• Title/Summary/Keyword: hydration characteristics

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Study of Lime Finishing Layer(intonaco) in Koguryo Tomb Murals (고구려 고분벽화의 석회마감층에 관한 연구)

  • Lee, Hwa-Soo;Han, Kyeong-Soon
    • Journal of Conservation Science
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    • v.19
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    • pp.43-56
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    • 2006
  • We checked the conditions and material properties after producing the lime finishing layers with a mortar mix of processed lime. In addition, we reproduced the lime finishing layers of the Koguryo Tomb Murals, colored the layers with a few different techniques and identified the characteristics for each painting technique. As a result of the experiment, we could infer the producing techniques as well as teaming the conditions and properties of the lime finishing layers of the Koguryo tomb murals, and examined the maintenance of the lime finishing layers. Of those samples produced under various conditions, the layers of slaked lime, which were obtained after being hydrated underground for a long time, showed quite a good condition. Thus the slaked lime mixes produced through particular hydration methods are judged to increase the maintenance of the lime finishing layers of the Koguryo Tomb Murals. Mostly, the paints of Koguryo Tomb Murals indicated that they have similar conditions with the samples produced with a secco method. In addition, Considering the compositional forms of the painting layers and the boundary layers which formed between the painting layers and the finishing layers, we can verify that, in some cases, the conditions of the painting layers of the Koguryo tomb murals are similar to those which were produced with a combination of fresco and secco.

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Durability and Strength of Ternary Blended Concrete Using High Early Strength Cement (조강(早彈)시멘트를 사용(使用)한 3성분계(性分系) 콘크리트의 강도(彈度) 및 내구특성(耐久特性))

  • Hong, Chang-Woo;Jeong, Won-Kyong
    • Resources Recycling
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    • v.19 no.5
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    • pp.50-57
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    • 2010
  • Ternary blended concrete(TBC), which contains both fly ash and granulated blast furnace slag, has an initial cost effective and is environment friendly. Furthermore, it has a lot of technical advantages such as the improvement of long term compressive strength, high workability, and the reduction of hydration heat. However, as the use and study on the performance of ternary blended concrete is limited, it is low short term compressive strength. This study was performed to evaluate the characteristics which are a long and short term compressive strengths, permeability and chemical attacks resistance of hardened high early concrete containing slag powder and fly-ash using high early strength cement(HE-TBC). Replacement rate of FA is fixed on 10% and replacement rate of slag powder are 0%, 10%, 20% and 30%. The test results showed that compressive and flexural strength of HE-TBC increased as the slag contents increased from 0% to 30% at the short term of curing. The permeability resistance of HE-TBC(fly ash 10%, blast 30%) was extremely good at the short and long terms. However, high early strength ternary blended concrete had weak on carbonation of chemical attack.

A Study on Analysis Technique for Chloride Penetration in Cracked Concrete under Combined Deterioration (복합열화에 노출된 균열부 콘크리트 내의 염화물 침투 해석 기법에 대한 연구)

  • Kwon, Seung-Jun;Song, Ha-Won;Byun, Keun-Joo
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.359-366
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    • 2007
  • Recently, analysis researches on durability are focused on chloride attack and carbonation due to increased social and engineering significance. Generally, chloride penetration and carbonation occur simultaneously except for in submerged condition and chloride behavior in carbonated concrete is evaluated to be different from that in normal concrete. Furthermore, if unavoidable crack occurs in concrete, it influences not only single attack but also coupled deterioration more severely. This is a study on analysis technique with system dynamics for chloride penetration in concrete structures exposed to coupled chloride attack and carbonation through chloride diffusion, permeation, and carbonation reaction. For the purpose, a modeling for chloride behavior considering diffusion and permeation is performed through previous models for early-aged concrete such as MCHHM (multi component hydration heat model) and MPSFM (micro pore structure formation). Then model for combined deterioration is developed considering changed characteristics such as pore distribution, saturation and dissociation of bound chloride content under carbonation. The developed model is verified through comparison with previous experimental data. Additionally, simulation for combined deterioration in cracked concrete is carried out through utilizing previously developed models for chloride penetration and carbonation in cracked concrete. From the simulated results, CCTZ (chloride-carbonation transition zone) for evaluating combined deterioration is proposed. It is numerically verified that concrete with slag has better resistance to combined deterioration than concrete with OPC in sound and cracked concrete.

