission in the construction industry. Many researchs are underway to use blast furnace slag, an industrial by-product, as a substitute for cement to reduce carbon dioxide emitted during the manufacturing the cement. When blast furnace slag is used as a substitute for cement, it has advantages such as long-term strength and chemical resistance improvement. However, blast furnace slag has a problem that makes initial strength low. This is due to the impermeable film on the surface created during the production of blast furnace slag. The created film is known to be destroyed in an alkaline environment, and based on this, previous studies have suggested a solution using various alkali activators. But, alkali activator is dangerous product since it is a strong alkaline material. And it has the disadvantage in price competitiveness. In this study, an experiment was conducted to improve the initial hydration reactivity of the blast furnace slag to secure the initial strength of the mortar substituted with the blast furnace slag and to check whether the carbonation resistance was increased. As a result of the experiment, it was confirmed that the mortar using alkaline water showed higher strength than the mortar using tap water, and there were more hydration products generated inside. In addition, it was confirmed that the mortar using alkaline water as a compounding water had high carbonation resistance.

Self-Healing Property of Hardened Cement Paste (시멘트 페이스트 경화체의 self healing 특성)

  • Kim, Jae Young;Byun, Seung Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.2A
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    • pp.297-304
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    • 2008
  • It is well known that cracks in concrete decrease permeability and durability of concrete because cracks enhance the penetration of water or corrosive chemicals like as chlorides, carbon dioxides, sulfates and some others. But some of cracks in hardened cements may be sealed in case of contacting water. This phenomenon is called "self healing" and it has a close relation to hydration products newly formed on surfaces of cracks. Many studies on self healing in concretes commonly showed that CSH gel has been observed on crack surfaces. And some studies have reported that calcium hydroxides and ettringite were observed as well as CSH gel on crack surfaces. This study was carried out to investigate hydration products formed by self healing process and also examine the influence of waterproof admixture for concretes on self healing of cement. As a result of XRD, DSC, SEM and EDX analysis of crack surfaces, it was found that self healing of cement was related to CSH gel, calcium hydroxides and ettringite. And waterproof admixture increased fibrous (needle-like) hydration products which were in network form. It is estimated that such fibrous products are effective for self healing process of cement system.

Engineering Characteristics Analysis of High Strength Concrete Followed in replacement ratio increase in Blast Furnace Slag (고로슬래그 미분말의 치환율 증가에 따른 고강도 콘크리트의 공학적 특성 분석)

  • Han, Cheon-Goo;Kim, Seoung Hwan;Son, Ho-Jung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.62-68
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    • 2009
  • This research examined engineering properties of high performance concrete, when substitution rate of BS increases. A summary of the test result is as follows. The fluidity of unset concrete increases as the substitution rate of BS increases. The amount of air is reduced more or less, but it seems that enough amount of air can be secured by using more air-entraining agent. Setting time is dramatically delayed as the substitution rate of BS increases. The compressive strength of hardening concrete was weaker than OPC before 28 days passes, due to latent hydraulic property of BS. However, after 28 days, it shows same or better property, which is exceptional for the practical uses of hyper strength concrete. Changes in drying shrinkage rate is quite much, because when hydration happens, the amount of free water in concrete increased as W/B gets larger. The amount of drying shrinkage increases as BS substitution rate increases, but every composition shows less than $-500{\times}10^{-6}$, which is relatively fine.

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A Study on High Strength Concrete of Concrete Filled Steel Tube Column (CFT 기둥용 초고강도 충전콘크리트에 관한 연구)

  • Jung, Keun-Ho;Lim, Nam-Gi;Lee, Young-Do
    • Journal of the Korea Institute of Building Construction
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    • v.4 no.1
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    • pp.127-132
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    • 2004
  • CFT(Concrete Filled Steel Tube) is a structure of circular or squared of steel column filled with concrete. The steel tube holds the concrete inside and that makes this structure to perform superior features on stiffness, proof stress, transformation, fire resistance and construction itself. In this study, by over the 800kgf/$\textrm{cm}^2$ of high strength concrete for CFT column, research has been done on the basic property of matter such as fluidity, resistance on segregation, compressive strength, setting icons of the concrete filled in the steel tube under conditions of standard weather. Physical properties of concrete for CFT that Concrete with silica fume, fly ash of air entraining and high-range water reducing agent, that used to CFT column research purpose to find the most ideal composition, which is achieved by the investigation in the concrete's property of matter like ability of Slump, Slump Flow, Air content, Bleeding, and Settlement. For this study, experiments which are bused on obtained the result through physical test are practiced, with all of the experiment, specimens only for control are produced in each method of curing and analyzed to relations with core strength in mock-up test. In mock-up test, the research is studied compactability of concrete filled in tube and degree of hydration hysteresis, as a basic reference for applying to field of CFT column which is used over 800kgf/$\textrm{cm}^2$ high strength concrete.

The Plastic Cracking Properties of Fly Ash Concrete with Various Curing Conditions (양생조건에 따른 플라이애쉬 콘크리트의 소성수축균열 특성)

  • Nam, Jae-Hyun;Park, Jong-Hwa
    • Journal of the Korea Institute of Building Construction
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    • v.7 no.1 s.23
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    • pp.91-98
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    • 2007
  • In this study, the property and plastic cracking pattern of concrete were compared and analyzed with the replacement ratio of fly ash 0, 5, 10, 15, 20% by cement weight. And curing conditions of concrete were given variously such as indoors(with wind speed as 0, 300, 500m/min), outdoors and chamber. The hydration temperature had a tendency to decrease as the replacement ratio of fly ash increased, and in the case of the wind speed 0m/min, it was showed that the moment that the amount of evaporation of water from surface of reference concrete was more than the volume of bleeding was 90 min since casting concrete. The time that the crack initiated had a tendency to be more quickly as the replacement ratio of fly ash increased. The number, length, width and area of crack in the indoor curing, exposed outdoor curing, enclosed outdoor curing had a tendency to decrease as the replacement ratio of fly ash increased. The crack had a tendency to decrease in sequence of exposed outdoor, enclosed outdoor curing, indoors curing. The outbreak of cracking by the change of temperature and humidity was affected by relative humidity more than temperature and the cracking had a tendency to increase as relative humidity lowered.