• Title/Summary/Keyword: hydration products

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Effects of subsequent curing on chloride resistance and microstructure of steam-cured mortar

  • Hu, Yuquan;Hu, Shaowei;Yang, Bokai;Wang, Siyao
    • Advances in concrete construction
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    • v.9 no.5
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    • pp.449-457
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    • 2020
  • The influence of subsequent curing on the performance of fly ash contained mortar under steam curing was studied. Mortar samples incorporated with different content (0%, 20%, 50% and 70%) of Class F fly ash under five typical subsequent curing conditions, including standard curing (ZS), water curing(ZW) under 25℃, oven-dry curing (ZD) under 60℃, frozen curing (ZF) under -10℃, and nature curing (ZN) exposed to outdoor environment were implemented. The unsteady chloride diffusion coefficient was measured by rapid chloride migration test (RCM) to analyze the influence of subsequent curing condition on the resistance to chloride penetration of fly ash contained mortar under steam curing. The compressive strength was measured to analyze the mechanical properties. Furthermore, the open porosity, mercury intrusion porosimetry (MIP), x-ray diffraction (XRD) and thermogravimetric analysis (TGA) were examined to investigate the pore characteristics and phase composition of mortar. The results indicate that the resistance to chloride ingress and compressive strength of steam-cured mortar decline with the increase of fly ash incorporated, regardless of the subsequent curing condition. Compared to ZS, ZD and ZF lead to poor resistance to chloride penetration, while ZW and ZN show better performance. Interestingly, under different fly ash contents, the declining order of compressive strength remains ZS>ZW>ZN>ZD>ZF. When the fly ash content is blow 50%, the open porosity grows with increase of fly ash, regardless of the curing conditions are diverse. However, if the replacement amount of fly ash exceeds a certain high proportion (70%), the value of open porosity tends to decrease. Moreover, the main phase composition of the mortar hydration products is similar under different curing conditions, but the declining order of the C-S-H gels and ettringite content is ZS>ZD>ZF. The addition of fly ash could increase the amount of harmless pores at early age.

The Effect of Blaine and SO3 Contents of OPC on Shotcrete Binder with Calcium Aluminate Accelerator (OPC의 분말도 및 SO3 함량이 시멘트 광물계 급결제를 사용한 숏크리트 결합재 물성에 미치는 영향)

  • Kang, Bong-Hee;Kim, Gyu-Yong;Choi, Jae-Won;Koo, Kyung-Mo;Hwang, Bong-Choon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.2
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    • pp.78-85
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    • 2020
  • Shotcrete concrete is generally used in the form of ready-mixed concrete products using type I ordinary portland cement(hereinafter referred to as OPC) and about 5% of accelerator mixed separately in the field. In this study, we tested the effect of OPC fineness and SO3 content on a penetration resistance, compressive strength of binder for shotcrete using calcium aluminate type accerlerator. And we analysed hydrates and pore structure effects on mortar performance. In the future, it is expected to be useful for manufacturing optimized OPC as a binder for shotcrete.

The Effect of Addition of Blast-furnace Slag Powder and Limestone powder on Shotcrete Binder with Calcium Aluminate Accelerator (고로슬래그 분말 및 석회석 분말이 시멘트 광물계 급결제를 사용한 숏크리트 결합재 물성에 미치는 영향)

  • Kang, ong-Hee;Kim, Gyu-Yong;Choi, Jae-Won;Koo, Kyung-Mo;Hwang, Bong-Choon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.2
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    • pp.86-93
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    • 2020
  • Shotcrete concrete is generally used in the form of ready-mixed concrete products using type I ordinary portland cement(hereinafter referred to as OPC) and about 5% of accelerator mixed separately in the field. In this study, we tested the effect of addition of slag powder(SP) and limestone powder(LSP) on a penetration resistance, compressive strength of binder for shotcrete using calcium aluminate type accerlerator. And we analysed hydrates and pore structure effects on mortar performance. In the future, it is expected to be useful for manufacturing optimized composite cement as a binder for shotcrete.