Theoretical Analysis of Critical Chloride Content in (Non)Carbonated Concrete Based on Characteristics of Hydration of Cement (시멘트 수화 특성 및 탄산화를 고려한 콘크리트의 임계 염소이온량에 대한 해석 기법)

  • Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.19 no.3
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    • pp.367-375
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    • 2007
  • Critical chloride content for corrosion initiation is a crucial parameter in determining the durability and integrity of reinforced concrete structures, however, the value is still ambiguous. Most of the studies reporting critical threshold chloride content have involved the experimental measurement of the average amount of the total chloride content at arbitrary time. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on critical threshold chloride content. Furthermore, the studies have tried to define the critical chloride content within the scope of their experimental concrete mix proportion at arbitrary time. However, critical chloride content for corrosion initiation is known to be affected by a lot of factors including cement content, type of binder, chloride binding, concentration of hydroxyl ions, and so on. It is necessary to define the unified formulation to express the critical chloride content for various mix proportions of concrete. The purpose of this study is to establish an analytical formulation of the critical chloride content of concrete. In this formulation, affecting factors, such as mix proportion, environment, chemical evolution of pore solution with elapsed time, carbonation of concrete and so on are taken into account. Based on the Gouda's experimental results, critical chloride content is defined as a function of $[Cl^-]$ vs. $[OH^-]$ in pore solution. This is expressed as free chloride content with mass unit to consider time evolution of $[OH^-]$ content in pore solution using the numerical simulation programme of cementitious materials, HYMOSTRUC. The result was compared with other experimental studies and various codes. It is believed that the approach suggested in this study can provide a good solution to determine the reasonable critical chloride content with original source of chloride ions, for example, marine sand at initial time, and sea water penetration later on.

Analysis on Survival and Prognostic Factors for Cancer Patients with Malignancy-associated Hypercalcemia

  • Zhang, Su-Jie;Hu, Yi;Cao, Jing;Qian, Hai-Li;Jiao, Shun-Chang;Liu, Zhe-Feng;Tao, Hai-Tao;Han, Lu
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.11
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    • pp.6715-6719
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    • 2013
  • Objective: To explore the incidence, clinical characteristics, diagnosis and treatment strategies, prognosis of patients with malignancy-associated hypercalcemia (MAH). Methods: The data of 115 patients with MAH who were treated at the Medical Oncology Department of Chinese PLA General Hospital from Jan., 2001 to Dec., 2010 was retrospectively reviewed. Survival analysis was performed using the Kaplan-Meier method and the Cox proportional hazard model with statistic software SPSS 18.0. Results: The patients had blood calcium levels ranging from 2.77 to 4.87 mmol/L. Except for 9 cases who died or were discharged within 5 days after admission, all other patients recovered to normal blood calcium level after treatment with bisphosphonates or intravenous hydration and diuretics; their survival after occurrence of MAH was from 1 day to 4,051 days, and the median survival time was only 50 days. In the log-rank test, the male, renal metastasis, central nervous system symptoms and hypercalcemia occurring over 140 days after cancer diagnosis were predictors of poor survival (P=0.002, P=0.046, P=0.000, P=0.009). In the COX analysis, being male, central nervous system symptoms and hypercalcemia lasting over 140 days after cancer diagnosis were independent prognostic factors for survival time (RR=2.131, P=0.027; RR=3.054, P=0.002; RR=2.403, P=0.001). According to these factors, a score system was established to predict the patient prognosis and adjust the treatment. Conclusion: Cancer patients with MAH have an extremely poor median survival. Some independent factors indicate poor prognosis, including male gender, central nervous system symptoms and hypercalcemia lasting over 140 days after cancer diagnosis. The prognostic score can serve as a reference for MAH prognosis and treatment, worthy of further investigation.