A Study on the Mechanical Properties of Polymer Repair-Mortars with CFBC Ash (순환유동층 보일러애시를 활용한 폴리머 보수 모르타르의 역학적 특성에 대한 연구)

  • Kang, Yong Hak;Lim, Gwi Hwan;Shin, Dong Cheol;Choi, Young Cheol
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.5
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    • pp.127-132
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    • 2018
  • The amount of generated Circulating Fluidized Bed Combustion ash (CFBC ash) is annually increasing, but most CFBC ash has been landfilled and discarded due to the limited utilization. The major chemical compositions of CFBC ash are $SiO_2$, CaO and $CaSO_4$, which could form hydration products by reacting with water as self-cementing property such as cement. The purpose of the this study is to derive the optimal mix proportions to improve polymer-modified mortar with the use of CFBC ash which has the self-cementing property. In order to develop polymer-modified mortar, three mix proportions were determined, and fundamental properties for the mixtures were obtained. As a result, the optimal mixture containing 10 percent of silica fume, 1.0 percent of polymer and 3.5 percent of expansive additives were proposed in this study.

Basic Performance Evaluation of Dry Mortar Recycled Basalt Powder Sludge (현무암석분 슬러지를 재활용한 드라이몰탈의 기초적 성능평가)

  • Ko, Dongwoo;Choi, Heebok
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.2
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    • pp.131-138
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    • 2013
  • This study was carried out to investigate the possibility of using basalt powder sludge instead of sand in a normal cement dry mortar as a way to recycle basalt powder sludge, which is a waste product from the manufacturing a process of basalt in Jeju. Basic performance evaluations of the dry mortar material included a compressive strength test, a flexural strength test, and SEM to observe the micro structure. The compressive and flexural strengths were increased to a replacement ratio of 21% of basalt powder sludge, whereby a strength enhancement of about 40% greater than that of normal dry mortar was shown. However, the creation of hydration products affected the replacement ratio of the basalt powder sludge. The possibility of using basalt powder sludge waste was identified in this study, and results showed that the basalt powder sludge waste could be used as a material for a secondary product of concrete.

Affecting Analysis of Air Content on the Freeze-Thaw Durability of Concrete (콘크리트의 동결융해 내구성에 공기량이 미치는 영향 분석)

  • Lee, Beung-Duk;Kim, Hyun-Joong;Kang, Hye-Jin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.565-568
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    • 2008
  • Domestic area of most be happened chloride deicer damage. Because daily mean temperature is below 0$^{\circ}C$ from the area of domestic most. Concrete durability influence Air Content. Presently, We used to AE(air-entraining agent) for increase freeze-thaw durability. So, on concrete Air Spacing ratio used $200{\mu}m{\sim}230{\mu}m$ in Canada and under $250{\mu}m$ in Japan institution. Use of Air content has been and will continue to be a major part of concrete durability and scaling. Chloride-containing chemicals such as calcium chloride or rock salt are main deicers for the road. The prepared optimum mix concrete in this study show that freeze-thaw and scaling resistance of Non-AE(air content 1.5%) and AE (air content 4.5%, 7.2%). Solution concentrations of deicing agent were good result, and the pore system and change of hydration products is not difference comparing before freeze-thaw test.

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An Experimental Study on Strength Development of Micro Grinding Fly-ash Mortar - Effect of Alkali Activator and High Temperature Curing on the Compressive Strength of Concrete - (미분쇄한 플라이애시 모르타르의 강도증진 방안에 관한 연구 - 알칼리 자극제와 고온양생이 강도에 미치는 영향 -)

  • Cho, Hyun-Dae;Jaung, Jae-Dong
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.1
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    • pp.39-47
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    • 2010
  • Fly ash has the advantages, among others, of improving the characteristics of concrete, reducing the price of concrete products, improving the durability, and reducing hydration heat. However, when added in mass, it leads to problems such as insufficient concrete intensity, increase of AE use, and others, resulting in a limitation of the use volume. Therefore, this study is undertaken to solve the problems associated with themass use of fly ash through the high concentration powder ($4000{\sim}8000cm^2/g$) of fly ash, curing method, the addition of an alkali stimulation agent and others for the purpose of increasing the added value of the fly ash. The research showed that the intensity manifestation has an outstanding status, with the hydrates reaching a very stable condition if the rate of addition of a stimulation agent is appropriately used with the heightening of the fineness of the fly ash in the temperature range of $40^{\circ}C$, and if the applicable study is continued, it is likely to result ineffective value generation on the massive replacement of fly ash.