Urinary Stone in Children (소아 요로 결석에 관한 연구)

  • Eun Young-Min;Rho Kwang-Sik;Kim Pyung-Kil;Han Sang-Won
    • Childhood Kidney Diseases
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    • v.1 no.1
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    • pp.60-66
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    • 1997
  • Even though the urinary stones are rare in children, careful observation and monitoring are necessary because the incidence has been increasing. This study is aimed to document the characteristics of urinary stones in children including the symptoms, diagnosis, with or without urinary tract infection, other urinary tract anomaly and treatment. 45 patients under the age of 15 years with urinary stones hospitalized during Jan. 1986 to Jun. 1996 at Severance Hospital were reviewed retrospectively. Patients' mean age was 6.5 years and sex ratio (male : female) was 5.4:1. The most common symptom was gross hematuria. Stones accompanied with urinary tract infection was 46.7%, and stones associated with urinary tract anomaly was 35.6%. Extracorporeal shock wave lithotripsy, percutaneous nephrolithotorny, hydration and diuretics were the treatment modality used. Urinary stone were found to be a significant cause of urinary tract obstruction in children, requiring prompt diagnosis and treatment. Although KUB, IVP, and ultrasonography were commonly used to make the diagnosis, many cases were detected only by ultrasonographic study.

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Analysis of Grounding Resistance and Soil Resistivity Using Mock-up System in Jeju Soil (제주토양 목업시스템을 사용한 접지저항 및 대지저항률 분석)

  • Boo, Chang-Jin;Ko, Bong-Woon;Kim, Jeong-Hyuk;Oh, Seong-Bo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.8
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    • pp.536-543
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    • 2016
  • The installation of grounding systems is important for the safe operation of power systems, and the soil resistivity is an important design consideration for such systems. It varies markedly with the soil type, moisture content and temperature. The Jeju geological structure is formed in a multi-layered structure characteristic of volcanic areas and, and the geological ground resistance values can appear even constructed the same areas ground system different from the soil structure. In this study, a mock-up system using representative soil from Jeju was constructed to analyze the variation of the grounding resistance. The mock-up system was configured using the Gauss-Newton algorithm inversion method to analyze the model numerically using the Wenner method through the soil resistivity measurements used to create the ground model. Also, we analyzed the change in the general ground resistance characteristics of the copper rod, copper pipe, and carbon rod that are used for grounding. The variation of the grounding resistance with the hydration status was found to be $2.9[{\Omega}]$, $16.5[{\Omega}]$ and $20.1[{\Omega}]$ for the copper rod, copper pipes, and carbon rod, respectively, and the influence of the ground moisture resistance of the carbon rod was found to be the lowest with a value of $141[{\Omega}]$.

Experimental Study on Properties of Temperature History Using Heating Sheet and Insulation Form at Low Temperature (발열시트 및 단열재를 사용한 거푸집 내부 콘크리트의 저온환경하 온도이력 특성에 관한 실험적 연구)

  • Choi, Si-Hyun;Lee, Han-Seung;Choi, Hyun-Kuk
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.4
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    • pp.132-139
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    • 2017
  • In this study, in order to prevent the frost damage of the concrete, the characteristics of the form using heating sheet utilizing the chemical reaction of quicklime and the insulation were evaluated through experiments at low temperature. In the case of form at $-10^{\circ}C$, the form with attached heating sheet showed a temperature history of more than $10^{\circ}C$ higher than that of wood form at the early of concreting due to heat of the quicklime in the heating sheet. In the case of the insulated form, the concrete was kept at a high temperature by preserving the hydration heat. When the heating sheet and the isopink(extruded polystyrene) were attached together on the form, the effect was the same as that of the vacuum insulation. The compressive strength of the form with vacuum insulation and form with isopink, heating sheet as measured about 5 MPa at age 3. The experimental in Mongolia, as with the pervious results, the form with the heating sheet and the insulation showed the highest temperature history over $25^{\circ}C$ for 48 hours. Therefore, it was confirmed that the heating sheet and insulation are attached to the form, which helps the concrete strength development at low temperature by heat generation and the insulation effect.