Performance of fly ash stabilized clay reinforced with human hair fiber

  • Rekha, L. Abi;Keerthana, B.;Ameerlal, H.
    • Geomechanics and Engineering
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    • v.10 no.5
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    • pp.677-687
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    • 2016
  • Industrialization and urbanization are the two phenomena that are going relentless all over the world. The consequence of this economic success has been a massive increase in waste on one hand and increasing demand for suitable sites for construction on the other. Owing to the surplus raw materials and energy requirement needed for manufacturing synthetic fibers, applications of waste fibers for reinforcing soils evidenced to offer economic and environmental benefits. The main objective of the proposed work is to explore the possibilities of improving the strength of soil using fly ash waste as an admixture and Human Hair Fiber (HHF) as reinforcement such that they can be used for construction of embankments and land reclamation projects. The effect of fiber content on soil - fly ash mixture was observed through a series of laboratory tests such as compaction tests, CBR and unconfined compression tests. From the stress - strain curves, it was observed that the UCC strength for the optimised soil - flyash mixture reinforced with 0.75% human hair fibers is nearly 2.85 times higher than that of the untreated soil. Further, it has been noticed that there is about 7.73 times increase in CBR for the reinforced soil compared to untreated soil. This drastic increase in strength may be due to the fact that HHF offer more pull-out resistance which makes the fibers act like a bridge to prevent further cracking and thereby it improves the toughness which in turn prevent the brittle failure of soil-flyash specimen. Hence, the test results reveal that the inclusion of randomly distributed HHF in soil significantly improves the engineering properties of soil and can be effectively utilized in pavements. SEM analysis explained the change of microstructures and the formation of hydration products that offered increase in strength and it was found to be in accordance with strength tests.

Microstructure of Non-Sintered Inorganic Binder using Phosphogypsum and Waste Lime as Activator

  • Kim, Ji-Hoon;An, Yang-Jin;Mun, Kyung-Ju;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.3
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    • pp.305-312
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    • 2018
  • This study is about the development of a non-sintered binder (NSB) which does not require a sintering process by using the industrial by-products Phosphogypsum (PG), Waste Lime (WL) and Granulated Blast Furnace Slag (GBFS). In this report, through SEM analysis of the NSB paste hardening body, micropore analysis of paste using the mercury press-in method and microstructure observation were executed to consider the influence of the formation of the pore structure and the distribution of pore volume on strength, and the following conclusions were reached. 1) Pore structure of NSB paste of early age is influenced by hydrate generation amount by GBFS and activator. 2) Through observing the internal microstructure of NSB binder paste, it was found that the strength expression at early age due to hydration reaction was achieved with a large amount of ettringite serving as the frame with C-S-H gel generated at the same time. It was confirmed that C-S-H gel wrapped around ettringite, and as time passed, the amount generated continually increased, and C-S-H gel tightly filled the pores of hardened paste, forming a dense network-type web structure. 3) For NSB-type cement, the degree of formation of gel pores below $10{\mu}m$ had a greater influence on strength improvement than simple pore reduction by charging capillary pores, and the pore size that had the greatest effect on strength was micropores with diameter below $10{\mu}m$.

Effect of diameter of MWCNT reinforcements on the mechanical properties of cement composites

  • Zaheer, Mohd Moonis;Jafri, Mohd Shamsuddin;Sharma, Ravi
    • Advances in concrete construction
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    • v.8 no.3
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    • pp.207-215
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    • 2019
  • Application of nanotechnology can be used to tailor made cementitious composites owing to small dimension and physical behaviour of resulting hydration products. Because of high aspect ratio and extremely high strength, carbon nanotubes (CNTs) are perfect reinforcing materials. Hence, there is a great prospect to use CNTs in developing new generation cementitious materials. In the present paper, a parametric study has been conducted on cementitious composites reinforced by two types of multi walled carbon nanotubes (MWCNTs) designated as Type I CNT (10-20 nm outer dia.) and Type II CNT (30-50 nm outer dia.) with various concentrations ranging from 0.1% to 0.5% by weight of cement. To evaluate important properties such as flexural strength, strain to failure, elastic modulus and modulus of toughness of the CNT admixed specimens at different curing periods, flexural bending tests were performed. Results show that composites with Type II CNTs gave more strength as compared to Type I CNTs. The highest increase in strength (flexural and compressive) is of the order of 22% and 33%, respectively, compared to control samples. Modulus of toughness at 28 days showed highest improvement of 265% for Type II 0.3% CNT composites. It is obvious that an optimum percentage of CNT could exists for composites to achieve suitable reinforcement behaviour and desired strength properties. Based on the parametric study, a tentative optimum CNT concentration (0.3% by weight of cement) has been proposed. Scanning electron microscope image shows perfect crack bridging mechanism; several of the CNTs were shown to act as crack arrestors across fine cracks along with some CNTs breakage.