Mineralogical Characteristics of Tachylite occurring in Basic Dike, Basaltic Agglomerate Formation, Ulleung Island and Its Implications of Volcanic Activity (울릉도의 하부층 현무암질 집괴암 층내 염기성 암맥에서 산출되는 타킬라이트의 광물학적 특성과 화산학적 의미)

  • Bae, Su-Gyeong;Choo, Chang-Oh;Jang, Yun-Deuk
    • Journal of the Mineralogical Society of Korea
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    • v.25 no.2
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    • pp.63-76
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    • 2012
  • Tachylite, black basaltic glass formed by the rapid cooling of molten basalt, locally occurs at the Basaltic Agglomerate Formation (BAF), the lowest formation of Ulleung Island. The purposes of this study are to characterize the occurrence and mineralogy of tachylite and to elucidate its formation condition, with emphasis on its fracture pattern, which can serve as implications for the early volcanic activity of Ulleung Island. To this end, we investigated the occurrence pattern of tachylite in the field and carried out mineralogical analyses using optical microscope, XRD, EPMA, and SEM. Tachylite occurs at the chilled margin of basic dikes which are distributed in Naesujeon, Dodong and Jeodong seasides, Turtle Rock, and Yaerimwon, whose widths vary from several cm to 10 cm. It is evident that the outer surface of tachylite is dense and smooth, whereas the inner surface, if fractured, is characterized by conchoidal fracture. The matrix of tachylite consists of amorphous, glass and some fine-grained phenocrysts present in tachylite include biotite, anorthoclase, sanidine, plagioclase, hornblende, and Fe-Ti oxides. The fracture patterns characteristic of tachylite are subrounded, oval, or less commonly polygonal, bounded by joints to form globule or lump. Taking into account texture and mineralogy, tachylite is interpreted to have undergone little subsequent alteration at low temperature via hydration or hydrolysis that could form clay minerals after it was formed. Because tachylite with peculiar fractures occurs as dikes in a close association with BAF, its presence is considered as reliable evidence that when tachylite formed, the most part of BAF was still under subaqueous conditions, or at least saturated with seawater.

Research of Early-age Strength Development Technology for Remove the Steel Form of Large-wide Tunnel Lining Concrete (대단면 터널 라이닝 거푸집의 조기 제거를 위한 초기 강도 발현 기법 연구)

  • Kim, Kwang-Don;Lee, Deuk-Bok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.5
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    • pp.116-127
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    • 2014
  • The studies were carried out to process one cycle for a day to the large section tunnel lining concrete. Climatic characteristics of the tunnel inside are changed, when the temperature of the concrete placement is low, the mold remove time is increased that the heat of hydration speed be delayed because affects the strength development, to compensate for this, after installing the curing sheet on both sides of the steel form and installation of tunnel entrance, when it comes to providing the additional heat source of $28{\pm}2^{\circ}C$ therein, it was to be achieved early strength development control standards (4.5MPa) presented as a crack control scheme or more, thus, It was able to remove after age of 14hr from mold. On the other hand, under the conditions of $10{\pm}1^{\circ}C$ that a natural curing temperature in the tunnel, it was analyzed must ensure the curing time of 36hr or more after concrete placement. Throughout this study, the concrete strength development and the temperature in the early-age concrete, it can find that reverify the curing temperature is greatly affected, even concrete fly ash is mixed 10%, if it is possible to raise the surface temperature for a predetermined time, is not a problem in the early strength development.